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Treaty Series

Treaties and international agreements

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Traitis et accords internationaux

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registered

or filed and recorded

with the Secretariat of the United Nations

VOLUME 1845

Recueil des Traites

Traitis et accords internationaux

enregistrisou classjs et inscrits au ripertoire


United Nations * Nations UniesNew York, 1998

Treaties and international agreementsregistered or filed and recorded


VOLUME 1845 1995 I. No. 31452

TABLE OF CONTENTS

ITreaties and international agreements

registered on 1 January 1995

Page

No. 31452. United Nations (United Nations Development Programme) andUkraine:

Basic Agreement concerning assistance by the United Nations Development Pro-gramme to the Government of Ukraine. Signed at Kiev on 18 June 1993 ......... 3

ANNEX A. Ratifications, accessions, subsequent agreements, etc., con-cerning treaties and international agreements registered with theSecretariat of the United Nations

No. 8940. European Agreement concerning the International Carriage of Dan-gerous Goods by Road (ADR). Done at Geneva, on 30 September1957:

Entry into force of amendments to annexes A and B, as amended, to the above-m entioned A greem ent ............................................................................................... 48

Corrigendum concerning the English text of the amendments proposed by theGovernment of France to annexes A and B, as amended, to the above-m entioned A greem ent ............................................................................................... 518

(The authentic French text of the amendments to annexes A and B appears involume 1846.)

Vol. 1845

Traitis et accords internationauxenregistris ou classe's et inscrits au ripertoire


VOLUME 1845 1995 I. NO 31452

TABLE DES MATIERES

I

Trait~s et accords internationaux

enregistris le Jerjanvier 1995

Pages

NO 31452. Organisation des Nations Unies (Programme des Nations Unies pourle d6veloppement) et Ukraine :

Accord de base relatif A une assistance du Programme des Nations Unies pour leddveloppement au Gouvernement ukrainien. Sign6 A Kiev le 18 juin 1993 ...... 3

ANNEXE A. Ratifications, adhisions, accords ultgrieurs, etc., concernantdes traits et accords internationaux enregistris au Secritariat del'Organisation des Nations Unies

NO 8940. Accord europ6en relatif au transport international des marchandisesdangereuses par route (ADR). Fait i Gen~ve, le 30 septembre 1957 :

Entr6e en vigueur des amendements aux annexes A et B, telles qu'amenddes, A'A ccord susm entionn6 ............................................................................................. 48

Rectificatif concernant le texte anglais des amendements, propos6 par le Gou-vernement franqais aux annexes A et B, telles qu'amend6es, A l'Accord sus-m ention n6 ................................................................................................................... 5 18

(Le texte authentique franfais des amendements aux annexes A et B paraftdans le volume 1846.)

Vol. 1845

NOTE BY THE SECRETARIAT

Under Article 102 of the Charter of the United Nations every treaty and every international agree-ment entered into by any Member of the United Nations after the coming into force of the Charter shall,as soon as possible, be registered with the Secretariat and published by it. Furthermore, no party to atreaty or international agreement subject to registration which has not been registered may invoke thattreaty or agreement before any organ of the United Nations. The General Assembly, by resolution 97 (1),established regulations to give effect to Article 102 of the Charter (see text of the regulations, vol. 859,p. VIII).

The terms "treaty" and "international agreement" have not been defined either in the Charter or inthe regulations, and the Secretariat follows the principle that it acts in accordance with the position of theMember State submitting an instrument for registration that so far as that party is concerned the instru-ment is a treaty or an international agreement within the meaning of Article 102. Registration of aninstrument submitted by a Member State, therefore, does not imply a judgement by the Secretariat on thenature of the instrument, the status of a party or any similar question. It is the understanding of theSecretariat that its action does not confer on the instrument the status of a treaty or an internationalagreement if it does not already have that status and does not confer on a party a status which it wouldnot otherwise have.

Unless otherwise indicated, the translations of the original texts of treaties, etc., published in thisSeries have been made by the Secretariat of the United Nations.

NOTE DU SECRIPTARIAT

Aux termes de l'Article 102 de la Charte des Nations Unies, tout traitd ou accord internationalconclu par un Membre des Nations Unies apris l'entr6e en vigueur de la Charte sera, le plus t6t possible,enregistr6 au Secr6tariat et publid par lui. De plus, aucune partie . un trait6 ou accord international quiaurait dO 8tre enregistrd mais ne l'a pas 6t6 ne pourra invoquer ledit trait6 ou accord devant un organe desNations Unies. Par sa r6solution 97 (I), l'Assembl6e g6n6rale a adopt6 un riglement destin6 A mettre enapplication l'Article 102 de la Charte (voir texte du r~glement, vol. 859, p. IX).

Le terme < trait6 > et l'expression < accord international > n'ont 6t6 d6finis ni dans la Charte ni dansle r~glement, et le Secr6tariat a pris comme principe de s'en tenir A la position adoptde i cet 6gard parl'Etat Membre qui a pr6sentd l'instrument A l'enregistrement, A savoir que pour autant qu'il s'agit de cetEtat comme partie contractante l'instrument constitue un trait6 ou un accord international au sens del'Article 102. I1 s'ensuit que l'enregistrement d'un instrument pr6sent6 par un Etat Membre n'implique,de la part du Secr6tariat, aucun jugement sur la nature de l'instrument, le statut d'une partie ou touteautre question similaire. Le Secr6tariat consid~re donc que les actes qu'il pourrait etre amen6 A accomplirne conferent pas A un instrument la qualit6 de < trait6 > ou d'< accord international > si cet instrumentn'a pas d6jA cette qualit6, et qu'ils ne conferent pas A une partie un statut que, par ailleurs, elle neposs6derait pas.

Sauf indication contraire, ies traductions des textes originaux des trait6s, etc., pubiids dans ce Re-cuei ont 6t6 6tablies par le Secretariat de l'Organisation des Nations Unies.


registered

on 1 January 1995

No. 31452

Traitds et accords internationaux

enregistris

le lerjanvier 1995

NO 31452

Vol. 1845

No. 31452

UNITED NATIONS(UNITED NATIONS DEVELOPMENT PROGRAMME)

andUKRAINE

Basic Agreement concerning assistance by the United NationsDevelopment Programme to the Government ofUkraine. Signed at Kiev on 18 June 1993

Authentic texts: English and Ukrainian.

Registered ex officio on 1 January 1995.

ORGANISATION DES NATIONS UNIES(PROGRAMME DES NATIONS UNIES

POUR LE DEVELOPPEMENT)et

UKRAINE

Accord de base relatif 'a une assistance du Programme desNations Unies pour le d6veloppement au Gouvernementukrainien. Signe ii Kiev le 18 juin 1993

Textes authentiques : anglais et ukrainien.

Enregistrg d'office le lerjanvier 1995.

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AGREEMENT1 BETWEEN THE GOVERNMENT OF UKRAINE ANDTHE UNITED NATIONS DEVELOPMENT PROGRAMME

WHEREAS the General Assembly of the United Nations hasestablished the United Nations Development Programme (hereinafter calledthe UNDP) to support and supplement the national efforts of recipientcountries at solving the most important problems of their economicdevelopment and to promote social progress and better standards of life; and

WHEREAS the Government of Ukraine (hereinafter called theGovernment) wishes to request assistance from the UNDP for the benefit ofits people;

NOW THEREFORE the Government and the UNDP (hereinaftercalled the Parties) have entered into this Agreement in a spirit of friendlyco - operation.

Article I

SCOPE OF THIS AGREEMENT

1. This Agreement embodies the basic conditions under which the UNDPand its Executive Agencies shall assist the Government in carrying out itsdevelopment projects, and under which such UNDP - assisted projects shallbe executed. It shall apply to all such UNDP assistance and to such ProjectDocuments or othc.: instruments (hereinafter called Project Documents) asthe Parties may conclude to define the particulars of such assistance and therespective responsibilities, of the Parties and the Executing Agencyhereunder in more detail in regard to such projects.

2. Assistance shall be provided by the UNDP under this Agreement onlyin response to requests submitted by the Government and approved by theUNDP. Such assistance shall be made available to the Government, or tosuch entity as the Government may designate, and shall be furnished andreceived in accordance with the relevant and applicable resolutions anddecisions of the competent UNDP organs, and subject to the availability ofthe necessary funds to the UNDP.

I Came into force on 18 June 1993 by signature, in accordance with article XIII (2).

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Article II

FORMS OF ASSISTANCE

I. Assistance which may be made available by the UNDP to theGovernment under this Agreement may consist of:

(a) The services of advisory experts and consultants, includingconsultant firms or organizations, selected by and reponsible to, the UNDPor the Executing Agency concerned;

(b) The services of operational experts selected by the ExecutingAgency, to perform Functions of an operational, executive or administrativecharacter as civil servants of the Government or as employees of suchentities as the Government may designate under Article I, paragraph 2,hereof;

(c) The services of members of the United Nations Volunteers(hereinafter called volunteers);

(d) Equipment and supplies not readily available in Ukraine(hereinafter called the country);

(e) Seminars, training programmes, demonstration projects, expertworking groups and related activities;

(f) Scholarships and fellowships, or similar arrangements underwhich candidates nominated by the Government and approved by theExecuting Agency concerned may study or receive training; and

(g) Any other form of assistance which may be agreed upon by theGovernment and the UNDP.

2. Requests for assistance shall be presented by the Government to theUNDP through the UNDP resident representative in the country (referred toin paragraph 4. (a) of this Article, and in the form and in accordance withprocedures established by the UNDP for such requests. The Governmentshall provide the UNDP with all appropriate facilities and relevantinformation to appraise the request, including an expression of its intentwith respect to the follow-up of investment- oriented projects.

3. Assistance may be provided by the UNDP to the Government eitherdirectly, with such external assistance as it may deem appropriate, or.through an Executing Agency, which shall have primary responsibility forcarrying out UNDP assistance to the project and which shall have the statusof an independent contractor for this purpose. Where assistance is providedby the UNDP directly to the Government, all references in this Agreement to

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an Executing Agency shall be construed to refer to the UNDP, unless clearlyinappropriate from the context.

4. (a) The UNDP may maintain a permanent mission headed by aresident representative, in the country to represent the UNDP therein and bethe principal channel of communication with the Government on allProgramme matters. The resident representative shall have full responsibilityand ultimate authority on behalf of the UNDP Administrator, for the UNDPprogramme in all its aspects in the country, and shall be team leader inregard to such representatives of other United Nations organizations as maybe posted in the country, taking into account their professional competenceand their relations with appropriate organs of the Government. The residentrepresentative shall maintain liaison on behalf of the Programme with theappropriate organs of the Government, including the Government's co-ordinating agency for external assistance, and shall inform the Governmentof the policies, criteria and procedures of the UNDP and other. relevantprogrammes of the United Nations. He shall assist the Government, as maybe required, in the preparation of UNDP country programme and projectrequests, as well as proposals for country programme or project changes,assure proper co - ordination of all assistance rendered by. the UNDPthrough various Executing Agencies or its own consultants, assist theGovernment, as may be required, in co - ordinatingUNDP activities with national, bilateral and multilateral programmes withinthe country, and carry out such other functions as may be entrusted to himby the Administrator or by an Executing Agency.

(b) The UNDP mission in the country shall have such other staff asthe UNDP may deem appropriate to its proper functioning. The UNDP shallnotify the Government from time to time of the names of the members, andof the families of the members, of the mission, and of changes in the statusof such persons.

Article III

EXECUTION OF PROJECTS

1. The Government shall remain responsible for its UNDP-assisteddevelopment projects and the realization of their objectives as described inthe relevant Project Documents, and shall carry out such parts of suchprojects as may be stipulated in the provisions of this Agreement and suchProject Documents. The UNDP undertakes to complement and supplementthe Government's participation in such projects through assistance to theGovernment in pursuance of this Agreement and the Work Plans formingpart of such Project Documents, and through assistance to the Governmentin fulfilling its intent with respect to investment follow-up. TheGovernment shall inform UNDP of the Government Co-operating Agency

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directly responsible for the Government's participation in each UNDP-assisted project. Without prejudice to the Government's overall responsibilityfor its projects, the Parties may agree that an Executing Agency shall assumeprimary responsibility for execution of a project in consultation andagreement with the Co-operating Agency, and any arrangements to thiseffect shall be stipulated in the project Work Plan forming part of theProject Document together with arrangements, if any, for transfer of suchresponsibility, in the course of project execution, to the Government or to anentity designated by the Government.

2. Compliance by the Government with any prior obligations agreed tobe necessary or appropriate for UNDP assistance to a particular project shallbe a condition of performance by the UNDP and the Executing Agency oftheir responsibilities with respect to that project. Should provision of suchassistance be commenced before such prior obligations have been met, itmay be terminated or suspended without notice and at the discretion of theUNDP.

3. Any agreement between the Government and an Executing Agencyconcerning the execution of a UNDP-assisted project or between theGovernment and an operational expert shall be subject to the provisions ofthis Agreement.

4. The Co-operating Agency shall as appropriate and in consultationwith the Executing Agency assign a full -time Director for each project whoshall perform such functions as are assigned to him by the Co-operatingAgency. The Executing Agency shall as appropriate and in consultationwith the Government appoint a Chief Technical Adviser or Project Co-ordinator responsible to the Executing Agency to oversee the ExecutingAgency's participation in the project at the project, level. He shall superviseand co -ordinate activities of experts and other Executing Agency personneland be responsible for the on-the-job training of national Governmentcounterparts. He shall be responsible for the management and efficientutilization of all UNDP-financed inputs, including equipment provided tothe project.

5. In the performance of their duties, advisory experts, consultants andvolunteers shall act in close consultation with the Government and withpersons or bodies designated by the Government, and shall comply withsuch instructions from the Government as may be appropriate to the natureof their duties and the assistance to be given and as may be mutually agreedupon between the UNDP and the Executing Agency concerned and theGovernment. Operational experts shall be solely responsible to, and beunder the exclusive direction of, the Government or the entity to which theyare assigned, but shall not be required to perform any functionsincompatible with their international status or with the purposes of theUNDP or of the Executing Agency. The Government undertakes that thecommencing date of each operational expert in its service shall coincidewith the effective date of his contract with the Executing Agency concerned.

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6. Recipients of fellowships shall be selected by the Executing Agency.Such fellowships shall be administered in accordance with the fellowshippolicies and practices of the Executing Agency.

7. Technical and other equipment, materials, supplies and other propertyfinanced or provided by the UNDP shall belong to the UNDP unless anduntil such time as ownership thereof is transferred, on terms and conditionsmutually agreed upon between the Government and the UNDP, to theGovernment or to an entity nominated by it.

8. Patent rights, copyright rights, and other similar rights to anydiscoveries or work resulting from direct UNDP assistance under thisAgreement shall belong to the UNDP. Unless otherwise agreed by theParties in each case, however, the Government shall have the right to useany such discoveries or work within the country free of royalty or any chargeof similar nature.

Article IV

INFORMATION CONCERNING PROJECTS

1. The Government shall furnish the UNDP with such relevant reports,maps, accounts, records, statements, documents and other information as itmay request concerning any UNDP-assisted project, its execution or itscontinued feasibility and soundness, gr concerning the compliance by theGovernment with its responsibilities under tis Agreement or Projectdocument.

2. The UNDP undertakes that the Government shall be kept currentlyinformed of the progress of its assistance activities under this Agreement.Either party shall have the right, at any time, to observe the progress ofoperations on UNDP-assisted projects.

3. The Government shall, subsequent to the completion of a UNDP-assisted project, make available to the UNDP at its request information as tobenefits derived from and activities undertaken to further the purposes ofthat project, including information necessary or appropriate to its evaluationor to evaluation of UNDP assistance, and shall consult with and permitobservation by the UNDP for this purpose.

4. Any information or material which the Government is required toprovide to the UNDP under this Article shall be made available by theGovernment to an Executing Agency at the request of the Executing Agencyconcerned.

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5. The Parties shall consult each other regarding the publication, asappropriate, of any information relating to any UNDP-assisted project or tobenefits derived therefrom. However, any information relating to anyinvestment- oriented project may be released by the UNDP to potentialinvestors, unless and until the Government has requested the UNDP inwriting to restrict the release of information relating to such project.

Article V

PARTICIPATION AND CONTRIBUTION OF GOVERNMENTIN EXECUTION OF PROJECT

I. In fulfillment of the Government's responsibility to participate andco-operate in the execution of the projects assisted by the UNDP underthis Agreement, it shall contribute the following in kind to the extentdetailed in relevant Project Documents:

(a) Local counterpart professional and other services, Includingnational counterparts to operational experts;

(b) Land, buildings, and training and other facilities available orproduced within the country; and

(c) Equipment, materials and supplies available or produced withinthe country.

2. Whenever the provision of equipment forms part of UNDP assistanceto the Government, the latter shall meet charges relating to customsclearance of such equipment, its transportation from the port of entry to theproject site together with any incidental handling or storage and relatedexpenses, its insurance after delivery to the project site, and its installationand maintenance.

3. The Government shall also meet the salaries of trainees and recipientsof fellowships during the period of their fellowships.

4. If so provided in the Project Document, the Government shall pay, orarrange to have paid, to the UNDP or an Executing Agency the sumsrequired, to the extent specified in the Project Budget of the ProjectDocument, for the provision of any of the items enumerated in paragraph Iof this Article, whereupon the Executing Agency shall obtain the necessaryitems and account annually to the UNDP for any expenditures out ofpayments made under this provision.

5. Moneys payable to the UNDP under the preceding paragraph shall bepaid to an account designated for this purpose by the Secretary-General of

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the United Nations and shall be administered in accordance with theapplicable financial regulations of the UNDP.

6. The cost of items constituting the Government's contribution to theproject and any sums payable by the Government in pursuance of thisArticle, as detailed in Project Budgets, shall be considered as estimatesbased on the best information available at the time of preparation of suchProject Budgets. Such sums shall be subject to adjustment whenevernecessary to reflect the actual cost of any such items purchased thereafter.

7. The Government shall as appropriate display suitable signs at eachproject identifying it as one assisted by the UNDP and the ExecutingAgency.

Article VI

ASSESSED PROGRAMME COSTSAND OTHER ITEMS PAYABLE IN LOCAL CURRENCY

1. In addition to the contribution referred to in Article V above, theGovernment shall assist the UNDP in providing it with assistance by payingor arranging to pay for the following local costs or facilities, in the amountsspecified in the relevant Project Document or otherwise determined by theUNDP in pursuance of relevant decisions of its governing bodies:

(a) The local living costs of advisory experts and consultantsassigned to projects in the country;

(b) Local administrative and clerical services, including necessarylocal secretarial help, interpreter -translators, and related assistance;

(c) Transportation of personnel within the country; and

(d) Postage and telecommunications for official purposes.

2. The Government shall also pay each operational expert directly thesalary, allowances and other related emoluments which Would be payable toone of its nationals if appointed to the post involved. It shall grant anoperational expert the same annual and sick leave as the Executing Agencyconcerned grants its own officials, and shall make any arrangementnecessary to permit him to take home leave to which he is entitled under theterms of his service with the Executing Agency concerned. Should hisservice with the Government be terminated by it under circumstances whichgive rise to an obligation on the part of an Executing Agency to pay him anindemnity under its contract with him, the Government shall contribute tothe cost thereof the amount of separation indemnity which would be payable

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to a national civil servant or comparable employee of like rank whoseservice is terminated in the same circumstances.

3. The Government undertakes to furnish in kind the following localservices and facilities:

(a) The necessary office space and other premises;

(b) Such medical facilities and services for international personnelas may be available to national civil servants;

(c) Simple but adequately furnished accommodation to volunteers;and

(d) Assistance in finding suitable housing accommodation forinternational personnel, and the provision of such housing to operationalexperts under the same conditions as to national civil servants of comparablerank.

4. The Government shall also contribute towards the expenses ofmaintaining the UNDP mission in the country by paying annually to theUNDP a lumpsum mutually agreed between the Parties to cover thefollowing expenditures:

(a) An appropriate office with equipment and supplies, adequate toserve as local headquarters for the UNDP in the country;

(b) Appropriate local secretarial and clerical help, interpreters,translators and related assistance;

(c) Transportation of the resident representative and his staff for

official purposes within the country;

(d) Postage and telecommunications for official purposes; and

(e) Subsistence for the resident representative and his staff while inofficial travel status within the country.

5. The Government shall have the option of providing in kind thefacilities referred to in paragraph 4 above, with the exception of items (b)and (e).

6. Moneys payable under the provisions of this Article, other than underparagraph 2, shall be paid by the Government and administered by theUNDP in accordance with Article V, paragraph 5.

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Article VII

RELATION TO ASSISTANCE FROM OTHER SOURCES

In the event that assistance towards the execution of a project isobtained by either Party from other sources, the Parties shall consult eachother and the Executing Agency with a view to effective co - ordination andutilization of assistance received by the Government from all sources. Theobligations of the Government hereunder shall riot be modified by anyarrangements it may enter into with other entities co-operating with it inthe execution of project.

Article VIII

USE OF ASSISTANCE

The Government shall exert its best efforts to make the most effectiveuse of the assistance provided by the UNDP and shall use such assistance forthe purpose for which it is intended. Without restricting the generality ofthe foregoing, the Government shall take such steps to this end as arespecified in the Project Document.

Article IX

PRIVILEGES AND IMMUNITIES

1. The Government shall apply to the United Nations and its organs,including the UNDP and U.N. subsidiary organs acting as UNDP ExecutingAgencies, their property, funds and assets, and to their officials, includingthe resident representative and other members of the UNDP mission in thecountry, the provisions of the Convention on the Privileges and Immunitiesof the United Nations.'

2. The Government shall apply to each Specialized Agency acting as aniExecuting Agency, its property, funds and assets, and to its officials, theprovisions of the Convention on the Privileges and Immunities of the

I United Nations, Treaty Series, vol. 1, p. 15, and vol. 90, p. 327 (corrigendum to vol. 1, p. 18).

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Specialized Agencies,' including any Annex to the Convention applicable tosuch Specialized Agency. In cace the International Atomic Energy Agency(the IAEA) acts as an Executing Agency, the Government shall apply to itsproperty, funds and assets, and to its officials and experts, the Agreement onthe Privileges and Immunities of the IAEA.2

3. Members of the UNDP mission in the country shall be granted suchadditional privileges and immunities as may be necessary for the effectiveexercise by the mission of its functions.

4. (a) Except as the Parties may otherwise agree in Project Documentsrelating to specific projects, the Government shall grant all persons, otherthan Government nationals employed locally, performing services on behalfof the UNDP, a Specialized Agency or the IAEA who are not covered byparagraphs I and 2 above the same privileges and immunities as officials ofthe United Nations, the Specialized Agency concerned or the IAEA underSections 18, 19 or 18 respectively of the Conventions on the Privileges andImmunities of the United Nations or of the Specialized Agencies, or of theAgreement on the Privileges and Immunities of the IAEA.

(b) For purposes of the instrument on privileges and immunitiesreferred to in the preceding parts of this Article:

(1) All papers and documents relating to a project in thepossession or under the control of the persons referred to insub-paragraph 4(a) above shall be deemed to be documentsbelonging to the United Nations, the Specialized Agencyconcerned, or the IAEA, as the case may be; and

(2) Equipment, materials and supplies brought into or purchased orleased by those persons within the country for purposes of aproject shall be deemed to be property of the United Nations,the Specialized Agency concerned, or the IAEA, as the casemay be.

5. The expression "persons performing services" as used in Articles IX, Xand XIII of this Agreement includes operational experts, volunteers,consultants, and juridical as well as natural persons and their employees. Itincludes governmental or non - governmental organizations or firms whichUNDP may retain, whetler as an Executing Agency or otherwise, to executeor to assist in the execution of UNDP assistance to a project, and theiremployees. Nothing in this Agreement shall be construed to limit theprivileges, immunities or facilities conferred upon such organizations orfirms or their employees in any other instrument.

I United Nations, Treaty Series, vol. 33, p. 261. For the final and revised texts of annexes published subsequently,see vol. 71, p. 318; vol. 79, p. 326; vol. 117, p. 386; vol. 275, p. 298; vol. 314, p. 308; vol. 323, p. 364; vol. 327, p. 326;vol. 371, p. 266; vol. 423, p. 284; vol. 559, p. 348; vol. 645, p. 340; vol. 1057, p. 320 and vol. 1060, p. 337.

2 Ibid., vol. 374, p. 147.

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Article X

FACILITIES FOR EXECUTION OF UNDP ASSISTANCE

1. The Government shall take any measures which may be necessary toexempt the UNDP, its Executing Agencies, their experts and other personsperforming services on their behalf from regulations or other legal provisionswhich may interfere with operations under this Agreement, and shall grantthem such other facilities as may be necessary for the speedy and efficientexecution of UNDP assistance. It shall, in particular, grant them thefollowing rights and facilities:

(a) prompt clearance of experts and other persons performingservices on behalf of the UNDP or an Executing Agency;

(b) prompt issuance without cost of necessary visas, licenses or

permits;

(c) access to the site of work and all necessary rights of way;

(d) free movement within or to or from the country, to the extentnecessary for proper execution of UNDP assistance;

(e) the most favourable legal rate of exchange;

(f) any permits necessary for the importation of equipment,materials and supplies, and for their subsequent exportation;

(g) Any permits necessary for importation of property belonging toand intended for the personal use or consumption of officials of the UNDP,its Executing Agencies, or other persons performing services on their behalf,and for the subsequent exportation of such property; and

(h) Prompt rcleasp from customs of the items mentioned in sub-paragraphs (f) and (g) above.

2. Assistance under this Agreement being provided for the benefit of theGovernment and people of Ukraine, the Government shall bear all risks ofoperations arising under this Agreement. It shall be responsible for dealingwith claims which may be brought by third parties against the UNDP or anExecuting Agency, their officials or other persons performing services ontheir behalf, and shall hold them harmless in respect of claims or liabilitiesarising from operations under this Agreement. The toregoing provision shallnot apply where the Parties and the Executing Agency are agreed that aclaim or liability arises from the gross negligence or wilful misconduct of theabove - mentioned individuals.

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Article XI

SUSPENSION OR TERMINATION OF ASSISTANCE

1. The UNDP may by written notice to the Government and to theExecuting Agency concerned suspend its assistance to any project if in thejudgement of the UNDP any circumstance arises which interferes with orthreatens to interfere with the successful completion of the project or theaccomplishment of its purposes. The UNDP may, in the same or asubsequent written notice, indicate the conditions under which it is preparedto resume its assistance to the project. Any such suspension shall continueuntil such time as such conditions are accepted by the Government and asthe UNDP shall give written notice to the Government and the ExecutingAgency that it is prepared to resume its assistance.

2. If any situation referred to in paragraph I of this Article shall continuefor a period of fourteen days after notice thereof and of suspension shallhave been given by the UNDP to the Government and the ExecutingAgency, then at any time thereafter during the continuance thereof, theUNDP may by written notice to the Government and the Executinc' Agencyterminate its assistance to the Project.

3. The provisions of this Article shall be without prejudice to any otherrights or remedies the UNDP may have in the circumstances, whether undergeneral principles of law or otherwise.

Article XII

SETTLEMENT OF DISPUTES

1. Any dispute between UNDP and the Government arising out of orrelating to this Agreement which is not settled by negotiation or otheragreed mode of settlement shall be submitted to arbitration at the request ofeither Party. Each Party shall appoint one arbitrator, and the two arbitratorsso appointed shall appoint a third, who shall be the chairman. If withinthirty days of the request for arbitration either Party has not appointed anarbitrator or if within fifteen days of the appointment of two arbitrators thethird arbitrator has not been appointed, either Party may request thePresident of the International Court of Justice to appoint an arbitrator. Theprocedure of the arbitration shall be fixed by the arbitrators, and theexpenses of the arbitration shall be borne by the Parties as assessed by thearbitrators. The arbitral award shall contain a statement of the reasons onwhich it is based and shall be accepted by the Parties as the finaladjudication of the dispute.

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2. Any dispute between the Government and an operational'expert arisingout of or relating to the conditions of his service with the Government maybe referred to the Executing Agency providing the operational expert byeither the Government or the operational expert involved, and the ExecutingAgency concerned shall use its good offices to assist them in arriving at asettlement. If the dispute cannot be settled in accordance with thepreceding sentence or by other agreed mode of settlement, the matter shallat the request of either Party be submitted to arbitration following the sameprovisions as are laid down in paragraph 1 of this Article, except that thearbitrator not appointed by either Party or by the arbitrators of the Partiesshall be appointed by the Secretary- General of the Permanent Court ofArbitration.

Article XIII

GENERAL PROVISIONS

I. This Agreement is an integral part of and supplementary to theAgreement between the United Nations and the Government of Ukrainerelating to the Establishment of a United Nations Interim Office in Ukraine.Insofar as any provision of this Agreement and any provision of the latterAgreement relate to the same subject matter, the two provisions shall,whenever possible, be construed as complementary so that both provisionsshall be applicable and neither shall narrow the effect of the other.

2. This Agreement shall enter into force upon signature. It shall continuein force until terminated under paragraph 3 below. Upon the entry intoforce of this Agreement, it shall supersede existing Agreements concerningthe provision of assistance to the Government out of UNDP resources andconcerning the UNDP office in the country, and it shall apply to allassivtance provided to the Government and to the UNDP office establishedin the country under the provisions of the Agreements now superseded.

3. This Agreement may be modified by written agreement between theParties hereto. Any relevant matter for which no provision is made in thisAgreement shall be settled by the Parties in keeping with the relevantresolutions and decisions of the appropriate organs of the United Nations.Each Party shall give full and sympathetic consideration to any proposaladvanced by the other Party under this paragraph.

4. This Agreement may be terminated by either Party by written noticeto the other and shall terminate sixty days after receipt of such notice.

5. The obligations assumed by the Parties under Articles IV (concerningproject information) and VIII (concerning the use of assistance) hereof shall

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survive the expiration or termination of this Agreement. The obligationsassumed by the Government under Articles IX (concerning privileges andimmunities), X (concerning facilities for project execution) and XII(concerning settlement of disputes) hereof shall survive the expiration ortermination of this Agreement to the extent necessary to permit orderlywithdrawal of personnel, funds and property of the UNDP and of anyExecuting Agency, or of any persons performing services on their behalfunder this Agreement.

IN WITNESS WHEREOF the undersigned, duly appointedrepresentatives of the Government of Ukraine and of the United NationsDevelopment Programme, respectively, have on behalf of the Parties signedthe present Agreement in the Ukrainian and English languages in twocopies at Kiev this eighteenth day of June 1993.

For the Governmentof Ukraine:

For the United NationsDevelopment Programme:

(j!

NNN4wi,

I Anatoliy Zlenko.2 Boutros-Boutros Ghali.

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Owv- ' L -LL-e

United Nations - Treaty Series * Nations Unies - Recueil des Trait~s

[UKRAINIAN TEXT - TEXTE UKRAINIEN]

YFOaA MIX YPAIQOM YKPAIHI4 I IPOFPAMOIO PO3BI4TKYOPFAHI3AIIII OB'CJHAHHIX HA[I1I

peDV'qH nO v mar , uo FeHepa~xbHa AcaM~neg OpraHi3aitil

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nporpecy Ta niABHmeHH PiBHS xHTTS, a Tamoz

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YpRA i 1IPOOH (Aa-ii CTOPOHIS) y JYCi jpyxHboroCU iBpOiTHHITBa yxianax Im YrojxY.

CraTTR ICeen nil uie! Yronx

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BHKOHaHH1 goro npoeXTiB P03BHTKY i B1InOB iAHO AO RIE(X

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YCTaHOBH Bi3.HOCHO Ta XEX IpoeHTiB.

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(DoDM1! nooMOTW

1. fonoMora, 1KY flPOOH Moze HaJaB3aTH YPDy 2' iAfIOBi to Ao

ic ! YrOZLE, moze BKimtqaTH:

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excnePTiB Ta iHni nOi0Hi 3aXOAH;

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3. IPOOH Maze HaaBaTH oromory aOo Oe3nocepeAHbo YpD.y,

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TaX0 npo 3MiHH Y CTaTyCi Ta8HX OCiO.

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3nijRCHeHH nDoneTiB

1. YpRA 3aJIHmaCTbCql Bi1JIOBi~anIHMd 3a CB0! nIpOORTH

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United Nations - Treaty Series o Nations Unies - Recueil des Traitks

7 ='-.aRcooL 3a aarzg 3a yqacTm B<oHaBwoi YCTaHOBH ypean13al:i npoeXTy Ha piBHi noro P03PO6xeHHR. BiH 3 IRCHmeHarnRA Ta KOOPAHHY6 A-,-. iCTb excInePTIB Ta iHmlmcCnIiBp0 iTHHKiB BXHKOHaBIO! YCTaHOBH i BilnOBZIae 3a ni IrOTOBKyHa KICIi AeP'E£ABHHX CniBpO0iTHHIKiB, npK3HaeHHX YPRAOM. BiHHece B i/fOB i±a.bH iCTb 3a xep iBHUTBO i eVeKTHBHe BHXODKCTaHHRBoiX BxnaAeHb, uO IDiHaHCY~rT bC. rIPOOH, BExl]0magqH YCTaTYBaHH5I,nOCTaBjIeHe 3r iHO 3 npoexTom.

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8. naTeHTHi npaBa, aBTOPCb~i npaBa Ta iHMi aajIoritHi

nDEBa Ha Oyb-RKi BiARPHKTTR MR POOOTy, Rmi BEHEKJIH Bpe3ylrbTaTi oe3nocepeAIHbol AonOMorm, a1O Ha~aCTbCR UPOOH 3ri/HO

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CTaTTR IV

IHODMniji mono nooeKTi

1. YPRAi Hajae IIP00H Taxi BiUInOBiHi OnOBii, xaPTH,oyxranTepcbx i Bi OMOCTi, 3anHCH, 3aRBH, AOxyMeHTH Ta iHmy

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Z. [IP00H 30OB 'sR3YCTbCR nOCTiiHO iHPOPMyBaTH YDRAf npoCBO 3aXOA.M 3 Ha~JaHHR AOIXOMOFH. MO BKBrDTbCR 3riAHO 3 AiCe

Yro00. KoxHa 3 CTOP1H Mac npaBo B 6yAb-RxxH Miac 3AifCHOBaTE

HariRA 3a CTaHOM peani3agir! poeXTiB. uzO Cy6CELUyuTCR IIPOOH.

3. Ilicnn 3aBepmeHHR npoeXTy, no RxOMy HanaJanacb AonomoraUPOOH, YP D Hanac IPOH, Ha i! !nDOXaHHR, iH0OpMaxio npoIOPRCTb BlA )IorO ripOeXTY i npo 3aXOAH moAO no~anbmoro goro

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noAaqi Taxoro InPOXaHHR.

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1. Ha BHXOHaHHR CBorO 3ooB'R3aHH;l opaTH y'laCTb Ta

CniBnp a3BaTH y peani3axi! npoeTiB, 9O Cy0CH UVITbCR flP00H

Vol. 1845, 1-31452


3riAHo 3 ixieD Yroxo,. YPRA HaJ~ac nepeniqeHi HHx4e 3aco0H, RxifleTanbHO BH3HaqeHi B npoeXTHila JoxyMeHTaii! :

a) nocnyrH MiCueBHX Koner-DaxiBIILB Ta iHmi noCiyrfH,

BKIvqa DqHl nOCiyrn AePDaBHHX yCTaHOB TeXHiqHHM eKcnepTaM;

6) 3emeflbHi AinRHIH, OY~iBJ3i, KxafpOBy ti .POTOBXY Ta iHmi3aC0OH, IKi c B HaRIBHOCTi a00 BHpO6JISIRrbcR B KpalIH, a

B) oo naAHaHHR, MaTepianH i IlpeXMeTH flOCTaqaHHRl, RK i 6 BHaRBHOCTi MH BHPO JIRgrrbCR B HpalHi.

Z. B yc ix BmInajaX, KOnIH HaaHHR 0OfiaHaHHa e MaCTHHHIDAonoMorH riPooH YP4AY, OCTaHHig BiA KO3OBYC MHTHi BTPaTH, RHi

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OIKAxeTiB. Ta i CyME3 i iinraIrb KOPHrYBaHH0 Y BHnaIAIaX, KOIH 6

Vol. 1845. 1-31452


HeoxiAHiCTb BiA0OPa3HTH 0aKTH'qHY BapTiCTb OyA-RHoro 3 Tamax

3aco~iB, npuAaHHX ni3Hime.

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YMOBaMH yxnaxeoro 3 HEM KOHTPaKTY, YPRA Oepe y'aCTb y B~nIaTI

Vol. 1845, 1-31452


BiZ.O BiAHO! KoMIIeHCaI il B TOMY 06CR3 i, RKHR 3BHqanHO

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Kpa! HH.

Vol. 1845, 1-31452

1995 United Nations - Treaty Series a Nations Unies - Recueil des Traits 27

b. YDf mae npBo mafa. -H Be3aIameHi B nYHKT i 4noCJUyrz HaTYOD, 3a BKHRITKOM fi IYHKTiB (0) Ta (A).

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00'WHaHHx HaIifl.

Vol 1845, 1-31452


Z. YPRI. 3aCTOCOBYC y BiAHOmeHHi A0 0yJ1b-RHK0Y

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Cnegiani3oBaHOT YCTaHOBH 00H ao MArATE.

