safety data sheet trade name: eucalytus citriodora ... · chem/iupac name: eucalyptus citriodora...

SAFETY DATA SHEET TRADE NAME: EUCALYTUS CITRIODORA ESSENTIAL OIL

Version number: 1 Revision number:1 Revision date: 10 /02 /2019 Página 1 de 14

(ACCORDING REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006 and REGULATION (EC) No 1272/2008 of 16 December 2008)

Essoils - Pure & Natural Essential Oils Company, Lda, Estrada da Ponte, Nº 2 2610-141 Amadora. Portugal.

NIF: 514 833 661; Portugal; +351 21 010 3900; [email protected]; www.happyvalley.pt

Section1: Identification of the substance/preparation and of the company/undertaking

1.1. Identification of the substance or preparation EUCALYPTUS CITRIODORA CAS No: 129828-24-61 EINECS No: 603-366-5 INCI name: CORYMBIA CITRIODORA OIL Botanical name: Corymbia citriodora Hook. Synonyms: Eucalytus citriodora, Lemon eucalyptus Chem/IUPAC Name: Eucalyptus Citriodora Oil is the volatile oil obtained from the fresh leaves of Corymbia Citriodora/Eucalyptus Citriodora and other species of Eucalyptus REACH Registration number:

1.2. Use of the substance/preparation We recommend for industrial uses: 1- For cosmetic ingredients:

a- Fragrance Ingredient.2 b- Cleansing products [cleansing lotions, liquids and pads]; c- Bath soaps d- Bath oils, tablets, and salts; e- Shampoos [Noncolouring]. f- Moisturising preparations: Skin Conditioning Agent – Miscellaneous; Skin care preparations,

miscellaneous; Tonic/masking g- Body and Hand preparations [Excluding shaving preparations].

2- For Food additives -> Flavoring Agents3 3- For Agrochemical Category, Herbicide4 4- For Detergents Uses advised against: Other uses than those recommended.

1 https://echa.europa.eu/pt/information-on-chemicals/pre-registered-substances/-/dislist/substance/100.117.447 2 EPA Safer Chemical Functional Use Classes: https://www.epa.gov/saferchoice/safer-ingredients 3 Source: EU Food Improvement Agents: http://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:32012R0872 4 Source: EU Pesticides Database: http://ec.europa.eu/food/plant/pesticides/eu-pesticides-database/public/?event=activesubstance.detail&language=EN&selectedID=1717

mailto:[email protected]

http://www.happyvalley.pt/

https://echa.europa.eu/pt/information-on-chemicals/pre-registered-substances/-/dislist/substance/100.117.447

https://www.epa.gov/saferchoice/safer-ingredients

https://pubchem.ncbi.nlm.nih.gov/source/EU%20Food%20Improvement%20Agents

http://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:32012R0872

https://pubchem.ncbi.nlm.nih.gov/source/EU%20Pesticides%20Database

http://ec.europa.eu/food/plant/pesticides/eu-pesticides-database/public/?event=activesubstance.detail&language=EN&selectedID=1717

http://ec.europa.eu/food/plant/pesticides/eu-pesticides-database/public/?event=activesubstance.detail&language=EN&selectedID=1717






1.3. Company/undertaking identification Full address: Essoils - Pure & Natural Essential Oils Company, Lda, Estrada da Ponte, Nº 2 2610-141 Amadora. Portugal. Telephone number: +351 21 010 3900 E-mail address of the competent person responsible for the Safety Data Sheet: [email protected]

1.4. Emergency telephone for Portugal. Centro de informações anti veneno: +351 808 250 143 Morada: Rua Almirante Barroso, 36. 1000-013 Lisboa www.inem.pt/ciav

Section2: Hazards identification

2.1Classification in accordance with Regulation (EC) No 1272/2008

Hazard Statements/Category Code Prevention Response Storage Disposal

Skin corrosion/irritation, Hazard Category 2;

