thesis orientation day - technologisch gezelschaptg.tudelft.nl/tod/tod_beijerinckzaal.pdfnuclear...

Thesis orientation day Welcome on behalf of Technologisch Gezelschap!

Section tours Date Section

Ma 12 dec OMI

Di 13 dec OM

Wo 14 dec PPE

Do 15 dec ASM

Vr 16 dec IRS

Ma 19 dec TP

Di 20 dec CE

Wo 21 dec BOC

Do 22 dec MECS

Guided tours of the various sections. 15 places available on each tour. Enrol at the TG website:

technologischgezelschap.nl/sectiontours

Schedule Time Beijerinckzaal Korvezeezaal

15:45 Start Start

15:50-16:00 MEP – Jan van Esch BEP – Erik Kelder

16:00-16:10 Break Break

16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50

17:50-18:00 Poster market & drinks (atrium) 18:00-18:10

18:10-18:20

18:20-18:30

Jan van Esch

Thesis Orientation Day – 30 November 2016

Second Year: Thesis Project & Internship Thesis Project (40 ec, 28 weeks) : Research, carried out at TU Delft Industrial Internship (18 ec, 13 weeks): Design/Research/Operations/etc, done at a company or non-academic institute

Decide yourself which one first Complete (almost) all compulsory courses before starting thesis project Today about Thesis Project

Master Thesis Project Orientation (today, websites of research groups, lunch meetings, etc) Visit several research groups, speak with people, inform yourself Choose Group, Supervisor and Project Subject of the project People you’ll work with: responsible supervisor / daily supervisor / other group members Number of students in the group <> available support from supervisor Make time planning and register the project at the thesis office Reporting and presentation. Thesis defence after 7 months

Chemical Product Engineering Track

Thesis projects can be done in 6 Research groups in the ChemE department: Advanced Soft Matter (ASM) - van Esch Catalysis Engineering (CE) - Kapteijn Materials for Energy Conversion and Storage (MECS) - Dam Opto-Electronic Materials (OM) - Siebbeles Organic Materials & Interfaces (OMI)- Sudhölter Product and Process Engineering (PPE) - Kreutzer or in other groups at TU Delft if the project is approved by the board of examiners before the start of the project.

Process Engineering Track 7 Research groups in ChemE department: Advanced Soft Matter (ASM) - van Esch Catalysis Engineering (CE) - Kapteijn Materials for Energy Conversion and Storage (MECS) - Dam Opto-Electronic Materials (OM) - Siebbeles Organic Materials & Interfaces (OMI)- Sudhölter Product and Process Engineering (PPE) - Kreutzer Transport Phenomena (TP) – Kleijn 1 Research group in Process & Energy department (3mE): Intensified Reaction & Separation Systems (IRS) – Stankiewicz or in other groups at TU Delft if the project is approved by the board of examiners before the start of the project.

Nuclear Science & Engineering Track

5 Research groups in the Radiation Science and Technology department: Radiation and Isotopes for Health (RIH) - Wolterbeek Nuclear Energy and Radiation Applications (NERA) - Kloosterman Fundamental Aspects of Materials and Energy (FAME) - Brück Neutron and Positron Methods in Materials (NPM2) - Pappas Radiation Detection and Medical Imaging (RD&M) - Beekman or in other groups at TU Delft if the project is approved by the board of examiners before the start of the project.

Information Blackboard Stagebureau TNW / Internship Office Applied Sciences Eindprojecten Administratie TNW / Thesis Office Applied Sciences Guidelines and forms, assessment criteria Information Experiences from fellow students Assessment done by Thesis Committee: at least three academic staff members (assistant, associate, full professors) from at least two different groups, and at least one full professor.