Vol. 1845. 1-31452


b. BHpa3 4goco6u, Rci HROHYDTb CIW6OBi O6OB'R31(!, IR0

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BHBe3eHHR :

Vol. 1845, 1-31452

30 United Nations - Treaty Series * Nations Unies - Recueil des Traits 1995

Z) OYJb-sIi O3BOIH, He0oxiJJ.i J nn BBe3eHHR ManHa, Rxie

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Vol. 1845, 1-31452


3. IIOnOzeHHR IZiC! CTaTTi He 3arlepenyuqrb HiRKHX iwmux npaaMH 3acoeiB Bfl)HBy, Rlx moze CXOPHCTaTHCb fIPOOH PHD BXa3aHzX

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United Nations - Treaty Series 9 Nations Unies - Recueil des Traitks

[TRADUCTION - TRANSLATION]

ACCORD' ENTRE LE GOUVERNEMENT DE L'UKRAINE ET LEPROGRAMME DES NATIONS UNIES POUR LE DEVELOP-PEMENT

Consid6rant que l'Assembl~e g6n6rale des Nations Unies a 6tabli le Programmedes Nations Unies pour le d6veloppement (ci-apr~s d6nomm6 le PNUD) afin d'ap-puyer et de compldter les efforts que les pays b6n6ficiaires d6ploient sur le plannational pour r6soudre les probl~mes les plus importants de leur d6veloppement6conomique, de favoriser le progres social et d'instaurer de meilleures conditions devie; et

Consid6rant que le Gouvernement de l'Ukraine (ci-apr~s d6nomm6 le Gou-vernement) souhaite demander l'assistance du PNUD dans l'int6r& de son peuple;

Le Gouvernement et le PNUD (ci-apr~s d6nomm6s les Parties) ont conclu lepr6sent Accord dans un esprit d'amicale coop6ration.

Article premier

CHAMP D'APPLICATION DE L'ACcORD

1. Le pr6sent Accord 6nonce les conditions de base dans lesquelles le PNUDet ses agents d'ex6cution aideront le Gouvernement A mener A bien ses projets ded6veloppement, et dans lesquelles lesdits projets bdn6ficiant de l'assistance duPNUD seront ex6cut6s. L'Accord vise l'ensemble de I'assistance que le PNUDfournit A ce titre, ainsi que les descriptifs de projets et autres instruments (ci-aprisd6nomm6s les descriptifs de projets) que les Parties pourront mettre au point d'uncommun accord pour ddfinir plus pr6cisdment les modalit6s de cette assistance et lesresponsabilit6s incombant respectivement aux Parties et A l'agent d'exdcution auregard desdits projets dans le cadre du pr6sent Accord.

2. Le PNUD fournira une assistance au titre du pr6sent Accord exclusivementsur la base de demandes pr6sent6es par le Gouvernement et approuv6es par lePNUD. Cette assistance sera mise A la disposition du Gouvernement ou de touteentitd 6ventuellement d6sign6e par lui, elle sera r6gie, tant pour ce qui est de safourniture que de son utilisation, par les resolutions et d6cisions pertinentes desorganes comp6tents du PNUD, et elle s'entend sous r6serve que ce demier disposedes fonds n6cessaires.

Article II

FORMES DE L'ASSISTANCE

1. L'assistance 6ventuellement apport6e au Gouvernement par le PNUD envertu du pr6sent Accord pourra notamment prendre les formes suivantes:

I Entrd en vigueur le 18juin 1993 par la signature, conform~ment au paragraphe 2 de l'article XIII.

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a) Services d'experts-conseils et de consultants - firmes et organismes deconsultants compris - ddsignds par le PNUD ou par l'agent d'ex~cution et respon-sables devant eux;

b) Services d'experts opdrationnels choisis par l'agent d'ex6cution pour exer-cer des fonctions d'ex6cution, de direction ou d'administration en tant que fonc-tionnaires du Gouvernement ou employ6s des entit6s 6ventuellement d6sign6es parcelui-ci conform6ment au paragraphe 2 de l'article premier;

c) Services de Volontaires des Nations Unies (ci-apr~s d6nomm6s les volon-taires);

d) Mat6riel et fournitures difficiles A se procurer en Ukraine (ci-apr~s d6nom-m6e le pays);

e) S6minaires, programmes de formation, projets de d6monstration, groupes detravail d'experts et activit6s connexes;

f) Bourses d'6tudes et de perfectionnement ou arrangements similaires per-mettant A des candidats d~sign6s par le Gouvernement et agr66s par 1'agent d'ex6cu-tion d'dtudier ou de recevoir une formation professionnelle; et

g) Toute autre forme d'assistance dont le Gouvernement et le PNUD pourrontconvenir.

2. Le Gouvernement pr6sentera ses demandes d'assistance au PNUD parl'interm6diaire du repr6sentant r6sident du PNUD dans le pays (voir alin6a a duparagraphe 4 ci-apris) sous la forme et suivant les proc~dures d6finies par le PNUD.11 fournira au PNUD toutes les facilit6s et toutes les informations voulues pourl'6valuation des demandes, en lui indiquant notamment ses intentions quant au suivides projets d'investissements.

3. Le PNUD pourra fournir son assistance au Gouvernement soit directementavec les concours ext6rieurs qu'il jugera appropri6s, soit par l'interm~diaire d'unagent d'ex&cution qui sera principalement responsable de la mise en ceuvre de l'as-sistance du PNUD pour le projet et aura, A cette fin, le statut d'entrepreneur ind6-pendant. Lorsque le PNUD fournira directement une assistance au Gouvernement,l'expression « agent d'ex6cution , telle qu'elle est utilis6e dans le pr6sent Accord,s'entendra du PNUD, A moins que le contexte ne s'y oppose manifestement.

4. a) Le PNUD pourra 6tablir dans le pays une mission permanente, dirig6epar un repr6sentant r6sident, pour le representer sur place et servir de principalagent de liaison avec le Gouvernement pour toutes les questions relatives au Pro-gramme. Le repr6sentant r6sident sera responsable au nom de l'Administrateur duPNUD, pleinement et en dernier ressort, de tous les aspects du programme duPNUD dans le pays et assumera les fonctions de chef d'6quipe A l'6gard des repr6-sentants d'autres organismes des Nations Unies en poste dans le pays, compte tenude leurs qualifications professionnelles et de leurs relations avec les organes com-p6tents du Gouvernement. Le repr6sentant resident assurera au nom du Programmela liaison avec les organes gouvernementaux int~ress6s, y compris l'organisme gou-vernemental charg6 de coordonner l'assistance ext6rieure, et il informera le Gou-vernement des principes, crit~res et proc6dures du PNUD et des autres programmespertinents des Nations Unies. I1 aidera le Gouvernement, le cas 6ch6ant, h 6tablir lesdemandes de programmes et de projets A rdaliser dans le pays ainsi que les proposi-tions de modification desdits programmes ou projets; il assurera comme il convientla coordination de l'ensemble de l'assistance que le PNUD fournira par l'inter-

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mddiaire de divers agents d'ex6cution ou de ses propres consultants; il aidera leGouvernement, le cas 6ch6ant, A coordonner les activit6s du PNUD avec les pro-grammes nationaux, bilat6raux et multilat6raux r6alis6s dans le pays et il remplira,en consultation avec le Gouvernement, toutes les autres fonctions que l'Adminis-trateur ou un agent d'ex6cution pourront lui confier.

b) La mission du PNUD dans le pays sera dotde du personnel additionnel quele PNUD jugera utile pour en assurer le bon fonctionnement. Le PNUD fera con-naitre au Gouvernement, de temps A autre, les noms des membres du personnelde la mission et des membres de leur famille, ainsi que toute modification de leursituation.

Article III

EXItCUTION DES PROJETS

1. Le Gouvemement demeurera responsable de ceux de ses projets de d6ve-loppement qui b6n6ficient de l'assistance du PNUD et de la r6alisation de leursobjectifs tels qu'ils seront d6crits dans les descriptifs de projets, et il ex6cutera lesparties de ces projets qui seront sp6cifi6es dans le pr6sent Accord et dans lesditsdescriptifs. Le PNUD s'engage a appuyer et compl6ter la participation du Gou-vernement A ces projets en lui fournissant une assistance conform6ment au pr6sentAccord et aux plans de travail contenus dans les descriptifs de projets et en l'aidantA r6aliser ses intentions quant A la suite donner aux investissements. Le Gouverne-ment indiquera au PNUD quel est l'organisme coop6rateur du Gouvernement direc-tement responsable de la participation du Gouvernement dans chacun des projetsb6n6ficiant de l'assistance du PNUD. Sans pr6judice de la responsabilit6 g6n6raledu Gouvernement A l'6gard de ses projets, les Parties pourront convenir qu'un agentd'ex6cution sera responsable au premier chef de l'ex6cution d'un projet, en consul-tation et en accord avec l'organisme coop6rateur, tous les arrangements A cet effet6tant stipul6s dans le plan de travail contenu dans le descriptif du projet, ainsi quetous les arrangements pr6vus, le cas 6ch6ant, pour d6l6guer cette responsabilit6, aucours de l'ex6cution du projet, au Gouvernement ou A une entit6 d6sign6e par lui.

2. Le PNUD et l'agent d'ex6cution ne seront tenus de s'acquitter des res-ponsabilit6s qui leur incombent dans le cadre d'un projet donn6 qu'A condition quele Gouvernement ait lui-meme rempli toutes les obligations pr6alables jug6es d'uncommun accord n6cessaires ou utiles pour l'assistance du PNUD audit projet. Sicette assistance commence A &re fournie avant que le Gouvernement ait rempli cesobligations pr6alables, elle pourra tre arrt6e ou suspendue sans pr6avis au Gou-vernement et A la discrdtion du PNUD.

3. Tout accord conclu entre le Gouvernement et un agent d'ex6cution au sujetde l'ex6cution d'un projet b6n6ficiant de l'assistance du PNUD ou entre le Gou-vernement et un expert op6rationnel sera subordonn6 aux dispositions du pr6sentAccord.

4. L'organisme coop6rateur affectera A chaque projet, selon qu'il conviendraet en consultation avec l'agent d'ex6cution, un directeur A plein temps qui s'acquit-tera des tdches que lui confiera l'organisme coop6rateur. L'agent d'ex6cution d6si-gnera, selon qu'il conviendra et en consultation avec le Gouvernement, un conseillertechnique principal ou un coordonnateur de projet qui supervisera sur place la par-ticipation de l'agent d'ex6cution audit projet et sera responsable devant lui. Cette

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United Nations - Treaty Series * Nations Unies - Recuei des Traitks

personne supervisera et coordonnera les activit6s des experts et des autres membresdu personnel de i'agent d'ex6cution et sera responsable de la formation en coursd'emploi du personnel national de contrepartie. Elle sera responsable de la gestionet de l'utilisation efficace de tous les 616ments financ6s par le PNUD, y compris dumatdriel fourni au titre du projet.

5. Dans 1'exercice de leurs fonctions, les experts-conseils, les consultants etles volontaires agiront en consultation 6troite avec le Gouvernement et avec lespersonnes ou organismes d6sign6s par celui-ci, et ils se conformeront aux directivesdu Gouvernement qui pourront 6tre applicables, eu 6gard A la nature de leurs fonc-tions et de l'assistance A fournir et dont le PNUD, l'agent d'ex6cution et le Gouver-nement pourront convenir d'un commun accord. Les experts op6rationnels serontuniquement responsables devant le Gouvernement ou l'entitd A laquelle ils serontaffect6s et ils en rel~veront exclusivement, mais ils ne seront pas tenus d'exercer desfonctions incompatibles avec leur statut international ou avec les buts du PNUD oude l'agent d'ex6cution. Le Gouvernement s'engage A faire concider la date d'entrdeen fonctions de chaque expert op6rationnel avec la date d'entr6e en vigueur de soncontrat avec l'agent d'ex6cution.

6. L'agent d'exdcution s6lectionnera les boursiers. L'administration desbourses s'effectuera conform6ment aux principes et pratiques de l'agent d'ex6cu-tion dans ce domaine.

7. Le PNUD restera propri6taire du mat6riel technique et autre, ainsi que desapprovisionnements, fournitures et autres biens financ6s ou fournis par lui, A moinsqu'ils ne soient c6d6s au Gouvernement ou A une entit6 d6signde par celui-ci, selondes modalit6s et A des conditions fix6es d'un commun accord par le Gouvernementet le PNUD.

8. Le PNUD restera propridtaire des brevets, droits d'auteur, droits de repro-duction et autres droits de m~me nature sur les d6couvertes ou travaux r6sultant del'assistance directe qu'il fournira au titre du pr6sent Accord. A moins que les Partiesn'en d6cident autrement dans chaque cas, le Gouvernement pourra toutefois utiliserces d6couvertes ou ces travaux dans le pays sans avoir A payer de redevances ouautres droits analogues.

Article IV

RENSEIGNEMENTS RELATIFS AUX PROJETS

1. Le Gouvernement fournira au PNUD tous les rapports, cartes, comptes,livres, 6tats, documents et autres renseignements pertinents que ce dernier pourralui demander concernant tout projet b6n6ficiant de l'assistance du PNUD ou sonex6cution, ou montrant qu'il demeure r6alisable et judicieux ou que le Gouverne-ment s'acquitte des responsabilit6s qui lui incombent en vertu du pr6sent Accord oudes descriptifs de projets.

2. Le PNUD s'engage A faire en sorte que le Gouvernement soit tenu au cou-rant des progr~s de ses activit6s d'assistance en vertu du pr6sent Accord. Chacunedes Parties aura le droit, A tout moment, d'observer l'6tat d'avancement des op6ra-tions entreprises dans le cadre des projets b6n6ficiant de l'assistance du PNUD.

3. Apr~s 1'ach~vement d'un projet b6n6ficiant de 'aide du PNUD, le Gou-vernement fournira au PNUD, sur sa demande, des renseignements sur les avan-

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1995


tages qui en r~sultent et sur les activitds entreprises pour atteindre les objectifs duprojet, notamment les renseignements n~cessaires ou utiles pour 6valuer le projet ouI'assistance du PNUD et, A cette fin, il consultera le PNUD et l'autorisera A observerla situation.

4. Tout renseignement ou document que le Gouvernement est tenu de fournirau PNUD en vertu du prdsent article sera 6galement communiqu6 A l'agent d'exdcu-tion si celui-ci en fait la demande.

5. Les Parties se consulteront au sujet de la publication, selon qu'il convien-dra, des renseignements relatifs aux projets brn6ficiant de l'assistance du PNUD ouaux avantages qui en rdsultent. Toutefois, s'il s'agit de projets orientds vers l'inves-tissement, le PNUD pourra communiquer les renseignements y relatifs A des inves-tisseurs 6ventuels, A moins que le Gouvernement ne lui demande, par 6crit, de limiterla publication de renseignements sur lesdits projets.

Article V

PARTICIPATION ET CONTRIBUTION DU GOUVERNEMENT

A L'EX12CUTION DES PROJETS

1. Pour s'acquitter de ses responsabilitds en ce qui concerne sa participationet sa contribution A l'exdcution des projets brnrficiant de l'assistance du PNUD envertu du present Accord, le Gouvernement fournira i titre de contribution en nature,et dans la mesure oii cela sera sprcifi6 en ddtail dans les descriptifs de projets per-tinents :

a) Les services de sprcialistes locaux et autre personnel de contrepartie,notamment les homologues nationaux des experts opdrationnels;

b) Les terrains, les bqtiments, les moyens de formation et autres installationset services qui existent dans le pays ou qui y sont produits;

c) Le materiel, les approvisionnements et les fournitures qui existent dans lepays ou qui y sont produits.

2. Chaque fois que l'assistance du PNUD prdvoit la fourniture de materiel auGouvernement, ce dernier prendra A sa charge les frais de drdouanement de cemateriel, les frais de transport du port d'entrre jusqu'au lieu d'exdcution du projet,les ddpenses imprrvues de manipulation ou d'entreposage et autres drpenses con-nexes ainsi que les frais d'assurance apr~s livraison sur le lieu d'exrcution du projetet les frais d'installation et d'entretien.

3. Le Gouvernement prendra 6galement A sa charge la rrmunrration des sta-giaires et des boursiers pendant la durde de leur bourse.

4. Le Gouvernement versera ou fera verser au PNUD ou A un agent d'exrcu-tion, si des dispositions en ce sens figurent dans le descriptif du projet et dans lamesure fixde dans le budget du projet contenu dans ledit descriptif, les sommesrequises pour couvrir le coot de Fun quelconque des biens et services 6numdrds auparagraphe 1 du prdsent article; l'agent d'exdcution se procurera alors les biens etservices ndcessaires et rendra compte chaque annre au PNUD de toutes ddpensescouvertes par prrl~vement sur les sommes versres en application de la prrsentedisposition.

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1995 United Nations - Treaty Series * Nations Unies - Recueil des Trait6s 39

5. Les sommes payables au PNUD en vertu du paragraphe prdc6dent serontd6pos6es a un compte qui sera d6sign6 A cet effet par le Secr6taire g6n6ral de l'Or-ganisation des Nations Unies et g6r6 conform6ment aux dispositions pertinentes dur~glement financier du PNUD.

6. Le coot des biens et services qui constituent la contribution du Gouverne-ment aux projets et toute somme payable par lui en vertu du pr6sent article, telsqu'ils sont indiqu6s en d6tail dans les budgets des projets, seront consid6r6s commedes estimations fond6es sur les renseignements les plus conformes A la rdalit6 donton disposera lors de l'6tablissement desdits budgets. Ces montants feront l'objetd'ajustements chaque fois que cela s'av6rera n6cessaire, compte tenu du coot effec-tif des biens et services achet6s par la suite.

7. Le Gouvernement disposera, selon qu'il conviendra, sur les lieux d'ex6cu-tion de chaque projet, des 6criteaux appropries indiquant qu'il s'agit d'un projetb6n6ficiant de l'assistance du PNUD et de l'agent d'ex6cution.

Article VI

CONTRIBUTION STATUTAIRE AUX DIPENSES DU PROGRAMMEET AUTRES FRAIS PAYABLES EN MONNAIE LOCALE

1. Outre la contribution vis6e A l'article V ci-dessus, le Gouvernement aiderale PNUD i lui fournir son assistance en payant ou en faisant payer les d6penseslocales et les services ci-apris, jusqu'A concurrence des montants indiqu6s dans ledescriptif du projet ou fix6s par ailleurs par le PNUD conform6ment aux d6cisionspertinentes de ses organes directeurs :

a) Les frais locaux de subsistance des experts-conseils et des consultantsaffect6s aux projets dans le pays;

b) Les services de personnel administratif et de personnel de bureau local, ycompris le personnel de secr6tariat, les interpr~tes-traducteurs et autres auxiliairesanalogues dont les services seront n6cessaires;

c) Le transport du personnel A l'int6rieur du pays; et

d) Les services postaux et de t6l6communications n6cessaires A des fins offi-cielles.

2. Le Gouvernement versera aussi directement A chaque expert op6rationnelle traitement, les indemnit6s et autres 616ments de r6mun6ration que recevrait l'unde ses ressortissants s'il 6tait nomm6 au meme poste. I1 lui accordera les mamescong6s annuels et cong6s de maladie que ceux accord6s par l'agent d'ex6cution Ason propre personnel et il prendra les dispositions n6cessaires pour qu'il puisseprendre le cong6 dans les foyers auquel il a droit en vertu du contrat qu'il a pass6avec l'agent d'ex6cution int6ress6. Si le Gouvernement prend l'initiative de mettrefin A l'engagement de l'expert dans des circonstances telles que l'agent d'ex6cutionsoit tenu de lui verser une indemnit6 en vertu du contrat qu'il a pass6 avec lui, leGouvernement versera, A titre de contribution au r~glement de cette indemnit6, unesomme 6gale au montant de l'indemnit6 de licenciement qu'il devrait verser A un deses fonctionnaires ou autres personnes employ6es par lui A titre analogue auxquelsl'int6ress6 est assimil6 quant au rang, s'il mettait fin A leurs services dans les memescirconstances.

Vol. 1845, 1-31452


3. Le Gouvernement s'engage A fournir, A titre de contribution en nature, lesinstallations et services locaux suivants :

a) Les bureaux et autres locaux n6cessaires;

b) Des facilitds et services mddicaux pour le personnel international compara-bles A ceux dont disposent les fonctionnaires nationaux;

c) Des logements simples mais ad6quatement meubl6s pour le personnel inter-national et la fourniture de logements appropri6s aux experts op6rationnels, dansdes conditions semblables A celles dont b6n6ficient les fonctionnaires nationauxauxquels les int6ress6s sont assimilds quant au rang.

4. Le Gouvernement contribuera 6galement aux d6penses d'entretien de lamission du PNUD dans le pays en versant tous les ans au PNUD une somme globaledont le montant sera fix6 d'un commun accord par les Parties, afin de couvrir lesfrais correspondant aux postes de d6penses ci-apr~s :

a) Bureaux appropri6s, y compris le mat6riel et les fournitures, pour le siegelocal du PNUD dans le pays;

b) Personnel local appropri6: secr6taires et commis, interpr~tes, traducteurs etautres auxiliaires;

c) Moyens de transport pour le repr6sentant r6sident et ses collaborateurslorsque ceux-ci, dans l'exercice de leurs fonctions, se d6placeront A l'int6rieur dupays;

d) Services postaux et de t lcommunications n6cessaires A des fins officielles;et

e) Indemnit6 de subsistance du repr6sentant rdsident et de ses collaborateurslorsque ceux-ci, dans l'exercice de leurs fonctions, se d6placeront A l'int6rieur dupays.

5. Le Gouvernement aura la facult6 de foumir en nature les installations etservices mentionnds au paragraphe 4 ci-dessus, A l'exception de ceux vis6s auxalin6as b et e.

6. Les sommes payables en vertu des dispositions du prdsent article, Al'exception du paragraphe 2, seront vers6es par le Gouvernement et g6rdes par lePNUD conform6ment au paragraphe 5 de l'article V.

Article VII

RAPPORT ENTRE L'ASSISTANCE DU PNUD ET L'ASSISTANCEPROVENANT D'AUTRES SOURCES

Au cas oa l'une d'elles obtiendrait, en vue de l'ex6cution d'un projet, une assis-tance provenant d'autres sources, les Parties se consulteront entre elles et consul-teront l'agent d'ex6cution afin d'assurer une coordination et une utilisation efficacesde l'ensemble de l'assistance revue par le Gouvernement. Les arrangements quipourraient 8tre conclus avec d'autres entit6s pretant leur concours au Gouverne-ment pour l'ex6cution d'un projet ne modifieront pas les obligations qui incombentaudit gouvernement en vertu du pr6sent Accord.

Vol. 1845. 1-31452


Article VIII

UTILISATION DE L'ASSISTANCE FOURNIE

Le Gouvernement ne m6nagera aucun effort pour tirer le meilleur parti possiblede l'assistance du PNUD, qu'il devra utiliser aux fins pr6vues. Sans limiter la port6eg6n6rale de ce qui pr6c~de, le Gouvernement prendra A cette fin les mesures indi-qu6es dans le descriptif du projet.

Article IX

PRIVILEGES ET IMMUNITIS

1. Le Gouvernement appliquera A 1'Organisation des Nations Unies et A sesorganes, y compris le PNUD et les organes subsidiaires de l'Organisation des Na-tions Unies faisant fonction d'agents d'ex6cution de projets du PNUD ainsi qu'Aleurs biens, fonds et avoirs et A leurs fonctionnaires, y compris le repr6sentant r6si-dent et les autres membres de la mission du PNUD dans le pays, les dispositions dela Convention sur les privileges et immunit6s des Nations Unies'.

2. Le Gouvemement appliquera A toute institution sp6cialis6e faisant fonctiond'agent d'ex6cution, ainsi qu'A ses biens, fonds et avoirs et A ses fonctionnaires, lesdispositions de la Convention sur les privileges et immunit6s des institutions sp6cia-lis6es 2, y compris celles de toute annexe A la Convention applicable A ladite institu-tion sp6cialis6e. Si l'Agence internationale de l'6nergie atomique (ALEA) fait fonc-tion d'agent d'ex6cution, le Gouvernement appliquera A ses fonds, biens et avoirs,ainsi qu'A ses fonctionnaires et experts, les dispositions de l'Accord relatif auxprivileges et immunit6s de I'AIEA3.

3. Les membres de la mission du PNUD dans le pays b6n6ficieront de tous lesautres privilges et immunit6s qui pourront tre n6cessaires pour permettre A lamission de remplir efficacement ses fonctions.

4. a) A moins que les Parties n'en d6cident autrement dans les descriptifs deprojets relatifs A des projets particuliers, le Gouvernement accordera A toutes lespersonnes, autres que les ressortissants du pays employ6s sur le plan local, fournis-sant des services pour le compte du PNUD, d'une institution sp6cialis6e ou deI'AIEA et qui ne sont pas vis6es aux paragraphes 1 et 2 ci-dessus, les m~mes pri-vileges et immunit6s que ceux auxquels ont droit les fonctionnaires de l'Organisa-tion des Nations Unies, de l'institution sp6cialis6e int6ress6e ou de I'AIEA en vertude la section 18 de la Convention sur les privileges et immunit6s des Nations Unies,de la section 19 de la Convention sur les privilges et immunit6s des institutionssp6cialis6es ou de la section 18 de l'Accord relatif aux privileges et immunit6s deI'AIEA, respectivement.

b) Aux fins des instruments sur les privileges et immunit6s qui sont mentionn6sci-dessus dans le pr6sent article :

I Nations Unies, Recuei des Trait~s, vol. 1, p. 15.2 Ibid., vol. 33, p. 261. Pour les textes finals et r6visds des annexes publi6es ult6rieurement, voir vol. 71, p. 319;

vol. 79, p. 326; vol. 117, p. 386; vol. 275, p. 299; vol. 314, p. 309; vol. 323, p. 365; vol. 327, p. 327; vol. 371, p. 267; vol. 423,p. 285; vol. 559, p. 349; vol. 645, p. 341; vol. 1057, p. 322 et vol. 1060, p. 337.

3 Ibid., vol. 374, p. 147.Vol. 1845, 1-31452


1) Tous les papiers et documents relatifs A un projet qui sont en possession ou sousle contr6le des personnes vis6es A l'alinda a du paragraphe 4 ci-dessus serontconsiddrds comme la propridt6 de l'Organisation des Nations Unies, de l'insti-tution sp6cialis6e int6ress6e ou de I'AIEA, selon le cas; et

2) Le matdriel, les approvisionnements et les fournitures import6s, achetds oulou6s par ces personnes dans le pays aux fins d'un projet seront consid6rdscomme la propri6t6 de l'Organisation des Nations Unies, de l'institution sp6cia-lisde int6ress6e ou de I'AIEA, selon le cas.

5. L'expression «< personnes fournissant des services telle qu'elle est uti-lisde dans les articles IX, X et XIII du pr6sent Accord vise les experts op6rationnels,les volontaires, les consultants et les personnes juridiques et physiques ainsi queleurs employ6s. Elle vise les organisations ou soci6tds gouvernementales ou nongouvernementales auxquelles le PNUD peut faire appel en tant qu'agent d'ex6cu-tion ou A tout autre titre, pour ex6cuter un projet ou aider A mettre en euvre l'assis-tance du PNUD A un projet, ainsi que leurs employ6s. Aucune disposition du prdsentAccord ne sera interpr6t6e comme limitant les privilges, immunitds ou facilit6saccord6s A ces organisations ou socidt6s ou h leurs employds en vertu d'un autreinstrument.

Article X

FACILITIS ACCORD9ES AUX FINS DE LA MISE EN CEUVREDE L'ASSISTANCE DU PNUD

1. Le Gouvernement prendra toutes les mesures qui pourront 8tre n6cessairespour que le PNUD, ses agents d'ex6cution, leurs experts et les autres personnesfournissant des services pour leur compte, ne soient pas soumis A des r~glements ouautres dispositions juridiques qui pourraient gener 1'ex6cution d'op6rations entre-prises en vertu du pr6sent Accord, et leur accordera toutes les autres facilit6s n6ces-saires A la mise en oeuvre rapide et satisfaisante de l'assistance du PNUD. Il leuraccordera notamment les droits et facilit6s ci-apr~s :

a) Admission rapide des experts et autres personnes fournissant des servicespour le compte du PNUD ou d'un agent d'ex6cution;

b) D61ivrance rapide et gratuite des visas, permis et autorisations n6cessaires;

c) Accs aux lieux d'ex6cution des projets et tous droits de passage neces-saires;

d) Droit de circuler librement A l'int6rieur du pays, d'y entrer ou d'en sortir,dans la mesure n6cessaire A la mise en ceuvre satisfaisante de l'assistance du PNUD;

e) Taux de change 16gal le plus favorable;

f) Toutes autorisations n6cessaires A b'importation de mat6riel, d'approvision-nements et de fournitures ainsi qu'A leur exportation ult6rieure;

g) Toutes autorisations n6cessaires h i'importation de biens appartenant auxfonctionnaires du PNUD et de ses agents d'ex6cution ou A d'autres personnes four-nissant des services pour leur compte, et destin6s A la consommation ou A 'usagepersonnel des int6ress6s, ainsi que toutes autorisations n6cessaires A l'exportationult6rieure de ces biens; et

h) D6douanement rapide des biens mentionn6s aux alin6asfet g ci-dessus.Vol. 1845, 1-31452


2. L'assistance fournie en vertu du prdsent Accord devant servir les intdr~tsdu Gouvernement et du peuple de l'Ukraine, le Gouvernement supportera tous lesrisques des opdrations ex6cut6es en vertu du pr6sent Accord. II devra r6pondre Atoutes r6clamations que des tiers pourraient pr6senter contre le PNUD ou contre unagent d'ex6cution, ou leur personnel, ou contre d'autres personnes fournissant desservices pour leur compte, et il les mettra hors de cause en cas de r6clamation et lesd6gagera de toute responsabilit6 r6sultant d'opdrations ex6cut6es en vertu du pr6-sent Accord. Les dispositions qui pr6c~dent ne s'appliqueront pas si les Partieset l'agent d'ex6cution conviennent que ladite r6clamation ou ladite responsabilitdr6sultent d'une n6gligence grave ou d'une faute intentionnelle des int6ress6s.

Article XI

SUSPENSION OU FIN DE L'ASSISTANCE

1. Le PNUD pourra, par voie de notification 6crite adress6e au Gouverne-ment et [ l'agent d'ex6cution, suspendre son assistance A un projet si, de l'avis duPNUD, des circonstances se pr6sentent qui g~nent ou menacent de gener la bonneex6cution du projet ou ]a r6alisation de ses fins. Le PNUD pourra, dans la mamenotification 6crite ou dans une notification ult6rieure, indiquer les conditions danslesquelles il serait dispos6 A reprendre son assistance au projet. Cette suspensionpourra se poursuivre jusqu'A ce que le Gouvernement ait accept6 ces conditions etque le PNUD ait notifi6 par 6crit le Gouvernement et l'agent d'ex6cution qu'il estdispose A reprendre son assistance.

2. Si une situation du type vis6 au paragraphe 1 du pr6sent article se poursuitpendant 14 jours apr~s que le PNUD a notifi6 cette situation et la suspension de sonassistance au Gouvernement et A 'agent d'ex6cution, le PNUD pourra A tout mo-ment, tant que cette situation se poursuivra, mettre fin A son assistance au projet parvoie de notification 6crite au Gouvernement et l'agent d'ex6cution.

3. Les dispositions du pr6sent article ne pr6jugent pas de tous autres droits ourecours dont le PNUD pourrait se pr6valoir en l'occurrence, selon les principesg6n6raux du droit ou 1 d'autres titres.

Article XII

REGLEMENT DES DIFF9RENDS

1. Tout diffdrend entre le PNUD et le Gouvernement auquel donnerait lieu lepr6sent Accord ou qui y aurait trait et qui ne pourrait etre r6g16 par voie de n6gocia-tion ou par un autre mode convenu de riglement sera soumis b l'arbitrage A lademande de l'une des Parties. Chacune des Parties d6signera un arbitre et les deuxarbitres ainsi d6sign6s en nommeront un troisieme, qui pr6sidera. Si, dans les30jours qui suivront la demande d'arbitrage, l'une des Parties n'a pas d6sign6d'arbitre ou si, dans les 15 jours qui suivront la nomination des deux arbitres, letroisi~me arbitre n'a pas t6 d6sign6, l'une des Parties pourra demander au Pr6sidentde la Cour internationale de Justice de ddsigner un arbitre. La proc6dure d'arbitragesera arret6e par les arbitres et les frais de 'arbitrage seront 'h la charge des Parties, iraison de la proportion fix6e par les arbitres. La sentence arbitrale sera motiv6e etsera accept6e par les Parties comme le r~glement dffinitif du diff6rend.

Vol. 1845, 1-31452


2. Tout diff6rend entre le Gouvernement et un expert op~rationnel auqueldonneraient lieu les conditions d'emploi de I'expert aupris du Gouvernement ou quiy aurait trait pourra &re soumis A l'agent d'ex6cution qui aura fourni les services de1'expert op6rationnel, soit par le Gouvernement, soit par 1'expert op6rationnel, etl'agent d'ex&cution int6ress6 usera de ses bons offices pour aider les Parties arriverA un r~glement. Si le diff6rend ne peut tre r6g16 conform6ment A la phrase pr6-c6dente ou par un autre mode convenu de r~glement, la question sera soumise Al'arbitrage At la demande de l'une des Parties, conform6ment aux dispositions 6non-c6es au paragraphe 1 du present article, si ce n'est que l'arbitre qui n'aura pas 6t6ddsign6 par l'une des Parties ou par les arbitres des Parties sera d6sign6 par lesecr6taire g6n6ral de la Cour permanente d'arbitrage.

Article XIII

DISPOSITIONS GENPERALES

1. Le pr6sent Accord fait partie int~grante de l'Accord entre l'Organisa-tion des Nations Unies et le Gouvernement de l'Ukraine relatif A rinstallation d'unBureau int6rimaire de l'Organisation des Nations Unies en Ukraine, qu'il complete.Etant donn6 que toutes les dispositions du pr6sent Accord et de l'Accord susmen-tionn6 ont le m~me objet, les deux instruments seront consid6r6s comme compl6-mentaires et seront applicables sans qu'aucun ne limite les effets de l'autre.

2. Le pr6sent Accord prendra effet d~s sa signature. I1 demeurera en vigueurtant qu'il n'aura pas 6t6 d6nonc6 conform6ment au paragraphe 3 ci-dessous. Lors deson entr6e en vigueur, il remplacera les accords existants en ce qui concerne l'assis-tance fournie au Gouvernement A l'aide des ressources du PNUD et le bureau duPNUD dans le pays; il s'appliquera A toute l'assistance fournie au Gouvernement etau bureau du PNUD cr6 en vertu des dispositions des accords dor6navant rem-plac6s.

3. Le pr6sent Accord pourra &re modifi6 par accord 6crit entre les Parties.Les questions non trait~es express6ment dans le pr6sent Accord seront r6gl6es parles Parties conform6ment aux r6solutions et d6cisions pertinentes des organes com-p6tents de l'Organisation des Nations Unies. Chacune des Parties examinera avecsoin et dans un esprit favorable toute proposition pr6sent~e par l'autre Partie enapplication du pr6sent paragraphe.

4. Le present Accord pourra 8tre d6nonc6 par rune ou l'autre des Parties parvoie de notification 6crite et il cessera de produire ses effets 60 jours apris la r6cep-tion de ladite notification.

5. Les obligations assum~es par les Parties en vertu des articles IV (Ren-seignements relatifs aux projets) et VIII (Utilisation de l'assistance fournie) sub-sisteront apr~s l'expiration ou la d6nonciation du present Accord. Les obligationsassum6es par le Gouvemement en vertu des articles IX (Privil~ges et immunit6s),X (Facilit6s accord6es aux fins de la mise en ceuvre de l'assistance du PNUD) etXII (R~glement des diff6rends) du pr6sent Accord subsisteront apras 1'expiration oula d6nonciation dudit Accord dans la mesure n&cessaire pour permettre de proc~derm6thodiquement au rapatriement du personnel, des fonds et des biens du PNUD etde tout agent d'ex6cution ou de toute personne foumissant des services pour leurcompte en vertu du pr6sent Accord.

Vol. 1845. 1-31452


EN FOI DE QUOI les soussign6s, repr6sentants dflment autoris6s du Gouverne-ment de l'Ukraine, d'une part, et du Programme des Nations Unies pour le d6velop-pement, d'autre part, ont, au nom des Parties, sign6 le pr6sent Accord en deuxexemplaires 6tablis en langues ukrainienne et anglaise, A Kiev, le 18 juin 1993.

Pour le Gouvernementde I'Ukraine:

ANATOLIY ZLENKO

Pour le Programe des Nations Uniespour le d6veloppement :

BOUTROS-BOUTRos GHALI

Vol. 1845, 1-31452

ANNEXA

Ratifications, accessions, subsequent agreements, etc.,

concerning treaties and international agreements

registered


ANNEXE A

Ratifications, adhisions, accords ultirieurs, etc.,

concernant des traitis et accords internationaux

enregistris



ANNEX A - ANNEXE A

No. 8940. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CAR-RIAGE OF DANGEROUS GOODS BY ROAD (ADR). DONE AT GENEVA, ON30 SEPTEMBER 1957'

ENTRY INTO FORCE of amendments to annexes A and B, as amended,2 to the above-mentioned Agreement

The amendments were proposed by the Government of France and circulated by theSecretary-General to the Contracting Parties on 30 June 1994. They came into force onI January 1995, in accordance with article 14 (3) of the Agreement.

Authentic texts of the amendments: English and French.

Registered ex officio on 1 January 1995.

(The authentic French text of the amendments appears in volume 1846 - Le texteauthentiquefrangais des amendements parait dans le volume 1846.)

The text of the amendments reads as follows:

United Nations, Treaty Series, vol. 619, p. 77; for subsequent actions, see references in Cumulative Indexes Nos. 9and II to 21, as well as annex A in volumes 1259, 1279, 1283, 1297, 1344, 1394, 1395, 1430, 1489, 1505, 1553, 1580, 1663,1679, 1696, 1701, 1719, 1723, 1724, 1732, 1775, 1777 and 1843.