H315 P264, P280 P302+P352, P321 P332+P313, P362

Sensitisation — Skin, Hazard Category 1;

H317 P261, P272 P280

P302+P352, P333+P313, P321, P363

P501

Causes serious eye damage H318 P280 P305+P351+P338, P310

Hazardous to the aquatic environment — long-term hazard, category chronic 2

H411 P273 P391 P501

1.5. Label elements

CAS No: 129828-24-6 EC Number: 223748-96-7 Eucalyptus citriodora oil









Pictograms: Skin corrosion/irritation, Hazard Category 2; H315 Serious eye damage/eye irritation, Hazard Category 2A; H319 Sensitisation — Skin, Hazard Category 1; H317 May cause respiratory irritation, H335

Hazardous to the aquatic environment — long-term hazard, category chronic 2; H411.

May be fatal if swallowed and enters airways: H304 May cause allergy or asthma symptoms or breathing difficulties if inhaled, H334 May cause cancer, H350

Signal word: WARNING Hazard Statements: H315: Causes skin irritation. H317: May cause an allergic skin reaction. H304: May be fatal if swallowed and enters airways H334: May be cause allergy or asthma symptoms or breathing difficulties if inhaled H335: May be cause respiratory irritation H411: Hazardous to the aquatic environment for long-term Precautionary Statements: P261: Avoid breathing dust/fume/gas/mist/vapours/spray P264: Wash your hands thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/eye protection/face protection. P285: In case of inadequate ventilation wear respiratory protection. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331: Do NOT induce vomiting. Response: P311: Call a POISON CENTER or doctor P312: Call a POISON CENTER or doctor/... if you feel unwell P321: Specific treatment (see ... on this label P362: Take off contaminated clothing P363: Wash contaminated clothing before reuse P391: Collect spillage P342: If experiencing respiratory symptoms P304+P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P332+P313: IF SKIN irritation occurs: Get medical advice/attention P302+P352: IF ON SKIN: wash with plenty of water








Storage Precautionary Statements P405: Store locked up P403+P233: Store in a well-ventilated place. Keep container tightly closed. Disposal Precautionary Statements P501: Do not dispose of contents/container to sewer.

1.6. Other hazards: Not available








3. Section3: Composition/information on ingredients;

3.1. Substances

Concentration range of the constituent (% weight/weight)

CE Number / Registration Number

CAS Chemical name

100% 129828-24-6 Eucalyptus citriodora oil

3.2. The chemical identity of any impurity, stabilising additive, or individual constituent other

than the main constituent (Only hazard codes with percentage values above 10% are shown).

CONCENTRATION

(%) CAS EC

NUMBER CHEMICAL NAME

IUPAC NAME HAZARD CLASS AND

CATEGORY CODE; HAZARD

STATEMENT CODES

PICTOGRAM

60-70 470-82-6 207-431-55

OXIDE: 1,8- cineol

(Eucalyptol)

4,7,7-trimethyl-8-oxabicyclo[2.2.2]-

octane

H226: Flammable liquid and vapor H315: Causes skin irritation H317: May cause an allergic skin reaction H319: Causes serious eye irritation H41: Toxic to aquatic life with long lasting effects H304: May be fatal if swallowed and enters airways

GHS02 GHS05 GHS07 GHS09

15-25 80-56-8 MONOTERPENE

alpha Pinene

Pin-2(3)-ene

Flam. Liq. 3;H226- Skin Irrit. 2;H315- Skin Sens. 1B;H317- Asp. Tox. 1;H304- Aquatic Acute 1;H400- Aquatic Chronic 1;H410

GHS02 GHS07 GHS09 GHS08

Dgr

Dgr

4. Section 4: First aid measures

4.1.Description of first aid measures

Consumption If swallowed, rinse mouth with water. Seek medical advice immediately and show this container or label. Do NOT induce vomiting.

