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Page 1: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Some topics about Nematic and Smectic-ALiquid Crystals

Chillan, enero de 2010

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 1/25

Page 2: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 2/25

Page 3: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 2/25

Page 4: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 2/25

Page 5: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 2/25

Page 6: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 2/25

Page 7: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 3/25

Page 8: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

http://moebius.physik.tu-berlin.de/lc/lcs.html

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 4/25

Page 9: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

http://www.doitpoms.ac.uk/

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 5/25

Page 10: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

Natural examples:Soap, soupBiological membranesThe protein solution to generate silk of a spiderDNA and polypeptides can form LC phases

Applications:Liquid Crystal Displays: wrist watches, pocket calculators,flat screens ...Liquid Crystal Thermometers: to show a map oftemperatures to find tumors, bad connections on a circuitboard ...Windows that can be changed from clear and opaque withthe flip of a switch.To make a stable hydrocarbon foam.Optical Imaging and recording.

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 6/25

Page 11: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

Natural examples:Soap, soupBiological membranesThe protein solution to generate silk of a spiderDNA and polypeptides can form LC phases

Applications:Liquid Crystal Displays: wrist watches, pocket calculators,flat screens ...Liquid Crystal Thermometers: to show a map oftemperatures to find tumors, bad connections on a circuitboard ...Windows that can be changed from clear and opaque withthe flip of a switch.To make a stable hydrocarbon foam.Optical Imaging and recording.

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 6/25

Page 12: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

http://atom.physics.calpoly.edu

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 7/25

Page 13: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Introduction

http://en.wikipedia.org/

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 8/25

Page 14: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 9/25

Page 15: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

d : Orientation of liquid crystal molecules (unit vector).n : Single optical axis perpendicular to the layer.

|d| = 1 −→ f Ginzburg-Landau penalization function

f(d) =1ε2 (|d|2 − 1)d

∇× n = 0 −→ n = ∇ϕ

ϕ : Layer variable

d = n −→ |∇ϕ| = 1

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 10/25

Page 16: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

Penalized Oseen–Frank energy:

(NC) Ee =

∫Ω

(12|∇d|2 + F (ϕ)) (SAC) Ee =

∫Ω

(12|∆ϕ|2 + F (∇ϕ))

where f(n) = ∇nF (n).

F (n) =1

4ε2 (|n|2− 1)2 potential function of f(n) =1ε2 (|n|2− 1)n.

Minimization problem −→ Euler-Lagrange equation

(NC) ω ≡ ∆d− f(d) = 0, (SAC) ω ≡ ∆2ϕ−∇ · f(∇ϕ) = 0,

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 11/25

Page 17: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

Penalized Oseen–Frank energy:

(NC) Ee =

∫Ω

(12|∇d|2 + F (ϕ)) (SAC) Ee =

∫Ω

(12|∆ϕ|2 + F (∇ϕ))

where f(n) = ∇nF (n).

F (n) =1

4ε2 (|n|2− 1)2 potential function of f(n) =1ε2 (|n|2− 1)n.

Minimization problem −→ Euler-Lagrange equation

(NC) ω ≡ ∆d− f(d) = 0, (SAC) ω ≡ ∆2ϕ−∇ · f(∇ϕ) = 0,

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 11/25

Page 18: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

Ω ⊂ IRN (N = 2 or 3), ∂Ω regular, Q = Ω× (0,+∞)

( Ericksen-Leslie, Lin, E)

Angular momentum

(NC) ∂td + u · ∇d + γω = 0 (SAC) ∂tϕ+ u · ∇ϕ+ γω = 0

Linear momentum

ρ(∂tu + (u · ∇)u)−∇ · (σd + λσe) +∇p = 0, ∇ · u = 0

where

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 12/25

Page 19: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

Ω ⊂ IRN (N = 2 or 3), ∂Ω regular, Q = Ω× (0,+∞)

( Ericksen-Leslie, Lin, E)

Angular momentum

(NC) ∂td + u · ∇d + γω = 0 (SAC) ∂tϕ+ u · ∇ϕ+ γω = 0

Linear momentum

ρ(∂tu + (u · ∇)u)−∇ · (σd + λσe) +∇p = 0, ∇ · u = 0

where

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 12/25

Page 20: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

The models

(NC)σd = µ4D(u),

σe = λ∇ · (∇d∇d)

(SAC)

σd = µ1(ntD(u)n)n⊗ n + µ4D(u) + µ5(D(u)n⊗ n + n⊗ D(u)n),

σe = −f(n)⊗ n +∇(∇ · n)⊗ n− (∇ · n)∇n

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 13/25

Page 21: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 14/25

Page 22: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Nematic Model

The equations∂tu + (u · ∇)u− ν∆u +∇p = −∇dt ∆d,

∇ · u = 0,

∂td + (u · ∇)d = (∆d− f (d)), |d| ≤ 1,

in Q

+ time-dependent (bc) on Σ = (0,∞)× ∂Ω.+ (iv) or (tp) in Ω.

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 15/25

Page 23: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Smectic Model

The equations

∂tu + (u · ∇)u− ν∆u−∇ · σdnl

−(∆2ϕ−∇ · f(∇ϕ))∇ϕ+∇q = 0,

∇ · u = 0,

∂tϕ+ u · ∇ϕ+ (∆2ϕ−∇ · f(∇ϕ)) = 0,

in Qwhere σd

nl := (ntD(u)n)n⊗ n + D(u)n⊗ n + n⊗ D(u)n

+ time-dependent (bc) on Σ = (0,∞)× ∂Ω.+ (iv) or (tp) in Ω.