2 Ibid., vol. 731, p. 3, and annex A in volumes 774, 828, 883, 907, 921, 922, 926, 951, 982, 987, 1003, 1023, 1035, 1074,1107, 1161, 1162, 1259, 1279, 1283, 1297, 1344, 1395, 1489, 1553, 1663 and 1701.

Vol. 1845, A-8940

United Nations - Treaty Series * Nations Unies - Recueil des Trait6s

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGEOF DANGEROUS GOODS BY ROAD (ADR)

WITH ANNEXES AND PROTOCOL OF SIGNATURE, DONE AT GENEVAON 30 SEPTEMBER 1957

Amendments proposed by the Government of France to Annexes A and B.as amended. to the above-mentioned Agreement

ANNEX A of ADR

TABLE OF CONTENTS

PART IT.

Amend the entry for Class 6.2 to read

"Class 6.2 Infectious substances ... 2650 et sea"

PART Ill.

Appendix A.]

Replace "flammable solids" with "nitrated mixtures of nitrocellulose,self-reactive substances"

Appendix A.3

Amend the title A as follows:

"A. Tests relating to flammable liquids of Classes 3, 6.1 and 8

(Test for determining flash-point,Test for determining peroxide content,Test for determining combustibility)"

Add:

"G. Tests for determining the ecotoxicity, persistence andbloaccumulation of substances in the aquatic environment for assignmentto Class 9."

Vol. 1845, A-8940

1995

United Nations - Treaty Series e Nations Unies - Recuei des Traitks

Part I. DEFINITIONS AND GENERAL PROVISIONS

2002 (1) Delete the following and add it to fourth sentence:

"6.2" and "2651".

(2) Amend the entry for Class 6.2 to read:

"Class 6.2 Infectious substances Non-restrictive"

2002(3)(a) Sixth subparagraph, amend as follows:

"the total quantity of dangerous goods (as a volume or as a grossmass or as a net mass and, in addition, in the case of explosivesubstances and articles of Class 1, as a total net mass ofexplosive contents).

NOTE 1: This information is not required in the case of uncleanedempty packagings, containers or tanks.

NOTE 2: In the case of the application of marginal 10 011, thequantities of dangerous goods carried per transport unit shall beexpressed as a gross mass".

(8) 1. Amend (a) to read as follows:

(a) A solution or mixture containing a dangerous substance listed byname in ADR together with one or more non-dangerous substances,shall be regarded as the dangerous substance listed by name,unless:

1. The solution or mixture is specifically listed by name

elsewhere in ADR;

or

2. It is quite clear from the item for the dangerous

substance that it is applicable only to the pure ortechnically pure substance; or

3. The class, physical state or packing group (letter), ofthe solution or mixture is different from that of thedangerous substance.

Vol. 1845, A-8940

United Nations - Treaty Series - Nations Unies - Recueil des Traitks

2002 (8) For such solutions and mixtures, the word "solution" or "mixture"(cont'd) shall then be added as part of the name in the transport document

for the purposes of clarity in the description, for example,"acetone solution".

If the class, physical state or packing group are different from

that for the pure substance, the solution or mixture shall beassigned to an appropriate n.o.s. entry, depending on the degree ofdanger.

2. Amend (b) 2.1 to read as follows:

"2.1 If there is no predominant danger, classification shall bebased on the following order of precedence:

substances and articles of Class I

substances and articles of Class 2

self-reactive and related substances and explosive substancesin non-explosive state (wetted or phlegmatized explosivesubstances) of Class 4.1

pyrophoric substances of Class 4.2

substances of Class 5.2

substances of Class 6.1 or Class 3 which, on the basis oftheir inhalation toxicity, are to be classified under letter(a) of the various items (excluding substances, solutions and

mixtures (such as preparations and wastes) meeting theclassification criteria of Class 8 and having an inhalationtoxicity of dust and mists (LC..) in the range of group (a)

and toxicity through oral ingestion or dermal contact only inthe range of group (c) or less; such substances, solutionsand mixtures (such as preparations and wastes) shall beassigned to Class 8)

infectious substances of Class 6.2."

Vol 1845, A-8940


2002 (8) (cont'd)

(cont'd) 3. Amend 2.3.2 to read as follows:

"2.3.2 Classification under an n.o.s. entry or an item of

a class determined in accordance with 2.3.1 on thebasis of the danger characteristics of the various

components of the solution or mixture.Classification under a general n.o.s. entry is

permitted only when classification under a

specific n.o.s. entry is not possible.

NOTE: Examples for the classification of mixtures

and solutions under classes and items:

A phenol solution of Class 6.1, 14" (b), in

benzene of Class 3, 3" (b) is to be classified inClass 3, 3" (b); this solution is to be classifiedunder the entry 1992 flammable liquid, toxic,n.o.s., Class 3, 19" (b), by virtue of the

toxicity of the phenol.

A solid mixture of sodium arsenate of Class 6.1,

51" (b) and sodium hydroxide of Class 8, 4W (b),

is to be classified under the entry 1557 arsenic

compound. solid. n.o.s. in Class 6.1, 51" (b).

A solution of crude or refined naphthalene of

Class 4.1, 6" (c) in petrol of Class 3, 3" (b), isto be classified under the entry I29hydrocarbons, liquid. n.o.s. in Class 3, 3" (b).

A mixturi' of hydrocarbons of Class 3, 31" (c), andof polychlorinated biphenyls (PCB) of Class 9,

2" (b), is to be classified under the entry 315

oolvchlorinated biohenvls in Class 9, 2" (b).

A mixture of propyleneimine of Class 3, 12", and

polychlorinated biphenyls (PCB) of Class 9,2" (b), is to be classified under the entry I921oroovleneimine. inhibited in Class 3, 12".

Vol 1845, A-8940

United Nations - Treaty Series • Nations Unies - Recueil des Traitks

;tI !-- -X - -'i i4b IIv l'I Z: :;I! z ;- - ---- - -

____ ___ ____ ___ __ j i IO S 1 ;

w* i v; ~ I - Z I= -Z wII 71Z

Itv

:c 1 -z ;z:

. - I

- a- a5, t

St ;1: 1'cn- __2,1 2 .EI

E1 27; 2z:tKiTg v I~

Vol. 1845, A-8940

0

L

0

0

02

0

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I 02

1995

II, I2 -j Z

54 United Nations - Treaty Series o Nations Unies - Recueil des Traitis 1995

Footnotes for the table in marginal 2002 (8)

I/ These mixtures and solutions may have explosive properties, in which

case they are not to be accepted for transport unless they meet therequirements of Class 1.

,/ Solutions or mixtures containing substances of Class 3,marginal 2301, 6, 12' or 13' shall be placed in that Class under those items.

./ Solutions or mixtures containing substances of Class 6.1,

marginal 2601, 1* to 5" shall be placed in that Class under those items.

4/ Solutions or mixtures containing substances of Class 8,

marginal 2801, 6', 14" and 15" shall be placed in that Class under those

items.

5./ Assignment to a class and a letter of an item may be based on thetest procedures.(see Appendix A.3).

/ Solutions or mixtures containing substances of Class 9,marginal 2901, 2" (b) shall be placed in that Class under that item, provided

they do not also contain substances mentioned in footnotes I to 4 above. If

they do contain such substances, they shall be classified accordingly.

7/ There is at present no test criterion for determining the degree of

danger (packing group) for liquids of Class 5.1. The degree of danger

(packing group) for such substances can be determined only by comparison withsubstances listed by name under an item and a group designated by the letters

(a), (b) or (c).

/ Class 6.1 for pesticides.

Vol. 1845, A-8940


2002 (9), amend to read:

"(9) The consignor ... (unchanged) ... shall certify that the

substance presented may be carried by road in conformity with theprovisions of ADR and that its condition, treatment and, asappropriate, its packaging, the intermediate bulk container or tankcontainer and the labelling conform to the provisions of ADR."(Second sentence unchanged.)

Add the following new paragraph (14):

"(14) For the purposes of ADR, substances, solutions and mixtures(such as preparations and wastes) which cannot be assigned toClasses 1 to 8 or 9, 1' to 8, 13" and 14, but which may beassigned to Class 9, 11 or 12, on the basis of the test methodsand criteria according to Appendix A.3, section G, marginals 3390to 3396, shall be considered to be pollutant to the aquaticenvironment. Solutions and mixtures (such as preparations andwastes) for which classification values conforming to theclassification criteria are not available shall be considered to bepollutant to the aquatic environment if the LC50,/ evaluatedaccording to the following formula:

LC,, of the pollutant x 100LCo =

percentage of the pollutant (by mass)

is equal to or lower than:

(a) 1 mg/i,

(b) 10 mg/1 if the pollutant is not readily degradable or, beingdegradable, has a log Pow; 3.0.

NOTE: For substances of Classes I to 8 and Class 9, 1* to 8, 13"and 14, which are pollutant to the aquatic environment accordingto the criteria of Appendix A.3, section G, marginals 3390 to 3396,no additional condition of carriage is applicable.

_/ According to the definition contained in marginal 3396.

Vol. 1845, A-8940


2003(4) Amend the titles of these Appendices in accordance with themodifications to these appendices:

In the title of Appendix A.1, replace "flammable solids" with

"nitrated mixtures of nitrocellulose, self-reactive substances";

In the title of Appendix A.3, amend as follows:

"Tests relating to flammable liquids of Classes 3, 6.1 and 8 (Testfor determining flash-point, Test for determining peroxide content,Test for determining combustibility)";

and add at the end:

"tests for determining ecotoxicity, persistence and bioaccumulationof substances in the aquatic environment by assignment to Class 9."

2007 Amend as follows:

"Packages, including intermediate bulk containers (JBCs), which donot entirely meet the packing, mixed packing and labellingrequirements of ADR but are in conformity with the requirements formaritime or air transport of dangerous goods 9/ shall be acceptedfor carriage prior to or following maritime or air carriage subjectto the following conditions:

(a) If the packages or IBCs are not labelled in accordancewith ADR, they shall be labelled in accordance with theprovisions for maritime or air transport; 9/

(b) The provisions for maritime or air transport 9/ shall beapplicable to mixed packing within a package;

(c) In addition to the particulars prescribed for ADR, thewords 'Carriage under marginal 2007 of ADR' shall beentered in the transport document."

Renumber existing footnote B/ as 9_/.

2010 Insert the following text after the first sentence:

"The period of validity of the temporary derogation shall be notmore than five years from the date of its entry into force. Thetemporary derogation shall automatically come to an end from thedate of the entry into force of a corresponding amendment to thisannex".

_8/ According to the definition contained in marginal 3396.

Vol. 1845. A-8940


Part II. LIST OF SUBSTANCES AND SPECIAL PROVISIONS FOR THE VARIOUS CLASSES

CLASS 1. EXPLOSIVE SUBSTANCES AND ARTICLES

2100 (6) Add: "1.6 Extremely insensitive articles which do not have a massexplosion hazard. The articles contain only extremelyinsensitive detonating substances and demonstrate anegligible probability of accidental initiation orpropagation."

NOTE: The risk from articles of Division 1.6 is limited

to the explosion of a single article.

(7) Add to "B":

"Some articles, such as detonators for blasting, detonatorassemblies for blasting and primers, cap-type, are included,even though they do not contain primary explosives."

Add: "N Articles containing only extremely insensitive

detonating substances."

2101 In table 1, columns (4) and (5), replace the references to marginal2103(5) and (6) by references to marginal 2103(6) and (7).

0029 Column 5: delete "19, 20, 54"0030 Column 5: delete "17"

0106 Column 5: insert "56"0360 Column 5: delete "25 26"0377 Column 5: delete "39, 40"

Vol. 1845, A-8940


2101(cont'd)

Item 2A

(a) Add:

Propellant, liouidNOTE: Unless it can bedemonstrated by testingthat its sensitivity whenfrozen is no greater thanwhen liquid, the propellantshall remain liquid duringnormal conditions oftransport and not freezeat temperatures above-15 'C.

Propellant, solid

1.1C

1.1c

E159(a) 58E159(b) 59

8,9,10"

Column 2: delete "for rocket motors"Column 5: delete "54"Delete whole entry

Amend the name to read: "Hexolite (hexotol). dry

NOTE: Amend to read:

"3064 nitroglycerin, solution in alcohol with more than 1 % but notmore than 5% nitroglycerin, carried under special conditions ofpacking, is a substance of Class 3 (see marginal 2301, 6')"

amend the name to read: "Hexotonal"

Column 1: amend to read:

"Pentaervthrite tetranitrate(Pentaervthritol tetranitrate: PETN)with not less than 7% wax, by mass".

"0497

0498

Item 3*

0271

0273

Item 4*

auI8

0144

0393

p4-u

Vol. 1845, A-8940


2101(cont'd)

Add:

Columns 4 and 5; read:

Column 5: add "57"

Column 4:Column 4:Column 5:Column 5:

"E107(a)E107(b)

delete "E 118"insert "E 106"delete "51"insert "49"

Column 5: add "57"

lItem9*

Column 2: delete "with explosive sound unit"

0D07 Column 5: insert "56"

Item 15"

0328041504]6

ColumnColumndelete

2: delete "(cartridges. small arms)"2: delete "for rocket motors", and Column 5: delete "54"whole entry

Item 17"

Columns 4 and 5; read: "E107(a)E107(b)

Vol. 1845, A-8940

0048

0056


2101(cont'd)

3] Column 2: delete "with explosive sound unit"334 Column 5: insert "37"

DMJ5) Column 5: add "49"

~Q1l)

02A4) Column 5: add "49"

024S)

24e Column 5: delete "29"

I12 Column 4: delete "E 103"Column 4: insert "E 2"Column 5: insert "1, 2"

05 Column 2: replace "35% (mass) water"with "25% (mass) water"

0203 Column 2: add "explosive" after "n.o.s."Column 4: delete "E 103"Column 4: insert "E 21"Column 5: insert ,2"

33 Column 2: amend the Note as follows:"For nitrocellulose mixture with not more than 12.6%nitrogen by dry mass with plasticizer, under specialconditions of packing, see class 4.1 [marginal 2401,24"(a)]".

Vol. 1845. A-8940

1995


2101(cont'd)

Add:

Prooellant, liquid 1.3CNOTE: Unless it can be

demonstrated by testing that

its sensitivity when frozen

is no greater than when liquid,

the propellant shall remain

liquid during normal conditions

of transport and not freeze at

temperatures above -15 *C.

El59(a)E159(b)

Propellant. solid

Column 2: delete "for rocket motors", and Column 5:

Delete whole entry

Column 2: delete "(cartridges, small arms, blank)"insert "or cartridges, small arms, blank"

Column 2: insert "or cartridges, small arms"

Column 5: add "49"

Column 5: insert "37"

Insert the following new entries:

"(1) (2)

0487 Signals. smoke0488 Ammunition. practice0492 Signals. railway track,

explosive

(3) (4) (5)

1.3G1.3G

E 150 12E 102 13, 48, 49

E 151 43, 44, 45"

Vol. 1845, A-8940

0499

Item 27°

8,9,10"

0272

0274

0327

0417

Item 30*

0010)0016)0019)

0335

delete "54"


2101(cont'd)

Column 5: add "49"

Column 5: add "49"

Column 5: delete "29"

deletedeletedeletedelete

deleteinsertdeleteinsert

20, 54"26"40"

"(cartridges. small arms. blank)""or cartridges, small arms, blank""(cartridges, small arms)""or cartridges. small arms"

Add the following new entry:

"(I) (3) (4) (5)

949 Charges. propelling 1.4C E.158 8, 10"

Column 5: add "57"

9244)o24k)

242

Item 34"

O249

Item 37"

ColumnColumnColumnColumn

ColumnColumnColumnColumn

0M2

Vol. 1845, A-8940


2101(cont'd)


(3) (4) (5)

39° 0494 Jet perforating auns.charged oil well,without detonator 1.4D E 140

Column 2: delete "without explosive sound unit"Column 5: insert "37"

Column 5: add "49"


(2) (3) (4) (5)

0493 Signals. railway track.explosive I .4G E 151 43, 44, 45"

Column 2: delete "(Cartridges. small arms)"Column 2: insert "or cartridges, small arms"Column 2: delete "(cartridges. small arms. blank)"Column 2: insert "or c'artridges. small arms. blank"Column 5: delete "39, 40"Column 5: add "49"Column 5: delete "19, 20, 54"Column 5: delete "18"

Vol. 1945, A-8940

019703360297)0300)0301)0303)0362)0363)

"(1)

ItmL

0012

0044

O404550456

64 United Nations - Treaty Series * Nations Unies - Recuei des Trait~s 1995

2101

Item4

Add a

(1)

"50"

In column 3, under Drums, add:

E 4(a) In column 3, under Boxes, add:

column

column

delete:

replace:

paper, multiwall, waterresistantwoven plastics"

"steel, removable head(IA2)"

"natural wood, ordinary

(4C1) steel (4A)"

"Drums, fibre (IG)"

"Optional" by "Notnecessary".

(cont'd)

48"

Add the synonym "(Articles EEl, n.o.s.)"

new iteL:

(2) (3) (4) (5)

ARTICLES CLASSIFIED AS 1.6N

0486 Articles. explosive. extremely 1.6N E 106 49"insensitive (Articles. EEl)"

1) Delete "other than cradles and crates"

In the title, delete "for substances and articles".

Insert new paragraph (5) as follows:

"(5) Plastics packagings shall not be liable to generate oraccumulate sufficient static electricity that a dischargecould cause the packaged explosive to ignite or the packagedarticle to function."

Renumber paragraph (5) Table 2 as paragraph (6) and amend as

follows:

Packing method

E 2 In column 2, add: "Bags

2102(

2103

In

E 4(b) In

Vol 1845. A-8940

United Nations - Treaty Series 9 Nations Unies - Recueil des Traitis

2103(cont'd)

Packing method

E 6(a)2 In column 2, under"Intermediate bags", add:

In column 3, under Boxes, add:




delete: "plastics (1H2)"

NOTE: delete:

E 13(a) In column 2, under Bags, add:

E 13(b) In column 2, under Bags, add:

In column 2,Receptacles,In column 3,

and replace:

underadd:under Boxes, add:

"steel (4A)aluminium (4B)plastics, solid (4H)"

"steel, removable head(1A2)aluminium, removable head(182)"

"steel (4A)

aluminium (4B)plastics, solid (4H2)"

"aluminium, removable head(282)"

"or plastic drums (IH2)"

"woven plastics

paper, multiwall, waterresistant"

.woven plastics


"fibreboard""plastics, solid (4H2)""steel, with inner liner orcoating (4A2)""steel (4A)

aluminium (4B)"

Vol. 1845, A-8940

"plastics"

E 12

E 20

United Nations - Treaty Series o Nations Unies - Recueil des Trait~s

2103(cont'd)

column 3, under Boxes, add:

column

column

delete:

under Drums, add:

E 26 In column 2, under Bags, add:

E 102 In column 3, under Boxes, add:

and replace:

by:

E 104

E 105

In column 3,

In column 3,

In column 2,

In column 3,and replace:

by:


by:

under Drums, add:

delete:

add:

under Boxes, add:

under Boxes, add:

Packing method

E 22(a), In

(b)

E 24(b) In

E 25 In

Vol. 1845. A-8940

"steel (4A)"

"with coating - other thanlead""steel, removable head(lA2)"

"paper


"aluminium (4B)""expanded plastics (4H1)""plastics, solid (4H)""steel (4A1)" and "steel,with inner liner or coating(4A2)""steel (4A)"

"aluminium, removable head(B2)""Crates A/ (for largearticles)""plastics"

"aluminium (4B)""steel, with inner liner orcoating (4A)""steel (4A)"

"aluminium (4B)""steel, with inner liner orcoating (4A2)""steel (4A)"

1995


2103(cont'd)

Paking method

E 105 A In column 3,and replace:

by:

E 106 In column 3,

and replace:by:In column 3,

In column.3,

E 107(a(b

E 108

Delete

E 109

E 112

In column 3,p),

In column 3,and replace:by:

footnotes 4/ and

In column 2,Receptacles,


by:

In column 3,

and replace:

by:

under Boxes, add: "aluminium (4B)""steel, with inner liner orcoating (4A2)""steel (4A)"

under Boxes, add: "aluminium (4B)" and"plastics, solid (4H2)""steel (4A1)""steel (4A)"

add: "Drums steel, removablehead (1A2)"

delete: "crates j/" and"cradles j/"

under Boxes, add: "steel (4A)aluminium (4B)"

under Boxes, add: "aluminium (4B)""steel (4A1)""steel (4A)"

j/ and renumber footnotes consequently.

underadd: "paper

under Boxes, add:

under Boxes, add:

fibreboard"


"aluminium (4B)" and"plastics,

solid (4H2)"

"steel (4A1)" and "steel,with inner liner or coating(4A2)""steel (4A)"

Vol. 1845, A-8940

68 United Nations - Treaty Series e Nations Unies - Recueil des Traitks 1995

2103(cont'd)

Packing method



and replace:

by:

In column 3, add:


and replace:

by:

"natural wood, withsift-proof walls (4C2)steel (4A)"

"aluminium (4B)""natural wood, withsift-proof walls (4C2)""steel, with inner liner orcoating (4A2)""steel (4A)"

"Drumssteel, removable head(A?)"

"aluminium (48)""expanded plastics (4H)""plastics, solid (4H2)""steel, with inner liner orcoating (4A2)""steel (4A)"

In column 3,and replace:by:

under Boxes, add:

In column 2 insert: "not necexisting wording

In column 3, under Boxes add:

and replace:

by:

In column 3, add:

"aluminium (4B)""steel (4A1)""steel (4A)"

essary" instead of the

"aluminium (4B)""fibreboard (4G)""steel, with inner liner orcoating (4A2)""steel (4A)"

"Drumssteel, removable head(1A2)"

Delete the entry and footnote Z/

E 116

E 117

E 118

Vol. 1945, A-8940


2103 (cont'd)

Packing method


and replace:

by:

In column 3, under Drums add:

In column 3, in the note, delete:

In column 2, under "Tubes" read:

In column 3, under Boxes, add:and replace:

by:

In column 3, add:


under Boxes, add:

In column 2, underReceptacles, add:


and replace:by:

E 119

"plastics"

"aluminium (4B)""expanded plastics (4HI)""steel (4A1)""steel (4A)"

Vol. 1845, A-8940

"aluminium (4B)""fibreboard (4G)""plastics, solid (4H2)""steel, with inner liner orcoating (4A2)""steel (4A)"

"aluminium, removable head(1B2)"

"plywood (4) andreconstituted wood (4F)"

"fibreboard or equivalentmaterial"


"Drumssteel, removable head (A2)aluminium, removable head(B2)"


E 120

E 121

E 122

E 123


2103 (cont'd)

Packing method

E 124 In column 2, add:


column

column

under

under

Boxes, add:

Boxes, add:

In column 3, add:


In column 3, add:

In column 2, under Receptacles,add:


and replace:

by:


and replace:by:

"Receptaclesmetal"

"steel, removable head(1A2)aluminium, removable head(1B2)"

"aluminium (4B)"

"steel (4A)

aluminium (4B)"

"Drumssteel, removable head (A2)aluminium, removable head(1B2)"

"steel (4A)aluminium (4B)"

"Drumssteel, removable head (1A2)aluminium, removable head(1B2)"

"metal

plastics"

"aluminium (4B)""fibreboard (4G)""steel, with inner liner orcoating (4A2)""steel (4A)"

"aluminium (4B)""fibreboard (4G)""steel (4A1)""steel (4A)"

E 125

E 126

E 127

E 128

Vol 1945, A-8940


2103 (cont'd)

Packing method

In column 2, under Receptacles,add:In column 3, under Boxes, add:



and replace:by:


In column 3, under Boxes, add:and replace:by:

In column 3, add:


and replace:

by:


"metal""steel (4A)aluminium (4B)expanded plastics (4H1)"

"steel, removable head(IA2)aluminium, removable head(B2)"

"aluminium (4B)""expanded plastics (4H1)""steel (4A1)""steel (4A)"

"steel, removable head(lA2)aluminium, removable head(IB2)"


"Drumssteel, removable head (A2)aluminium, removable head(1B2)"

"aluminium (4B)""plastics, solid (4H2)""steel, with inner liner orcoating (4A2)""steel (4A)"

"steel, removable head(IA2)aluminium, removable head(B2)"

Vol. 1845, A-8940

E 130

E 133

E 134

E 136

72 United Nations - Treaty Series e Nations Unies - Recueil des Traits 1995

2103 (cont'd)

Packing method


and replace:by:

In column 3, add:


and replace:by:

E 139 In column 2,add:


under Receptacles,

under Boxes, add:

In column 3, add:


by:


under Boxes, add:

under Boxes, add:

E 137

In column 2, amend "optional" to read: "not necessary"


under Boxes, add: "aluminium (4B)""steel, with inner liner orcoating (4A2)""steel (4A)"

"aluminium (48)""fibreboard (4G)""plastics, solid (4H2)""steel (4A1)""steel (4A)"

"Drumssteel, removable head(1A2)"

"aluminium (4B)""plastics, solid (4H2)""steel (4A1)""steel (4A)"

"fibreboard"


"Drumssteel, removable head(]A2)"



E 138

E 140

E 141

E 142

Vol. 1845, A-8940


2103 (cont'd)Packing method

E 143 In column 3,and replace:by:

E 145 In column 3,and replace:


under Boxes, add:

under Boxes, add:

under Boxes, add:






and replace:

by:





under Boxes, add:

under BoRes, add:

under Boxes, add:

"metal"

"aluminium (4B)""expanded plastics (4HI)""plastics, solid (4H2)""steel (4A1)""steel (4A)"

"steel, removable head(IA2)aluminium, removable head(IB2)plastics, removable head(1H2)"



"aluminium (4B)""steel (4A1)" and"steel, inner lirer orcoating (4A2)""steel (4A)"

Vol. 1845. A-8940

E 15O

E 156


2103 (cont'd)Packing method

E 157 In column 3, under Boxes, add:and replace:by:


Add a new packing method E 159 as follows:

1 2 3

E 159 Receptacles Boxes(a) plastics natural wood,

ordinary (4C1)plywood (4D)reconstitutedwood (4F)

Intermediate

Bagsplastics, in metal cans

(b) Receptacles Drumsplastics steel, removable

head (A2)aluminium,removable head (1M2)

Intermediate

Drums.metal

Renumber paragraph (6) Table 3 as paragraph (7) and delete SpecialPacking Requirements 17, 18, 19, 20, 25, 26, 29, 39, 40 and 54.

Vol. 1845, A-8940

1995 United Nations - Treaty Series e Nations Unies - Recueil des Trait6s 75

2103 (cont'd)

Amend the following Special Packing Requirements as follows:

8. Amend to read:

"The inside of metal packagings shall be galvanized, painted

or otherwise protected. Bare steel shall not come into

contact with the propellant."

32. Text in column 2 to read:

"Unless the ends of the article are sealed, plastics bags

shall be used as inner packaging".

38. Amend to read:

"The fuzes shall be separated from each other in the innerpackaging."

49. Text in column 2 to read:

"Large articles without their means of initiation, or withtheir means of initiation containing at least two effectiveprotective features, may be carried unpacked".

Add the following new Special Packaging Requirements:

"56. Fibreboard boxes (4G) shall not be used as outer packaging.

57. Liner or inner coating required for metal outer packagings

(e.g., 4A, 4B, 1A2, 1B2) unless another means such as the use

of an inner packaging or cushioning material protects theexplosive substance from contact with the metal outerpackaging during normal conditions of transport.

58. Plastics receptacles shall have taped screw cap closures and

be of not more than 5 litres capacity each. Each receptacle

shall be contained within an intermediate packaging. Eachplastics bag shall be surrounded on all sides with at least

50 mm of non-combustible absorbent cushioning material; metal

cans in the outer box shall also be cushioned from each other

in all directions.

Vol. 1845. A-8940

United Nations - Treaty Series e Nations Unies - Recueil des Trait~s

2103 (cont'd)

58.(cont'd)

59.

Net mass of propellant shall be limited to 30 kg foreach package.

The intermediate drum shall be surrounded on all sides withat least 50 mm of non-combustible absorbent cushioningmaterial. A composite packaging consisting of a plasticsreceptacle in a metal drum may be used instead of the innerand intermediate packagings. The net volume of propellant ineach package shall not exceed 120 litres."

2105 (2) Add: "..., and those containing articles of item 50 shallbear a label conforming to model No. 1.6."

(3) Add "and 0303" to the text after "43, 0301" (for label No. 8only).

2201 2" (b). Add:

"... mixtures containing not more than 10% silane by volume withone or more of the following gases: hydrogen, nitrogen, argon,helium, krypton, neon, deuterium and methane".

2" (bt): Delete "or silane" (twice).

9"(at) NOTE: Amend to read:

"2672 Amnonia solution, relative density between 0.880 and 0.957 at15" C in water, with more than 10 % but not more than 35 % ammonia,is a substance of Class 8 [see marginal 2801, 43"(c)]".

(14'): Amend as follows:

"Empty receptacles, empty tank-vehicles or empty tank-containersuncleaned, which have contained substances of Class 2."

NOTE 2, to be deleted; NOTE 1 becomes NOTE in which the words"listed under 14"" are replaced with "of Class 2".

2201 a (b) At the end add the following sentence:

"These freezing appliances shall be protected and loaded in such away as to prevent any damage to their freezing circuit".

Vol. 1945. A-8940


2201 a (c) Amend as follows:

(cont'd)

"(c) carbon dioxide and nitrous oxide (N2O) of 5" (a) in

metal capsules (sodors, sparklets, cream capsules), if the

carbon dioxide and nitrous oxide in the gaseous state do notcontain more than 0.5% air and the capsules contain not morethan 25 g carbon dioxide or 25 g nitrous oxide and not morethan 0.75 g of carbon dioxide or nitrous oxide per cm3 ofcapacity;"

2208 (2) Replace "gases of 4" (a) and (b)" with "gases of 4" (a) and (b) and

(c)".

2212 (3) (b) and (c)

Delete "or silane" (four times)

2217 Insert the following new paragraph (3):

"(3) The cylinders referred to in marginal 2212 (1) (a) may becarried after the expiry of the time-limit set for the periodic

test prescribed in marginal 2215 for the purpose of undergoing the

test."

2219 (5) Delete "or silane" (twice).

2226 (2) and (3) Delete.

Paragraph (4) becomes (2).

Insert the following new paragraph (3):

"(3) For the carriage of cylinders in conformity with marginal2212 (1) (a) under the conditions of marginal 2217 (3), thefollowing entry shall be included in the transport document:

'Carriage in conformity with marginal 2217 (3)'".

CLASS 3: marginals 2300 to 2399 should be replaced by the following:

Vol. 1845, A-8940


'CLASS 3. FLAMMABLE LIQUIDS

I. List of substances

2300 (1) Among the substances and mixtures covered by the heading ofClass 3, those listed in marginal 2301 or which fall under acollective heading of that marginal, and articles containing suchsubstances, are subject to the conditions prescribed inmarginals 2300 (2) to 2322 and to the provisions of this Annex andof Annex B and are consequently substances of ADR.

NOTE: For the quantities of substances listed in marginal 2301which are not subject to the provisions for this Class, either inthis Annex or in Annex B, see marginal 2301a.

2300 (2) The heading of Class 3 covers substances and articles containingsubstances of this Class which:

are liquid at a maximum temperature of 20 'C, or for viscoussubstances for which a specific melting point cannot bedetermined, are highly viscous according to the criteria ofthe penetrometer test (see Appendix A.3, marginal 3310), orare liquid according to the ASTM D 4359-90 test method;

have at 50 *C a vapour pressure of not more than 300 kPa

(3 bar);

have a flashpoint of not more than 61 'C.

The heading of Class 3 also covers flammable liquid substances andmolten solid substances with a flashpoint of more than 61 "C andwhich are carried or handed over for carriage whilst heated attemperatures equal to or higher than their flashpoint.

Substances having a flashpolnt above 35 *C, non-toxic andnon-corrosive, which, under the test conditions given, do notsustain combustion (see Appendix A.3, marginal 3304) are excluded;if however these substances are handed over for carriage andcarried whilst heated at temperatures equal to or higher than theirflashpoint, they are substances of this Class.

Flammable liquids which, because of supplementary dangerousproperties, are listed in, or assigned to, other classes are alsoexcluded. The flashpoint shall be determined as indicated inAppendix A.3, marginals 3300 to 3302.

Vol. 1845, A-8940


2300 (2)(cont'd)

NOTE 1: For gasoil, diesel fuel, heating oil (light)

(identification number 1202) having a flashpoint above 61 *C see,

however, NOTE under marginal 2301, 31" (c).

NOTE 2: For substances having a flashpoint above 61 "C which arecarried or handed over for carriage at or above their flashpoint,

see however marginal 2301, 61" (c).

(3) The substances and articles of Class 3 are subdivided as

follows:

A. Substances having a flashpoint below 23 "C not toxic, not

corrosive;

B. Substances having a flashpoint below 23 "C and toxic;

C. Substances having a flashpoint below 23 "C and corrosive;

D. Substances having a flashpoint below 23 "C, toxic and

corrosive and articles containing those substances;

E. Substances having a flashpoint between 23 °C and 61 *C

inclusive which might be slightly toxic and/or slightly

corrosive;

F. Substances and preparations used as pesticides having a

flashpoint below 23 "C;

G. Substances having a flashpoint above 61 *C which are carried

or handed over for carriage at or above their flashpoint;

H. Empty packagings.

Substances and articles of Class 3, other than those of 6, 12,

13', and 28° classified under the various item numbers ofmarginal 2301 shall be assigned to one of the following groups

designated by the letter (a), (b) or (c) according to their degree

of danger:

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80 United Nations - Treaty Series - Nations Unies - Recueil des Traitis 1995

2300 (2)(cont'd)

letter (a): very dangerous substances: flammable liquidshaving a boiling point or initial boiling point not exceeding35 'C, and flammable liquids having a flash-point below23 'C, which are either highly toxic according to the

criteria of marginal 2600 or highly corrosive according tothe criteria of marginal 2800;

letter (b): danaerous substances: flammable liquids having

a flash-point below 23 'C which are not classified underletter (a), with the exception of substances ofmarginal 2301, 5" (c);

letter (c): substances presenting a minor danger: flammableliquids having a flashpoint of 23 "C to 61 "C inclusive andsubstances of marginal 2301, 5" (c).

(4) If substances of Class 3, as a result of admixtures, come intodifferent categories of risk from those to which the substancesspecifically named in marginal 2301 belong, these mixtures or

solutions shall be assigned to the items and letters to which they

belong on the basis of their actual degree of danger.

NOTE: For the classification of solutions and mixtures (such aspreparations and wastes), see also marginal 2002 (8).

(5) On the basis of the test procedures in accordance withAppendix A.3, marginals 3300 to 3302, 3304 and 3310, and the

criteria set out in (2), it may also be determined whether thenature of a solution or a mixture specifically named or containinga specifically named substance is such that the solution or mixtureis not subject to the provisions for this Class.

(6) Certain highly toxic flammable liquid substances having aflashpoint below 23 "C are substances of Class 6.1 (marginal 2601,1" to 10').

(7) Substances of Class 3 which are liable to form peroxideseasily (as happens with ethers or with certain heterocyclicoxygenated substances) are to be accepted for carriage only iftheir peroxide content, calculated as hydrogen peroxide (H,02),does not exceed 0.3%. The peroxide content shall be determined asindicated in Appendix A.3, marginal 3303.

Vol 1845. A-8940


2300 (8) The chemically unstable substances of Class 3 are to be(cont'd) accepted for carriage only if the necessary steps have been taken

to prevent their dangerous decomposition or polymerization duringcarriage. To this end, it shall in particular be ensured thatreceptacles do not contain any substance liable to promote thesereactions.

2301 A. Substances having a flashpoint below 23 *C. not toxic,not corrosive.

I Substances, solutions and mixtures (such as preparations andwastes) having a vapour pressure at 50 "C of more than175 kPa (1.75 bar):

(a) 1089 acetaldehyde (ethanal), 1108 I-Dentene (n-amylene),1144 crotonylene (2-butyne), 1243 methyl formate,1265 Oentanes, liquid (isopentane), 1267 petroleumcrude oil, 1303 vinylidene chloride, inhibited (1.-dichloroethvlene: inhibited), 1308 zirconium suspendedin a flammable liouid, 1863 fuel. aviation, turbineengine, 2371 isooentenes, 2389 furan,2456 2-chloroorooene, 2459 2-methvl-l-butene,2561 3-methvl-l-butene (1-isoamylene)(isopropylethylene), 2749 tetramethylsilane,1268 oetroleum distillates. n.o.s., or 1268 petroleumproducts, n.o.s,3295 hydrocarbons, liquid, n.o.s., 1993 flammableliquid. n.o.s.

2' Substances, solutions and mixtures (such as preparations andwastes) having a vapour pressure at 50 *C of more than110 kPa (1.10 bar) but not more than 175 kPa (1.75 bar):

(a) 1155 diethyl ether (ethyl ether), 1167 divinyl etherinhibited, 1218 isoprene. inhibited, 1267 petroleumcrude oil, 1280 oropvlene oxide. inhibited, 1302 vinylethyl ether, inhibited, 1308 zirconium susoended in aflammable liouid, 1863 fuel. aviation, turbine engine,2356 2-chloroprooane, 2363 ethyl mercaotan,1268 oetroleum distillates. n.o.s., or 1268 oetroleumoroducts. n.o.s,

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82 United Nations - Treaty Series 9 Nations Unies - Recueil des Trait6s 1995

2301 2" (a) 3295 hydrocarbons, liouid, n.o.s., 1993 flammable(cont'd) (cont'd) liouid, n~o~s,;,

(b) 1164 dimethyl sulohide, 1234 methvlal(dimethoxymethane), 1265 Dentanes, liquid (n-pentane),

1267 petroleum crude oil, 1278 1-chlorooropane

(propyl chloride), 1308 zirconium suspended in a

flammable liquid, 1863 fuel. aviation, turbine enoine,

2246 cyclopentene, 2460 2-methvl-2-butene, 2612 methylproDyl ether,

1224 ketones: n.o.s., 1987 alcohols. flammable. n.o.s.,

1989 aldehydes. flammable. n.o.s., 1268 petroleumdistillates. n.o.s., or 1268 petroleum oroducts. n.o.s..