5 Source: European Chemicals Agency (ECHA): URL: https://echa.europa.eu/substance-information/-/substanceinfo/100.006.757



https://pubchem.ncbi.nlm.nih.gov/source/European%20Chemicals%20Agency%20(ECHA)

https://echa.europa.eu/substance-information/-/substanceinfo/100.006.757

https://www.google.pt/url?sa=i&rct=j&q=&esrc=s&source=images&cd=&cad=rja&uact=8&ved=2ahUKEwiEuJOPs4bfAhWv34UKHVl0A1AQjRx6BAgBEAU&url=https://de.wikipedia.org/wiki/Datei:(-)-a-Pinen.svg&psig=AOvVaw3e_ZfSgufenh0j-osLylyP&ust=1544020550261402






Eye contact First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.

Inhalation Remove person to fresh air and keep at rest

Skin contact Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.

4.2 Most important symptoms and effects, both acute and delayed: There are three common signs of eucalyptus poisoning: CNS depression, abnormal respiration and pinpoint pupils. Also likely are epigastric pain, vomiting, weakness in the legs, cold sweats and headache. Cardiovascular colapse is a feature of severe intoxication, and convulsions are notable for their rarity. There is frequently vertigo and lack of coordination, but there are indications of mind poisoning, unless they are rapidly superseded by stupor. Death há occured from 15 minutes to 15 hours following ingestion, and some cases survive even the most severe stage of intoxication (Gurr&Scroggie 1965). Respiratory effects are avaible, with either shallow, or labored breathing (Craing 1953). There may be great individual variation in sensibility to eucalytus poisoning. 1,8- cineol can cause serious poisoning in young children when accidentally instilled into the nose (Melis et al 1989). 6

4.3 Indication of any immediate medical attention and special treatment needed Go to the hospital.

5. Section 5: Fire-fighting measures;

5.1 Extinguishing media:

Recommended: Foam or dry powder. For safety reasons do not use full water jet.

5.2 Special hazards arising from the substance or mixture:

Not applicable.

5.3 Advice for firefighters:

Closed containers may build up pressure at elevated temperatures. Avoid inhalation of fumes or vapours. Use appropriate respiratory protection. Prevent run-off from fire fighting to enter drains or water courses.

6 Robert Tisserand/Rodney Young; Essential oil safety; Churchill Livingstone, 2014, p. 274








6. Section 6: Accidental release measures;

6.1 Personal precautions, protective equipment and emergency procedures: Do NOT smoke and do NOT expose the product to an open flame or to any other potential source of ignition. Wear appropriate gloves to prevent skin exposure. Avoid contact with skin and inhalation of its vapours or smoke. Maintain adequate ventilation in the working area after spilling.

6.2 Environmental precautions: Avoid contaminating the environment via the sewers or water sources.

6.3 Methods and material for containment and cleaning up: Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations.

6.4 Reference to other sections:

See also sections 8 and 13.

7. Section 7: Handling and storage;

7.1 Precautions for safe handling: Keep away from food, drink and animal feedingstuffs. Do not smoke. Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

7.2 Conditions for safe storage, including any incompatibilities: Keep the product in its original container well sealed,in a dry and ventilated area,away from potential sources of ignition and protected from light. Keep the container at 25ºC. Products containing eucalyptus oil should be stored at a temperature not exceeding 25°C in well filled containers. Protect from light (Reynolds, 1982). Liquid products containing eucalyptus oil are best stored in child resistant containers. Store in accordance with local/national regulations and follow the warnings on the label.

7.3 Specific end use(s): Not available.








8. Section 8: Exposure controls/personal protection;

8.1 Occupational Exposure Limits:

Not available

8.2 Exposure controls

Personal protection equipment

Appropriate personal protective equipment shall be worn in accordance with Regulation (EU) 2016/425

Engineering Controls-Ventilation

The areas where the product is handled and stored should be adequately ventilated.

Respiratory Protection:

Use personal breathing apparatus whenever deemed necessary.