Internship & Thesis Office Applied Sciences

Internship Office

TN-building, Room A.210 [email protected]

Thesis Project Office

TN-building, Room A.208 [email protected]

Ms. Suzanne Karssen Internship Officer

Ms. Linda van der Elst Thesis Project Officer

mailto:[email protected]






Program for today 16.00 - 17.45 Simultaneous PPT presentations by research groups: Beijerinckzaal: 16:10 Organic Materials & Interfaces (OMI) 16:30 Materials for Energy Conversion and Storage (MECS) 16:50 Product & Process Engineering (PPE) 17:10 Optoelectronic Materials (OM) 17:30 Catalysis Engineering (CE) Korvezeezaal: 16:10 Intensified Reaction and Separation Systems (IRS) 16:30 Biocatalysis (department of Biotechnology) 16:50 Advanced Soft Matter (ASM) 17:10 Transport Phenomena (TP) Atrium: 17.30 - 19.00 Poster presentations and free drinks! 12 – 19 December: Labtours to research groups

Thank you for your attention!


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30

Prof. Ernst Sudholter Section leader

2 (+ 1 guest) associate professor 3 assistant professor 7 PhD students 4 Postdocs 4 Research Assistants

Dr. Rajeev K. Dubey Thesis Orientation Day

30th November 2016

Sensors

Membranes Colloids and Interface

Energy Conversion and Storage

Energy Conversion and storage

Chemistry of colours. Design and Synthesis of Systems

based on Perylene Dyes Dr. Rajeev K. Dubey Dr. Wolter F. Jager

R.K. Dubey et al. Organic Letters 2016, DOI: 10.1021/acs.orglett.6b02887. R.K. Dubey et al. Organic Chemistry Frontiers 2016 3, 1481–1492. R.K. Dubey et al. Chemical Science 2016 7, 3517–3532.

Silicon anodes for Li ion batteries

Pierre Ranque Dr. Erik Kelder

Problem: Silicon expansion and deterioration during cycling!

Solution: Synthesis of polymers that will accomodate silicon expansion during Li uptake. Self-healing

polymers Shape shifting

polymers

Membranes

Membranes for Phosphate Removal and Solvent Nanofiltration

Laura Paltrinieri

Dr. Louis de Smet

Mohammad Amirilargani

Polymer grafting Pore size adjustment

Increasing hydrophobicity

Surface polarity Applications: Petrochemical and pharmaceutical industries.

Sensors

Silicone nanowires and MOF for sensing

Cao, A. et al; Sensors 2014, 14, 245-271. Cao, A. et al; Analytical Chemistry 2015, 87, 1173–1179. Cao, A. et al; Nano letters, accepted.

Anping Cao

Look out for explosives!!!

Dr. Louis de Smet Sumit Sachdeva

MOF – polyimide composite for impedimetric detection of methanol.

Biomimetic soft interface

Dr. Lukasz Poltorak Electrified liquid – liquid interface (LLI)

L.Poltorak et al; Langmuir 2014, 30, 11453-11463 L. Poltorak et al; Electrochemistry Communications 2013, 37, 76-79 L. Poltorak et al; Electrochimica Acta 2016, 188, 71-77

Forensic Chemistry

Dr. Marcel de Puit

Analytical Methods, 7 (24), 10121-10124 Nature Sci. Rep., 5, 2015, 11716

1. Smart materials for fingerprint visualization (e.g. Fluorescent polyelectrolyte). 2. Detection and sensing of illict drugs. 3. Illicit drugs in fingerprints. 4. Analitical chemistry for Forensics (MALDI MS, UPLC MS, Surface MS...)