3295 hydrocarbons. liguid. n.o.s., 1993 flammable liquidn.o.s.

3: Substances, solutions and mixtures (such as preparations and

wastes) having a vapour pressure at 50 "C of not more than

110 kPa (1.10 bar):

(b) 1203 motor spirit, 1267 petroleum crude oil, 1863 fuelaviation, turbine engine,

1268 petroleum distillates. n.o.s, or 1268 Detroleum

products. n.o.s.

NOTE: While in some climatic conditions petrol

(gasoline) may have a vapour pressure at 50 'C of morethan 110 kPa (1.10 bar) but not more than 150 kPa

(1.50 bar), it is to continue to be classified under

this item number.

Hydrocarbons:

1114 benzene, 1136 coal tar distillates,1145 cyclohexane, 1146 cyclopentane, 1175 ethvlbenzene,

1206 heptanes, 1208 hexanes, 1216 isooctenes,1262 octanes, 1288 shale oil, 1294 toluene,

1300 turnentine substitute (white spirit), 1307 xylenes

(o-xylene;dimethylbenzenes), 2050 diisobutvlene.

isomeric compounds,2057 trioropylene (propylene trimer),

2241 cvcloheptane,2242 cycloheotene, 2251 bicyclo-

(2.2.1) -heota-2.5-diene. inhibited (2.5-norbornadiene.

inhibited), 225& cyclohexene, 2263 dimethvlcvclohexanes,

2278 n-heotene, 2287 isoheptenes, 2288 isohexenes,

2296 methylcyclohexane, 2298 methylcyclooentane,

Vol. 1845, A-8940


2301 3" 2309 octadienes, 2358 cyclooctatetrene, 2370 l-hexene,(cont'd) (cont'd) 2457 2.3-dimethylbutane, 2458 hexadienes,

2461 methvloentadienes,

3295 hydrocarbons. liouid. n.o.s.;

Halogenated substances:

1107 amyl chlorides, 1126 1-bromobutane, (n-butylbromide), 1127 chlorobutanes (butyl chlorides),

1150 1.2-dichloroethylene, 1279 1.2-dichloroorooane,

(oroovlene dichloride) 2047 dichloroprooenes,2338 benzotrifluoride, 2339 2-bromobutane,

2340 2-bromoethyl ethyl ether, 2342 bromomethylorooanes,2343 2-bromooentane, 2344 bromoorooanes,2345 3-bromoorooyne, 2362 1.1-dichloroethane (ethylidenechloride), 2387 fluorobenzene, 2388 fluorotoluenes,

2390 2-iodobutane, 2391 iodomethvloropanes,

2554 methvlallyl chloride;

Alcohols:

1105 amvl alcohols, 1120 butanols, 1148 diacetonealcohol technical, 1170 ethanol (ethyl alcohol) or

1170 ethanol (ethyl alcohol) in aqueous solutioncontaining more than 70% alcohol by volume,1219 isooropanol (isoprooyl alcohol), 1274 n-orooanol

(oroovl alcohol. normal), 3065 alcoholic beveragescontaining more than 70% alcohol by volume,1987 alcohols, flammable. n.o.s.;

NOTE: Alcoholic beverages containing more than 24% andnot more than 70% alcohol by volume are substances of

31" (c).

Ethers:

1088 acetal (1,1-diethoxyethane), 1159 diisooropyl

ether, 1165 dioxane, 1166 dioxolane, 1179 ethyl butyl

ether, 1304 vinyl isobutvl ether. inhibited,2056 tetrahvdrofuran, 2252 1.2-dimethoxvethane,

2301 2-methvlfuran, 2350 butyl methyl ether, 2352 butylvinyl ether, inhibited, 2373 diethoxymethane,

Vol. 1845, A-8940


2301 3 " 2374 3.3-diethoxvorooene, 2376 2.3-dihydrooyran,(cont'd) (cont'd) 2377 1.1-dimethoxyethane, 2384 di-n-orooyl ether,

2398 methyl tert-butyl ether,2536 methyltetrahydrofuran, 2615 ethyl nroovl ether,2707 dimethyldioxanes, 3022 1.2-butylene oxide,

stabilized,3271 ethers, n.o.s.,;

Aldehydes:

1129 butyraldehyde, 1178 2-ethylbutyraldehyde,1275 orooionaldehyde, 2045 isobutyraldehyde (isobutylaldehyde), 2058 valeraldehyde,2367 aloha-methvlvaleraldehvde,1989 aldehydes. flammable. n.o.s.;

Ketones:

1090 acetone, 1156 diethyl ketone, 1193 methyl ethylketone (ethyl methyl ketone), 1245 methyl isobutylketone, 1246 methyl isooropenyl ketone. inhibited,1249 methyl orooyl ketone, 1251 methyl vinyl ketone,2346 butanedione (diacetyl), 2397 3-methylbutan-2-one,1224 ketones. n.o.s.;

Esters:

1123 butyl acetates, 1128 n-butyl formate, 1161 dimethylcarbonate, 1173 ethyl acetate, 1176 ethyl borate,1190 ethyl formate, 1195 ethyl oropionate, 1213 isobutylacetate, 1220 isorooyl acetate, 1231 methyl acetate,1237 methyl butyrate, 1247 methyl methacrvlate monomer.inhibited, 1248 methyl orooionate, 1276 n-orooylacetate, 1281 oroovl formates, 1301 vinyl acetate.inhibited, 1862 ethyl crotonate, 1917 ethyl acrylate.inhibited, 1919 methyl acrylate inhibited, 2277 ethylmethacrylate, 2385 ethyl isobutyrate, 2393 isobutylformate, 2394 isobutvl propionate, 2400 methylisovalerate, 2403 isoorooenyl acetate, 2406 isovroovlisobutyrate, 2409 isoproovl orooionate,2416 trimethyl borate, 2616 triisooroovl borate,2838 vinyl butyrate. inhibited,

3272 esters, n.o.s.;

Vol. 1845, A-8940


2301 3" (cont'd) Substances containing sulphur:(cont'd)

1111 amvl mercaptans, 2347 butyl mercagtans,2375 diethyl sulohide, 2381 dimethyl disulohide,2402 oropanethiols (propyl mercaptans),

2412 tetrahvdrothioohene (thiolanne), 2414 thioohene,

2436 thioacetic acid;

Substances containing nitrogen:

1113 amyl nitrites, 1222 isooroovl nitrate,1261 nitromethane, 1282 pyridine, 1648 acetonitrile

(methyl cyanide), 1865 n-nroovl nitrate, 2351 butyl

nitrites 2372 1.2 di-(dimethvlamino) ethane(tetramethylethylenediamine), 2410 1. 2. 3. 6-tetrahvdroovridine;

Other flammable substances and mixtures and preparations

containing flammable liquids:

1091 acetone oils, 1201 fusel oil, 12M3 tinctures.

medicinal, 1308 zirconium suspended in a flammableliouid, 2380 dimethvldiethoxvsilane,1993 flammable liquid. n.o.s.

NOTE: For viscous substances, mixtures andpreparations, see 5".

4 Solutions of nitrocellulose in mixtures of substances of

I to 3" containing more than 20% but not more than55% nitrocellulose with a nitrogen content not exceeding

12.6% (by dry mass):

(a) 2059 nitrocellulose solution. flammable;

(b) 2059 nitrocellulose solution. flammable.

NOTE 1: Mixtures having a flashpoint below 23 *C andcontaining more than 55% nitrocellulose, whatever its

nitrogen content or containing not more than 55%nitrocellulose with a nitrogen content above 12.6% (by

dry mass), are substances of Class 1, (see

Vol. 1845, A-8940


2301 3"(cont'd)

(cont'd) marginal 2101, 4, identification number 0340, or 26,

identification number 0342), or of Class 4.1 (seemarginal 2401, 24").

NOTE 2: Mixtures containing 20% or less nitrocellulosewith a nitrogen content not exceeding 12.6% (by dry

mass) are substances of 5".

5" Liquid or viscous mixtures and preparations, includingthose containing 20% or less nitrocellulose with a

nitrogen content not exceeding 12.6% (by dry mass):

(a) having a boiling point or initial boiling pointnot exceeding 35"C provided that they do not come

under (c):

1133 adhesives, 1139 coatino solution,1169 extracts. aromatic. liouid, 1197 extracts

flavourino. liquid, 1210 printing ink, 1263 paint

(including paint, lacquer, enamel, stain, shellac,varnish, polish, liquid filler and liquid lacquer

base), 1263 oaint related material (includingpaint thinning or reducing compound),1266 oerfumerv oroducts, 1286 rosin oil,1287 rubber solution, 1866 resin solution;

(b) having a boiling point or initial boiling point

exceeding 35 'C provided that they do not come

under (c):

1133 adhesives, 1139 coating solution,

1169 extracts. aromatic. liquid, 1197 extracts.

flavouring, liouid, 1210 orintina ink, 1263 paint

(including paint, lacquer, enamel, stain, shellac,varnish, polish, liquid filler and liquid lacquer

base), 1263 paint related material (includingpaint thinning or reducing compound),1266 perfumerv products, 1286 rosin oil,

1287 rubber solution, 1306 wood oreservatives,

1866 resin solution, 1999 tars. liquid including

road asphalt and oils, bitumen and cut backs,

3269 Dolvester resin kit;

Vol. 1845, A-8940


2301 5" (c) 1133 adhesives, 1139 coating solution,(cont'd) (cont'd) 1169 extracts. aromatic, liouid, 1197 extracts.

flavouring, liquid, 1210 orinting ink, 1263 paint(including paint, lacquer, enamel, stain, shellac,varnish, polish, liquid filler and liquid lacquerbase), 1263 oaint related material (includingpaint thinning or reducing compound),1266 oerfumerv oroducts, 1286 rosin oil,

1287 rubber solution, 1306 wood oreservatives,liouid, 1866 resin solution, 1999 tars. liquidincluding road asphalt and oils, bitumen and cut

backs, 3269 oolvester resin kit,1993 flammable liquid. n.o.s.

Classification under letter (c) is only possibleif the following requirements are met:

1. that the height of the separated layer ofsolvent is less than 3% of the total heightin the solvent-separation test; 2/ and

9/ Solvent-separation test: This test is carried out at 23" C using

a 100 ml graduated measuring cylinder of the stoppered type of approximately25 cm total height and of a uniform internal diameter of approximately 3 cmover the calibrated section. The substance should be stirred to obtain a

uniform consistency and poured into the measuring cylinder up to the 100 mlmark. The stopper should be inserted and the cylinder left standingundisturbed for 24 hours. After 24 hours the height of the upper separatedlayer should be measured and the layer's height as a percentage of the totalheight of the sample should be calculated.

Vol. 1845, A-8940


2301 5" (cont'd)(cont'd)

2. that the viscosity D/0 and flash-point arein accordance with the following table:

Flow time t inKinematic viscosity accordance with ISO 2431:1984 IFlashpointi (extrapolated) (at 1 i

near-zero shear rate) I Jet diameter fin "CImm2 /s at 23 "C in s in mm I

120 < y< 80 20 < t 601 4 jabove 17I 80 < y. 135 I 60 < t : 100 1 4 labove 10I 135 < y < 220 .1 20 < t - 32 6 jabove 51220 < y 300 132 < t s 44 6 jabove -11300 < y 700 I44 < t 1O0 6 jabove -5700 < y 1100 < t 6 I-5 and below

NOTE 1: Mixtures containing more than 20% but not more than 55%nitrocellulose with a nitrogen content not exceeding 12.6% by dry massare substances of 4.

Mixtures having a flashpoint below 23 'C and containing:

more than 55% nitrocellulose, whatever their nitrogen content; or

not more than 55% nitrocellulose with a nitrogen contentabove 12.6% by dry mass,

are substances of Class I (see marginal 2101, 4, No. 0340, or 22',No. 0342) or of Class 4.1 (see imarginal 2401, 24").

NOTE 2: No substances of ADR listed by name under other entries may becarried under the entry 1263 Paint or 1263 Paint related material.Substances carried under identification number 1263 may contain not morethan 20% nitrocellulose provided that the nitrogen content does notexceed 12.6% by dry mass.

IQ/ Viscosity determination: Where the substance concerned isnon-Newtonian, or where a flow cup method of viscosity determination isotherwise unsuitable, a variable shear-rate viscometer should be used todetermine the coefficient of dynamic viscosity of the substance, at 23 *C, ata number of shear rates, the values obtained are plotted against shear rateand then extrapolated to zero shear rate. The dynamic viscosity thusobtained, divided by the density, gives the apparent kinematic viscosity atnear-zero shear rate.

Vol. 1845, A-8940

1995


2301 5* (cont'd)(cont'd)

NOTE 3: 3269 Polyester resin kits have two components: a basicproduct (Class 3, Group (b) or (c)), and an activator (organicperoxide), each packed separately in an inner packaging. Theorganic peroxide shall be of types D, E or F, not requiringtemperature regulation and restricted to 125 ml liquid and 500 gsolid per inner packaging. The components may be placed in thesame outer packaging, provided that they do not react dangerouslywith each other in the event of leakage.

6" 3064 nitroalycerin solution in alcohol with more than 1% butnot more than 5% nitroglycerin.

NOTE: Special packing conditions are applicable for thissubstance (see marginal 2303); see also Class 1,marginal 2101, 4, identification number 0144.

7 (b) 1204 nitroglycerin solution in alcohol with not morethan 1% nitroglycerin.

B. Substances having a flashpoint below 23 'C and toxic.

NOTE: 1. Toxic substances having a flashpoint of 23 *C orabove, and some substances listed by name in I' to 10" ofmarginal 2601 are substances of Class 6.1.

NOTE: 2. For toxicity criteria, see marginal 2600.

11* Nitriles or isonitriles (isocyanides):

(a) 1093 acrvlonitrile. inhibited,3079 methacrvlonitrile. inhibited,3273 nitriles. flammable. toxic. n.o.s.;

(b) 2284 isobutyronitrile, 2378 2-dimethvl-aminoacetonitrile, 2404 prooionitrile,2411 butyronitrile,3273 nitriles. flammable. toxic. n.o.s.

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90 United Nations - Treaty Series e Nations Unies - Recueil des Traitis 1995

2301(cont'd) 12* 1921 oroovleneimine. inhibited.

NOTE: Special packing conditions are applicable for thissubstance (see marginal 2304).

13" 2481 Ethyl isocvanate.

NOTE: Special packing conditions are applicable for thissubstance (see marginal 2304).

14' Other isocyanates:

(a) 2483 isooroovl isocvanate, 2605 methoxvmethvlisocvanate;

(b) 2486 isobutyl isocvanate,2478 isocyanates. flammable. toxic. n.o.s., or2478 isocyanates solution, flammable. toxic. n.o.s.

NOTE: Solutions of isocyanates having a flashpoint above23 *C are substances of Class 6.1 (see marginal 2601, 18" or19").

15" Other substances containing nitrogen:

(a) 1194 ethyl nitrite, solution.

16" Halogenated organic substances:

(a) 1099 allvl bromide, 1100 allvl chloride,1991 chloroorene. inhibited;

(b) 1184 ethylene dichloride (1,2-dichloroethane),2354 chloromethvl ethyl ether.

17" Oxygenated organic substances:

(a) 2336 allvl formate, 2983 ethylene oxide and Dropylenexide mixture, with not more than 30% ethylene oxide,

I9 alcohols. flammable. toxic, n.o.s.,1988 aldehydes. flammable. toxic. n.o.s.;

Vol. 1845, A-8940


2301(cont'd) 17" (b) 1230 methanol, 2333 allyl acetate, 2335 allyl ethyl

(cont'd) ether, 2360 diallyl ether, 2396 methacrylaldehyde.

inhibited, 2622 olycidaldehyde,1986 alcohols. flammable, toxic. n.o.s.,1988 aldehydes. flammable. toxic. n.o.s.

18' Organic substances containing sulphur:

(a) 1131 carbon disulohide (carbon sulphide);

(b) 1228 mercaptans. liquid, flammable, toxic. n.o.s.,

1228 mercaotan mixture, liouid, flammable, toxic. n.o.s.

19° Substances, solutions and mixtures (such as preparations andwastes), having a flashpoint below 23 'C and toxic which

cannot be classified under another collective heading:

(a) 1992 flammable liquid, toxic. n.o.s.;

(b) 2603 cycloheotatriene,3248 medicine, liquid, flammable, toxic. n.o.s.,

1992 flammable liouid, toxic. n.o.s.

NOTE: Pharmaceutical products ready for use, e.g. cosmetics,drugs and medicines, which are substances manufactured and

packed in packagings of a type intended for retail sale or

distribution for personal or household consumption, which

would otherwise be substances of item 19" b), are not subjectto the provisions of ADR.

C. Substances having a flashooint below 23 "C and corrosive

NOTE 1: Corrosive liquids having a flashpoint of 23 "C or

above are substances'of Class 8 (see marginal 2801).

NOTE 2: Certain flammable corrosive liquids having aflashpoint below 23 *C and a boiling point above 35 *C are

subitances of Class 8 (see marginal 2800 (7) (a)).

Vol. 1845, A-8940


2301(cont'd) NOTE 3: For corrosivity criteria, see marginal 2800.

21' Chlorosilanes:

(a) 1250 methvltrichlorosilane,

1305 vinvltrichlorosilane. inhibited;

(b) 112 dimethvldichlorosilane, 1196 ethyltrichlorosilane,

1298 trimethvlchlorosilane,2985 chlorosilanes. flammable. corrosive. n.o.s.

NOTE: Chlorosilanes which give off flammable gases oncontact with water are substances of Class 4.3, 1* (a)[see marginal 2471, 1' (a)].

22* Amines and their solutions:

(a) 1221 isoorooylamine, 1297 trimethvlamine. aoueous

solution containing 30% to 50% trimethylamine (by mass),2733 amines. flammable. corrosive. n.o.s., or 2733polvamines. flammable. corrosive, n.o.s.;

(b) 1106 amvlamines (n-amylamine, tert-amylamine), n-butylamine, 1154 diethvlamine, 1158 diisooropvlamine,1160 dimethvlamine aoueous solution, 1214 isobutvlamine,1235 methvlamine, aueous solution, 1277 Dropylamine,1296 triethvlamine, 1297 trimethvlamine, aqueous

solution with not more than 30% trimethylamine by mass,2266 N.N-dimethylpropvlamine (dimethyl-N-propylamine),2270 ethvlamine aoueous solution with not less than 50%but not more than 70% ethylamine (by mass), 2379 1. 3-dimethylbutvlamine, 2383 dioropylamine, 2945 N-methvlbutvlamine,2733 amines. flammable. corrosive. n.o.s. or 2733polvamines. flammable. corrosive. n.o.s.

NOTE: Anhydrous dimethylamine, ethylamine, methylamine andtrimethylamine are substances of Class 2 (see marginal 2201,

3 (b t)].

Vol 1145, A-8940

1995 United Nations - Treaty Series - Nations Unies - Recueil des Trait6s 93

2301(cont'd) 23" Other substances containing nitrogen:

(b) 1922 ovrrolidine, 2386 1-ethylpieridine,

2399 1-methvlpioeridine, 2401 oiperidine,

2493 hexamethyleneimine, 2535 4-methylmoroholine

(N-methvlmorpholine).

24" Solutions of alcoholates:

(b) 1289 sodium methvlate solution in alcohol,

3274 alcoholates solution. n.o.s. in alcohol.

25" Other halogenated corrosive substances:

(b) 1717 acetyl chloride, 1723 allvl iodide,

1815 Drooionyl chloride, 2353 butvrvl chloride,

2395 isobutyryl chloride.

26° Substances, solutions and mixtures (such as preparations and

wastes) having a flashpoint below 23 'C and highly corrosive,

corrosive or slightly corrosive which cannot be classified

under another collective heading:

(a) 2924 flammable liouid, corrosive. n.o.s.;

(b) 2924 flammable liquid, corrosive, n.o.s.

0. Substances having a flashooint below 23 'C. toxic and

corrosive and articles containing those substances

27* (a) 3286 flammable liquid, toxic, corrosive. n.o.s.;

(b) 2359 diallvlamine,3286 flammable liouid. toxic. corrosive. n.o.s.

28* 3165 Aircraft hydraulic power unit fuel tank containing a

mixture of anhydrous hydrazine and methylhydrazine.

NOTE: Special packing conditions are applicable for these

tanks (see marginal 2309).

Vol 1845, A-8940


2301 E. Substances having a flashooint between 23 "C and 61 'C(cont'd) inclusive which might be slightly toxic or sliahtlv corrosive

NOTE: Non-toxic and non-corrosive solutions and homogeneousmixtures having a flashpoint of 23 'C or above (viscoussubstances, such as paints or varnishes, excluding substancescontaining more than 20% nitrocellulose) packed inreceptacles of less than 450 litres capacity, are subjectonly to the requirements of marginal 2314 if, in thesolvent-separation test, as described in footnote 1/ to 5,the height of the separated layer of solvent is less than 3%of the total height, and if the substances at 23 *C have, inthe flow cup conforming to ISO 2431:1984 having a jet 6 mm indiameter, a flow time of:

(a) not less than 60 seconds, or

(b) not less than 40 seconds and contain not more than60% of substances of Class 3.

31" Substances, solutions and mixtures (such as preparations andwastes) having a flashpoint between 23 *C and 61 "Cinclusive, not slightly toxic and not slightly corrosive:

(c) 1202 diesel fuel or 1202 gasoil or 1202 heatingoil (light), 1223 kerosene, 1267 petroleum crudeoi., 1863 fuel. aviation, turbine enoine,1268 petroleum distillates. n.o.s. or ]28petroleum products. n.o.s.

NOTE: By derogation from marginal 2300 (2), diesel fuel,gasoil and heating oil (light) having a flashpoint above61 "C shall be deemed substances of 31" (c), substanceidentification number 1202.

Hydrocarbons:

1136 coal tar distillates, 1147 decahvdronaohthalene(decalin), 1288 shale oil, 1299 turpentine, 1300 turpentine

substitute (white spirit), 1307 xylenes (m-xylene, p-xylene,dimethylbenzenes), 1918 isooroovlbenzene (cumene), 1 Mnonanes, 1999 tars. liauid including road asphalt and oils,bitumen and cut backs, 2046 cXmenes (o-,m-,p-) (methylisopropyl benzenes), 2048 dicvclooentadiene, 2049 diethylbenzenes (o-,m-,p-), 2052 dinentene (limonene), 2055 styrenemonomer, inhibited (vinylbenzene monomer inhibited), 2057tripropylene (propylene trimer), Z247 n-decane, Z8pentamethvlheotane (isododecane), 2303 isoprooenvlbenzene,

Vol. 1845, A-8940


2301(cont'd) 31* 2324 triisobutylene, 2325 1. 3. 5-trimethvlbenzene

(cont'd) (mesitylene), 2330 undecane, 2364 n-oroovlbenzene, ZMaIlha-ninene, 2520 cyclooctadienes, 2541 teroinolne, 2Ml8vinvltoluenes. inhibited (o-,m-,p-), 2709 butvlbenzenes, Zoroovlene tetramer (tetraproovlene), 2319 terpene

hydrocarbons. n.o.s.,

3295 hydrocarbons. liouid. n.o.s.;

Halogenated substances:

1134 chlorobenzene (phenyl chloride),1152 dichlorooentanes, 2047 dichloroorooenes,2234 chlorobenzotrifluorides (o-,m-,p-),2238 chlorotoluenes (o-,m-,p-), 2341 1-bromo-3-methvlbutane,2392 iodooropanes, 2514 bromobenzene, 2711 m-dibromobenzene;

Alcohols:

1105 amvl alcohols, 1120 butanols, 1148 diacetone alcoholchemically pure, 1170 ethanol solution (ethyl alcohol

solution) containing more than 24% and note more than70% alcohol, 1171 ethylene olvcol monoethvl ether(2-ethoxyethanol), 1188 ethylene olvcol monomethvl ether

(2-methoxyethanol), 1212 isobutanol (isobutyl alcohol),1274 n-oropanol, (oropyl alcohol, normal), 2053 methyl

isobutyl carbinol (methyl amyl alcohol), 2244 cyclooentanol,2275 2-ethylbutanol, 2282 hexanols, 2560 2-methvloentan-2-ol,2614 methallvl alcohol, 2617 methvlcyclohexanols, flammable,

2686 diethylaminoethanol, 3065 alcoholic beveraoes containingnot more than 24% and not more than 70% alcohol by volume3092 1-methoxv-2-orooanol,1987 alcohols. flammable. n.o.s.;

NOTE I: Aqueous solutions of ethyl alcohol and alcoholicbeverages containing not more than 24% alcohol by volume are

not subject to the provisions of ADR.

NOTE 2: Alcoholic beverages containing more than 24% and notmore than 70% alcohol by volume are subject to the provisions

of ADR only if carried in receptacles with a capacity of morethan 250 litres or in tank-vehicles, tank-containers or

demountable tanks.

Vol 1845. A-8940


2301(cont'd) 31 * Ethers:

(cont'd)1149 dibutyl ethers, 1153 ethylene glvcol diethyl ether(1, 2-diethoxyethane), 2219 allyl glycidyl ether,

2222 anisole (phenyl methyl ether), 2707 dimethyldioxanes,2752 1.2-eooxv-3-ethoxvorooane,3271 ethers. n.o.s.;

Aldehydes:

1191 octvl aldehydes (ethylhexaldehydes) (2-ethylhexaldehyde)

(3-ethylhexaldehyde), 1199 furfural (furfuraldehyde),1207 hexaldehyde, 1264 oparaldehyde, 2498 1. 2. 3. 6 -

tetrahvdrobenzaldehvde, 2607 acrolein dimer. stabilized, 305

n-heptaldehyde,1989 aldehydes, flammable. n.o.s.;

Ketones:

1110 n-amyl methyl ketone, 1157 diisobutyl ketone,

1229 mesityl oxide, 1915 cyclohexanone,2245 cyclopoentanone, 2271 ethyl amvl ketones,2293 4-methoxv-4 methvloentan-2-one,2297 methylcyclohexanones, 2302 5-methylhexan - 2 - one,

2310 oentan-2.4-dione (acetylacetone), 2621 acetvl methylcarbinol, 2710 dioroovl ketone,1224 ketones. n.o.s.;

Esters:

1104 amyl acetates, 1109 amyl formates, 1123 butyl acetates,1172 ethylene glycol monoethvl ether acetate (2-ethoxyethyl

acetate), 1177 ethvlbutvl acetate, 1180 ethyl butyrate, J).8ethylene alycol monomethvl ether acetate, 1192 ethyl lactate,1233 methvlamvl acetate, 1292 tetraethyl silicate, 1914

n-butyl oropionate, 2227 n-butyl methacrylate. inhibited,2243 cyclohexyl acetate, 2283 isobutyl methacrylate.

inhibited, 2323 triethyl hosohite, 2329 trimethyl ohosohite,2348 n-butyl acrylate inhibited, 2366 diethyl carbonate

(ethyl carbonate), 2405 isooroovl butyrate, 2413 tetraorooylorthotitanate, 2524 ethyl orthoformate, 2527 isobutylacrylate inhibited, 2528 isobutyl isobutyrate, Zjktriisoorooyl borate, 2620 amvl butyrates, 2708 butoxyl

(3-methoxy-l-acetoxybutane), 2933 methyl 2 - chlorooro-pij.1 , 2934 isoorogyl 2-chloroorooionate, 2935 ethyl

2-chlorooropionate, 2947 isooroovl chloroacetate,3272 esters. n.o.s;

Vol. 1845. A-8940

1995 United Nations - Treaty Series 9 Nations Unies - Recueil des Trait~s 97

2301 31" Substances containing nitrogen:

(cont'd) (cont'd)1112 amvl nitrates, 2054 moroholine, 2265 N.N-

dimethylformamide, 2313 picolines (methylpyridines)

2332 acetaldehyde oxime, 2351 butyl nitrites, M

nitrooropanes, 2840 butyraldoxime,2842 nitroethane, 2906 triisocvanatoisocvanurate of

isoohoronediisocyanate. solution (70% by mass),

2943 tetrahYdrofurfurvlamine;

Substances containing sulphur:

3054 cyclohekvl mercaotan;

Other flammable substances, mixtures and preparationscontaining flammable liquids:

1130 camohor oil, 1133 adhesives, 1139 coating solution,

1169 extracts. aromatic, liouid,

1197 extracts, flavouring, liouid, 1201 fusel oil,1210 printing ink, 1263 paint (including paint, lacquer,

enamel, stain, shellac, varnish, polish, liquid filler andliquid lacquer base) or 1263 paint related material

(including paint thinning or reducing compound),

1266 oerfumery products, 1272 pine oil, 1286 rosin oil,1287 rubber solution, 1293 tinctures. medicinal, 1306 wood

preservatives, liquid, 1308 zirconium susoended in a

flammable liquid, 1866 resin solution, 3269 oolvester resin

kit, 1993 flammable liouid. n.o.s.

NOTE 1: Mixtures containing more than 20% but not more than55% nitrocellullose with a nitrogen content not exceeding

12.6% (by dry mass) are substances of 34' (c).

NOTE 2: For 3269 polyester resin kits, see 5" NOTE 3.

32' Substances, solutions and mixtures (such as preparations and

wastes) having a flashpoint between 23 "C and 61 *C

inclusive, slightly toxic:

Vol. 1845, A-8940


2301 32"

(cont'd) (cont'd)(c) 2841 di-n-amvlamine,

1228 mercaotans. liquid. flammable. toxic, n.o.s. or

1228 mercaotan mixture. liquid, flammable. toxic.n.o.s.,

1986 alcohols flammable. toxic. n.o.s., 1988 aldehdeflammable. toxic. n.o.s., 2478 isocyanates, flammable,

toxic' n.o.s. or 2478 isocyanate solution. flammable.

toxic. n.o.s., 3248 medicine, liquid. flammable. toxic.n.o.s., 1992 flammable. liouid, toxic. n.o.s.

NOTE: Pharmaceutical products ready for use, e.g. cosmetics,

drugs and medicines, which are substances manufactured and

packed in packagings of a type intended for retail sale or

distribution for personal or household consumption, which

would otherwise be substances of 32" (c) are not subject to

the provisions of ADR.

33" Substances, solutions and mixtures (such as preparations and

wastes) having a flashpoint between 23 "C and 61 *C

inclusive, slightly corrosive:

(c) 1106 amvlamine (sec-amylamine), 1198 formaldehyde

solution. flammable, 1289 sodium methvlate solution in

alcohol, 1297 trimethvlamine. aqueous solution (not more

than 30% trimethylamine, by mass), 2260 trioroovlamine,

2276 2-ethylhexylamine, 2361 diisobutvlamine,

2526 furfurylamine, 2529 isobutyric acid,

2530 isobutyric anhydride, 2610 triallylamine,

2684 diethvlaminooronvlamine,

2733 amines. flammable. corrosive. n.o.s., or

2733 nolvamines, flammable. corrosive. n.o.s.,2924 flammable liquid, corrosive. n.o.s.

34' Solutions of nitrocellulose in mixtures of substances of

31' (c) containing more than 20% but not more than 55%

nitrocellulose with a nitrogen content not exceeding 12.6%

(by dry mass):

Vol 1845. A-8940


2301 34" (cont'd)(cont'd) (c) 2059 nitrocellulose solution, flammable.

NOTE: Mixtures containing more than 55% nitrocellulose,whatever its nitrogen content, or containing not more than55% nitrocellulose with a nitrogen content above 12.6% (bydry mass), are substances of Class 1 (see marginal 2101, 4,identification number 0340 or 26"% identification number0342) or of Class 4.1 (see marginal 2401, 24")

F. Substances and preparations used as pesticides having aflashpoint below 23 'C

NOTE 1: Flammable liquid substances and preparation, used aspesticides, which are highly toxic, toxic orslightly toxic and have a flashpoint of 23 *C orabove are substances of Class 6.1 (see marginal2601, 71' to 87").

NOTE 2: In the tables, pesticides are subdivided into items41 to 57" as follows:

highly toxic substances and preparationstoxic substances and preparationsslightly toxic substances and preparations.

NOTE 3: All active substances and their preparations used aspesticides shall be classified under 41" to 57"highly toxic, toxic and slightly toxic in accordancewith marginal 2600(3).

NOTE 4: If only the LDo value of the active substance isknownand not that of the preparations of the activesubstance, the preparations may be classified under4W to 57" highly toxic, toxic and harmful using thefollowipg tables, where the figures shown in columns"highly toxic", "toxic" and "slightly toxic" of 410to 57" represent the percentage of active pesticidesubstance in the preparations.

Vol. 1845, A-8940


2301(cont'd) NOTE 5: For substances which are not named in the list, and

for which only the LD,, value of the activesubstance is known and not the LD.o values of thevarious preparations, the classification of a

preparation may be determined from the table inmarginal 2600(3), using an LD.o value obtained bymultiplying the LD5 o value of the active substanceby jO0, x being the percentage of active substance

X

by mass according to the following formula:

1050 value - LD,5 value of the active substance x 100

percentage of active substance by mass

NOTE 6: The classification according to NOTES 4 and 5 above

shall not be used when the preparations contain

additives which affect the toxicity of the active

substance or when a preparation contains more thanone active substance. In such cases theclassification shall be based on the LD. value of

the preparation in question according to thecriteria in marginal 2600(3). If the LD.o value isnot known, the substance shall be classified underhighly toxic of 4W to 57*.

41" 2784 oraanoohosphorus pesticide. liquid. flammable, toxic,

flashpoint less than 23 "C

(a) having a boiling point or initial boiling point not

exceeding 35 *C and/or highly toxic;

Vol. 1845. A-8940


2301 41" (cont'd)(cont'd) (b) having a boiling point or initial boiling point

exceeding 35 "C and toxic or slightly toxic;

such as:

Highly toxic Toxic Slightly toxic

% %%

Azinohos-ethylAzinphos-methyl

Bromoohos-ethylCarbonhenotionChlorfen inohosChlormeohosChlorovriphosChlorthiophosCrotoxvo hosCrufomate

CvanoohosD LFDemethionDemetonDemeton-O(Svstox)Demeton-O-methvlDemeton-S-methvlDemeton-S-methvlsulfoneDialifosDiazinon

DichlofenthionDichlorvosDicrotohosDimefoxDimethoate

DioxathionDisulfotonEdifenohosEndothion

EthionEthoate-methvlEthoprophosFenaminphos

100->O100->30100->34

100->20

100->40

100->62

100->65100->40

100->25100->10

100->20100->20100->15

100->15

30->334->3.4

100->80100->74100->10

100->35100->2520->2

100->4040->4

100->4562->12.5100->25

65->1340->4

25-210-1

100-1420-220-215-1

100-1015-1

100-15100-gO100-55100-40

3->03.4-0.34100-35

80-1074-7.410-1

100-15100-5435-725-22-0

100-2940-44->0

100-3045-4

12.5-2.525-2

100-2513-24->0

Vol. 1845, A-8940

102 United Nations- Treaty Series * Nations Unies - Recueil des Traitks 1995

?301 410cont 'd)


Fenitrothion - - 100-48Fensulfothion 100->40 40->4 4->0Fenthion - - 100-38EQnpho 100->60 60->6 6-0.5Formothion - - 100-65Heotenoohos - 100-19Iprobenfos - - 100-95Isofenhos - 100->60 60-6Isothioate - - 100-25Isoxathion - - 100-20Mecarba - 100->30 30-3Meohosfolan 100->25 25->5 5-0.5Methamidophos - 100->15 15-1.5Methidathion - 100->40 40-4Methyltrithion - - 100-19Mevinphos 100->60 60->5 5-0.5Monocrotophos - 100->25 25-2.5Naled - - 100-50Omethoate - - 100-10Oxvdemeton-methyl - 100->93 93-9Oxvdisulfoton 100->70 70->5 5-0.5Paraoxon 100->35 35->3 3-0.35Parathion 100->40 40->4 4-0.4Parathion-methyl - 100->12 12-1.2Phenkaoton - 100-10Phenthoat - - 100-70Phorate 100->20 20->2 2->0Phosalone - - 100-24Phosfolan - 100->15 15-1Phosmet - - 100-18Phosohamidon - 100->34 34-3Pirimiohos-ethyl - - 100-28Prooaphos - 100->75 75-15Prothoate - 100->15 15-1Pvrazoohos - - 100-45Pvrazoxon 100->80 80->8 8-0.5Ouinalohos - 100->52 52-5Salithion - - 100-25Schradan - 100->18 18-3.6Sulfote - 100->10 10-1Sulprofos - - 100-18Temeros - - 100-90TEPR 100->10 10->O -Terbufos 100->15 15->3 3-0.74Thiomethon - 100->50 50-5Thionazin 100->70 70->5 5-0.5Triamio.hos - 100->20 20-1Triazohos - - 100-13Trichlorfon - - 100-23Trichloronat - 100->30 30-3Vamidothion - - 100-10

Vol, 1845, A-8940


42* 2762 organochlorine pesticide, liquid, flammable.toxic, flashpoint less than 23 "C(a) having a boiling point or initial boiling point

not exceeding 35 C and/or highly toxic;(b) having a boiling point or initial boiling point

exceeding 35 "C and toxic or slightly toxic;such as:

43" 2766 ohenoxv pesticide, liquid. flammable. toxic, flashpoint

less than 23 C

(a) having a boiling point or initial boiling point notexceeding 35 "C and/or highly toxic;

(b) having a boiling point or initial boiling pointexceeding 35 "C and toxic or slightly toxic;such as:

44* 2758 carbamate pesticide, liquid. flammable. toxic,flashpoint less than 23 "C

Vol. 1945, A-8940

2301(con'd)


Aldrin - 100->75 75-7Allidochlor - - 100-35Camohechlor - - 100-15Chlordane - - 100-55Chlordimeform - - 100-50Chlordimeform.hvdrochloride - 100-70Chlorophacinone 100->40 40->4 1-0.4Crimidin 100->25 25->2 2->0DDT - - 100-20Dibromo-1,2-chloro-3-propane - - 100-34Dieldrine - 100->5 75-7Endosulfan - 100->80 80-8

Endrin 100->60 60->6 6-0.5Heptachlor - 100->80 80-8

Isobenzane 100->10 10->2 2-0.4Isodrin - 100->14 14-1Lindane (BHC) - 100-15

- - 100-60

Pentachlorophenol 100->54 54-5

104 United Nations - Treaty Series 9 Nations Unies - Recueil des Traitks

2301 44" (cont'd)(cont'd)

(a) having a boiling point or initial boiling point not exceeding35 C and/or highly toxic;

(b) having a boiling point or initial boiling point exceeding 35 "Cand toxic or slightly toxic;such as:


% % : %

Aldicarb 100->15 15->1 1->0

Aminocarb 100->60 60-6Bendiocarb 100->65 65-5Benfuracarb - 100-20Butocarboxim - 100-30Carbaryl -100-10Carbofuran -100->10 10-1Cartap HCI 100-40Diallate 100-75Dimetan j 100-24Dimetilan - 100->50 50-5Dioxacarb - - 100-10Formetanate 100->40 40-4Isolan 100->20 20-2Isoorocarb -100-35

Mercaotodimethur - 100->70 70-7Methasulfocarb - - 100-20Methomyl - 100->34 34-3Mexacarbate 100->28 28-2Mobam- - 100-140xamyl 100->10 10-1Pirimicarb - 0-2gpromecarb, 100-14Promorit(Muritanl 100->5.6 5.6->0.56 I 0.56->0Proooxur - 100-18

45* 2778 mercury based pesticide. liQuid, flammable, toxic,flashpoint less than 23 "C

(a) having a boiling point or initial boiling point notexceeding 35 'C and/or highly toxic;

(b) having a boiling point or initial boiling pointexceeding 35 C and toxic or slightly toxic;such as:

Vol. 1845, A-8940

1995


2301 45"(cont'd) (cont'd)


%. %%

Phenylmercuric acetate (PMA) - 100->60 60-6Mercuric chloride - 100->70 70-7Chloro-methoxvethvlmercury 100->40 40-4Mercury oxide - 100->35 35-3Phenvlmercurv ovrocatechinLEi.- 100->60 60-6

46* 2787 oraanotin oesticide. liouid. flammable. toxic,flashpoint less than 23 *C

(a) having a boiling point or initial boiling point notexceeding 35 *C and/or slightly toxic;


IHighly toxici Toxic JSlightly toxici

II I IS% % %Fentin acetate I - I 100-25Cyhexatin - I - 100-35Fentin hvdroxvde I - I I 100-20

Ii I I

47* 3024 coumarin derivative oesticide. liauid. flamnable. toxic,flashpoint less than 23 *C


(b) having a boiling point or initial boiling pointexceeding 35 *C and toxic or slightly toxic;such as:

Vol. 1845, A-8940


2301(cont'd)

47* (c.Qnt'd)

I I I

lHighly toxicl Toxic ISlightly toxic

% I % I %II II II Brodifacoum 100->5 5->0.5 0.5-0.05Coumachlor 100-10Coumafurvl - 100-80Coumaphos 100->30 30-3Coumatetralvl(Racumin) 100->34 34-3.4Dicoumarol 100-10Difenacoum 100->35 35->3.5 3.5-0.35Warfarin (and salts of 100->60 60->6 6-0.6warfarin)

48* 2782 biovridilium pesticide, liouid.flashpoint less than 23 *C

flammable. toxic.