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 16/25

Page 24: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Lifting functions

Boundary condition depending on the time

(NC) d = d(t)

stationary (for weak norms) or non-stationary (for regularnorms) lifting function

d(t) = d(t)− d(t), d = 0 on ∂Ω

Unknows: u,p, d

(SAC) ϕ = ϕ(t)

non stationary lifting function

ϕ(t) = ϕ(t)− ϕ(t), ϕ = 0 on ∂Ω

Unknows: u,p, ϕ

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 17/25

Page 25: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 18/25

Page 26: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Nematic Case

Weak solution:

u ∈ L∞(0,+∞; L2) ∩ L2w (0,+∞; H1),

d ∈ L∞(0,+∞; H1) ∩ L2w (0,+∞; H2)

Regular solution:

u ∈ L∞(0,+∞; H1) ∩ L2w (0,+∞; H2),

d ∈ L∞(0,+∞; H2) ∩ L2w (0,+∞; H3)

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 19/25

Page 27: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Nematic Case

Asymptotic Stability:

E(t) =12|u(t)|2 + Ee(t)→ E∞,

u(t)→ 0 in H10(Ω), ω(t) = (∆ϕ− f (ϕ))(t)→ 0 in L2(Ω)

when t ↑ +∞, where E∞ = Ee,d =12|∇d|2 +

∫Ω

F (d) and d is a

critical point of Ee. Moreover, d→ d ”for subsequences” inH2(Ω)-weak.

Stability:

If initial data are small, |u|, |ω|, and E(t) are small for each t ≥ 0

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 20/25

Page 28: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Nematic Case

Previous result: (iv)-problem, boundary condition independentof time. Existence of a weak global solution. Existence anduniqueness of a regular solution for larger viscosity. [Lin,Liu’95]

Goal Time-dependent (bc) case[Climent,Guillen,Rojas’06](tp)-problem. Existence of a weak periodic solution.Regularity N = 2[Climent,Guillen,Moreno’08](iv)-problem. Existence of a weak global solution.Existence of a global strong solution, ν big enough.Uniqueness of strong/weak solutions.(tp)-problem. Existence of a regular solution, ν big enough.[Climent,Guillen,Rodrıguez] Stability and asymptoticstability (tp)-problem, time-independent (bc) case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 21/25

Page 29: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Nematic Case

Previous result: (iv)-problem, boundary condition independentof time. Existence of a weak global solution. Existence anduniqueness of a regular solution for larger viscosity. [Lin,Liu’95]

Goal Time-dependent (bc) case[Climent,Guillen,Rojas’06](tp)-problem. Existence of a weak periodic solution.Regularity N = 2[Climent,Guillen,Moreno’08](iv)-problem. Existence of a weak global solution.Existence of a global strong solution, ν big enough.Uniqueness of strong/weak solutions.(tp)-problem. Existence of a regular solution, ν big enough.[Climent,Guillen,Rodrıguez] Stability and asymptoticstability (tp)-problem, time-independent (bc) case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 21/25

Page 30: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Table of contents

1 Introduction

2 The Models

3 Statement of the Problems

4 Nematic Case

5 Smectic-A Case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 22/25

Page 31: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Smectic-A Case

Weak solution:

u ∈ L∞(0,+∞; H1) ∩ L2w (0,+∞; H2),

ϕ ∈ L∞(0,+∞; H4) ∩ L2w (0,+∞; H6)

Regular solution:

u ∈ L∞(0,+∞; H1) ∩ L2w (0,+∞; H2),

ϕ ∈ L∞(0,+∞; H2) ∩ L2w (0,+∞; H3)

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 23/25

Page 32: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Smectic-A Case

Asymptotic Stability:

u(t)→ 0 in H10(Ω) (∆2ϕ−∇ · f (∇ϕ))(t)→ 0 in L2(Ω)

when t ↑ +∞. Moreover, ϕ→ ϕ for ”sequences” inH4(Ω)-weak, where ϕ is a solution of a Euler-Lagrangeproblem.

Stability:If initial data are small, u, ϕ, and ω are small for each t ≥ 0

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 24/25

Page 33: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Smectic-A Case

Previous result: (iv)-Problem, time-independent boundaryconditions. Existence of weak solutions in [0,T ], globalregularity of weak solutions (for big enough viscosity). [Liu’00]

Goal Time-dependent (bc) case [Climent,Guillen]1 Uniqueness weak/strong solutions (iv)-Problem,2 Existence of global weak solutions (iv)-Problem, “bounded”

up to infinity time,3 Existence of weak time-periodic solutions,4 Existence of regular solutions for both previous cases

(dominant viscosity coefficient).5 Stability and asymptotic stability Time-independent (bc)

case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 25/25

Page 34: Some topics about Nematic and Smectic-A Liquid Crystalspersonal.us.es/bcliment/images/comunicaciones/10Chillan.pdf · Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010

Smectic-A Case

Previous result: (iv)-Problem, time-independent boundaryconditions. Existence of weak solutions in [0,T ], globalregularity of weak solutions (for big enough viscosity). [Liu’00]

Goal Time-dependent (bc) case [Climent,Guillen]1 Uniqueness weak/strong solutions (iv)-Problem,2 Existence of global weak solutions (iv)-Problem, “bounded”

up to infinity time,3 Existence of weak time-periodic solutions,4 Existence of regular solutions for both previous cases

(dominant viscosity coefficient).5 Stability and asymptotic stability Time-independent (bc)

case

Blanca Climent Ezquerra. Universidad de Sevilla. III WIMA 2010. Nematics and Smectic-A Liquid Crystals 25/25