the use of sea water in well c

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    THE SPE IMAGE LIBRARY SPE 5030

    The Use of Sea Water in Well Cementing

    5030

    Smith, R.C., SPE-AIME,

    Amoco Production Co.Calvert, D.G., SPE-AIME,

    Dowell

    June 1975

    The performance of cement slurries using sea water can be predictable

    to a safe degree. Using sea water reduces placement time, increases

    early strength development, and shortens waiting-on-cement time.

    The effects of sea water on accelerators, retarders, fluid loss, and

    dispersant additives are discussed.

    Introduction

    This study shows that if sea water is used in place of fresh

    water for mix water in cementing systems, the setting rate

    of cement is accelerated. This affects cement thickening

    time, early strength development, and waiting-on-cement time.

    Using sea water also affects the prehydration of bentonite

    and the activity of accelerators, retarders, fluid loss, and

    dispersant additives. Also, improved bonding characteristics

    are indicated.

    Uncontaminated waters from seven oceans under current

    drilling activity are analyzed and are shown to be very

    similar in composition. For preliminary laboratory testing

    with cements, the composition of sea water can be approximated

    by the ASTM standard sea water. Also, a complete analysis of

    a specific sea water can be obtained by measuring only the

    chloride content. The other major constituents can be

    calculated from this chloride ion. Other investigators have

    found that, for most practical purposes, the ratios of all

    major components of sea water to chlorides are constant.

    Cement slurries for well completions generally perform

    best when mixed with fresh water. It is generally believedthat if the water is potable, it is satisfactory for cements.

    This practice is followed generally on land operations, where

    practical and economical, and has been the practice in

    several offshore areas. However, with increased offshore

    drilling activities, the use of sea water for mixing cement

    slurries for down-hole cementing applications has increased

    significantly. Sea water is being used as the mix water for

    casing, liner, and squeeze cementing operations. Also,

    because of the large loads placed on offshore platforms,

    it is now the practice in many cases to grout the piles to

    the jacket structures for effective load transfer. Some of

    these grouts are mixed with sea water. The reasons for this

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    THE SPE IMAGE LIBRARY SPE 5030

    increased application of sea water become readily apparent

    when the advantages of sea-water cementing are examined. The

    advantages include (1) ready availability, (2) lower costs

    because transportation is eliminated, and (3) reduced

    fresh-water storage on offshore platforms.

    Perhaps the most significant effect on cement

    performance is caused by the presence of sodium chloride in

    sea water. The effect of sodium chloride on physicalproperties of oilwell cements has been discussed by Ludwig

    and by Slagle and Smith. These are both excellent

    presentations on the effect of sodium chloride, but generally

    only limited data on sea water were included, or the

    concentration of the salt studied was considerably higher

    than salt concentration in sea waters. Therefore, a better

    definition of the effects of sodium chloride and other salts

    in sea water on the various physical properties of cement

    in the slurry state and the set state was required.

    Sea-Water Composition

    The concentration of dissolved materials in ocean water

    varies with location and with seasons of the year. Sea

    water is diluted by rivers, rain, or melting ice, or is

    concentrated by evaporation. Sea water also contains all

    types of suspended material, such as colloidal and larger

    particulate minerals, insoluble organic compounds, and

    living creatures.

    JPT

    P. 759

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