(b) having a boiling point or initial boiling pointexceeding 35 'C and toxic or slightly toxic;such as:

II I 1

iHighly toxici Toxic iSlightly toxic'I I

I I IDiuatI 100-45IParaouat 1 jI00->40 40-8 ISI I I

I I I

49* 2760 arsenical pesticide. liouid, flammable. toxic,flashpoint less than 23 *C

(a) having a boiling point or initial boiling.pointnot exceeding 35 'C and/or highly toxic;

(b) having a boiling point or initial boiling pointexceeding 35 'C and toxic or slightly toxic;

Vol. 1845, A-8940


2301(cont'd)

49" (cont'd)

such as:SI I I

JHighly toxicJ Toxic JSlightly toxictII I III I I III I I

Arsenic trioxide " I 100->40 40-4 ICalcium arsenate I - I 100->40 I 40-4Sodium arsenite I I00->20 j 20-2 I

iI I II

50* 2776 copper based pesticide. liauidflashpoint less than 23 *C

flammable, toxic.



I I I I

[Highly toxici Toxic ISlightly toxic,S I I II I I I

II IICoDDer sulphate I I - 100-20

I I1

51' 2780 substituted nitrophenol pesticide. liouid. flammable.toxic, flashpoint less than 23 *C



exceeding 35 "C and toxic or slightly toxic;such as:

Vol 1945, A-8940

flammable toic


2301(cont'd)

51" (cont'd)

Highly toxici Toxic ISlightly toxic

I % I % I %III I

I in.pacryl 100-25Dinobuton 100-10Dinoseb 100->40 40-8Dinoseb acetate 100-10Dinoterb 100->50 50-5Dinoterb acetate 100->50 50-5DKO. 100->50 50-5Medinoterb 100->80 80-8

52* 2764 triazine pesticide. liouid, flammable. toxic, flashpointless than 23 "C



I I I

IHighly toxict Toxic ISlightly toxiciI I % I % I

II ItCvanazine I I I 100-35 iTerbumeton j - I 100-95 I

53' 2770 benzoic derivative pesticide. liouid. flammable. toxic,flashpoint less than 23 *C



Vol. 1845, A-8940


2301(cont'd)

53" (cont'd)

II I I I

IHighly toxici Toxic ISlightly toxic,% I I III I I I

II I I II iTib 1 i -o100-60 i

SI I II

54" 2774 ohthalimide derivative oesticide. liouid. flaImmable.toxic, flashpoint less than 23 'C

(a) having a boiling point or initial boiling pointnot exceeding 35 "C and/or highly toxic;


II I I

iHighly toxici Toxic iSlightly toxic!S) I I Il I l i 0

SI I ISI % I -I

II III

55" 2768 ohenvl urea pesticides, liquid, flammable. toxic,flashpoint less than 23 °C

(a) having a boiling point or initial boiling pointnot exceeding 35 'C and/or highly toxic;


I I I

iHighly toxic, Toxic ISlightly toxic I

I I % I % II p I I eI - .I - I - I I

II I II

*/No pesticide currently assigned to this collective entry.

Vol. 1845, A-8940

109


56* 2772 dithiocarbamate pesticide. liouid, flammable. toxic,flashpoint less than 23 'C

(a) having a boiling point or initial boiling pointnot exceeding 35 "C and/or highly toxic;


III I

iHighly toxici Toxic Slightly toxiciI I% % % ~II I I

IMetam-sodium I - I II I II

57' 3021 pesticide. liouid. flammable, toxic. n.o.s., flashpointless than 23 *C

(a) having a boiling point or initial boiling pointnot exceeding 35 *C and/or highly toxic;


exceeding 35 "C and toxic or slightly toxic;

nitrogenated organic compounds, such as:


Benouinox 100-20Chinomethionate 100-50Cvcloheximide 100->40 40->4 4->ODrazoxolon 100-25

Alkaloids, such as:


Nicotine oreoarations - 100->25 25-5Strychnine 100->20 20->0 -

Vol. 1845, A-8940

2301(cot'd)


2301 57*(cont'd) (cont'd)

Other organo-metallic compounds, such as:


Inorganic compounds of fluorine, such as:


r % 1

Barium silicofluoride 100-35

Sodium silicofluoride - -- 100-25

Inorganic compounds of thallium, such as:


Thallium sulohate - I0->30 30-3

!/ No pesticide currently assigned to this collective entry.

Vol. 1845, A-8940


2301 (cont'd) Other pesticides, such as:

Highly toxici Toxic ISlightly toxici% I % I

I AU 100->40 40->4 4-0.8Blasticidine-S-3 - I100-10Bromoxvnil - 100-38Dazomet - 100-60Diphacinone 100->25 25->3 3-0.2Difenzoouat - 100-90

I - I - I 100-48Endothal-sodium 100->75 75-7

IfFenaminosulph - 100->50 50-10FenoropathriI - - 00-10Fluoracetamide - 100->25 25-2.5Imazlil- 100-64lzxni1- 100-20Kelevan - 100-48Norbormide 100->88 88->8.8 8.8-0.8Pindone (and salts ofPindone) - 0-55

1Rotenone - 100-25 1

Pyrethrinoids, such as:II I I

'Highly toxicl Toxic ISlightly toxiciSI I ICyI 1 I 3

I voretri I - I I00-32 ISi i I

G. Substances having a flashobint above 61 "C whitth are carried nr

Vol. 1945, A-8940

handed over for carriage at or above their flashooint

61" (c) 3256 Elevated temoerature liauid. flammable, no.s- witha flashpoint above 61 'C at or above its flashpoint.

United Nations - Treaty Series e Nations Unies - Recueil des Traitis

2301(cont'd)

H. Empty oackaings

71" Empty oackagins including emptv intermediate bulkcontainers, (IBCs), empty tank-vehicles. emotv demountabletanks, emoty tank-containers, uncleaned having contained

substances of Class 3.

2301a Neither the provisions for this Class contained in this Annex northose contained in Annex B are applicable to:

(1) Substances of I' to 5, 21" to 26" and 31* to 34' andslightly toxic substances of 41" to 57* carried in conformity with

the following provisions:

(a) Substances classified under (a) of each item: not morethan 500 ml per iner packaging and not more than I litreper package;

(b) Substances classified under (b) of each item except5* (b) and alcoholic beverages of 3" (b): not more than3 litres per inner packaging and not more than 12 litres

per package;

(c) Alcoholic beverages of 3* (b): not more than 5 litresper inner packaging;

(d) Substances classified under 5" (b): not more than5 litres per inner packaging and not more than 20 litres

per package;

(e) Substances classified under (c) of each item: not morethan 5 litres per inner packaging and not more than

45 litres per package.

These quantities of substances shall be carried in combination

packagings conforming at least to the conditions of marginal 3538.

The "General conditions of packing" of marginal 3500 (1), (2) and(5) to (7) shall be observed.

NOTE: In the case of homogeneous mixtures containing water, thequantities specified relate only to the substance of this Class

contained in those mixtures.

Vol. 1845, A-8940

1995


2301a (2) Alcoholic beverages of 31' (c) in packagings containing(cont'd) not more than 250 litres.

(3) The motor-fuel contained in the tanks of transportvehicles for their propulsion or the operation of theirspecialized equipment.(refrigerators, for example). The fuelcocks between the engine and the fuel tank of motor cyclesand motor-assisted pedal cycles whose tanks contain fuel,shall be closed during transport; in addition, these motorcycles and motor-assisted pedal cycles shall be loadedupright and secured against falling.

2. Provisions

A. Packages

1. General conditions of packing

2302 (1) Packagings shall satisfy the conditions of Appendix A.5,unless special conditions for the packing of certain substances areprescribed in marginals 2303 to 2310.

(2) Intermediate bulk containers (IBCs) shall satisfy theconditions of Appendix A.6.

(3) In accordance with the provisions of marginals 2300 (3)and 3511 (2) or 3611 (2) the following shall be used:

Packagings of packing group I, marked with the letter "X",for the very dangerous substances classified under theletter (a) of each item;

Packagings of packing group II or I, marked with the letter"Y", or "X", or IBCs of packing group II, marked with theletter "Y", for the dangerous substances classified under theletter (b) of each item;

Packagings of packing group III, II or I, marked with theletter "Z", "Y" or "X", or IBCs of packing group III or II,marked with the letter "Z" or "Y", for the less dangeroussubstances classified under the letter (c) of each item.

NOTE: For the carriage of substances of Class 3 in tank-vehicles,demountable tanks or tank-containers, see Annex B.

Vol. 1845, A-8940

1995 United Nations - Treaty Series 9 Nations Unies - Recueil des Traitks 115

2. Special conditions for Qacking of certain substances

2303 Nitroglycerine, solution in alcohol, of 6" shall be packed in metalcans of not more than I litre capacity each, overpacked in a woodenbox capable of containing not more than 5 litres of solution.Metal cans shall be completely surrounded with absorbent cushioningmaterial. Wooden boxes shall be completely lined with suitablematerial impervious to water and nitroglycerine.

Packages of this kind shall satisfy the test requirements forcombination packagings in accordance with Appendix A.5 for packing

group II.

2304 (1) Propyleneimine of 12" shall be packed:

(a) in steel receptacles of sufficient thickness, whichshall be closed by a screw-threaded bung or plugrendered leakproof both to liquid and to vapour by meansof a suitable gasket. The receptacles shall initiallyand periodically, at least every five years, be testedat a pressure of not less than 0.3 MPa (3 bar) gaugepressure in accordance with marginals 2215 (1) and 2216.

Each receptacle shall be secured by absorbent cushioningmaterials in a strong leakproof protective metalpackaging. The protective packaging shall behermetically closed and its closure shall be securedagainst any inadvertent opening. The mass of thecontents shall not exceed 0.67 kg per litre of capacity.A package shall not weigh more than 75 kg. Packagesweighing more than 30 kg, other than those forwarded asa full load, shall be fitted with means of handling; or

(b) in steel receptacles of sufficient thickness, whichshall be closed by a screw-threaded bung and a

screw-threaded protective cap or equivalent deviceleakproof both to liquid and to vapour. The receptacles

shall initially and periodically, at least everyfive years, be tested at a pressure of at least 1 MPa(10 bar) gauge pressure in accordance with marginals2215 (1) and 2216. The mass of the contents shall notexceed 0.67 kg per litre of capacity. A package shallnot weigh more than 75 kg.

Vol. 1845. A-8940


2304 (1) (cont'd)(c) Receptacles in conformity with (a) and (b) shall bear,(cont'd) in clearly legible and durable characters:

the name or mark of the manufacturer and the number ofthe receptacle;

the word "propyleneimine";

the tare of the receptacle and its maximum permittedmass when filled;

the date (month and year) of the initial test and of themost recent test undergone;

the stamp of the expert who carried out the tests andexaminations.

(2) Ethyl isocyanate of 13' shall be packed:

(a) in hermetically closed receptacles made of purealuminium and having a capacity not exceeding 1 litre,which shall not be filled beyond 90% of their capacity.The receptacles shall be secured, not more than 10 to abox, with appropriate cushioning material in a woodenbox. Packages of this kind shall satisfy the testrequirements for combination packagings conforming tomarginal 3538 for packing group I, and shall not weighmore than 30 kg; or

(b) in receptacles made of pure aluminium having a wallthickness of not less than 5 nun or in receptacles ofstainless steel. The receptacles shall be fully weldedand shall initially and periodically, at least everyfive years, be tested at a pressure of at least 0.5 MPa(5 bar) gauge presslure in accordance with marginals2215 (1) and 2216. They shall be so closed as to beleakproof by means of two closures one above the other,one of which shall be screw-threaded or secured in anequally effective manner.

The degree of filling shall be not more than 90%.

Drums weighing more than 100 kg shall be fitted withrolling hoops or stiffening ribs;

Vol. 1845, A-8940


2304 (2)(cont'd) (cont'd)(c) Receptacles in conformity with (b) shall bear, in

clearly legible and durable characters:

the name or mark of the manufacturer and the number of

the receptacle;

the words "ethyl isocyanate";

the tare of the receptacle and its maximum permitted

mass when filled;

the date (month and year) of the initial test and of the

most recent test undergone;

the stamp of the expert who carried out the tests and

examinations.

2305 Substances classified under (a) of the various items shall be

packed:

(a) in non-removable head steel drums conforming to

marginal 3520; or

(b) in non-removable head aluminium drums conforming to

marginal 3521; or

(c) in non-removable head steel jerricans conforming to

marginal 3522; or

(d) in non-removable head plastics drums of a capacity not

exceeding 60 litres or non-removable head plastics

jerricans conforming to marginal 3526; or

(e) in composite packagings (plastics material) conforming

to marginal 3537; or

(f) in combination packagings with inner packagings of

glass, plastics material or metal conforming to

marginal 3538.

Vol. 1845, A-8940


2306 (I) Substances classified under (b) of the various itemsshall be packed:

(a) in steel drums conforming to marginal 3520; or

(b) in aluminium drums conforming to marginal 3521; or

(c) in steel jerricans conforming to marginal 3522; or

(d) in plastics drums or jerricans conforming to

marginal 3526; or

(e) in composite packagings (plastics material) conformingto marginal 3537; or

(f) in combination packagings conforming to marginal 3538.

NOTE 1 to (a), (b), (c) and (d): Nitromethane of 3" (b)shall not be carried in removable head packagings.

NOTE 2 to (a), (b), (c) and (d): Simplified conditions areapplicable to removable-head drums or jerricans forviscous substances having a viscosity above200 mm2 /s at 23 *C (see marginals 3512, 3553, 3554and 3560).

(2) Substances classified under (b) of 3', 15', 17, 22, 24" and25" as well as the slightly toxic substances classified under (b)of 41 to 57" may also be packed in composite packagings (glass,porcelain or stoneware) conforming to marginal 3539.

(3) Substances classified under (b) of the various itemswith the exception of nitromethane of 3" (b) which have a vapourpressure at 50 "C of n6t'more than 110 kPa (1.10 bar) may also bepacked in metal IBCs conforming to marginal 3622, in rigid plasticsIBCs conforming to marginal 3624 or in composite IBCs with rigidplastics inner receptacle conforming to marginal 3625.

2307 (1) Substances classified under (c) of the various items shall bepacked:



Vol. 1845, A-8940


2307 (1) (c) in steel jerricans conforming to marginal 3522; or(cont'd) (cont'd)

(d) in plastics drums or jerricans conforming tomarginal 3526; or

(e) in composite packagings (plastics material) conformingto marginal 3537; or

(f) in combination packagings conforming to marginal 3538;or

(g) in composite packagings (glass, porcelain or stoneware)conforming to marginal 3539.

NOTE to (a), (b), (c) and (d): Simplified conditions areapplicable'to removable-head drums and jerricans for viscoussubstances having a viscosity of more than 200 mm2/s at 23 'C(see marginals 3512, 3553, 3554 and 3560).

(2) Substances classified under (c) of the various items may alsobe packed in metal IBCs conforming to marginal 3622, in rigidplastics IBCs conforming to marginal 3624 or in composite IBCs withrigid plastics inner receptacle conforming to marginal 3625.

2308 (1) Ethyl alcohol and its aqueous solutions and alcoholicbeverages of 3" (b) and 31' (c) may also be packed in bung-typewooden barrels conforming to marginal 3524.

(2) Alcoholic beverages containing more than 24% alcohol but notmore than 70% by volume, when transported as part of themanufacturing process, may be transported in wooden casks with acapacity of not more than 500 litres, deviating from the provisionsof Appendix A.5 on the following conditions:

(a) the casks shall be checked and tightened before filling;

(b) sufficient ullage (not less than 3%) shall be left to

allow for the expansion of the liquid;

(c) the casks shall be transported with the bungholespointing upwards and,

Vol. 1845, A-8940

120 United Nations - Treaty Series * Nations Unies - Recueil des Traitas 1995

2308 (2) (d) the casks shall be transported in containers meeting the(cont'd) requirements of the International Convention for Safe

Containers (CSC),*I1/ as amended.* Each cask shall besecured in custom made cradles and be wedged byappropriate means to prevent them from being displacedin any way during transport.

(3) Substances of 3" (b), 4 (b), 5' (b) and (c), 20" (b),31' (c), 32" (c), 33' (c), 34' (c) and the slightly toxicsubstances classified under (b) of 41' to 57" may also be packed inlight gauge metal packagings conforming to marginal 3540.Simplified conditions are applicable to removable-head light gaugemetal packagings for viscous substances having a viscosity of morethan 200 mm2/s at 23 *C and for substances of 5" (c). (Seemarginals 3512 and 3552 to 3554).

NOTE: Nitromethane of 3" (b) shall not be carried inremovable-head packagings.

(4) The following substances: 1133 adhesives, 1210 printing ink,1263 paint, 1263 oaint-related material, 1866 resin solution and3269 polyester resin kit of 5' (b), 5" (c) and 31" (c) may becarried in quantities not exceeding 5 litres in metal or plasticspackagings meeting only the requirements of marginal 3500 (1), (2)and (5) to (7), provided the packagings are secured on pallets bystraps, by shrink or stretch-wrapping or by other suitable means,or provided the packagings are inner packagings of a combinationpackaging with a maximum total gross mass of 40 kg. Theinformation in the transport document shall conform to marginal2314 (1) and (3).

2309 Aircraft hydraulic power unit fuel tanks of 28" are admittedsubject to either of the following conditions.

(a) the unit shall consist of an aluminium pressure vesselmade from tubing and having welded heads. Primarycontainment of the fuel within this vessel shall consistof a welded aluminium bladder having a maximum internalvolume of 46 litres. The outer vessel shall have a

11/ International Convention for Safe Containers (Geneva, 1972), asamended, published by the International Maritime Organization, 4 AlbertEmbankment, London SEI 7SR.

• United Nations, Treaty Series, vol. 1064, p. 3.** Ibid., vol. 1263, p. 477; vol. 1348, p. 328 and vol. 1714, No. A-16198.

Vol. 1845, A-8940


2309 (a) minimum design gauge pressure of 1.275 kPa and a minimum

(cont'd) (cont'd) burst gauge pressure of 2.755 kPa. Each vessel shall be

leak-checked during manufacture and before shipment and

shall be found leakproof. The complete inner unit shall

be securely packed in non-combustible cushioning

material, such as vermiculite, in a strong outer tightly

closed metal packaging which shall adequately protect

all fittings. Maximum quantity of fuel per unit and

package is 42 litres; or

(b) the unit shall consist of an aluminium pressure vessel.

Primary containment of the fuel within this vessel shall

consist of a welded hermetically sealed fuel compartment

with an elastomeric bladder having a maximum internal

volume of-46 litres. The pressure vessel shall have a

minimum design gauge pressure of 2.860 kPa and a minimum

burst gauge pressure of 5.170 kPa. Each vessel shall be

leak-checked during manufacture and before shipment and

shall be found leakproof. The complete inner unit shall

be securely packed in non-combustible cushioning

material, such as vermiculite, in a strong outer tightly

closed metal packaging which shall adequately protect

all fittings. Maximum quantity of fuel per unit and

package is 42 litres.

2310 Receptacles or IBCs, containing preparations of 31" (c), 32" (c),

and 33' (c), which give off small quantities of carbon dioxide

and/or nitrogen, shall be vented, in accordance with marginals

3500 (8) or 3601 (6).

3. Mixed packing

2311 (1) Substances covered by the same item number may be packed

together in a combination packaging conforming to marginal 3538.

(2) Substances or articles of different items of this Class in

quantities not exceeding 5 litres per inner packaging, may be

packed together and/or with goods not subject to the provisions of

ADR in a combination packaging conforming to marginal 3538,

provided they do not react dangerously with one another.

(3) Substances of 6', 7, 12' and 13" shall not be packed with

other goods.

Vol. 1845. A-8940


2311 (4) Substances classified under (a) of the various items shall(cont'd) not be packed together with substances and articles of classes 1

and 5.2 (other than hardeners and compound systems) and material ofclass 7.

(5) Except as otherwise specially provided, substances classifiedunder (a) of the various items, in quantities not exceeding0.5 litre per inner packaging and 1 litre per package, andsubstances classified under (b) or (c) of the the various items, inquantities not exceeding 5 litres per inner packaging may bepacked together in a combination packaging conforming to marginal3538 with substances or articles of other classes, provided thatmixed packing is also permitted for substances or articles of theseclasses, and/or with goods which are not subject to the provisionsof ADR, provided they do not react dangerously with one another.

(6) The following are considered dangerous reactions:

(a) combustion and/or giving off considerable heat;

(b) emission of flammable and/or toxic gases;

(c) formation of corrosive liquids;

(d) formation of unstable substances.

(7) The mixed packing of acid substances with basic substances ina package shall not be permitted if the two substances are packedin fragile receptacles.

(8) The provisions of marginals 2001 (7), 2002 (6) and (7)and 2302 shall be complied with.

(9) If wooden or fibreboard boxes are used, a package shall not

weigh more than 100 kg.

4. Marking and danger labels on packages (see Appendix A9)

Mking

2312 (1) Each package shall be clearly marked with the identificationnumber of the goods to be entered in the transport document,preceded by the letters "UN".

Vol. 1845, A-8940


2312 Danger labels(cont'd)

(2) Packages containing substances or articles of thisClass shall bear a label conforming to model No. 3.

(3) Packages containing substances of 1 to 19, 32" and 41'to 57" shall in addition bear a label conforming to model No. 6.1.

(4) Packages containing substances of 21* to 26° and 33" shall inaddition bear a label conforming to model No. 8.

(5) Packages containing substances or articles of 27" and 28"shall in addition bear a label conforming to model No. 6.1 and alabel conforming to model No. 8.

(6) Packages containing fragile receptacles not visible from theoutside shall in addition bear on two opposite sides a labelconforming to model No. 12.

(7) Packages containing receptacles, the closures of which arenot visible from the outside and packages containing ventedreceptacles or vented receptacles without outer packaging shall inaddition bear on two opposite sides a label conforming to modelNo. 11.

2313-

B. Particulars in the transoort document

2314 (1) The description of the goods in the transport document shallconform to one of the identification numbers and names underlinedin marginal 2301.

If the substance is not mentioned by name, but is assigned to ann.o.s. entry, or to another collective entry the description of thegoods shall consist of the identification number and the n.o.s.designation or the collective entry designation, followed by thechemical or technical name. A/

1/ The technical name shall be a name currently used in scientific andtechnical handbooks, journals and texts. Trade names shall not be used forthis purpose.

Vol. 1845, A-8940

124 United Nations - Treaty Series * Nations Unies - Recuei des Traitis 1995

2314 (1) The description of the goods shall be followed by particulars of(cont'd) the class, the item number, if applicable the letter. and the

initials "ADR" (or "RID"), (e.g. "3, 1' (a), ADR).

For substances and preparations of 41" to 57, the name shall beentered for the most dangerous component, both of the pesticideelement 5/ and of the flammable liquid element (e.g. "parathionin hexane").

For the carriage of wastes (see marginal 2000 (5)), the descriptionof the goods shall be: "Waste containing ...", the component(s)used for the classification of the waste under marginal 2002 (8) tobe entered under its/their chemical name(s), e.g. "Waste,containing 1230 methanol, 3, 17" (b)".

For the carriage of solutions or mixtures (such as preparations andwastes) containing several components subject to the provisions ofADR, it will not in general be necessary to refer to more thantwo components which most predominantly contribute to the danger ordangers of the solutions and mixtures.

For the carriage of solutions or mixtures containing only onecomponent subject to the provisions of ADR, the words "solution" or"mixture" should be added as part of the name in the transportdocument (see marginal 2002 (8)).

If a solution or mixture specifically named or containing aspecifically named substance is not subject to the conditions ofthis Class in accordance with marginal 2300 (5), the consignor mayenter in the transport document: "Not goods of Class 3".

(2) For consignments in accordance with the NOTE under E ofmarginal 2301, the consigopr shall enter in the transport document"Transport in accordance with NOTE under E of marginal 2301*.

(3) For consignments in accordance with marginal 2308 (4), theconsignor shall enter in the transport document 'Transport inaccordance with marginal 2308 (4)'.

V] For the description of the pesticide element, the name according toISO Standard 1750:1981 (see marginal 2601) should be used, if it appearstherein.

Vol. 1845, A-8940


2315-2321

C. Emotv oackaainos

2322 (1) Empty packagings, including empty IBCs, uncleaned, of 71,

shall be closed in the same way and with the same degree ofleakproofness as if they were full.

(2) Empty packagings, including empty IBCs, uncleaned, of 71",

shall bear the same danger labels as if they were full.

(3) The description in the transport document shall conform to one

of the names underlined in 71, e.g. "Empty packaging 3, 71', ADR'.

In the case of empty tank-vehicles, empty demountable tanks and

empty tank-containers, uncleaned, this description shall be

completed by adding the words "Last load", together with the name

and item number of the goods last loaded, e.g. "Last load 1089acetaldehyde, I' (a)".

2323-2324

D. Transitional measures

2325 Substances of class 3 may be carried until 30 June 1995 in

accordance with the requirements for class 3 applicable until31 December 1994. The transport document shall, in such cases,

bear the inscription "Carriage in accordance with the ADR in force

before 1 January 1995".

2326-23990

Vol. 1845, A-8940


CLASS 4.1. FLAMMABLE SOLIDS

2400 (2) Amend as follows:

"(2) The title of Class 4.1 covers substances and articles which

have a melting-point greater than 20"C or are pasty, according

to the criteria of the penetrometer test (see Appendix A.3,marginal 3310) or are not liquid according to the ASTM D 4359-90 test method, or which are self-reactive liquids. The

following are assigned to Class 4.1:

- readily flammable solid substances and articles,

and those which can be ignited by flying sparks orcan cause fire through friction;

- self-reactive substances which (at normal or

elevated temperatures) are liable to undergostrongly exothermal decomposition caused byexcessively high carriage temperatures or bycontact with impurities;

- substances related to self-reactive substances,which are distinguished from the latter by having aself-accelerating decomposition temperature greaterthan 75"C, and are liable to undergo a stronglyexothermic decomposition and may, in certain

packagings, meet the criteria for explosive

substances of Class 1;

- explosives, which are wetted with such a quantity

of water or alcohol or which contain such aquantity of plasticizing or inerting agent, thattheir explosive properties are neutralized.

NOTE 1: Self-reactive substances and formulations of self-reactive substances are not considered to be self-reactivesubstances of Class 4.1 if:

- they are explosives according to the criteria of

Class 1;

- they are oxidizing substances according to the

assignment procedure of Class 5.1;

Vol. 1845, A-8940

1995 United Nations -Treaty Series o Nations Unies - Recueil des Trait~s 127

2400 (2) they are organic peroxides according to the(cont'd) criteria of Class 5.2;

their heat of decomposition is less than 300 J/g;

their self-accelerating decomposition temperature(SADT) is greater than 75C for a 50 kg package;

tests have proved that they are exempted as type G(see Appendix A.1, marginal 3104 (2) (g)).

NOTE 2: The heat of decomposition can be determined using anyinternationally recognized method e.g. Differential ScanningCalorimetry and adiabatic calorimetry.

NOTE 3: The self-accelerating decomposition temperature (SADT)

is the lowest temperature at which self-acceleratingdecomposition may occur with a substance in the packaging asused during carriage. Requirements for the determination of theSADT are given in Appendix A.1, marginal 3103."

(3) Amend the beginning of paragraph (3) to read:

"(3) The substances and articles of Class 4.1 are subdivided asfollows:

A Solid organic flammable substances and articles

B Solid inorganic flammable substances and articles

C Explosive substances in non-explosive state

D Substances related to self-reactive substances

E Self-reactive substances not requiring temperature

control

F Self-reactive substances requiring temperature control

G Empty packagings"

Vol 1845, A-8940


2400 Append to paragraph (3) the following:

(cont'd)"Substances related to self-reactive substances are assigned toletters (b) or (c) of various items."

(12) to (20) Add the following new heading and paragraphs:

"Self-reactive substances

(12) The decomposition of self-reactive substances can be initiated

by heat, contact with catalytic impurities (e.g. acids, heavy-

metal compounds, bases), friction or impact. The rate ofdecomposition increases with temperature and varies with the

substance. Decomposition, particularly if no ignition occurs,may result in the evolution of toxic gases or vapours. For

certain self-reactive substances, the temperature should be

controlled. Some self-reactive substances may decompose

explosively, particularly if confined.

This characteristic may be modified by the addition of diluents

or by the use of appropriate packagings. Some self-reactivesubstances burn vigorously. Self-reactive substances are, for

example, some compounds of the types listed below:

aliphatic azo compounds (-C-N=N-C-);

organic azides (-C-N 3 );

diazonium salts (-CN 2 Z-);N-nitroso compounds (-N-N=0); andaromatic sulphohydrazides (-S0 3 -NH-NH2 ).

This list is not exhaustive and substances with other reactive

groups and some mixtures of substances may have similar properties.

(13) Self-reactive substances are classified into seven types

according to the degree of danger. The principles to be applied tothe classification of substances not listed in marginal 2401 are set

out in Appendix A.1, marginal 3104. The types of self-reactive

substance range from type A, which is not accepted for carriage in

the packaging in which it is tested, to type G, which is not subject

to the provisions for self-reactive substances of Class 4.1 (see

marginal 2414 (5)). The classification of types B to F is directly

related to the maximum quantity allowed in one packaging.

Vol. 1845. A-8940


2400 (14) The following self-reactive substances shall not be permitted(cont'd) for carriage:

- self-reactive substances type A (see Appendix A.1,

marginal 3104 (2) (a));

(15) Self-reactive substances and formulations of self-reactivesubstances listed in marginal 2401 are assigned to 31" to 50,identification numbers 3221 to 3240.

The classifications for substances of 31" to 50" are based on thetechnically pure substance (except where a concentration of less than100% is specified). For other concentrations, the substance may beclassified differently following the procedures in Appendix A.1,

marginal 3104.

The collective entries specify:

- self-reactive substances types B to F, see paragraph (13) above;

- physical state (liquid / solid); and

- temperature control (when required), see paragraph (20) below.

(16) Classification of self-reactive substances or formulations ofself-reactive substances not listed in marginal 2401 and assignmentto a collective entry shall be made by the competent authority of the

country of origin. If the country of origin is not a party to ADR,the classification and the conditions of carriage shall be recognizedby the competent authority of the first ADR country reached by theconsignment.

(17) Activators, such as zinc compounds, may be added to some self-reactive substances to change their reactivity. Depending on boththe type and the concentration of the activator, this may result in adecrease in thermal stability and a change in explosive properties.If either of these properties is altered, the new formulation shallbe assessed in accordance with the classification procedure.

Vol. 1845, A-8940


2400 (18) Samples of self-reactive substances or formulations of self-

(cont'd) reactive substances not listed in marginal 2401, for which a completeset of test results is not available and which are to be carried for

further testing or evaluation, shall be assigned to one of the

appropriate entries for self-reactive substances type C provided the

following conditions are met:

- the available data indicates that the sample would be no more

dangerous than self-reactive substances type B;

- the sample is packaged in accordance with packing method OP2A

or OP2B and the quantity per transport unit is limited to 10

kg;

- the available data indicate that the control temperature, ifany, is sufficiently low to prevent any dangerous decompositionand sufficiently high to prevent any dangerous phaseseparation.

(19) In order to ensure safety during carriage, self-reactive

substances are in many cases desensitized by use of a diluent. Where

a percentage of a substance is stipulated, this refers to thepercentage by mass, rounded to the nearest whole number. If adiluent is used, the self-reactive substance shall be tested with thediluent present in the concentration and form used in carriage.

Diluents which may allow a' self-reactive substance to concentrate to

a dangerous extent in the event of leakage from a packaging shall notbe used. Any diluent shall be compatible with the self-reactive

substance. In this regard, compatible diluents are those solids orliquids which have no detrimental influence on the thermal stability

and hazard type of the self-reactive substance. Liquid diluents in

formulations requiring temperature control (see paragraph (20)) shall

have a boiling point of at least 60C and a flash point not less than5"C. The boiling point of the liquid shall be at least 50C higherthan the control temperature of the self-reactive substance.

Vol. 1845, A-8940


2400 (20) The control temperature is the maximum temperature at which the(cont'd) self-reactive substance can be safely carried. It is assumed that

the temperature of the immediate surroundings of a package only

exceeds 55"C during carriage for a relatively short time in a 24 hourperiod. In the event of loss of temperature control, it may benecessary to implement emergency procedures. The emergencytemperature is the temperature at which such procedures shall be

implemented.

The control and emergency temperatures are derived from the SADT (seeTable 1). The SAOT shall be determined in order to decide whether asubstance shall be subjected to temperature control during carriage.Provisions for the determination of the SADT are given in Appendix

A.1, marginal 3103.

Table I DERIVATION OF CONTROL AND EMERGENCY TEMPERATURES

SADT Control temperature Emergency temperature

20"C or less 20C below SADT 1OC below SADT

over 20"C to 35*C 15C below SADT 10C below SADT

over 35"C 10"C below SADT 5C below SADT

Self-reactive substances with an SADT not greater than 55"C shall besubject to temperature control during carriage. Where applicable,control and emergency temperatures are listed in marginal 2401. Theactual temperature during carriage may be lower than the controltemperature but shall be selected so as to avoid dangerousseparation of phases."

Vol. 1845, A-8940


2401 Amend the nameslisted below as

Item number

1" (b) and 5'

6" (b)

6" (c)

7" (b) and (c)

8" (b) and (c)

(b) and (c)

(c) add

(b) and (c)

of substances correspondingindicated:

Identification number

1345 and 3176

I325

M5

1M

• 'R di r vr lnhp'Y vlamnn ill

13" (c)

16" (b) and (c)

17" (b) and (c)

to identification numbers

fNam: should read

(French text only)

(French name only)

hexamethylenetetramine

flammable solid. toxic.organic, n o~s

flammable solid.corrosive, organic.

(French name only)

m nitrite"

metal oowder. flammable,

titanium soonge aranulesor

titanium soonoe oowder

flammable solid, toxic,inorganic. n.o.s.

flammable solid.corrosive. Inornanic.n o~s

Vol 1845, A-8940

yyAR . . .... ... .... ............