(in collaboration with National Forensic Institute)

Colloids and Interface

Enhanced Oil recovery Dr. Naveen Kumar

(Project in collaboration with Shell)

Atomic force microscopy: adhesion force measurements

Dr. Klaas Besseling

Interested in MSc thesis? https://chemeomi.wordpress.com/

MSC/BSC projects

Membranes for organic solvent nanofiltration

• Applications: – Oil, chemical and petrochemical industries – Pharmaceutical industries – Food industries

Polymer grafting Pore size adjustment

Increasing hydrophobicity

Surface polarity

Mohammad Amirilargani

Dr. Louis C. P. M. de Smet

Membranes for Phosphate Removal

Laura Paltrinieri

Dr. Louis C. P. M. de Smet

Commercial membranes modified with:

Functionalized Polyelectrolytes P-attractive nanomaterials

Silicone nanowires (SiNW) for sensing

Cao, A. et al; Sensors 2014, 14, 245-271. Cao, A. et al; Analytical Chemistry 2015, 87, 1173–1179. Cao, A. et al; Nano letters, accepted.

SiNW chip Silicone nanowires

Anping Cao Dr. Louis C. P. M. de Smet

Gas sensing – MOF

S. Sachdeva et al. CrystEngComm, 2016,18, 4018-4022 S. Sachdeva et al. ACS Sens., 2016, 1 (10), pp 1188–1192

Sumit Sachdeva Dr. Louis C. P. M. de Smet


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30

Materials for Energy Conversion and

Storage

Research projects - Artificial fuel synthesis like H2, CH4, CH3OH, NH3 (Wilson Smith) - Direct light to hydrogen conversion (Wilson Smith) - Novel low cost electrolysis (Fokko Mulder) - H-based batteries (with start-up) (Fokko Mulder) - Nanoparticle production for sensors, catalysis, etc. (with start-up) (Andreas Schmidt-Ott) - Metal hydrides for sensors (with industry) (Bernard Dam) - Photochromic materials (Bernard Dam) -Li ion batteries and electrolytes (Fokko Mulder)

A high capacity rechargeable metal hydride based battery

These Ni-MH batteries are in current hybrid cars and contain costly, heavy metal, LaNi5. We work on novel low cost, light metal hydride, electrode materials. Contact: [email protected]

STONE A long life, low cost, environmentally friendly battery

Storing electricity from solar and wind power takes batteries that live as long as solar cells (20-30 years). Together with a TUD spin-off we work on a proton based battery that can be placed in e.g. houses. Contact: [email protected]

Next generation Li ion batteries Lithium ion batteries provide large energy density. We work on new electrodes based on nanostructured conductive carbon materials with Li storing materials in between. Collaboration with industries. Contact: [email protected]

37

combinatorial

R. Gremaud et al. Adv Mat 19 (2007) 2813

Hydrogenation cell

3 CCD Camera

Combinatorial approach MH-based hydrogen sensor materials [email protected]

Ngene et al., Advanced Functional Materials 24 (2014) 2374

38

Photochromic YOyHx The mysterious role of hydrogen in metal oxides

[email protected]

Mongstad et al.: Solar Energy Materials & Solar Cells 95 (2011) 3596–3599

400 600 800 10000

20

40

60

80

100

Tr

ansm

ittanc

e %

Wavelength (nm)

before illumination 10 min 20 min 90 min 380 min

Photodarkening of a thin YOH film: • What is the mechanism • Can we tune the excitation wavelength • Can we speed up the darkening/bleaching

39

Natural Photosynthesis Artificial Photosynthesis

Sustainable Production of Solar Fuels [email protected]

Using sunlight and water to create a clean, renewable, and sustainable fuel We focus on only using cheap and earth abundant materials to make a fuel that is technically,

economically, and environmentally able to replace fossil fuels

Challenge the future

Delft University of Technology

Artificial Photosynthesis [email protected]

Solar water splitting to make H2 Electrochemical reduction of CO2 to synthetic fuels

Two ways to make CO2-neutral fuels

Producing Nanoparticles from the Gas Phase [email protected] Feng, Biskos, Schmidt-Ott, www.nature.com/scientificreports

Applications of Nanoparticles from the gas phase being studied [email protected]

Sharpen AFM or STM tip by nanoparticle impaction

(together with PPE)

