thermo chemical conversion processes/file/ongoing research... · process optimization research...
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Ongoing research/competence areas
Thermo Chemical Conversion Processes
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Research structure
Experimental & Numerical Methods
Optimizing design and operation of
thermochemical processes
Ash Transformation & Reactions
Fuel Conversion Reacting Multi- Phase Flow
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Research cycle
Pilot-scale experiments CFD simulation
Fundamental experiments
Fundamental modelling
Process optimization
Research needs
Supply of data
Sub-model delivery
Understanding mechanism
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Process integration
System optimization
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Fuel conversion Research field: Conversion of solid fuels during thermochemical conversion processes. Transport phenomena inside fuel particles, and product distribution and characterization (oil, tar, soot, and char).
Research aims: To understand and predict fuel conversion kinetics, to avoid problems related to unconverted fuels, to maximize the desired product yields and properties dependent on the technical applications, and to develop high-fidelity sub-models for CFD simulation.
Powder flame Snapshot
Raw biomass After pyrolysis
Volatile flame
Char combustion
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Ash Transformation and Reactions/Emissions
00.20.40.60.8
11.21.41.6
Stem-wood
Bark Twigs Needles Shoots Contam. (3% )
wt %
of e
lem
ent (
D.S
)
KNaCaMgSiSClP
Ash forming elements in Norwegian spruce: Werkelin J, Thesis, 2008, Åbo Akademi University
Research field: Studies of the behaviour of ash forming elements/ash forming matter in thermochemical conversion processes (e.g. ash- and particle formation/-emissions, bed agglomeration, fouling).
Research aims: To understand, predict and avoid ash related problems in thermochemical conversion processes as well as suggest processes for production of more useful ashes (e.g. nutrients, construction materials)
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Reacting Multi-Phase Flow
Research field: Studies of multi-phase, turbulent reacting flow in thermo-chemical conversion processes (e.g. entrained flow gasification, powder combustion and heat exchangers). Assessment of submodels for particle transport, turbulent, reactions etc.
Research aims: To develop models that can be used for optimisation and trouble shooting of industrial scale thermo-chemical conversion processes as well as for developing new processes. To perform advanced experiments that can complement the theoretical models.
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Advanced experimental methods Research field: Laser heating, laser diagnosis, particle- gaseous- and deposit measurements. Advanced experiments in lab-, bench-, pilot- and full-scale FB’s-, fixed bed’s- and powder/entrained flow- combustors and gasifiers.
Research aims: To support the research activities of thermochemical conversion processes (e.g. pyrolysis , gasification and combustion) with advanced techniques and experimental methods.
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ECO-Lab Fuel preparation and characterization
Rotary sample divider Sieves IR moisture analyser
Size and shape analyser Bomb calorimeter CHNS/O analyser
• Carl-Fischer moisture analyzer
• Drying oven
No picture
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ECO lab high temp. reactors
• Macro TG (<1000 C) • Optical single particle burner • Batch-type fluidized bed reactor • Drop tube reactor (<1400 C) • High temperature furnaces (<1400 C)
• Pulverized burners • Residential pellet boilers • High pressure reactors (<350
bar)
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ECO lab Measurement methods (1)
Extractive sampling: Gas - microGC, Testo portable analyzer Liquid - GC-FID, soxhlet extractor (SPA), rotary evaporator (impinger) Solid - Particle impactor, micro balance, SEM (at the department), XRD (at the department), etc.
µGC
Soxhlet
Rotary evap. GC-FID (auto-sampler, TDC)
2 micro balances (1 µg) & 2 precision balances (1 mg)
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Measurement methods (2) Non-intrusive methods: • Temperature – 2 color
pyrometry • Soot – Laser extinction • Velocity – PIV (gas), PTV
(particle), streak line (particle) • Size and shape of particles • Qualitative image analyses
Equipment: • 2 image intensifiers • 2 high speed
cameras (5400 fps) • 3-CCD camera • 2-color diode laser • Photo diodes • Spectrometer • IR thermocamera • IR thermometer • Black body furnace
Visualization of jet/swirl burners
Particle ignition
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LTU Green Fuels pilot plant
• Entrained flow gasifier for liquid fuels (former Chemrec) • Optimised for alkaline fuels (black liquor) • 3 MWth @ 30 bar and 1000 – 1100 °C
• Cleaning and conditioning of raw gas to ultra clean syngas (impurities < 1 ppm)
• Compression to 120 bar • Methanol and DME synthesis (app. 4 ton DME/24h) • Mothball project until end of 2019