1995 United Nations - Treaty Series * Nations Unies -Recueil des Traitks 133

2401

(cont'd)Item number Identification number Name: should read

24" (a) 257 nitrocellulose, with not

more than 12.6%

nitrogen, by dry mass,mixture with or withoutplasticizer, with or

(NOTE I to be amended accordingly)

25" (a) NOTE 2: to be deleted and NOTE I becomes NOTE.

Section 0, Delete item 26* and the whole of section D, and replace by the

following new section D:

"D. Substances related to self-reactive substances.

26* The following substances related to self-reactive substances:

(b) 3242 azodicarbonamide

(c) 2956 5-tert-butvl-2.4.6-trinitro-m-xvlene (musk xylene)

3251 isosorbide-5-mononitrate

NOTE 1: Special packing requirements are applicable for substances of

26" (see marginal 2404(3)].

NOTE 2: Isosorbide-5-mononitrate or formulations of this substance

which have been showrk by the performance of tests series 2 of the

Class 1 assignment procedure (see Appendix A.], marginal 3101 (1)) to

be too insensitive for inclusion in Class 1 are not subject to the

provisions of ADR."

Section E, Section E becomes Section G.

41"(former) End, read:

"... uncleaned which have contained substances of Class 4.1"

Vol. 1845, A-8940

United Nations - Treaty Series • Nations Unies - Recueil des Traitis

41' (former ) becomes 51.

Insert a new section E to read:

"E. Self-reactive substances not requiring temperature control

31"(b) 3221 self-reactive liouid tvoe B !/

32"(b) 3222 self-reactive solid type B, such as:

Substance Concentra- Packingtion method

(M) (see

marginal

2405)

2-diazo-]-naphthol-4-sulhonvlchloride 100 OP5B2-diazo-I-naohthol-5-sulhonvlchloride 100 OPSB

33'(b) 3223 self-reactive liquid type C, such as

L/ See marginal 2400(18).

!/ No self-reactive substances are currently included under this item.

Vol. 1845, A-8940

1995


2401 34"(b)(cont'd)

3224 self-reactive solid tve C, such as:

I LII d UIIIjdLUa I i UI IU . Ild il d UU I Ilin pUInt.

than 150OC2/ See marginal 2400(18).

35'(b) 3225 self-reactive liouid type D. */

of IIUL less

36'(b) 3226 self-reactive solid tvoe D, such as:

Substance Con- Packingcen- methodtra- (seetion marginal(%) 2405)

1.1'-azodi-(hexahydrobenzonitrileI 100 OP7Bbenzene-1.3-disulphonvlhvdrazide, as a paste 52 OP7Bbenzene sulphonylhydrazide 100 OP7B4-(benzvl(ethvl amino)-3-ethoxvbenzenediazoniumzinc chloride 100 OP7B3-chloro-4-diethvlaminobenzenediazonium zincchlorid 100 OP7Bdiohenvloxide-4.4'-disulohonvlhydrazide I00 OP7B4-diorooylaminobenzenediazonium zinc chloride 100 OP7B4-methvlbenzenesulohonvlhvdrazide 100 OP7Bsodium 2-diazo-l-naphthol-4-sulohonate 100 OP7Bsodium 2-diazo-1-naphthol-5-sulIhonate 100 OP7B

*_ No self-reactive substances are currently included under thisitem.

Vol. 1845, A-8940

Substance Con- Packingcen- methodtra- (seetion marginal(%) 2405)

N.N'-dinitroso-N.N'-dimethvltereohthalamide,as a paste 72 OP6BN.N'-dinitrosopentamethvlenetetramine L/ 82 OP6Bself-reactive solid. samole 2 OP2B


2401(cont'd)

37'(b) 3227 self-reactive liouid type F. !/

38"(b) 3228 self-reactive solid tve E.

39" (b) 3229 self-reactive liouid tye F. _/

40" (b) 3230 self-reactive solid tve F. -/

Section F (new), insert a new section F to read:

"F. Self-reactive substances reauiring temoerature control.

NOTE: Substances of 4W to 50" are self-reactive substances whichdecompose easily at normal temperatures and shall therefore becarried only under conditions of adequate refrigeration. For theseself-reactive substances, the maximum temperature during carriageshall not exceed the control temperature indicated.

4W (b) 3231 self-reactive liguid type B. temperature controlled _/

42" (b) 3232 self-reactive solid type B. temoerature controlled, such as:

Substance Concentra- Packing methodtion (see marginal(%) 2405)

azodicarbonamide formulation type < 100 OP5B

i/ Azodicarbonamide formulations which fulfil the criteria ofAppendix A.1, marginal 3104 (2) (b). The control and emergencytemperatures shall be determined by the procedure in marginal2400 (20).

_/ No self-reactive substances are currently included under thisitem.

2401 (cont'd)

Vol. 1845. A-8940


2401 (cont'd)

43" (b) 3233 self-reactive liauid type C. temperature controlled, such as:

Substance Packing method

(see marginal2405)

self-reactive liouid. samole, temoerature OP2A

L7 See marginal 2400 (18).

44"(b) 3234 self-reactive solid type C. temoerature controlled,

such as:

Substance Concen- Packing Control Emer-tration method tempe- gency(%) (see rature temper-

marginal ('C) ature2405) (C)

azodicarbonamideformulation tvoe C 1/ <100 OP6B

azodi(isobutvronitrile) 100 0P68 +40 +45

3-methvl-4-(ovrrolidin-l-yl)benzenediazonium

tetrafluoroborate 95 OP6B +45 +50

self-reactive solid.sample. temoerature

controlled Z/ OP2B

tetramine oalladium (II)

nitrate 100 OP6B +30 +35

1/ Azodicarbonamide formulations which fulfil tte criteria ofAppendix A.1, marginal 3104 (2) (c). The control and emergencytemperatures shall be determined by the procedure in marginal2400 (20).

Z/ See marginal 2400 (18).

Vol. 1845. A-8940


2401 (cont'd)

45"(b) 3235 self-reactive liouid tv e D. temperature controlled,such as:

Substance Con- Packing Control Emergencycentra- method tempera- tempera-tion (see ture ture

(%) marginal (*C) (*C)2405)

2.2'-azodi(ethvl 2- 100 OPIA +20 +25

methyloronionate)

46" (b) 3236 self-reactive solid tvoe D. temoerature controlled,such as:

Vol 1845, A-8940


2401 (cont'd)

Substance Con- Packing Control Emer-cen- method temp- gency

tra- (see era- temp-

tion marginal ture era-(%) 2405) (C) ture

(C)azodicarbonamide formulation

type D L/ <100 OP7B2.2'-azodi(2.4-di-methvl-4-methoxvvalero-

nitril.) 100 OP7B -5 +52.2'-azodi(2.4-dimethvlvaleronitrile) 100 OP7B +10 +15

2.2'-azodi(2-methvlbutvronitrile) 100 OP7B +35 +404-(benzyl(methyl)amino)-3-ethoxvbenzene-

diazonium zinc chloride 100 OP7B +40 +452.5-diethoxy-4-moroholinobenzenediazonium 67-

= chloride 100 OP7B +35 +402.5-diethoxy-4-moroholinobenzenediazonium

zinc chloride 66 OP78 +40 +452.5-diethoxv-4-moroholinobenzenediazoniumtetrafluoroborate 100 OP7B +30 +35

2.5-diethoxy-4-(ohenvlsulohonvl)benzene-diazonium chloride 67 OP78 +40 +45

2.5-dimethoxv-4-(4-methylohenylsulohonyl)-

benzenediazonium zinc chloride 79 OPTB +40 +454-dimethvlamino-6-(2-di-methylaminoethoxvl-toluene-2-diazonium zinc chloride 100 OP7B +40 +45

2-(2-hvdroxvethoxv)-1-(ovrrolidin-]-vll-benzene-4-diazonium zinc chloride 100 OP7B +45 +50

3-(2-hydroxvethoxvl-4-ovrrolidin-l-vl-benzenediazonium zinc chlo~ide 100 OP7B +40 +45

N-formYl-2-(nitromethvleneH1.3-nerhvdro-tOiazin. 100 OP7B +45 +50

4-nitrosoohenol 100 OP78 +35 +402-(N.N-ethoxvcarbonylohenvlamino)-3-methoxy-4-

(N-methvl-N-cvclohexvlamino)- 63-benzenediazonium zinc c 92 OP7B +40 +45

2-(N.N-ethoxycarbonyIohenvlamino)-3-methoxy-4-(N-methvl-N-cvclohexvlamino)-benzenediazonium zinc chloride 62 OP7B +35 +40

2-(N.N-methvlaminoethvlcarbonvl)-4-(3,4-dimethylhenylsulohonyl benzene-diazonium hvdrogen sulphate 96 OP7B +45 +50

1

Vol. 1945, A-8940


Footnote of the last table:

1/ Azodicarbonamide formulations which fulfil the criteria of Appendix

A.1, marginal 3104 (2) (d). The control and emergency temperaturesshall be determined by the procedure in marginal 2400 (20).

47" (b) 3237 self-reactive liquid type E,temperature controlled

48" (b) 3238 self-reactive solid tvoe E. temoerature controlled _/

49" (b) 3239 self-reactive liouid tvoe F. temoerature controlled ./

50' (b) 3240 self-reactive solid type F. temoerature controlled

2404 (2) Amend the subparagraph beginning with "If 2557 nitrocellulose

..." to read:

"If 2557 nitrocellulose, with not more than 12.6% nitrogen, by drymass, mixture with or without plasticizer, with or without pigment ispacked ..." (rest unchanged).

(3) Replace the existing paragraph (3) by the following:

"(3) (a) Substances of item 26" shall be packed in fibre drumsconforming to marginal 3525 with plastics lining or an equallyeffective inner coating.A package shall not weigh more than 50 kg.

(b) 3242 azodicarbonamide of 26" (b) may also be packed in:

- an inner packaging of a single plastics bag in a fibreboardbox, of maximum contents 50 kg, or

- inner packagings of plastics bottles, jars, bags or boxes, ofmaximum contents 5 kg each, within an outer packaging of a

fibreboard box or a fibre drum of maximum contents 25 kg."

2405 Replace the existing text by the following:

"(1) Substances of items 31" to 50" shall be packed using packingmethods listed in Table 2 and designated OPlA to OPBA for liquids

and OPIB to OP8B for solids. Substances shall be packed as indicated

in marginal 2401 and as set out in detail in Table 2 (A) and 2 (B). A

packing method corresponding to a smaller package size (i.e. with a

_/ No self-reactive substances are currently included under this item.

Vol. 1845, A-8940


2405 lower OP number) may be used but a packing method corresponding to a

(cont'd) larger package size (i.e. with a higher OP number) shall not beused.Metal packagings meeting the test criteria of packing group Ishall not be used. For combination packagings, cushioning materialsshall not be readily combustible and shall not cause decomposition ofthe self-reactive substance if leakage occurs.

(2) Packages bearing a label conforming to model No. 01 inaccordance with marginal 2412(4) shall comply with the provisions of

marginal 2102 (4) and (6).

(3) For self-reactive substances or formulations of self-reactivesubstances not listed in marginal 2401, the following procedure shallbe used to assign the appropriate packing method:

(a) self-reactive substances type B:

Substances shall be assigned packing method OP5A or OP5Bprovided that they satisfy the criteria of Appendix A.1,marginal 3104 (2) (b) in one of the packagings indicated. Ifthe self-reactive substance can only satisfy these criteria in

a smaller packaging than those listed for packing method OP5Aor OP5B (i.e. one of the packagings listed for OPIA to OP4A orOPiB to OP48), then the corresponding packing method with the

lower OP number shall be assigned.

(b) self-reactive substances type C:

Substances shall be assigned packing method OP6A or OP6Bprovided that they satisfy the criteria of Appendix A.1,

marginal 3104 (2) (c) in one of the packagings indicated. Ifthe self-reactiv6 substance can only satisfy these criteria ina smaller packaging than those listed for packing method OP6Aor OP6B then the corresponding packing method with the lower OPnumber shall be assigned.

(c) self-reactive substances type D:

Packing method OP7A or OP7B shall" be used.

(d) self-reactive substances type E:

Packing method OPSA or OP8B shall be used.

Vol. 1845, A-8940


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Vol. 1845. A-8940

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144 United Nations - Treaty Series - Nations Unies - Recueil des Traitks 1995

2405 (e) self-reactive substances type F:

(cont'd)Packing method OP8A or OP8B shall be used.

(4) Substances of 39" (b), 40" (b), 49" (b) or 50" (b) may be carried

in IBCs under conditions laid down by the competent authority of the

country of origin when, on the basis of testing, the competent

authority is satisfied that such carriage may be safely conducted.

The tests shall include those necessary:

- to prove that the self-reactive substance complies with the

principles for classification given in Appendix A.1, marginal 3104

(2) (f);

- to prove the compatibility with all materials normally in contact

with the substance during carriage;

- to determine, when applicable, the control and emergency

temperatures associated with the carriage of the substance in the IBC

concerned as derived from the SADT;

- to design, when applicable, emergency-relief devices; and

- to determine if any special requirements are necessary.

If the country of origin is not a Party to ADR, these conditionsshall be recognized by the competent authority of the first ADR

Country reached by the consignment.

(5) To prevent explosive rupture of metal IBCs or composite IBCs withfull wall metal casing, the emergency-relief devices shall be

designed to vent all the decomposition products and vapours evolved

during a period of not less than one hour of fire engulfment (heat

load 110 kW/m') or self-accelerating decomposition.

(6) Receptacles or IBCs; containing substances of 31" (b), 33" (b),

35" (b), 37" (b), 39" (b), 41" (b), 43" (b), 45" (b), 47" (b) or 49"

(b), which give off small quantities of gases, shall be vented, inaccordance with marginal 3500 (8) or 3601 (6)."

2406 (2), (4), (5)) Insert after "which have a melting-point greater

and ) than 45*C" "or are pasty according to the criteria

of the penetrometer test (see Appendix A.3,

2407 (2) and (3) ) marginal 3310), or are not liquid according to

the ASTM D 4359-90 test method."

Vol. 1845, A-8940

1995 United Nations - Treaty Series o Nations Unies - Recueil des Traitks 145

2411 (2) Amend paragraph (2) to read:

"(2) Substances of 21° to 26" and items 31" to 50" shall not be

packed with other goods."

2412 Add the following text under the subheading "Marking":

"(1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in thetransport document, preceded by the letters "UN.""

Renumber the existing paragraphs as (1) and (2) as (2) and (3).

Add new paragraphs (4) and (6) to read:

"(4) Packages containing self-reactive substances of items 31, 32",

41' and 42" shall in addition bear a label conforming to model No. 01unless the competent authority has permitted this label to be

dispensed with for the type of packaging tested because the resultshave proved that the self-reactive substance in such a packaging does

not exhibit explosive behaviour (see marginal 2414 (4)).

"(6) Packages containing liquids in packagings the closures of which

are not visible from the outside, packages containing ventedpackagings or vented packagings without outer packagings shall in

addition bear on two opposite sides a label conforming to

model No. 11.

Renumber existing paragraph (3) as paragraph (5).

2414 After "For the carriage of wastes" read "(see marginal 2000 (5))".

Add "or collective entry" after "N.O.S. entry" and "N.O.S. designation",

number the existing text as paragraph (1) and add the following newparagraph numbers (2) to (8) to read:

"(2) When substances are carried under conditions fixed by the

competent authority (see marginals 2400 (16) and 2405 (4), thefollowing statement shall be included in the transport

document:

"Carriage in accordance with marginal 2414 (2)."

Vol. 1845, A-8940


2414 (3) When a sample of a self-reactive substance is carried in(cont'd) accordance with marginals 2400 (18) and 2405 (6), the following

statement shall be included in the transport document:

"Carriage in accordance with marginal 2414 (3)."

(4) When, by permission of the competent authority, a label

conforming to model No. 01 is not required, the following statement

shall be included in the transport document.

"The danger label conforming to model No. 01 is not

required."

(5) When self-reactive substances type G [see Appendix A.1 marginal

3104 (2) (g)] are.carried, the following statement may be given in

the transport document:

"Not a self-reactive substance of Class 4.1."

(6) For self-reactive substances requiring temperature control during

carriage, the following statement shall be given in the transport

document:

"Control temperature: ..... .C Emergency temperature: .... 'C"

(7) For the solutions and mixtures containing only one component

subject to the provisions of ADR, the word "solution" or "mixture"shall be added as part of the name in the transport document (seemarginal 2002 (8) (a)].

(8) When a solid is handed over for carriage in the molten state the

description of the goods shall further specify "molten", unless the

term already appears in the name."

2422 Change "41"' to "51"" throughout and in paragraph (3) change "31" to

37° " to "31" to 50" ' .

Insert a new amendment as follows:

Vol. 1845, A-8940


"D. Transitional mesures

2425 Substances of class 4.1 may be carried until 30 June 1995 inaccordance with the requirements for Class 4.1 applicable until 31December 1994. The transport document shall, in such cases, bear theinscription "Carriage In accordance with the ADR in forcebefore I January 1995".

2426-2429

CLASS 4.2. SUBSTANCES LIABLE TO SPONTANEOUS COMBUSTION

2431 (English text only)

Items 12" (a). (b and (c); ]6° (c); 33" (a):

The names for identification numbers 1383, 3189, 2210, 3203 should bemade singular.

13" (b) NOTE, Amend to read:

"1847 potassium sulphide, hydrated with not less than 30 % water ofcristallization and 2949 sodium hydrosulphide with not less than 25 %water of cristallization, are substances of Class 8 [see marginal2801, 45 '(b) I.]".

15" (a) NOTE: Amend to read:

"2869 .... titanium trichloride mixture, non pyrophoric, is asubstance of Class 8 (see marginal 2801, If" (b) or (c)]".

Items 7" (b) and (c): 8" (b) and (c); 9" (b and (c): 10" (b) and(c): 18" (b) and (c); 19" (b) and (c): 20" (b and (c): 21 (b) and

In the names for identification numbers 3128, 3184, 3126, 3185, 3191,3187, 3188 and 3192, transter the word "organic" or "inorganic" atthe end, just before the word "n.o.s."

2442 (1) Under the subheading "Marking", add the following text:

"(1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument, preceded by the letters "UN" "

Renumber the existing paragraphs as (2) to (7).

Vol. 1845. A-8940

147


2444 After "For the carriage of wastes" read "(see marginal 2000 (5))."

Insert the following new paragraphs:

"For the solutions and mixtures containing only one component subject

to the provisions of ADR, the word "solution" or "mixture" shall be

added as part of the name in the transport document (see marginal

2002 (8) (a)).

When a solid is handed over for carriage in the molten state thedescription of the goods shall further specify "molten", unless the

term already appears in the name."

CLASS 4.3 SUBSTANCES WHICH, IN CONTACT WITH WATER,

EMIT FLAMMABLE GASES


Items 3° (a). (b) and (c): 11 (a) and (b): 14" (a). (b) and (c). 20"Wf,

The name for identification numbers 3207, 1389, 1391, 1392, 1421,

1393, 3209, 2968 should be made singular.

1" (a): The name for identifaction number 2988 shoud read: "2M8chlorosilanes. water-reactive. flammable, corrosive.n.oS."

13" (a), (b) and (c): The name for identication number 3208 shoudread: "3208 metallic substance. water-reactive. n.o.s."

The name for identification number 3170 shoud read: "3170 aluminiumorocessino bv-oroducts."

18"(a) NOTE 2: Amend to read:

"3048 aluminium phosphide pesticides, with additives inhibitingthe emission of flammable gases are substances of Class 6.1

[see marginal 2601, 43"(a)]".

Vol. 1845, A-8940


2476 Insert the following new note:

"NOTE: Substances of 15" (c) may also be packed in packagings, which need

only meet the requirements of marginal 3500 (1), (2) and (5) to (7), and

they may in addition be packed in IBCs of type 13HI."

2482 (1) Under the subheading "Marking", add the following text:

"(1) Each package shall be clearly and durably marked with the

identification number of the goods to be entered in the transport document,

preceded by the letters "UN""


2484 After "For the carriage of wastes"...read "(see marginal 2000 (5))"


"For the solutions and mixtures containing only one component subject to

the provisions of ADR, the word "solution" or "mixture" shall be added aspart of the name in the transport document (see marginal 2002 (8) (a)).

When a solid is handed over for carriage in the molten state the

description of the goods shall further specify "molten", unless the term

already appears in the name."

CLASS 5.1 OXIDIZING SUBSTANCES


Items I* (a) and (b), 11" (b), 13" (b), 15" (b) and (c), 16" (b) and

(c), 17" (b), 18" (cf, 22" (b) and (c), 23" (b) and (c), 24" (b);

The names for identification numbers 2014, 2015, 1458, 1459, 3210,

3211, 2208, 2880, 1748," 3213, 3214, 3216, 3218, 3219, 1487 should bemade singular.

1" (b) NOTE, In the second sentence of the NOTE, replace:

"...and an organic liquid compatible with peroxyacetic acid and with

a boiling point not less than 150"C shall be used fordesensitization" by "and a liquid compatible with peroxyacetic acid

shall be used for desensitization".

Vol. 1845, A-8940


2501 3" (a) NOTE 2: Amend to read:

(cont'd)

"1802 perchloric acid with not more than 50% acid, by mass, inaqueous solution, is a substance of Class 8 [see ,marginal 2801,4"(b)]".

14"(b) NOTE 1, amend to read:

"1908 chlorite solution is a substance of Class 8 [see marginal 2801,

61"(b) or (c)]."

15'(b) and (c) NOTE 2, amend to read:

"1791 hypochlorite solution is a substance of Class 3 [see marginal

2801, 61"(b) or (c)I".

22*(b) and (c) NOTE 1, amend to read:

"1625 mercuric nitrate, 1627 mercurous nitrate and 2727 thallium

nitrate are substances of Class 6.1 [see marginal 2601, 52'(b) and68"(b)). 2976 thorium nitrate, solid ..." (remainder unchanged).

31(b) and (c) NOTE 2, amend to read:

"1755 chromic acide solution is a substance of Class 8 [see marginal

2801, 17(b) or (c)]".

2507 (2) (b) Add after:

"or 3535 for plastics film" "or 3536 for water-resistant paper," (the

rest unchanged.)

2512 (1) Under the subheading "Markilng", add the following text:

"(I) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument, preceded by the letters "UN""


Vol. 1845, A-8940


2514 After "For the carriage of wastes..." read "(see marginal 2000 (5))."


"For the solutions and mixtures containing only one component subject-to the provisions of ADR, the word "solution" or "mixture" shall beadded as part of the name in the transport document (see marginal2002 (8) (a)).

When a solid is handed over for carriage in the molten state thedescription of the goods shall further specify "molten", unless theterm already appears in the name."

CLASS 5.2 ORGANIC PEROXIDES

2550 (7) Add to paragraph (7) the following text:

"Mixtures of these formulations may be classified as the same type oforganic peroxide as that of the most dangerous component and betransported under the conditions of transport given for this type.However, as two stable components can form a thermally less stablemixture, the self-accelerating decomposition temperature of themixture should be determined and, if necessary, the control andemergency temperature derived from the SADT in accordance withmarginal 2550 (17)."

Amend the beginning of paragraph (8) to read:

"(8) Classification of organic peroxides, formulations or mixtures oforganic peroxides not listed in marginal 2551 ..." (the restunchanged)

2553 (4) Add a new paragraph (4), to read:

"(4) Receptables or IBCs, containing substances of 1" (b), 3 (b),5" (b), 7" (h), 9" (b), 11" (b), 13" (b), 15" (b), 17 (b) or 19"(b), which give off small quantities of gases, shall be vented, in

accordance with marginal 3500 (8) or 3601 (6)."

Vol. 1845, A-8940


2559 (1) Under the subheading "Marking", Add the following text:

"(1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument preceded by the letters "UN"

Add the subheading "Danger labels" above the existing text and renumber the

paragraphs as (2) to (6).

2561 (1), third paragraph, after "For the carriage of wastes..." read (seemarginal 2000 (5))."

CLASSES 6.1 AND 6.2:

Replace marginals 2600 to 2699 by the following:

Vol. 1845, A-8940


'CLASS 6.1 - TOXIC SUBSTANCES

1. List of substances

2600 (1) Among the substances and articles covered by the title of

Class 6.1, those which are listed in marginal 2601 or are covered by

a collective heading of that marginal are subject to the conditionsset out in marginals 2600(2) to 2622 and to the provisions of thisAnnex and of Annex B. They are then considered as substances andarticles of ADR.

NOTE: For the quantities of substances of marginal 2601 which arenot subject to the provisions for this class either in this Annex or

in Annex B, see marginal 2601a.

(2) The title of Class 6.1 covers the toxic substances of which it

is known by experience or regarding which it is presumed fromexperiments on animals that in relatively small quantity they are

able by a single action or by action of short duration to causedamage to human health, or death, by inhalation, by cutaneousabsorption or by ingestion.

Substances of Class 6.1 are subdivided as follows:

A. Substances which are highly toxic on inhalation with aflash-point below 23 *C which are not substances ofClass 3;

B. Organic substances which have a flash-point of not less

than 23 "C or non-flammable organic substances;

C. Organometallic compounds or carbonyls;

D. Inorganic substances which may release toxic gases oncontact with water (or atmospheric humidity), aqueous

solutions or acids and other toxic water-reactive ,/substances;

E. Other inorganic substances and metallic salts of organic

substances;

F. Substances and preparations used as pesticides;

• / The term "water reactive" denotes a substance which, in contact

with water, emits flammable gases.

Vol. 1845, A-8940


2600 (2) (cont'd)

(cont'd) G. Substances intended for laboratories and experiments andfor the manufacture of pharmaceutical products, if notlisted in other items of this Class;

H. Empty packagings.

(3) Substances and articles of Class 6.1,of 1*to 5, which are classified under themarginal 2601, shall be assigned to one ofdesignated by the letters (a), (b) or (c),of toxicity:

other than the substancesvarious items ofthe following groupsaccording to their degree

(a): highly toxic substances(b): toxic substances(c): slightly toxic substances

Substances, mixtures and solutions, including pesticides of 71° to87', not expressly mentioned shall be classified under theappropriate item and letter according to the following criteria:

1. To assess the degree of toxicity, account shall be taken ofhuman experience of instances of accidental poisoning, as wellas special properties possessed by any individual substances:liquid state, high volatility, any special likelihood ofcutaneous absorption, and special biological effects.

2. In the absence of observations on humans, the degree oftoxicity shall be assessed using the available data from animalexperiments in accordance with the table below:

Subdivision Oral toxicity Dermal Toxicityinto groups LD,0 toxicity onwithin an -(mg/kg) LDo inhalationitem (mg/kg) LC,, dusts

and mists(mg/1)

Highly (a) 5 <40 <_0.5toxic

Toxic (b) >5-50 >40-200 >0.5-2

Slightly (c) 1/ solids: >50-200 >200-1 000 > 2-10toxic liquids: >50-500 , _ _

1/ Tear gases shall be included in group (b) even if dataconcerning their toxicity correspond to group (c) criteria.

2.1 Where a substance exhibits different degrees of toxicity fortwo or more kinds of exposure, it shall be classified under thehighest such degree of toxicity.

Vol. 1845, A-8940


2600 (3) (cont'd)2.2 Substances meeting the criteria of Class 8 and with an

inhalation toxicity of dusts and mists (LC..) leadingto Packing Group I shall only be accepted for anallocation to class 6.1 if the toxicity through oral ingestionor dermal contact is at least in the range of Group (a) or (b).Otherwise an assignment to Class 8 shall be made if appropriate(see footnote 1/, marginal 2800).

LD50 value for acute oral toxicity

2.3 That dose of the substance administered which is most likely tocause death within 14 days in one half of both male and femaleyoung adult albino rats. The number of animals tested shall besufficient to give a statistically significant result and shallbe in conformity with good pharmacological practices. Theresult is expressed in mg per kg body mass.

LDs value for acute dermal toxicity

2.4 That dose of the substance which, administered by continuouscontact for 24 hours with the bare skin of albino rabbits, ismost likely to cause death within 14 days in one half of theanimals tested. The number of animals tested shall besufficient to give a statistically significant result and shallbe in conformity with good pharmacological practices. Theresult is expressed in mg per kg body mass.

L,, value for acute toxicity on inhalation

2.5 That concentration of vapour, mist or dust which, administeredby continuous inhalation for one hour to both male and femaleyoung adult albino rats, is most likely to cause death within14 days in one half of the animals tested. If the substance isadministered to the-animals as dust or mist, more than 90% ofthe particles available for inhalation in the test shall havea diameter of 10 pm or less, provided that it is reasonablyforeseeable that such concentrations could be encounteredby humans during carriage. The result is expressed in mgper litre of air for dusts and mists and in ml per m' ofair (ppm) for vapours.

2.6 These criteria for inhalation toxicity of dusts and mists arebased on LC., data relating to I-hour exposure, and where suchinformation is available it shall be used. However, where onlyLC.. data relating to 4-hour exposure are available, suchfigures can be multiplied by four and the product substitutedin the above criteria, i.e. LC,, value multiplied by four(4 hour) is considered the equivalent of LC,0 (I hour).

Vol. 1845, A-8940

155


2600 (3) (cont'd)(cont'd)

Inhalation toxicity of vaoours

3. Liquids giving off toxic vapours shall be classified into thefollowing groups where "V" is the saturated vapourconcentration (in ml/m 3 of air) (volatility) at 20 "C andstandard atmospheric pressure:

Subdivisioninto groupswithin anitem

Highly (a) Where V k 10 LC5 o and LC.. S 1 000 ml/m3

toxic

Toxic (b) Where V k LC50 and LC,. 1 3 000 ml/m3 and

the criteria for (a) are not met

Slightly (c) Where V > 1/5 LC50 and LCo : 5 000 ml/m3

toxic and the criteria for (a) and (b) are notmet

These criteria for inhalation toxicity of vapours are based onLC5o data relating to 1-hour exposure, and where suchinformation is available, it shall be used.

However, where only LC.0 data relating to 4-hour exposure tothe vapours are available, such figures can be multiplied bytwo and the product substituted in the above criteria,i.e. LC6o (4 hour) x 2 is considered the equivalent of LC.,(I hour).

INHALATION TOXICITY:PACKING GROUP SORDERUNES

i0.000

1.000

IIAN I I I RNOT'DAGEOUS FOR TRANSPORT' I I

111i--.I. 14 III I 1.. 4-1 I1E

G-UP-I I I 1liiiGROUP

._ ~ ~~ _-4 11,, ....

10 100 1.000 10.000 100.000

VOLATIUTY mrn'3

Vol. 1845, A-8940

m

-7

IIH li Z 11V I 111A 111 i" Id I -"111R. I i


2600 (3) In this figure, the criteria are expressed in graphical(cont'd) form, as an aid to easy classification. However, due to

approximations inherent in the use of graphs, substancesfalling on or near group borderlines shall be checked usingnumerical criteria.

Mixtures of liquids

4. Mixtures of liquids which are toxic on inhalation shall beassigned to danger categories according to the followingcriteria:

4.1 If LCo is known for each of the toxic substances constituting

the mixture, the group may be determined as follows:

(a) calculation of the LC,, of the mixture:

LCo (mixture) IS fl

LC 0 ,i=]

Where f, - molar fraction of constituent i of themixture.

LC,., = average lethal concentration of constituent iin ml/m 3 .

(b) calculation of volatility of each mixture constituent:

106 ml/m 3= x 6101.3

where Pi - partial pressure of constituent i in kPa at20 *C and at. stanaard atmospheric pressure.

(c) calculation of the ratio of volatility to LC,,:

LC501i=1

Vol. 1845. A-8940


2600 (3) (d) the values calculated for LC,, (mixture) and R are then(cont'd) used to determine the group of the mixture:

Group (a) R k 10 and LC,, (mixture) 1,000 ml/m3

Group (b) R k I and LC,0 (mixture) 3,000 ml/m 3 , if themixture does not meet the criteria for (a)

Group (c) R 1/5 and LC5 0 (mixture) : 5,000 ml/m', if themixture does not meet the criteria of group (a) orgroup (b).

4.2 In the absence of LC,, data on the toxic constituentsubstances, the mixture may be assigned to a group based on thefollowing simplified threshold toxicity tests. When thesethreshold tests are used, the most restrictive group shall bedetermined and used for carrying the mixture.

4.3 A mixture is assigned to group (a) only if it meets both of thefollowing criteria:

(i) A sample of the liquid mixture is vaporized and dilutedwith air to create a test atmosphere of 1,000 ml/m

3

vaporized mixture in air. Ten albino rats (5 male and5 female) are exposed to the test atmosphere for I hour andobserved for 14 days. If five or more of the animals diewithin the 14-day observation period, the mixture ispresumed to have an LC,, equal to or less than 1,000 ml/m 3.

(ii) A sample of vapour in equilibrium with the liquid mixtureis diluted with 9 equal volumes of air to form a testatmosphere. Ten albino rats (5 male and 5 female) areexposed to the test atmosphere for 1 hour and observed for14 days. If five or more of the animals die within the14-day observation period, the mixture is presumed to havea volatility equal to or greater than 10 times the mixtureLC,0 .

4.4 A mixture is assigned to group (b) only if it meets both of thefollowing criteria, and does not meet the criteria forgroup (a):

(i) A sample of the liquid mixture is vaporized and dilutedwith air to create a test atmosphere of 3,000 ml/m

3

vaporized mixture in air. Ten albino rats (5 male and 5female) are exposed to the test atmosphere for 1 hour andobserved for 14 days. If five or more of the animals die

Vol. 1845, A-8940


2600 (3) within the 14-day observation period, the mixture

(cont'd) is presumed to have an LC50 equal to or less than

3,000 ml/m 3 .

(ii) A sample of the vapour in equilibrium with the liquid

mixture is used to form a test atmosphere. Ten albino rats

(5 male and 5 female) are exposed to the test atmosphere

for I hour and observed for 14 days. If five or more of

the animals die within the 14-day observation period, the

mixture is presumed to have a volatility equal to or

greater than the mixture LCo.

4.5 A mixture is assigned to group (c) only if it meets both of the

following criteria, and does not meet the criteria for groups

(a) or (b):

(i) A sample of the liquid mixture is vaporized and diluted

with air to create a test atmosphere of 5,000 ml/m3

vaporized mixture in air. Ten albino rats (5 male and 5

female) are exposed to the test atmosphere for I hour and

observed for 14 days. If five or more of the animals die

within the 14-day observation period, the mixture is

presumed to have an LC,, equal to or less than 5,000 ml/m3 .

(ii) The vapour concentration (volatility) of the liquid mixture

is measured and if the vapour concentration is equal to or

greater than 1,000 ml/m3, the mixture is presumed to have a

volatility equal to or greater than 1/5 the mixture LC 0 .

(4) When, as a result of additions, substances of Class 6.1 pass

into other danger categories than those to which the substances

mentioned by name in marginal 2601 belong, these mixtures or

solutions shall be listed under the items and letters to which they

belong, based on their actual degree of danger.

NOTE: For classification of solutions and mixtures

(such as preparations and wastes), see also marginal 2002(8).

(5) On the basis of the criteria of paragraph 2600(3), it may also

be determined whether the nature of a solution or mixture mentioned

by name or containing a substance mentioned by name is such that the

solution or mixture is not subject to the requirements for this

Class.

(6) Flammable liquids which are toxic on inhalation, having a

flash-point below 23 *C, except substances of 1" to 10, are

substances of Class 3 (see marginal 2301, 11" to 19").

Vol. 1845. A-8940

1995


2600 (7) Flammable liquids slightly toxic, with the exception of

(cont'd) substances and preparations used as pesticides, having a flash-point

between 23 *C to 61 'C, inclusive, are substances of Class 3 (see

marginal 2301).

(8) Self-heating substances slightly toxic are substances of

Class 4.2 (see marginal 2431).

(9) Water-reactive substances slightly toxic are substances of

Class 4.3 (see marginal 2471).

(10) Oxidizing substances slightly toxic are substances of Class 5.1

(see marginal 2501).

(11) Substances slightly toxic and slightly corrosive are substancesof Class 8 (see marginal 2801).

(12) Chemically unstable substances of Class 6.1 shall not be

accepted for carriage unless the necessary steps have been taken toprevent their dangerous decomposition or polymerization during

carriage. To this end, it shall in particular be ensured thatreceptacles do not contain any substance(s) likely to cause aboutsuch a reaction.

(13) Substances and mixtures of substances having a melting point

above 45 'C are considered as solids within the meaning of the

packing requirements of marginals 2606(2), 2607(4) and 2608(3).

(14) The flash-point referred to below shall be determined in themanner described in Appendix A.3.

2601 A. Highly toxic substances having a flash-point below 23 *C which

are not substances of Class 3

I* Hydrogen cyanide, stabilized:

1051 hvdrogen cyanide, stabilized, containing not more than

3% water,

1614 hvdrogen cyanide. stabilized, containing not more than

3% water and'absorbed in a porous inert material.

NOTE 1: Special conditions of packing are applicable to this

substance (see marginal 2603(1)].

NOTE 2: Anhydrous hydrogen cyanide not satisfying these conditions

is not to be accepted for carriage.

NOTE 3: Hydrogen cyanide (Hydrocyanic acid) containing less than3% water is stable, if the pH-value is 2.5 ± 0.5 and the liquid is

clear and colourless.

Vol. 1845, A-8940


2601 2° Hydrogen cyanide solutions:(cont'd)

1613 hvdrogen cyanide. aoueous solution (hydrocyanic acid),with not more than 20% hydrogen cyanide.

3294 hydrogen cyanide. solution in alcohol, with not more than

45% hydrogen cyanide.

NOTE 1: Special conditions of packing are applicable to these

substances [see marginal 2603(2)].

NOTE 2: Solutions of hydrogen cyanide which do not conform to theseconditions are not to be accepted for carriage.

3" Metal carbonyls:

1259 nickel carbonyl, 1994 iron pentacarbonvi.