Particulate porous layers of controllable and variable composition

Extremely sensitive Chemical Sensors

Catalysis CO CH4 H2 O H2

Well-defined (mixed) nanoparticles

Efficiency enhancement for thin-film solar cells and solar water splitting

Nanoparticles from spark generator

Water decontamination by demobilized nano-particles

(with Univ. Capetown)

(with ETH Zurich)

http://www.google.nl/url?sa=i&rct=j&q=&esrc=s&source=images&cd=&cad=rja&uact=8&ved=0ahUKEwiylc-nvMvQAhVHPBQKHb1bCXYQjRwIBw&url=http://www.wsd.gov.hk/en/water_resources/water_treatment_and_distribution_process/water_treatment_process/&psig=AFQjCNFdVsS_zXtf6mkSgnODIoZ1VZOTdw&ust=1480423196415046

Immobilizing nanoparticles for different purposes [email protected]

Water decontamination by demobilized nanoparticles

(Together with University of Cape Town, South Africa)

Sharpen AFM or STM tip by nanoparticle impaction

(together with PPE)

1) Immobilization by diffusion to fibres of filter

2) Immobilization by impaction


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30

Life at the Product & Process Engineering Group cheme.nl/ppe

Do you like: • Reaction Engineering • Transport phenomena • Working on relevant applications

and are you interested in: • Lab-on-a-Chip / Organ-on-a-chip technology • Behavior of biofluids, bubbles, droplets or biological cells on the

micro/nanoscale • Transport phenomena in health applications • Interaction between and flow of nanoparticles • Scalable production of nanostructured materials

Product & Process Engineering Group

Lab-on-a-chip: each droplet is a test tube

van Steijn et al., Phys. Rev. Lett. (2009)

Create Mix

Song et al., Angew. Chem. Int. Ed. (2006)

Connects to FTV/MTP/ATP. Ideal if you want to make a career in medicine/health/pharma


Extract

van Steijn et al.

Time lapse of yeast growth

Numerical simulation (with TP group)

Multidisciplinary health projects

Blood

Extracellular fluid

Blood vessel-on-a-chip

Nice transport phenomena problem for physicist

Drug release from a drug eluting stent


Rheology of DNA and Complex Fluids Macromolecules P

Q

Die lip

Extr

usio

n

Product Processing

50 um

From Molecule to

Phys. Rev. Lett. (2010) Soft Matter, (2010) Macromolecules, (2011) Macromolecules, (2014)


Engineering of DNA Transfer into Cells

Nature Nanotech., (2011)

Adv. Healthcare Mat., (2014)


1. Precise 2. Scalable 2. Versatile 4. Efficient

Scalable production of nanostructured materials Al2O3 on TiO2 Pt on TiO2

Self-healing materials Catalysts

Atomic layer deposition in a fluidized bed

Product & Process Engineering Group 2D materials

Controlled release medicines

Novel approaches for Chem. Reaction Eng.

I0 IL x

(1-ω)I I

ωI Photoreactor design & modelling


Atomic-level understanding for

nanoscale engineering

Production of novel materials for LED lighting

Novel methods for making medical isotopes

Overview of BEP/MEP projects


cheme.nl/ppe


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30

1-12-2016


Delft University of Technology

Opto-electronic Materials Ferdinand Grozema

14.12a14.12a

56

Section Opto-electronic Materials

Prof. dr. L. D.A. Siebbeles Dr. F. C. Grozema Dr. ir. T. J. Savenije Dr. A. J. Houtepen

Interactions between light and matter: Exploiting the power of light !

Applications: • Solar cells • Quantum dots for lighting applications • Displays • Medical applications • New materials for electronics • Fundamental understand of material properties

57

Novel nanostructured materials for: cheap solution processable, mechanically flexible, highly efficient solar cells and other molecular devices

Organics Quantum Dots Solar Cell

LED

Section Opto-electronic Materials

Perovskites Laser

59

Perovskites • Hybrid organic inorganic materials

• Currently the most promising new materials in

solar cells

• Next big thing in photovoltaics!!