Skin Protection:

Avoid contact with skin. Compatible chemical-resistant gloves are recommended. Rinse and remove gloves immediately after use. Wash hands with soap and water thoroughly after handling. Material oh the gloves: NBR with >0,11 mm. Make recovery periods for skin regeneration without gloves. Preventive protection for the hands is recommended by applications of the protective creams.

Eye/Face protection:

Chemical safety goggles are recommended. Wash contaminated goggles before reuse

9. Section 9: Physical and chemical properties;

9.1 Appearance: LIQUID

9.2 Odour: Intense lemon odor7

9.3 Specific Gravity 0.585 – 0.870 (20 °C)

9.4 Refractive Index: 1.448 – 1.478 (20 °C)

9.5 Optical Rotation: 0-100

9.6 pH: Not available

9.7 Solubility: 5g/100cm3 etanol 90º

7 Lewis, R.J. Sr. (ed) Sax's Dangerous Properties of Industrial Materials. 12th Edition. Wiley-Interscience, Wiley & Sons, Inc. Hoboken, NJ. 2012., p. V2: 1165








9.8 Solubility in Water Not available

9.9 Flash Point: 74ºC

9.10 Flammability Limits [as % v/v in Air] Not available

Lower Explosion Limit: Not available

Upper Explosion Limit: Not available

9.11 Autoignition Temperature: Not available

9.12 Melting Point: Not available

9.13 Boiling Point: Not available

9.14 Vapour Pressure: Not available

9.15 Vapour Density: Not available

SHELF LIFE: When stored within advised conditions, re-test after 12 months then at 3 monthly intervals up to a maximum life of 36 months.

10. Section 10: Stability and reactivity;

10.1. Reactivity: Risk of ignition. On heating: Vapors may form explosive mixtures with air.

10.2. Chemical stability: Stable under normal operating conditions.

10.3. Possibility of hazardous reactions: Hazardous Polymerization: It does not undergo any dangerous reactions under normal conditions.

10.4. Conditions to avoid: Heat, flames and other sources of ignition. No special precautions other than good housekeeping of chemicals.

10.5 Incompatible materials: Oxidizing mineral acids, strong reducing agents, strong oxidizing agents.

10.6 Hazardous decomposition products: Carbon monoxide and other unidentified organic compounds may be formed upon combustion.








11.Section 11 - Toxicological information;

Acute toxicity:8 Oral: LD50 in rats > 5g/Kg Dermal: LD50 in rabbits 2.48g/Kg

Skin Corrosion / Irritation:

This substance meets the criteria for classification in accordance with Regulation (EC) No 1272/2008.

Adverse skin reactions Undiluted lemon eucalyptus oilwas irritating to rabbits, producing scab formation and sloughing9; Tested at 10% on 25 volunteers it was neither irritating nor sensitizing. It is non-phototoxic. 10 When injected, inhibited inflammaion induced in rat paw 11

Serious eye damage/irritation:

This substance does not meet the criteria for classification in accordance with Regulation (EC) No 1272/2008

Respiratory or skin sensitisation:

This substance meets the criteria for classification in accordance with Regulation (EC) No 1272/2008.

Germ cell mutagenicity: No mutagenic activity was found for citronellal in the Ames test12. It shows antimutagenic activity through concentration-dependent, competitive inhibition of PROD, with na IC50 of 1.56µM13. In one report, citronellal was weakly genotoxic in Chinese hamster cell14

Endocrine toxicity This substance does not meet the criteria for classification in accordance with Regulation (EC) No 1272/2008.

Carcinogenicity: No information was found, but it contains no known carcinogens. Reproductive toxicity: No information was found, but it contains no known carcinogens. STOT-single exposure: This substance does not meet the criteria for classification in accordance with

Regulation (EC) No 1272/2008.

STOT-repeated exposure: This substance does not meet the criteria for classification in accordance with Regulation (EC) No 1272/2008.