NOTE 1: Special conditions of packing are applicable to these

substances (see marginal 2604).

NOTE 2: Other metal carbonyls having a flash-point below 23 *C arenot to be accepted for carriage.

4* 1185 ethyleneimine, inhibited.

NOTE: Special conditions of packing are applicable to thissubstance (see marginal 2605(1)].

5" 2480 methyl isocyanate.

NOTE: Special conditions of packing are applicable to thissubstance [see marginal 2605(2)].

6" Other isocyanates having a flash-point below 23 "C:

(a) 2482 n-orooyl isocyanate, 2484 tert-butyl isocyanate,2485 n-butyl isocyanate.

7" Nitrogenous substances:

(a) 1. 1163 dimethvlhvdrazine. unsymmetrical, ]24Amethylhvdrazine;

2. 2334 allylamine, 2382 dimethvlhvdrazine. symmetrical.

8o Oxygenated substances:

(a) 1092 acrolein. inhibited, 1098 allyl alcohol,1143 crotonaldehyde. stabilized,2606 methyl orthosilicate.

Vol. 1845, A-8940


2601 9' Halogenated substances:

(cont'd)

(a) 1239 methyl chloromethvl ether.

10" Corrosive halogenated substances:

(a) 1182 ethyl chloroformate, 1238 methyl chloroformate,

2407 isoproovl chloroformate, 2438 trimethylacetyl

B. Organic substances which have a flash-point of 23 'C or over ornon-flamable organic substances

NOTE: Organic substances and preparations used as pesticides aresubstances of 71" to 78" and 81" to 87.

11" Nitrogenous substances having a flash-point between 23 "C and

61 "C inclusive:

(a) 3275 nitriles. toxic. flammable. n.o.s.;

(b) 2668 chloroacetonitrile, 3073 vinyloyridines, inhibited,3275 nitriles. toxic. flammable. n.o.s.

12o Nitrogenous substances having a flash-point above 61 oC:

(a) 1541 acetone cyanohydrin, stabilized, 3276 nitriles.

toxic. n.o.s.;

(b) 1547 aniline, 1577 chlorodinitrobenzenes,1578 chloronitrobenzenes, 1590 dichloroanilines,1596 dinitroanilines, 1597 dinitrobenzenes,

1598 dinitro-o-cresol, 1599 dinitroohenol solution,

1650 beta-naohthvlamine, 1652 naohthvlurea,1661 nitroanilines (o-,m-p-), 1662 nitrobenzene,1664 nitrotoluenes (o-,m-p-), 1665 nitroxylenes, (o-,m-p-)

1708 toluidines, 1711 xylidines, 1843 ammoniumdinitro-o-cresolate, 1885 benzidine, 2018 chloroanilines,solid, 2019 chloroanilines. liquid, 2038 dinitrotoluenes,2224 benzonitrile, 2253 N.N-dimethvlaniline,2306 nitrobenzotrifluorides,

2307 3-nitro-4-chlorobenzotrifluoride,

2522 dimethvlaminoethvl methacrvlate,2572 ohenvlhydrazine, 2647 malononitrile,

2671 aminopyridines (o-,m-p-), 2673 2-amino-4-

chlorooheno], 2690 N.n-butvlimidazole,2738 N-butvlaniline, 2754 N-ethvltoluidines,2822 2-chloronyridine. 3276 nitriles. toxic, n.o.s.;

Vol. 1845. A-8940


2601 (c) 1548 aniline hydrochloride, 1599 dinltroohenol solution,(cont'd) 1663 nitroohenols (o-,m,-p-), 1673 ohenvlenediamines (o-

,m,-p-), 1709 2.4-toluvlenediamne, 2074 acrvlamide,2077 aloha-naohthvlamlne, 2205 adiponitrile,2272 N-ethvlaniline, 2273 2-ethlantllne, 2274 N-ethyl-N-

benzylaniline, 2294 N-methvlaniline,2300 2-methvl-5-ethvlovridine, 2311 ohenetidines,2431 anisidines, 2432 N.N-diethvlaniline,2446 nttrocresols,2470 nhenylacetonitrile. liouid,2512 aminoohenols(o-.m-.o-,2651 4.4'-diaminodiohenylmethane, 2656 ouinoline,2660 nitrotoluidines (mono), 2666 ethyl canoacetate,

2713 acridine, 2730 nitroanisole, 2732 nitrobromobenzene,2753 N-ethvlbenzvltoluidines, 2873 dibutylaminoethanol,2941 fluoroanilines, 2942 2-trifluoromethvlaniline,2946 2-amino-5-diethvlaminooentane,3276 nitriles. toxic, n.o.s.

NOTE: Isocyanates having a flash-point above 61 oC are substancesof 190.

13o Oxygenated substances having a flash-point between 23 oC and

61 oC inclusive:

(a) 2521 diketene. inhibited.

14o Oxygenated substances having a flash-point above 61 aC:(b) 1594 diethyl sulphate, 1671 ohenol. solid, 2261 xvlenols,

2587 benzoouinone, 2669 chlorocresols, 2821 phenolsolution, 2839 aldol;

(c) 2369 ethylene olvcol monobutvl ether, 2525 ethyl oxalate,2609 triallvl borate, 2662 hydroouinone,2716 1.4-butynediol, 2821 ohenol solution, 2874 furfuryl

alcohol, 28T6 resorcinol, 2937 aloha-methvlbenzvl alcohol,2938 methyl benzoate.

15o Halogenated hydrocarbons:

(a) 1605 ethylene dibromide, 1647 methyl bromide and ethylenedibromide mixture. liquid, 2646 hexachlorocvclooentadiene;

NOTE: Mixtures of ethylene dibromide (sym-dibromoethane) withmethyl bromide having, at 50 oC, a vapour pressure greater than300 kPa (3 bar) are substances of Class 2 [see marginal 2201,40 (bt)].

(b) 1669 oentachloroethane, 1701 xvlvl bromide,1702 1.1.2.2-tetrachloroethane, 1846 carbon tetrachloride,1886 benzvlidene chloride, 1891 ethyl bromide,2322 trichlorobutene, 2644 methyl iodide, 2653 benzvliodide;

Vol. 1845, A-8940

164 United Nations - Treaty Series * Nations Unies - Recueil des Trait~s 1'

2601 (c) 1591 o-dichlorobenzene, 1593 dichloromethane (methylene

(cont'd) chloride), 1710 trichloroethylene,1887 bromochloromethane, 1888 chloroform,1897 tetrachloroethylene,

2279 hexachlorobutadiene, 2321 trichlorobenzenes, liouid,

2504 tetrabromoethane, 2515 bromoform, 2516 carbontetrabromide, 2664 dibromoethane, 2688 1-bromo-3-

chloroorooane, 2729 hexachlorobenzene,2831 1.1.1-trichloroethane, 2872 dibromochloroorooanes.

NOTE: Mixtures of methyl chloride with methylene chloride

(dichloromethane) having, at 500 C, a vapour pressure greater than300 kPa (3 bar) are substances of Class 2 [see marginal 2201,4o (bt).

16o Other halogenated substances having a flash-point between 23 oCand 61 oC inclusive:

(a) 1135 ethylene chlorohvdrin, 2558 eoibromohvdrin;

(b) 1181 ethyl chloroacetate, 1569 bromoacetone, 1603 ethyl

bromoacetate, 1916 2.2'-dichlorodiethvl ether,2023 eoichlorohvdrin, 2295 methyl chloroacetate,2589 vinyl chloroacetate, 2611 oropvlene chlorohvdrin.

17o Other halogenated substances having a flash-point above 61 oC:

(a) 1580 chloropicrin, 1670 oerchloromethvl mercaotan,1672 ohenylcarbylamine chloride, 1694 bromobenzvl

c , 2232 chloroacetaldehvde, 2628 potassiumfluoroacetate, 2629 sodium fluoroacetate,

2642 fluoroacetic acid,1583 chlorooicrin mixture. n.o.s., 1610 haloaenatedirritating liquid. n.o.s.;

NOTE: Mixtures of methyl bromide or methyl chloride withchloropicrin , having, at 50 oC, a vapour pressure greater than300 kPa (3 bar) are substances of Class 2 [see marginal 2201, 4o(at) or 4o (bt)].

(b) 1695 chloroacetone. stabilized, 1697 chloroacetoohenone,

2075 chloral, anhydrous, inhibited, 2490 dichloroisooroovlether, 2552 hexafluoroacetone hydrate, 2567 sodium

pentachloroohenate, 2643 methyl bromoacetate,2645 Dhenacvl bromide, 2648 1.2-dibromobutan-3-one,

2649 1.3-dichloroacetone, 2650 1.1-dichloro-l-nitroethane,2750 1.3-dichloroorooanol-2,2948 3-trifluoromethvlaniline, 3155 oentachloroohenol,1583 chlorooicrin mixture. n.o.s.,1610 halooenated irritating liquid. n.o.s.;

Vol. 1845, A-8940


2601 (c) 1579 4-chloro-o-toluidine hydrochloride,(cont'd) 2020 chloroohenols, solid, 2021 chloroohenols. liouid,

2233 chloroanisidines, 2235 chlorobenzvl chlorides,

2237 chloronitroanilines, 2239 chlorotoluidines,

2299 methyl dichloroacetate, 2433 chloronitrotoluenes,

2533 methyl trichloroacetate, 2659 sodium chloroacetate,2661 hexachloroacetone, 2689 alvcerol

aloha-monochlorohvdrin, 2747 tert-butylcyclohexyl

chloroformate, 2849 3-chlorooroooanol-1, 2Z5hexachloroohene, 3241 2-bromo-2-nitroorooane-1.3-diol,

1583 chiorooicrin mixture. n.o.s.,

1610 halogenated irritating liquid. n.o.s.

NOTE: Chloroformates having predominantly corrosive properties are

substances of Class 8 (see marginal 2801, 640).

18o Isocyanates having a flash-point between 23 oC and 61 oCinclusive:

(b) 2285 isocvanatobenzotrifluorides, 2487 ohenvl isocyanate,2488 cvclohexvl isocyanate,

3080 isocyanates. toxic. flammable. n.o.s. or

3080 isocyanate solution. toxic. flammable, n.o.s.

NOTE: Solutions of these isocyanates having a flash-point below

230 C are substances of Class 3 [see marginal 2301, 14o (b)].

19o Isocyanates having a flash-point above 61 *C:

(b) 2078 toluene diisocvanate and isomer mixtures,

2236 3-chloro-4-methvlohenvl isocyanate,

2250 dichloCoohenvl isocyanates, 2281 hexamethvlenediisocvanate,

2206 isocyanates. toxic. n.o.s. or 2206 isocyanate

solution, toxic. n.o.s.;

NOTE 1: Solutions of these isocyanates having a flash-point below

23 oC are substances of Class 3 (see mlarginal 2301, 14o).

NOTE 2: Solutions of these isocyanates having a flash-point between

23 oC and 61 oC inclusive are substances of 18o (b).

(c) 2290 isoohoronediisocvanate, 2328 trimethvlhexamethvlene

diisocyanate and isomer mixtures,2489 diohenvlmethane-4.4'-diisocyanate,

2206 isocvanates. toxic. n.o.s., or 2206 isocyanate

solution. toxic. n.o.s.

Vol. 1845. A-8940


2601(cont'd)

20* Substances containing sulphur and having a flash-point between

23 'C and 61 'C inclusive:

(a) 2337 ohenvl mercaPtan;

(b) 1545 allvl isothiocyanate. inhibited, 2477 methyl

isothiocyanate, 3023 tert-octyl mercaptan,3071 mercaptans. liouid. toxic. flammable. n.o.s., or3071 mercaptan mixture, liquid, toxic. flammable. n.o.s.

210 Substances containing sulphur and having a flash-point above

61 oC:

(b) 1651 naphthvlthiourea, 2474 thiophosoene, 2936 thiolacticacid, 2966 thioalvcol;

(c) 2785 4-thianentanal.

22o Substances containing phosphorus and having a flash-pointbetween 23 oC and 61 oC inclusive:

(a) 3279 oroanoohosohorus compound, toxic, flammable. n.o.s.;

(b) 3279 oroanophosohorus compound. toxic, flammable, n.o.s.

230 Substances containing phosphorus and having a flash-point above61 oC:

(a) 3278 oroanoohosohorus compound, toxic, n.o.s.;

(b) 1611 hexaethvl tetraphosphate, 1704 tetraethyl

dithiopyroohosohate, 2501 tris-(H-aziridinvl) ohosohineoxide. solution, 2574 tricresvl ohosohate with more than

3% ortho isomer,

3278 oroanoohosohorus compound. toxic. n.o.s.;

(c) 2501 tris-(]-aziridinvl) ohosohine oxide. solution,

3278 organophosohorus comoound. toxic. n.o.s.

24o Toxic organic substances carried in the molten state:

(b) 1. 1600 dinitrotoluenes. molten, 2312 ohenol. molten;2. 3250 chloroacetic acid. molten.

25o Organic substances and articles and solutions and mixtures oforganic substances (such as preparations and wastes) whichcannot be classified under another collective heading:

(a) 1601 disinfectant. solid, toxic. n.o.s.,1602 dye. liouid, toxic, n.o.s. or 1602 dye intermediate.

liquid, toxic. n.o.s.,

Vol 1845, A-8940

e

1995 United Nations - Treaty Series & Nations Unies - Recueil des Traitks 167

2601 1693 tear gas substance. liouid orsolid, n.o.s., 3142

(cont'd) disinfectant. liouid, toxic. n.o.s.,3143 dye. solid, toxic. n.o.s. or 3143 dye intermediate.

solid, toxic. n.o.s.,

2810 toxic liouid, organic. n.o.s., 2811 toxic solid.

organic. n.o.s.;

NOTE: 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in concentrations

considered highly toxic according to the criteria in

marginal 2600(3) is not to be accepted for carriage.

(b) 2016 ammunition. toxic, non-explosive without burster or

expelling charge, non-fused,1601 disinfectant. solid, toxic. n.o.s.,

1602 dye. liquid, toxic. n.o.s. or 1602 dye intermediate.

liquid, toxic, n.o.s.,1693 tear gas substance. liquid or solid. n.o.s.,

3142 disinfectant, liquid, toxic. n.o.s.,

3143 dye. solid, toxic. n.o.s., or 3143 dye intermediate.solid. toxic, n.o.s.,

2810 toxic liouid, organic. n.o.s., 2811 toxic solid.

organic. n.o.s.;

(c) 2518 1.5.9-cyclododecatriene, 2667 butyltoluenes,1601 disinfectant. solid, toxic. n.o.s.,

1602 dye. liouid, toxic. n.o.s., or 1602 dye intermediate,

liouid, toxic. n.o.s.,

3142 disinfectant, liquid, toxic. n.o.s., 3143 dye. solid.

toxic. n.o.s. or 3143 dye intermediate, solid, toxic.n.o.s.,

2810 toxic liouid, organic. n.o.s., 2811 toxic solid.organic, n.o.s.;

26' Flammable toxic organic substances, articles containing

flammable toxic organic substances and solutions and mixtures

of flammable toxic organic substances (such as preparations andwastes), which cannot be classified under another collectiveheading:

(a) 1. 2929 toxic liouid. flammable. organic. n.o.s.;

2. 2930 toxic solid. flammable. oroanic. n.o.s.;

NOTE: Dichloromethyl ether, symmetrical, (identification No. 2249)

is not to be accepted for carriage.

(b) 1. 2929 toxic liquid, flammable organic, n.o.s.;

2. 1700 tear gas candles,

2930t nxic soli,. flammable. organic, n.o.s.;

Vol. 1845. A-8940


2601(cont'd) 27o Corrosive toxic organic substances, articles containing such

substances and solutions and mixtures of corrosive toxicorganic substances (such as preparations and wastes):

(a) 1595 dimethyl sulohate, 1752 chloroacetvl chloride,1889 cyanonen bromide, 3246 methanesulohonyl chloride,2927 toxic liouid. corrosive, organic. n.o.s.,

2928 toxic solid, corrosive, oroanic. n.o.s;

(b) 1737 benzvl bromide, 1738 benzvl chloride,1750 chloroacetic acid solution,1751 chloroacetic acid. solid, 2017 ammunition.tear-oroducino, non-explosive without burster or expellingcharge, non-fuzed, 2022 cresvltc acid,2076 cresols (o-,m-,p-), 2267 dimethvl thioohosohorvlchloride, 2745 chloromethvl chloroformate, 2746 phenylchloroformate. 2748 2-ethvlhexvl chloroformate,3277 chloroformates. toxic. corrosive. n.o.s.,2927 toxic liquid. corrosive, oraanic, n.o.s.,2928 toxic solid. corrosive, organic. n.o.s.

NOTE: Chloroformates having predominantly corrosive properties aresubstances of Class 8 (see marginal 2801, 64").

28" Flammable corrosive toxic chloroformates:

(a) 1722 allvl chloroformate, 2740 n-oroovl chloroformate;

(b) 2743 n-butyl chloroformate, 2744 cvclobutvl chloroformate,

2742 chloroformates. toxic. corrosive, flammable. n.o.s.

NOTE: Chloroformates having predominantly corrosive properties aresubstances of Class 8 sae marginal 2801, 64').

C. Oroanometallic comoounds and carbonvls

NOTE 1: Toxic organometallic compounds used as pesticides aresubstances of 75o and 760.

NOTE 2: Spontaneously combustible organometallic compounds aresubstances of Class 4.2 (see marginal 2431, 31a to 33o).

NOTE 3: Water-reactive organometallic compounds, flammable, are

substances of Class 4.3 (see marginal 2471, 3o).

310 Organic lead compounds:

(a) 1649 motor fuel anti-knock mixture (tetraethyl lead,

tetramethyl lead).

Vol. 1945, A-8940


2601 320 Organic tin compounds:

(cont'd)(a) 2788 oroanotin compound. liouid. n.o.s.,

3146 organotin compound, solid. n.o.s.;

(b) 2788 organotin compound. liouid. n.o.s.,3146 organotin compound, solid. n.o.s.;

(c) 2788 oroanotin compound. liouid. n.o.s.,

3146 organotin compound. solid, n.o.s.

33o Organic mercury compounds:

(a) 2026 ohenylmercuric compound. n.o.s.;

(b) 1674 ohenylmercuric acetate, 1894 ohenylmercuric

hydroxide, 1895 ohenvlmercuric nitrate,2026 ohenylmercuric compound, n.o.s.;

(c) 2026 ohenxlmercuric comound. n.o.s.

34o Organic arsenic compounds:

(a) 1698 diohenylamine chloroarsine,1699 diohenylchloroarsine, 1892 ethyldichloroarsine,3280 oroanoarsenic compound. n.o.s.;

(b) 3280 oruanoarsenic compound. n.o.s.;

(c) 2473 sodium arsanilate,3280 oroanoarsenic comoound. n.o.s.

35o Other organometallic compounds:

(a) 3282 oroanometallic comoound, toxic. n.o.s.;

(b) 3282 oroanometallic compound, toxic, n.o.s.;

(c) 3282 organometallic compound, toxic, n.o.s.

36o Carbonyls:

(a) 3281 metal carbonvls. n.o.s.;

(b) 3281 metal carbonvls. n.o.s.;

(c) 3281 metal carbonyls. n.o.s.

Vol. 1845. A-8940


D. Inorganic substances which. on contact with water (oratmospheric humidity). may emit toxic oases, aoueous solutionsor acids and other toxic water-reactive substances

41o Inorganic cyanides:

2601 (a) 1565 barium cyanide, 1575 calcium cyanide, 1626 mercuric

(cont'd) potassium cyanide, 1680 potassium cyanide, 1689 sodium

cyanide, 1713 zinc cyanide, 2316 sodium cuorocyanide,solid, 2317 sodium cuorocyanide. solution,

1588 cyanides. inorganic. solid. n.o.s.,

1935 cyanide solution. n.o.s.;

(b) 1587 cooper cyanide, 1620 lead cyanide, 1636 mercurycyaide, 1642 mercury oxvcyanide. desensitized,1653 nickel cyanide, 1679 potassium cuorocLanide,

1684 silver cyanide,1588 cyanides. inoraanic, solid. n.o.s.;

1935 cyanide solution. n.o.s.;

(c) 1588 cyanides. inorganic. solid. n.o.s.,

1935 cyanide solution. n.o.s.

NOTE 1: Ferricyanides, ferrocyanides, alkaline thiocyanates and

ammonium thiocyanate are not subject to the provisions of AOR.

NOTE 2: Solutions of inorganic cyanides with a total cyanide ion

content of more than 30% shall be classified under letter (a),solutions with a total cyanide ion content of more than 3% and notmore than 30% under letter (b) and solutions with a cyanide ion

content of more than 0.3% and not more than 3% under letter (c).

420 Azides:

(b) 1687 sodium azide.

NOTE 1: 1571 barium azide, wetted, is a substance of Class 4.1 (seemarginal 2401, 250).

NOTE 2: Barium azide in the dry state or with less than 50% wateror alcohol is not to be accepted for carriage.

43o Preparations of phosphides containing additives inhibiting theemission of flammable gases:

(a) 3048 aluminium ohosohide pesticide.

NOTE 1: These preparations are not to be accepted for carriageunless they contain additives inhibiting the emission of flammablegases.

Vol. 1945. A-8940


2601 NOTE 2: 1397 aluminium phosphide, 2011 magnesium phosphide,

(cont'd) 1714 zinc phosphide, 1432 sodium phosphide, 1360 calcium phosphide

and 2013 strontium phosphide are substances of Class 4.3 (see

marginal 2471, 18o).

44o Other water-reactive toxic substances:

(b) 3123 toxic liquid, water-reactive. n.o.s.,3125 toxic solid, water-reactive. n.o.s.;

(c) 3123 toxic liouid. water-reactive, n.o.s.,

3125 toxic solid, water-reactive. n.o.s.

NOTE: The term "water-reactive" denotes a substance which, in

contact with water, emits flammable gases.

E. Other inorganic substances and metallic salts of organicsubstances

51o Arsenic and arsenical compounds:

(a) 1553 arsenic acid. liouid, 1560 arsenic trichloride,

1556 arsenic compound. liouid. n.o.s., (arsenates,

arsenites, and arsenic sulphides),

1557 arsenic compound. solid. n.o.s., (arsenates,

arsenites, and arsenic sulphides);

(b) 1546 ammonium arsenate, 1554 arsenic acid. solid,

1555 arsenic bromide, 1558 arsenic, 1559 arsenic

pentoxide, 1561 arsenic trioxide, 1562 arsenical dust,

1572 cacodvlic acid, 1573 calcium arsenate, 1574 calcium

arsenate and calcium arsenite mixture. solid, 1585 coooer

acetoarsenite, 1586 cooper arsenite, 1606 ferric arsenate,

1607 ferric arsenite, 1608 ferrous arsenate, 1617 lead

arsenates, 1618 lead arsenites, 1621 london ourole,

1622 magnesium arsenate, 1623 mercuric arsenate,

1677 potassium arsenate, 1678 ootassium arsenite,

1683 silver arsenite, 1685 sodium arsenate, 1686 sodium

arsenite. aqueous solution, 1688 sodium cacodvlate,

1691 strontium arsenite, 1712 zinc arsenate, or 1712 zinc

arsenite or 1712 zinc arsenate and zinc arsenite mixture,

2027 sodium arsenite. solid,1556 arsenic compound. liouid. n.o.s. (arsenates,

arsenites, and arsenic sulphides),

1557 arsenic compound, solid, n.o.s. (arsenates,

arsenites, and arsenic sulphides);

Vol 1945, A-8940


2601 (c) 1686 sodium arsenite. aoueous solution,(cont'd) 1556 arsenic compound, liouid. n.o.s. (arsenates,

arsenites, and arsenic sulphides),1557 arsenic compound. solid. n.o.s. (arsenates,arsenites, and arsenic sulphides).

NOTE: Substances and preparations containing arsenic and used aspesticides are substances of 79o.

520 Mercury compounds:

(a) 2024 mercury compound, liquid. n.o.s.,

2025 mercury compound, solid. n.o.s.;

(b) 1624 mercuric chloride, 1625 mercuric nitrate,1627 mercurous nitrate, 1629 mercury acetate, 1630 mercuryammonium chloride, 1631 mercury benzoate, 1634 mercuryb2omides, 1637 mercury aluconate, 1638 mercury iodide,1639 mercury nucleate, 1640 mercury oleate, 1641 mercuryoxide, 1643 mercury potassium iodide,1644 mercury salicylate, 1645 mercury sulphate,1646 mercury thiocyanate,2024 mercury compound, liquid. n.o.s.,2025 mercury compound, solid. n.o.s.;

(c) 2024 mercury compound. liauid. n.o.s.,2025 mercury compound. solid, n.o.s.

NOTE 1: Substances and preparations containing mercury and used aspesticides are substances of 75o.

NOTE 2: Mercurous chloride (calomel) is a substance of Class 9 (seemarginal 2901, 12 "c). Cinnabar is not subject to the provisions ofADR.

NOTE 3: Fulminates of mercury are not to be accepted for carriage.

53o Thallium compounds:

(b) 1707 thallium compound. n.o.s.

NOTE 1: Substances and preparations containing thallium and used aspesticides are substances of 85o.

NOTE 2: 2727 thallium nitrate is a substance of 68".

Vol. 1845. A-8940


2601 54o Beryllium and beryllium compounds:

(cont'd)(b) 1. 1567 beryllium, powder;

2. 1566 beryllium compound. n.o.s.;

(c) 1566 beryllium comoound. n.o.s.

NOTE: 2464 beryllium nitrate is a substance of Class 5.1 [see

marginal 2501, 29o (b)].

55o Selenium and selenium compounds:

(a) 2630 selenates or 2630 selenites,

3283 selenium compound. n.o.s.;

(6) 2657 selenium disulohide,3283 selenium comoound. n.o.s.;

(c) 2658 selenium powder,

3283 selenium compound. n.o.s.

NOTE: 1905 selenic acid is a substance of Class 8 [see

marginal 2801, 16o (a)].

560 Osmium compounds:

(a) 2471 osmium tetroxide.

57o Tellurium compounds:

(b) 3284 tellurium comoound. n.o.s.;

(c) 3284 tellurium compound. n.o.s.

580 Vanadium compoundsi

(b) 2859 ammonium metavanadate, 2861 ammonium oolyvanadate,

2862 vanadium entoxide, non-fuzed form, 2863 sodium

ammonium vanadate, 2864 potassium metavanadate,2931 vanadvl sulphate,

3285 vanadium compound. n.o.s.;

(c) 3285 vanadium compound, n.o.s.

NOTE 1: 2443 vanadium oxytrichloride, 2444 vanadium tetrachloride

and 2475 vanadium trichloride are substances of Class 8 (see

marginal 2801, 11o and 120).

Vol. 1845, A-8940

174 United Nations - Treaty Series * Nations Unies - Recueil des Traitks

2601 NOTE 2: Vanadium pentoxide, fused and solidified, is not subject to

(cont'd) the provisions of ADR.

59o Antimony and antimony compounds:

(c) 1550 antimony lactate, 1551 antimony potassium tartrate,2871 antimony powder,1549 antimony compound, solid, n.o.s.,3141 antimony compound, inorganic, liouid. n.o.s.

NOTE 1: 1730 antimony pentafluoride, liquid, 1731 antimonypentafluoride solution, 1733 antimony trichloride and 1732 antimonypentafluoride are substances of Class 8 (see marginal 2801, 10o, 11oand 12o).

NOTE 2: Antimony oxides and antimony sulphide with an arseniccontent not exceeding 0.5% of the total mass, are not subject to theprovisions of ADR.

60o Barium compounds:

(b) 1564 barium compound. n.o.s.;

(c) 1884 barium oxide, 1564 barium compound. n.o.s.

NOTE 1: 1445 barium chlorate, 1446 barium nitrate,1447 barium perchlorate, 1448 barium permanganate and 1449 bariumperoxide are substances of Class 5.1 (see marginal 2501, 290).

NOTE 2: 1571 barium azide, wetted, is a substance of Class 4.1 (seemarginal 2401, 250).

NOTE 3: Barium stearate, barium sulphate and barium titanate arenot subject to the provisions of ADR.

61o Cadmium compounds:

(a) 2570 cadmium compound;

(b) 2570 cadmium compound;

(c) 2570 cadmium compound.

NOTE: Cadmium pigments, such as cadmium sulphides, cadmiumsulphoselenides and cadmium salts of higher fatty acids(e.g. cadmium stearate), are not subject to the provisions of ADR.

Vol. 1845, A-8940


2601 620 Lead compounds:

(cont'd)(c) 1616 lead acetate,

2291 lead compound, soluble. n.o.s.

NOTE 1: 1469 lead nitrate and 1470 lead perchlorate are substances

of Class 5.1 (see marginal 2501, 290).

NOTE 2: Lead. salts and lead pigments which, when mixed in a ratioof 1:1,000 with 0.07 M hydrochloric acid and stirred for one hour ata temperature of 230 C + 20 C, exhibit a solubility of 5% or lessare not subject to -the provisions of ADR.

630 Fluorides soluble in water:

(c) 1690 sodium fluoride, 1812 potassium fluoride,

2505 ammonium fluoride.

NOTE: Corrosive fluorides are substances of Class 8 (see

marginal 2801, 60 to 10o).

640 Fluorosilicates:

(c) 2655 potassium fluorosilicate, 2674 sodium fluorosilicate,2853 magnesium fluorosilicate, 2854 ammoniumfluorosilicate, 2855 zinc fluorosilicate,

2856 fluorosilicates. n.o.s.

650 Inorganic substances and solutions and mixtures of inorganicsubstances (such as preparations and wastes) which cannot beclassified under another collective heading:

(a) 3287 toxicdliquid. inorganic. n.o.s.,3288 toxic solid, inorganic. n.o.s.;

(b) 3243 solids tontainino toxic liguid. n.o.s.,

3287 toxic liauid. inorganic. n.o.s.,3288 toxic solid, inorganic. n.o.s.;

NOTE: Mixtures of solids and toxic liquids which are not subject tothe provisions of ADR may be carried under number 3243 without the

classification criteria for Class 6.1 being applied to them,provided that no liquid overflow is visible during loading or when

the packaging or transport unit is closed. Each packaging shall

correspond to a design type which has passed the leakproofness testfor packing group II. This number shall not be used for solids

containing a liquid classified under letter (a).

Vol. 1845. A-8940

1995


2601 (c) 3293 hydrazine aoueous solution, with not more than 37%(cont'd) hydrazine by mass,

3287 toxic liouid. inorganic. n.o.s., 3288 toxic solid.inorganic. n.o.s.

NOTE: 2030 hydrazine hydrate and 2030 hydrazine aqueous solution,with not less than 37% and not more than 64% hydrazine, by mass, aresubstances of Class 8 [see marginal 2801, 44"(b)].

66o Toxic, self-heating substances:

(a) 3124 toxic solid, self-heating, n.o.s.;

(b) 3124 toxic solid, self-heating. n.o.s.

670 Toxic substances, corrosive:

(a) 3289 toxic liquid, corrosive, inorganic, n.o.s.,3290 toxic solid, corrosive, inorganic. n.o.s.;

(b) 3289 toxic liquid. corrosive. inorganic. n.o.s.,3290 toxic solid. corrosive, inorganic. n.o.s.

680 Toxic substances, oxidizing:

(a) 3086 toxic solid. oxidizing. n.o.s..3122 toxic liouid, oxidizing. n.o.s.;

(b) 2727 thallium nitrate,3086 toxic solid, oxidizing. n.o.s..3122 toxic liouid. oxidizina. n.o.s.

Vol. 1845, A-8940


2601 F. Substances and Dreoarations used as oesticides(cont'd)

NOTE 1: Flammable liquid substances and preparations, used aspesticides, which are. highly toxic, toxic or harmful and have aflash-point below 23 oC, are substances of Class 3 (see marginal

2301, 41o to 57o).

NOTE 2: (a) Articles impregnated with substances and preparationsused as pesticides of 71o to 87o, such as fibreboard plates, paperstrips, cotton-wool balls, sheets of plastics material, etc. inairtight, hermetically closed wrappings are not subject to theprovisions of ADR.

(b) Substances such as baits and cereals impregnated withsubstances and preparations used as pesticides of 71" to 87" orother substances of Class 6.1 shall be classified according to theirtoxicity (see marginal 2600(3) and NOTE 3 below).

71* to 87": In these items, substances and preparations used aspesticides are tabulated under groups designated bythe letters (a), (b), (c):

(a): Highly toxic substances and preparations,(b): Toxic substances and preparations,(c): Slightly toxic substances and preparations.

NOTE 1: All active substances and their preparations used aspesticides shall be classified under 71o to 87o (a), (b) and (c) inaccordance with marginal 2600(3).

NOTE 2: If only the LDs, value of the active substance is known andnot that of the preparations of the active substance, thepreparations may be classified under 71o to 87o (a), (b) or (c)using the following tables, where the figures shown in columns (a),(b) and (c) of 71o to 870 represent the percentage of activepesticide substance in the preparations.

NOTE 3: The aim of the following tables is to show the range of

pesticides and their preparations corresponding to the differentpacking groups according to the concentration of active substance.If the LD,, of the preparation is known and if the packing groups

determined by applying the criteria in marginal 2600(3) do notcorrespond to the packing groups indicated in the following tablesbased on the concentration of active substance in the preparation,the packing group determined in accordance with the criteria in

marginal 2600(3) shall take precedence.

NOTE 4: For substances which are not named in the list, andfor which only the LDo value of the active substance

Vol. 1845, A-8940

United Nations - Treaty Series 9 Nations Unies - Recuei des Traitis

2601 is known and not the LD, value of the various preparations,(cont'd) the classification of a preparation may be determined from the table

in marginal 2600(3), using an LD.o value obtained by multiplying theLDo value of the active substance by:

IN0,X

X being the percentage of active substance by mass according to thefollowing formula:

LDo value of the preparation =

LQo value of the active substance X 100% of active substance by mass

NOTE 5: The classification according to Notes 2, 3 and 4 aboveshall not be used when the preparations contain additives whichaffect the toxicity of the active substance or when a preparationcontains more than one active substance. In such cases, theclassification shall be based on the LDo value of the preparationin question according to the criteria in marginal 2600(3). If the10o value is not known, the substance shall be classified under (a)of 71o to 870.