60

Quantum dots

Aerts, M., et al., Nature Communications 2014, 5, 3789 Suchand Sandeep et al., Nature Communications 2013, 4, 2360 Gao. Y. et al. Nature Communications 2013, 4, 2329 Talgorn, E., et al. Nature Nanotechnology 2011, 6, (11), 733-739. Trinh, M. T., et al. Nano Letters 2011, 11, (4), 1623-1629.

61

Quantum dots

• Tunable color by variations in size, composition • Light absorber/emitter • Display: ultra-HD TVs: Samsung • Quantum dot solar cells

62

Molecular/organic electronics

Charge transfer through single molecules: -Fundamental studies of charge transfer: elementary process in many applications, for instance solar cells

-Clear link with single molecule electronics

Charge transport in molecular solids -Charge carrier mobility measured by microwave conductivity

-Mobility strongly depends of mutual orientation of molecules in solid

63

Lots of possibilities • Synthesis/processing

• Organic molecules for electronics • New quantum dot materials

• Characterize opto-electronic properties

• Laser spectroscopy: fluorescence, transient absorption measurements • Follow processes on very short time-scale • Conductivity experiments

• Simulate/predict properties

• Computational chemistry: quantum chemical calculations

• Make devices • Quantum dot or perovskite solar cells

64

Collaborations

Universities all over the world Industrial:

65

We are nice!


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30


atalysis E ngineering

C http://cheme.nl/ce/

Jorge Gascon and Freek Kapteijn

C atalysis E ngineering

Ina Vollmer Maria Jose Valero

Martijn de Lange

Irina Prokopyeva

Maxim Navisalevich

Sumit Sachdeva

Alla Dikhtiarenko

Filipe Lopes

Alma Olivos

Rupali Bhardwaj

Beba Seoane

Eduardo Andres

Nastya Bavykina

Dmitrii Osadchii Anahid Sabetghadam

Xiaohui Sun

Tim Wezendonk Francesc Sastre

Elena Rozhko

Meixia Shan

Sonia Castellanos Lide Oar-Arteta

Vijay M. Shinde

Jara Garcia

Ágnes Szécsényi Yixiao Wang

Key challenge of today’s society: Supply energy and chemicals in a sustainable manner

The answer is not one unique solution, but many…

The energy challenge: roadmap

The energy challenge: roadmap

New ‘smart’ materials and reactors are needed: • Multifuntional • Based on abundant elements

The energy challenge: roadmap Our philosophy

C1 Catalysis

Direct activation of CH4 Fischer Tropsch Synthesis

Syngas to Methanol Hydroformylation

CatalysisE ngineeringCatalysisE ngineering

Methanol to olefins CO2 Hydrogenation

Methane Dehydroaromatization


Water Gas Shift

C1 Catalysis


Spectroscopy / Microscopy

In situ IR-Spectroscopy In situ EXAFS

0 1 2 3 4 5 60.0

0.1

0.2

0.3

0.4

0.5

|x(R

)| A-2

R (A)

CoS CoSK CoMoSK

In situ SAXS-WAXS Ultrafast spectroscopy

Photocatalysis Biomass valorization

Electro-Catalysis


FCC

New and old processes

Ethylene Oligomerization

Mixed Matrix Membranes Zeolite Membranes

Adsorptive based separations


Chiral Separations

Separation & Membrane development


atalysis E ngineering

C http://cheme.nl/ce/

Jorge Gascon and Freek Kapteijn

C atalysis E ngineering


15:45 Start Start



16:10-16:20 OMI IRS


16:30-16:40 MECS BOC


16:50-17:00 PPE ASM


17:10-17:20 OM TP


17:30-17:40 CE BT

17:40-17:50


18:10-18:20

18:20-18:30

thesis orientation day - technologisch gezelschaptg.tudelft.nl/tod/tod_beijerinckzaal.pdfnuclear...

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