Aspiration toxicity: This substance meets the criteria for classification in accordance with Regulation (EC) No 1272/2008.

Citronellal presente a minimal acute toxicity.

8 Ford et al 1988a p.323 9 Robert Tisserand/Rodney Young; Essential oil safety; Churchill Livingstone, 2014, p.335-336 10 (Ford et al 1988ª p. 323) 11 Silva et al 2003. 12 Kasamaki et al 1982; gomes-Carneiro et al 1998 13 De-Oliveira et al 1997a 14 Kasamaki et al 1982








12. Section 12: Ecological information;

Keep away from sewers, surface and ground water.

12.1 Acute aquatic toxicity: May cause long-term adverse effects in the aquatic environment.

12.2 Persistence and degradability: Not available.

12.3 Bioconcentration Factor: Not determined

12.4 Mobility in soil: Not available.

12.5 Results of PBT and vPvB assessment: Not determined

12.6 Other adverse effects: Not available.

13. Section 13: Disposal considerations;

Waste treatment methods

Container disposal Containers must be disposed of as hazardous waste. Do not reuse empty containers. Dilute the remaining material and neutralise. Empty residue into a suitable disposal site. Do not empty into drains. Avoid release to the environment for specific instructions /Safety Data Sheets.

Disposal conditions Dispose of in accordance with all state and local environmental regulations. This material and its container must be disposed of in a safe way.








14. Section 14: Transport information;

International Carriage of Dangerous Goods by Road (ADR)

UN No.: UN3082

Proper Shipping Name: EXTRACTS, AROMATIC, LIQUID

Packing Group: III (flammable liquids)

Class: 9

Tunnel restriction code: E

Label:

Sea Transport (IMDG)

UN No.: UN3082


Packing Group: III

Class: 9

Marine Pollutant: yes

Label:

Air Transport (ICAO/IATA)

UN No.: UN3082


Packing Group: III

Class: 9

Label:

UE No Standart Packing: carry in metal packing with 10L net weight or carry in glass packing with 2.5L net weight. UE Standart Packing: carry in metal packing with 60L net weight or carry in glass packing with 2.5L net weight. (singles and combination packages are allowed)








15. Section 15 - Regulatory information;

15.1 Safety, health and environmental regulations/legislation specific for the substance or

mixture:

Not available

15.2 Chemical safety assessment: Not available.

16. Section 16 - Other information

16.1. Text of hazard statement codes in section 3 (impurities, stabilising additives,

constituents):

H315: Causes skin irritation. H317: May cause an allergic skin reaction. H304: May be fatal if swallowed and enters airways H334: May be cause allergy or asthma symptoms or breathing difficulties if inhaled

H335: May be cause respiratory irritation H411: Hazardous to the aquatic environment for long-term This material should only be used for industrial purposes.

16.2. Recomendations: To keep out of reach of children and to not take internally.








Key literature references and sources for data: 1. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008

on classification, labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

2. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006

concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH),

establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council

Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive

76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.

3. ECHA INFORMATION: https://echa.europa.eu/pt/substance-information/-

/substanceinfo/100.028.848

4. Regulation (EC) No 2015/830 1907/2006 of the European Parliament and of the Council of 25 May

2015 on classification, labelling and packaging of substances and mixtures, amending and repealing.

Declaration: Information in this SDS is from available published sources and is believed to be accurate. No warranty,

express or implied, is made and our company assumes no liability resulting from the use of this SDS. This

information is offered in good faith.Each user of this material needs to evaluate the conditions of use

and design the appropriate protective mechanisms to prevent employee exposures, property damage

or release to the environment and must determine suitability of this information for his application.

END OF THE SAFETY DATA SHEET



https://echa.europa.eu/pt/substance-information/-/substanceinfo/100.028.848

https://echa.europa.eu/pt/substance-information/-/substanceinfo/100.028.848

safety data sheet trade name: eucalytus citriodora ... · chem/iupac name: eucalyptus citriodora...

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