710 2783 orqanoohosohorus oesticide, solid, toxic.3017 organophosohorus pesticide. liquid, toxic.flammable. flash-point not less than 23 oC,3018 orqanophosphorus oesticide. liouid. toxic. including:

71" (a) 71" (b) 71* (c)

% solid % liquid %

Azinphos-ethyl - 100->25 25-6 25-2Azinphos-methyl - 100->10 10-2 10-1Bromoohos-ethyl - - 100-35 100-14

Carboohenothion - 100->20 20-5 20-2Chlorfenvinphos - 100->20 20-5 20-2Chlormephos - 100->15 15-3 15-1Chloroyriohos - - 100-40 100-10

Chlorthiophos - 100->15 15-4 15-1Crotoxyohos - - 100-35 100-15

Crufomate - - 100-90

Cvanoohos - 100-55 100-55

DEF - I - 100-40

Vol. 1845, A-8940


2601(cont'd)

DemeDhion

Demeton-O (svstox)Demeton-0-methylDemeton-S-methvlDemeton-S-methylsulohone

DiaJlifoDiazJinOichlofenthionDichlorvosOicrotophos

Dimethoate

DioxathionDisulfotonEdifenohosFndothionEPN

EtionEthoate-methylEthopronhos

FenaminnhosFenitrothionFensulfothion

FonoohosFormothionHeotenophosInrobenfosIsofenohosIsothioate

Isoxathion

MecrbarMeohosfolanMethamidophosMethidathionMethyltrithionMevinosMonocrotophoS

Omethoate

Oxvdemeton-methvlOxydisulfoton

Parathion

Parathion-methylPhenkaotonPhenthoat

~1

71' (a) 71' (b) 71° (c)

% % solid % liquid %

100->O - -

100->30 30->3 3-0.5 3->O100->34 34->3.4 3.4-0.85 3.4-0.34

- - 100-90 100-35- 100->80 80-30 80-10- 100->74 74-18.5 74-7.4- 100->10 10-2.5 10-1

- 100-38 100-15- - 100-54

100->35 35-7 35-7- 100->25 25-6 25-2

100->20 20->2 2-0.5 2->0- - 100-73 100-29- 100->40 40-10 40-4

100->40 40->4 4-1 4->0- - 100-75 100-30- 100->45 45-10 45-4

100->62 62->12.5 12.5-2.5 12.5-2.5- 100->25 25-5 25-2- - 100-60 100-25

100->65 65->13 13-2 13-2100->40 40->4 4-1 4->0

- - - 100-48100->40 40->4 4-1 4->0

- - 100-95 100-38100->60 60->6 6-1 6-0.5

- - 100-65100-48 100-19

- - 100-95100->60 60-15 60-6

- 100-25 100-25- 100-55 100-20

100->30 30-7 30-3100->25 25->5 5-0.5 5-0.5

100->15 15-3 15-1.5100->40 40-10 40-4

- 100-49 100-19100->60 60->5 5-1 5-0.5

- 100->25 25-7 25-2.5- - 100-50- 100-25 100-10

- 100->93 93-23 93-9100->70 70->5 5-1.5 5-0.5100->35 35->3 3-0.9 3-0.35

100->40 40->4 4-1 4-0.4- 100->12 12-3 12-1.2

- 100-25 100-10

- 100-70 100-0

Vol 1845, A-8940

1995


2601 71* (a) 71' (b) 710 (C)(cont'd) solid % liquid %

Phorate 100->20 20->2 2-0:5 2->0Phosalone - - 100-60 100-24Phosfolan - 100->15 15-4 15-1Phosmet - - 100-45 100-18Phosvhamidon - 100->34 34-8 34-3Piriminhos-ethyl - - 100-70 100-28Provaohos - 100->75 75-15 75-15Prothoate - 100->15 15-4 15-1Pyrazophos - - - 100-45Pyrazoxon 100->80 80->8 8-2 8-0.5Ouinalphos - 100->52 52-13 52-5Salithion - - 100-60 100-25Schradan - 100->18 18-9 18-3.6Sulfote - 100->10 10-2 10-1Suliprofos - - 100-45 100-18Temephos - 100-90 100-90TEPP 100->10 10->0 - -Terbufos 100->15 150->3 3-0.74 3-0.74Thio nethon - 100->50 50-10 50-5Thionazin 100->70 70->5 5-1 5-0.5Triamiphos - 100->20 20-5 20-1Triazophos - 100-33 100-13Trichlorfon - 100-70 100-23Trichloronat - 100->30 30-8 30-3Vamidothion - 100-30 100-10

720 2761 orpanochlorine pesticide. solid, toxic.2995 organochlorine Desticide. licruid. toxic, flammable,flash-point not less than 23 *C,2996 oroanochlorine pesticide, licuid, toxic, including:

72* (a) 720 (b) 72* (c)

% solid % liquid %

Aldrin - 100->75 75-19 75-7Allidochlor - - 100-35 100-35Camphechlor - - 100-40 100-15Chlordane - - 100-55Chlordimeform - - 100-50Chlordimeform hydrochloride - - - 100-70Chloronhacinone 100->40 40->4 4-1 4-0.4Crimidine 100->25 25->2 2-0.5 2->02nT - - 100-55 100-201. 2-dibromo-3-chlorooropane - - 100-85 100-34Dieldrin - 100->75 75-19 75-7Endosulfan - 100->80 80-20 80-8Endrin 100->60 60->6 6-1 6-0.5Hentachlor - 100->80 80-20 80-8Isobenzane 100->10 10->2 2-0.4 2-0.4Indan - 100->14 14-3 14-1tindane (S8HCI - - 100-44 100-55Mirex - - - 100-60PentachloroRhenol - 100->54 54-13 54-5

Vol. 1845, A-8940


2601 730 2765 phenoxy pesticide, solid, toxic(cont'd) 2999 Phenoxy pesticide, licruid, toxic, flammable, flash-point

not less than 23 *C,3000 vhenoxv pesticide, liauid. toxic, including:

73* (a) 730 (b) 730 (c)

9. 9. solid % liquid •

2. 4-D - 100-75- - 100-40

2. - - 100-60

Triadimefon - - 100-70

740 2757 carbamate pesticide, solid, toxic,

2991 carbamate vesticide. liauid. toxic, flammable, flash-pointnot less than 23 *C,2992 carbamate vesticide. liquid. toxic, including:

740 (a) 74- (b) 740 (c)

% % solid • liquid

100-> 15 15->l 2->0 1->0Aminocarb - 100->60 60-15 60- 6Bendiocarb - 100->65 65-15 65- 5Benfuracarb - - 100-55 100-20Butocarboxim - 100-75 100-30Carbar-l - 100-30 100-10Carbofuran - 100->10 10- 2 10- 1Cartao HCL - - 100-40 100-40Di-allate - - 100-75Dietan -- 100-60 100-24Dimetilan - 100->50 50-12 50- 5Dioxacarb - - 100-30 100-10Formetanate - 100->40 40-10 40- 4Isolan - 100->20 20- 5 20- 2Isovro arb - - 100-85 100-35Mercatodimethur - 100->70 70-17 70- 7Methasulfocarb - - 100-55 100-20Methom-l 100->34 34- 8 34- 3Mexacarbate - iPO->28 28- 7 28- 2Mobam - - 100-35 100-14Oxamvl - 100->10 10- 2.5 10- 1Pirimicarb - - 100-73 100-29Promecarb - - 100-35 100-14Promurit (Muritanl 100->5.6 5.6-0.56 0.56-0.14 0.56->0ECoxoPu- - 100-45 100-18

Vol. 1845. A-8940

182 United Nations - Treaty Series * Nations Unies - Recueil des Trait~s

2601(cont'd)

75" 2777 mercury based pesticide. solid, toxic,3011 mercury based pesticide, liguld. toxic. flammable,flash-point not less than 23 "C,3012 mercury based oesticide. liouid. toxic, including:

75' (a) 1 75" (b) 1 75" (c)

Phenylmercuric acetate (PMA) - 100->60 60-15 60-6Mercuric chloride - 100->70 70-17 70-7Chloro-methoxy

ethyl mercury 100->40 40-10 40-4Mercury oxide - 100->35 35- 8 35-3Phenvlmercurv Dvrocatechin (PMB- 100->60 60-15 60-6

76' 2786 oroanotin pesticide, solid, toxic,3019 oroanotin pesticide. liouid. toxic. flammable,flash-point not less than 23 *C,3020 oroanotin pesticide. liouid. toxic, including:

76" (a) 76" (b) 76" (c)


Fentin acetate - 100- 62 100-25

Cyhexatin 100- 95 100-35Fentin hydroxide - 00- 54 100-20

77" 3025 coumarin derivative pesticide. liouid. toxic. flammable,flash-point not less than 23 'C,3026 coumarin derivative pesticide. liouid. toxic,3027 coumarin derivative pesticide, solid, toxic, including:

77" (a) 77' (b) 77" (c)


Brodifacoum 100-> 5 5->0.5 0.5- 0.13 0.5- 0.05Coumachlor - 100- 25 100-10Coumafurvl - - 100-80Coumaohos 100->30 30- 8 30- 3Coumatetralvl (Racumin) 100->34 34- 8.5 34- 3.4Dicoumarol - 100- 25 100-10Difenacou 100->35 35->3.5 3.5- 0.9 3.5- 0.35Warfarin (and salts of1 100->60 60-> 6 6- 1.5 6- 0.6

Vol. 1845, A-8940

liquid %solid %

1995


2601(cont'd)

78* 2781 biovridilium pesticide, solid, toxic,3015 bioyridilium pesticide, liguid, toxic. flammable,flash-point not less than 23 *C,3016 bioyridilium pesticide, liouid, toxic, including:

78" (a) 78" (b) 78" (c)

% % solid % liquid %Diouat - 100-45

Para~uat 100->40 40-8 40- 8

79" 2759 arsenical oesticide, solid, toxic,2993 arsenical pesticide. liauid, toxic. flammable,flash-point not less than 23 *C2994 arsenical pesticide. liouid, toxic, including:

79' (a) 79" (b) 79* (c)


Arsenic anhydride 100->40 40-10 40-4Calcium arsenate 100->40 40-10 40-4Sodium arsenite 100->20 20- 5 20-2

80" 2775 cooper based pesticide. solid, toxic,3009 cooper based pesticide. liquid, toxic. flammable,

flash-point not less than 23 *C,3010 copper based pesticide, liquid, toxic, including:

80" (a) 80" (b) 80" (c)


Conner sulohate 100-50 100-20

81' 2779 substituted-nitroohenol pesticide. solid, toxic,3013 substituted nitroohenol pesticide. liqouid. toxic.flammable, flash-point not less than 23 'C,3014 substituted nftroohenol pesticide. liquid, toxic,

including:

Vol. 1845, A-8940

1995


2601 82* 2763 triazine pesticide, solid. toxic,(cont'd) 2997 triazine pesticide, liauid, toxic, flammable,

flash-point not less than 23 IC,2998 triazine pesticide, licuid. toxic, including:

82' (a) 82' (b) 82 (c)

I solid% liquid%

- 100-90 100-35

- - 100-95

83' 2769 benzoic derivative pesticide, solid, toxic,3003 benzoic derivative pesticide. liauid. toxic. flammable,flash-point not less than 23 *C,3004 benzoic derivative pesticide. liauid, toxic, including:

83' (a) 83' (b) 83' (c)

solid • liquid %

I, f - - - 100-60

84' 2773 phthalimide derivative pesticide, solid. toxic,3007 phthalimide derivative pesticide, liquid. toxic,flammable, flash-point not less than 23 'C,3008 Phthalimide derivative pesticide, lipuid. toxic,

including:

84' (a) 84- (b) 84' (c)

Polid • liquid %

• . -/ --

85' 2767 Phenvl urea Pesticide, solid, toxic,3001 phenyl urea pesticide, liauid, toxic, flammable,

flash-point not less than 23 *C,3002 phenvl urea pesticide. liauid. toxic, including:

85' (a) 85- (b) 85' (c)

% % solid~ •liquid %

... -/ ..

./ No pesticide currently assigned to this collective entry.

Vol. 1845, A-8940


2601

(cont'd)

860 2771 dithiocarbamate3005 dithiocarbamate pesticide, liguid. toxic. flammable,flash-point not less than 23 *C,3006 dithiocarbamate venticide. liquid. toxic,including:

86* (a) 86- (b) 86* (c)

%. I % I solid % I liquid %

netam sodium - - 100-85 100-35

87* Pesticides which cannot be classified under items 710 to 860:2588 Pesticide. solid, toxic. n.o.s.,2902 Pesticide. liauid. toxic. n.o.s.,2903 pesticide. liauid. toxic, flammable, n.o.s., flash-pointnot less than 23 *C, such as:

Organonitrogenous compounds

87* (a) 870 (b) 870 (c)


Benouinox - - 100-50 100-20

Chinomethionate - - 100-50 100-SO

Cycloheximide 100-)40 40-)4 4-1 4-)0

Drazoxalon - - 100-63 100-25

Alkaloids

870 (a) 87- (b) 870 (c)


Preparations of - 100-)25 25-5 25-5nicotine

=Synine 100-)20 20-)0 - -

Other organometallic compounds

870 (a) 87- (b) 870 (c)

9. 9. solid liquid '

•77.- -/ +

./ No pesticide currently assigned to this collective entry.

Vol. 1845, A-8940

. .. . . . . . . . . . . . . . . . .Bt

1995

Icide. solid, t xi .


2601(cont'd)

Inorganic fluorine compounds

87* (a) 87" (b) 87* (c)


Barium silico- - - 100-88 100-35fluoride

Sodium silico- - - 100-62 100-25fluoride

Inorganic thallium compounds

87° (a) 87=-(=b) 87* (c)

% B solid 7 liquid %

Thallium sulphate - 100-)30 30-8 30-3

Other pesticides

87°

(a) 870 (b) 870 (c)

% % solid • liquid %

ANTU 100-)40 40-)4 4-1 4-0.8

Blasticidin-S-3 - - 100-25 100-10

Bromoxynil - - 100-95 100-38

Dazomet - - 100-60

Difenzoauat - - 100-90

pimexano - - - 100-48

Diphacinone 100-)25 25-)3 3-0.7 3-0.2

Endothal-sodium - 100-)75 75-19 75-7

renaminosulph - 100-)50 50-10 50-10

Fenpropathrin - - 100-30 100-10

Fluoracetamide - 100-)25 25-6.7 25-2.5

Imazalil - - 100-64

Ioxfl- - 100-80 100-20

Kelevan - - - 100-48

Norbormide 100-)88 88-)8.8 8.8-2.2 8.8-0.8

Pindone and its salts - - 100-55

Rotenon - 100-65 100-25

Vol. 1845, A-8940


2601 Pyrethrinoids

(cont'd)

87 (a) 87 (b) 87" (c)


Cyoermethrin 100-80 100-32

NOTE: Aluminium phosphide pesticides are substances of 43o (a).

G. Active substances such as those intended for laboratoriesand experiments and for the manufacture of nharmaceuticalproducts. if not listed under other items of this Class.

90o Active substances, including:

(a) 1570 brucine, 1692 strychnine or 1692 strychnine salts,1544 alkaloids, solid. n.o.s. or1544 alkaloid salts. solid. n.o.s.,1655 nicotine compound. solid. n.o.s. or1655 nicotine oreparation. solid. n.o.s.,3140 alkaloids. liouid. n.o.s. or

3140 alkaloid salts. liquid. n.o.s.,3144 nicotine compound. liouid. n.o.s. or

3144 nicotine preparation. liouid. n.o.s.,3172 toxins extracted from living sources. n.o.s.

(b) 1654 njotine, 1656 nicotine hydrochloride or ]65nicotine hydrochloride solution, 1657 nicotine salicylate,1658 nicotine sulphate, solid or 1658 nicotine sulohate

s , 1659 nicotine tartrate, 1544 alkaloids, solid.n.o.s, or 1544 alkaloid salts. solid. n.o.s.,1655 nicotine comoqund. solid. n.o.s. or 1655 nicotinepreparatioll. solid. n.o.s., 1851 medicine. liquid, toxic.n.o.s., 3140 alkaloids, liouid, n.o.s. or 3140 alkaloidsalts, liouid. n.o.s., 3144 nicotine comoound. liouid.

n.o.s. or 3194 nieotine preparation. liouid. n.o.s.,3172 toxins extracted from living sources. n.o.s.,3249 medicine. solid, toxic. n.o.s.

(c) 1544 alkaloids, solid. n.o.s. or1544 alkaloids salts. solid. n.o.s..

1655 nicotine comoound. solid. n.o.s. or1655 nicotine oreparation. solid. n.o.s..

1851 medicine, liouid. toxic. n.o.s..3140 alkaloids, liquid. n.,I, or3140 alkaloid salts. liouid. n.o.s..3144 nicotine compound, liouid. n.o.s. or

Vol 1845. A-8940

188 United Nations - Treaty Series o Nations Unies - Recueil des Trait6s 1995

2601 3144 nicotine oreoaration. liouid. n.o.s.,(cont'd) 3172 toxins extracted from living sources. n.o.s.,

3249 medicine. solid, toxic. n.o.s.

NOTE 1: The active substances and triturations or mixturesof substances of 90" with other substances shall be classifiedaccording to their toxicity [see marginal 2600(3)J.

NOTE 2: Pharmaceutical products ready for use, e.g. cosmetics,drugs and medicines, which are substances manufactured and packed inpackagings of a type intended for retail sale or distribution forpersonal or household consumption, which would otherwise besubstances of 90" are not subject to the provisions of ADR.

NOTE 3: Substances and preparations containing alkaloids or

nicotine used as pesticides are substances of 87'.

H. Emptv nackagings

NOTE: Empty packagings with residues from their previous contents

adhering to the outside are not to be accepted for carriage.

91" Empty oackaginas. including emoty intermediate bulk containers(IBCs) emoty tank-vehicles, emotv demountable tanks, emp-tytank-containers, empty bulk vehicles and empty bulk containers,uncleaned, which have contained substances of Class 6.1.

2601a Substances of 11, 12', 14' to 28', 32" to 36', 41, 42', 44, 51"to 55, 57" to 68', 71' to 87' and 90o carried in conformity with

the following provisions are subject neither to the provisions forthis Class contained in this Annex nor to those contained inAnnex B:

(a) Substances classified under (b) of each item:

Liquids: not more than 500 ml per inner packaging and not

more than 2 litres per package;

Solids: not more than I kg per inner packaging and not

more than 4 kg per package.

(b) Substances classified under (c) of each item:

Liquids: not more than 3 litres per inner packaging andnot more than 12 litres per package.

Solids: not more than 6 kg per inner packaging and notmore than 24 kg per package.

Vol. 1945, A-8940


2601a These quantities of substances shall be carried in combination(cont'd) packagings conforming at least to the conditions of marginal 3538.

The "General conditions of packing" of marginal 3500 (1), (2)

and (5) to (7) shall be observed.

2. Provisions

A. Packages

1. General conditions of oackinq

2602 (1) Packagings shall satisfy the conditions of Appendix A.5, unlessspecial conditions for the packing of certain substancesare prescribed in marginals 2603 to 2608.

(2) Intermediate Bulk Containers (IBCs) shall satisfy theconditions of Appendix A.6.

(3) In accordance with the provisions of marginals 2600 (3)and 3511 (2) or 3611 (2) the following shall be used:

packagings of packing group I, marked with the letter "X", forthe highly toxic substances classified under the letter (a) ofeach item;

packagings of packing group II or I, marked with the letter "Y"or "X, or IBCs of packing group II, marked with the letter"Y", for the toxic substances classified under the letter (b)of each item;

packagings of packing group III, II or I, marked with theletter "Z", "Y"-br "X", or IBCs of packing group III or II,marked with the letter "Z" or "Y", for the slightly toxicsubstances classified under the letter (c) of each item.

NOTE: For the carriage of substances of Class 6.1 in tank-vehicles,demountable tanks or tank-containers; and for the carriage in bulkof solids of this Class, see Annex B.

2. Special conditions for oacking of certain substances

2603 (1) Stabilized hydrogen cyanide of I shall be packed:

(a) when completely absorbed by an inert porous material:in strong metal receptacles of a capacity of not more than7.5 litres, placed in wooden cases in such a manner thatthey cannot Lome into contact with one another. Such acombination packaging shall comply with the following

conditions:

Vol 1845, A-8940


2603 (1) (cont'd) 1. The receptacles shall be tested at a pressure of not

(cont'd) less than 0.6 MPa (6 bar) (gauge pressure);

2. The receptacles shall be entirely filled with

the porous material. The porous material shall not

shake down or form dangerous spaces evenafter prolonged use or under impact, even at

temperatures of up to 50 *C. The date of filling

shall be durably marked on the lid of each receptacle;

3. The combination packaging shall be tested andapproved, in accordance with Appendix A.5, for packing

group I. The package shall not weigh more than120 kg.

(b) when liquid,.but not absorbed by a porous material:in carbon-steel pressure-resistant cylinders which

shall satisfy the following conditions:

1. Before being used for the first time, the

pressure-resistant cylinders shall undergo a hydraulic

pressure test at a pressure of not less than 10 MPa(100 bar) (gauge pressure). The pressure test shallbe repeated every two years and shall include a

meticulous inspection of the inside of the receptacle

and a check of the tare;

2. The cylinders shall comply with the relevant

provisions of Class 2 (see marginals 2211, 2212(l)(a),

2213, 2215 and 2218);

3. Maximum permissible mass of the contents: 0.55 kg per

litre of capacity.

(2) Solutions of hydrocyanic acid of 2* shall be packed inflame-sealed glass ampoules, containing not more than 50 g, or inglass bottles so closed as to be leakproof and containing not morethan 250 g.

The ampoules or bottles shall be carried in combination packagingswhich meet the following conditions:

(a) The ampoules and bottles shall be secured by absorbent

cushioning materials in leakproof steel or aluminium outer

packagings; a package shall not weigh more than 15 kg; or

(b) The ampoules and bottles shall be secured by absorbent

cushioning materials in wooden cases with a leakproof

tin-plate lining; a package shall not weigh more than

75 kg.

Vol. 1845, A-8940


2603 (2) The combination packagings referred to in(a) and (b) shall be(cont'd) tested and approved, in accordance with Appendix A.5, for packing

group I.

2604 Iron pentacarbonyl and nickel tetracarbonyl of 3" shall be packed asfollows:

(1) In seamless moulded bottles made of pure aluminium of acapacity not exceeding 1 litre and a wall thickness not less than1 mm, which shall be tested at a pressure of not less than I MPa(10 bar) (gauge pressure). The bottles shall be closed by meansof a metal screw-.threaded plug with an inert gasket, thescrew-threaded plug being screwed firmly into the neck of the bottleand so secured that it cannot work loose under normal conditions ofcarriage.

A maximum of four aluminium bottles of this type may be secured inouter packagings of wood or fibreboard by non-flammable absorbentcushioning material. Such a combination packaging shall conform toa design type which has been tested and approved for packing group Iin accordance with Appendix A.5.

A package shall not weigh more than 10 kg.

(2) In metal receptacles fitted with completely leakproof closingdevices which shall, if necessary, be secured against mechanicaldamage by protective caps. Steel receptacles of a capacity notexceeding 150 litres shall have a minimum wall thickness of 3 mm,and larger steel receptacles and receptacles made of other materialsshall have walls at least thick enough to guarantee equivalentmechanical strength. The maximum capacity of receptacles permittedshall be 250 litres. The mass of the contents shall be not morethan 1 kg of liquid per litre of capacity.

Before being used for the first time, the receptacles shall undergoa hydraulic pressure testat a pressure of not less than 1 MPa(10 bar) (gauge pressure). The pressure test shall be repeatedevery five years and shall include a meticulous inspection ofthe inside of the receptacle and a check of the tare. Metalreceptacles shall bear the following particulars in clearlylegible and durable characters:

(a) the name of the substance in full (the names of bothsubstances may also be shown side by side in the event ofalternative use);

(b) the name of the owner of the receptacle;

(c) the tare of the receptacle, including such fittings andaccessories as valves, protective caps, etc.;

Vol. 1845, A-8940


2604 (2) (d) the date (month, year) of the initial test and of the most(cont'd) recent test, and the stamp of the expert who carried out

the test;

(e) the maximum permissible mass of the contents of thereceptacle in kg;

(f) the internal pressure (test pressure) to be applied in thehydraulic pressure test.

2605 (1) (a) Ethyleneimine, inhibited, of 4" shall be packed in steelreceptacles of sufficient thickness, which shall be closedby a screw-threaded bung or plug rendered leakproof bothto liquid and to vapour by means of a suitable gasket.The receptacles shall initially and periodically, at leastevery five years, be tested at a pressure of not less than0.3 MPa (3 bar) (gauge pressure) in accordance withmarginals 2215 (1) and 2216. Each receptacle shall besecured by absorbent cushioning materials in a strongleakproof protective metal packaging. The protectivepackaging shall be hermetically closed and its closureshall be secured against any inadvertent opening. Themass of the contents shall not exceed 0.67 kg per litre ofcapacity. A package shall not weigh more than 75 kg.Packages weighing more than 30 kg, other than thoseforwarded as a full load, shall be fitted with means ofhandling.

(b) Ethyleneimine, inhibited, of 4" may also be packed in

steel receptacles of sufficient thickness, which shall beclosed by a screw-threaded bung and a screw-threadedprotective cap or equivalent device leakproof both toliquid and to vapour. The receptacles shall initially andperiodically, at least every five years, be tested at apressure of at least 1 MPa (10 bar) (gauge pressure) inaccordance with marginals 2215 (1) and 2216. The massof the contents shall not exceed 0.67 kg per litre ofcapacity. A package shall not weigh more than 75 kg.

(c) Receptacles in conformity with (a) and (b) shall bear, inclearly legible and durable characters:

the name or mark of the manufacturer and the number of the

receptacle;

the word "ethyleneimine";

the tare of the receptacle and its maximum permitted masswhen filled;

Vol. 1845. A-8940


2605 (1) the date (month and year) of the initial test and of the(cont'd) most recent test undergone;


(2) Methyl isocyanate of 5* shall be packed:

(a) in hermetically closed receptacles made of pure aluminiumand having a capacity not exceeding one litre, which shallnot be filled beyond 90% of their capacity.The receptacles shall be secured, not more than 10 to abox, with appropriate cushioning material in a wooden box.Packages of this kind shall satisfy the test requirementsfor combination packagings conforming to marginal 3538 forpacking group I, and shall not weigh more than 30 kg; or

(b) in receptacles made of pure aluminium having a wallthickness of not less than 5 mm or in receptaclesof stainless steel. The receptacles shall be fully weldedand shall initially and periodically, at least everyfive years, be tested at a pressure of at least 0.5 MPa (5bar) (gauge pressure) in accordance with marginals 2215(1) and 2216. They shall be so closed as to be leakproofby means of two closures one above the other, one of whichshall be screw-threaded or secured in an equally effectivemanner.

The degree of filling shall be not more than 90%.

Drums weighing more than 100 kg shall be fitted with rollinghoops or stiffening ribs.

(c) Receptacles in conformity with (b) shall bear, in clearlylegible and durable characters:

the name or mark of the manufacturer and the number of thereceptacle;

the words "methyl isocyanate";

the tare of the receptacle and its maximum permitted masswhen filled;

the date (month and year) of the initial test and of themost recent test undergone;


Vol. 1845, A-8940


2606 (1) Substances classified under (a) of the various items shall bepacked:

(a) in non-removable head steel drums conforming tomarginal 3520; or

(b) in non-removable head aluminium drums conforming tomarginal 3521; or

(c) in non-removable head steel jerricans conforming tomarginal 3522; or

(d) in non-removable head plastics drums of a capacity notexceeding 60 litres or non-removable head plasticsjerricans conforming to marginal 3526; or

(e) in-composite packagings (plastics material) conforming tomarginal 3537; or

(f) in combination packagings with inner packaging of glass,plastics or metal conforming to marginal 3538.

(2) Solid substances within the meaning of marginal 2600 (13) mayalso be packed:

(a) in removable head drums conforming to marginals 3520 forsteel, 3521 for aluminium, 3523 for plywood, 3525 forfibreboard, or 3526 for plastics material, or in removablehead jerricans conforming to marginals 3522 for steel or3526 for plastics material, if necessary with one or moresift-proof inner bags; or

(b) in combination packagings conforming to marginal 3538,with one or more sift-proof inner bags.

(3) Sodium cyanide of 41* (a) may also be packed in metal IBCsconforming to marginal 3622 or in wooden IBCs with a sift-proofinner liner conforming to marginal 3627, provided it is carried as afull load.

2607 (1) Substances classified under (b) of the various items shall bepacked:




(d) in plastics drums or plastics jerricans conforming to

marginal 3526; or

Vol 1845. A-8940

1995


2607 (1) (e) in composite packagings (plastics material) conforming to

(cont'd) marginal 3537; or

(f) in combination packagings conforming to marginal 3538.

NOTE to (a). (b). (c) and (dl: Simplified conditions are applicableto removable-head drums and jerricans for viscous substances having

a viscosity of more than 200 mm2 /s at 23 *C and for solids (see

marginals 3512, 3553, 3554 and 3560).

(2) Substances classified under (b) of the various items which have

a vapour pressure at 50 *C of not more than 110 kPa (1.10 bar) mayalso be packed in metal lBCs conforming to marginal 3622 or in rigid

plastics IBCs conforming to marginal 3624 or in composite IBCs with

rigid plastics inner receptacle conforming to marginal 3625.

(3) Substances classified under 15'(b) may also be packed in

composite packagings (glass, porcelain or stoneware) conforming tomarginal 3539.

(4) Solid substances within the meaning of marginal 2600 (13) may

also be packed:

(a) in removable-head drums conforming to marginal 3523 forplywood or 3525 for fibreboard, if necessary with one or

more sift-proof inner bags; or

(b) in water-resistant bags conforming to marginals 3533

for textile nfaterial, 3534 for woven plastics material,

3535 for plastics film or 3536 for water-resistant paper,provided the goods are carried as a full load or the bags

secured on pallets; or

(c) in composite IBCs with flexible plastics inner receptacle

conforming to marginal 3625, fibreboard IBCs conforming to

marginal 3626 or wooden IBCs conforming to marginal 3627;or

(d) in flexible IBCs conforming to marginal 3623, with the

exception of IBCs of types 13H1, 13LI, 13MI, provided that

the goods are carried as a full load or the flexible IBCs

are loaded on pallets.

2608 (1) Substances classified under (c) of the various items shall be

packed:




Vol. 1845, A-8940


2608 (d) in plastics drums or plastics jerricans conforming to(cont'd) marginal 3526; or

(e) in composite packagings (plastics material) conforming tomarginal 3537; or

(f) in combination packagings conforming to marginal 3538; or

(g) in composite packagings (glass, porcelain or stoneware)conforming to marginal 3539; or

(h) in light gauge metal packagings conforming tomarginal 3540.

NOTE to (al. (bl. (c). (di. and (hi: Simplified conditions areapplicable to removable-head drums, jerricans and light gauge metalpackagings for viscous substances having a viscosity of more than200 mm2/s at 23 *C and for solids (see marginals 3512, 3552 to 3554and 3560).

(2) Substances classified under (c) of the various items which havea vapour pressure at 50 *C of not more than 110 kPa (1.10 bar) mayalso be packed in metal IBCs conforming to marginal 3622, in rigidplastics IBCs conforming to marginal 3624 or in composite IBCs withrigid plastics inner receptacle conforming to marginal 3625.

(3) Solid substances within the meaning of marginal 2600 (13) mayalso be packed:

(a) in movable-head drums conforming to marginal 3523 forplywood, or 3525 for fibreboard, if necessary with one ormore sift-proof inner bags; or

(b) in water-resistant bags conforming to marginals 3533for textile material, 3534 for woven plastics material,3535 for plastics film or 3536 for water-resistant paper;or

(c) in flexible IBCc conforming to marginal 3623 withthe exception of IBCe of types 13HI, 13L1 and 13MI,in composite IBCs with flexible plastics inner receptacleconforming to marginal 3625, in fibreboard IBCs conformingto marginal 3626 or in wooden IBCs conforming to marginal3627.

2609-2610

Vol. 1845, A-8940


2611 3. Mixed Packing

(1) Substances covered by the same item number may be packedtogether in a combination packaging conforming to marginal 3538.

(2) Substances of different items of Class 6.1 in quantities notexceeding, per inner packaging, 3 litres for liquids and/or 5 kg forsolids, may be packed together and/or with goods not subject to theprovisions of ADR, in a combination packaging conforming tomarginal 3538, provided they do not react dangerously with oneanother.

(3) Substances of 1*, 3, 4 and 5* shall not be packed with othergoods.

(4) Substances of 2* and substances classified under (a) of thevarious items shall not be packed together with substances andarticles of classes 1 and 5.2 and material of class 7.

(5) Except as otherwise specially provided, substances of 2* andliquid substances classified under (a) of the various items ofmarginal 2601, in quantities not exceeding 0.5 litre per innerpackaging and I litre per package, and substances classified under(b) and (c) of the various items, in quantities not exceeding, perinner packaging, 3 litres for liquids and/or 5 kg for solids, may bepacked together in a combination packaging conforming to marginal3538, with substances or articles of other classes, provided thatmixed packing is also permitted for the substances of these classes,and/or with goods which are not subject to the provisions of ADR,provided they do not react dangerously with one another.


(a) combustion and/or giving off considerable heat;

(b) emission of flammable and/or toxic gases;

(c) formation of corrosive liquids;

(d) formation of unstable substances.

(7) The mixed packing of acid substances with basic substances in apackage shall not be permitted if the two substances are packed infragile receptacles.

(8) The provisions of marginal* 2001 (7), 2002 (6) and (7) and 2602shall be complied with.

(9) If wooden or fibreboard boxes are used, a package shall notweigh more than 100 kg.

Vol. 1845, A-8940


4. Marking and danger labels on Packages (See Appendix A.9)

Marking

2612 (1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument, preceded by the letters "UN".

Danoer labels

(2) Packages containing substances or articles of this Class shallbear a label conforming to model No. 6.1.

(3) Packages containing substances of 1* to 6*, 70(a)2., 8*, 9*,ii1, 13-, 16-, 18-, 200, 220 or 26*(a)l. or (b)l. shall, inaddition, bear a label conforming to model No. 3.

(4) Packages containing flammable pesticides of 71* to 87* having aflashpoint of 23 *C or above shall, in addition, bear a labelconforming to model No. 3.

(5) Packages containing substances of 7*(a)l., 100 or 28* shall, inaddition, bear labels conforming to models Nos. 3 and 8.

(6) Packages containing substances of 26*(a)2. or (b)2. or 54*(b)l.shall, in addition, bear labels conforming to model Nos. 4.1.

(7) Packages containing substances of 660 shall, in addition, beara label conforming to model No. 4.2.

(8) Packages containing substances of 44* shall, in addition, beara label conforming to model No. 4.3.

(9) Packages containing substances of 68* shall, in addition, beara label conforming to model No. 05.

(10) Packages containing substances of 24*(b)2., 27* or 67* shall,in addition, bear a label conforming to model No. S.

(11) Packages containing fragile receptacles not visible from theoutside shall, in addition, bear on two opposite sides a labelconforming to model No. 12.

(12) Packages containing liquids in receptacles the closures ofwhich are not visible from the outside, packages containingreceptacles with vents, and receptacles with vents but without outerpackaging, shall, in addition, bear on two opposite sides a labelconforming to model No. 11.

2613

Vol 1845, A-8940

United Nations - Treaty Series e Nations Unies - Recuel des Traitis


2614 The description of the goods in the transport document shall conformto one of the substance identification numbers and one of the namesunderlined in marginal 2601.

If the substance is not mentioned by name but is assigned to ann.o.s. entry,.or to another collective entry the description of the

goods shall consist of the identification number, the n.o.s.designation or the collective entry designation, followed by thechemical or technical name. 2/

The description of the goods shall be followed by particulars of theclass, the item number, the letter. if apolicable. and the initials

"ADR" (or "RJI") e.g. "6.1, 11C(a), ADR".

For the carriage of wastes (see marginal 2000 (5)), the description

of the goods shall be: "Waste containing ...', the component(s)used for the classification of the waste under marginal 2002 (8) to

be entered under its/their chemical name(s), e.g. "Waste, containing2570 cadmium compounds, 6.1, 61'(c) ADR".

For the carriage of solutions and mixtures (such as preparations and

wastes) containing several components subject to the provisions ofADR, it will not in general be necessary to refer to more thantwo components which most predominantly contribute to the danger or

dangers of the solutions and mixtures.

For the carriage of solutions and mixtures containing only one

component subject to the provisions of ADR, the words "solution" or"mixture" should be added as part of the name in the transport

document (see marginal 2002 (8)).

When a solid substance is handed over for carriage in the moltenstate, the description of the goods shall be completed by the word"molten", unless it is already included in the name.

If a solution or mixture containing a named substance in accordancewith marginal 2600 (5), is not subject to the conditions of thisClass the consignor may enter in the transport document "Not goods

of Class 6.1".

Z The technical name shall be a name currently used in scientific andtechnical handbooks, journals and texts. Trade names shall not be used for thispurpose. In the case of pesticides, the name to be entered should be that givenin ISO Standard 1750:1981 if listed.

Vol 1845, A-8940

199


2615-2621

C. Emotv packaginas

2622 (1) If the empty packagings, uncleaned, of 91" are bags or flexibleIBCs, these shall be placed in boxes or waterproof bags to preventany leakage of substance.

(2) Other empty packagings, including uncleaned empty IBCs of 91'shall be closed in the same manner and with the same degree ofleakproofness as if they were full.

(3) Empty packagings, including uncleaned empty IBCs of 91" shall

bear the same danger labels as if they were full.

(4) The description in the transport document shall conform to oneof the names underlined in 91', e.g.: "Empty packaging, 6.1, 91"ADR".

In the case of empty tank-vehicles, empty demountable tanks, emptytank-containers as well as empty vehicles for carriage in bulk andempty bulk containers, uncleaned, this description shall becompleted by adding the words "Last load" together with the name anditem of the goods last loaded, e.g.: "Last load: 2312 phenol,

molten, 24' (b)".

2623-

2624


2625 Substances of class 6.1 may be carried until 30 June 1995 inaccordance with the requirements for Class 6.1 applicable until31 December 1994. The transport document shall, in such cases, bearthe inscription "Carriage in accordance with the ADR in force before

I January 1995".

2626-

2649

Vol 1845. A-8940


CLASS 6.2 - INFECTIOUS SUBSTANCES


2650 (1) Among the substances 1/ covered by the title of Class 6.2,those which are listed in marginal 2651 or are covered by acollective heading of that marginal are subject to the conditionsset out in marginal 2650 (2) to marginal 2675 and the provisions ofthis Annex and of Annex B. They are then considered as substancesof ADR.

(2) Class 6.2 comprises substances containing viablemicro-organisms, including bacteria, viruses, rickettsia, parasites,fungi, also as recombinant, hybrid or mutant micro-organisms, thatare known or reasonably believed to cause disease in animals orhumans. They are subject to the provisions of this Class if theyare capable of spreading diseases to humans or animals when exposureto them occurs.

NOTE 1: Genetically modified micro-organisms and organisms,biological products, diagnostic specimens and infected live animalsshall be assigned to this Class if they meet the conditions for thisClass.

NOTE 2: Toxic toxins from plant, animal or bacterial sources whichdo not contain any infectious substances or organisms or which arenot contained in them are substances of Class 6.1(see marginal 2601, 90o, identification number 3172).

(3) Substances of Class 6.2 are subdivided as follows:

A: infectious substances with a high risk potential

B: other infectious substances

C: empty packagings.

The substances of marginal 2651, 3o and 4o, are assigned to thegroup designated by the letter (b) on the basis of their degreeof danger:

(b) dangerous substances.

[/ For the purposes of this Class, viruses, micro-organisms and

organisms as well as articles contaminated with these shall be considered assubstances of this Class.

Vol. 1845, A-8940


2650 (4) The assignment of substances which are not listed by name(cont'd) to 1o, 20 and 3o of marginal 2651, shall be made, on the basis of

current scientific knowledge, in accordance with the following riskgroups ?_:

(i) Risk group IV (high individual risk, high community risk)covers micro-organisms that can cause severe human oranimal disease, which may present a high risk of spreading,and for which there is usually no effective prophylaxis ortreatment available;

(ii) Risk group III (high individual risk, low community risk)covers micro-organisms that can cause severe human oranimal disease and may present a high risk of spreading,but for which there is usually effective prophylaxis ortreatment available;

(iii) Risk group II (moderate individual risk, limited communityrisk) covers micro-organisms that can cause human or animaldisease, which are unlikely to spread, and for which thereis usually effective prophylaxis or treatent available;

(iv) Risk group I (low individual and community risk) coversmicro-organisms that are unlikely to cause human or animaldisease.

NOTE 1: Micro-organisms of risk group I are not infectioussubstances within the meaning of this Class.

NOTE 2: Genetically modified micro-organisms and organisms 2/ aremicro-organisms and organisms in which the genetic material has beendeliberately altered by technical methods or by means that cannotoccur naturally in nature.

NOTE 3: Genetically modified micro-organisms which are infectiouswithin the meaning of this Class, are substances of lo, 2o or 3o.They may not however be assigned to 4o. Genetically modifiedmicro-organisms which are not infectious substances within themeaning of this Class, may be substances of Class 9 (seemarginal 2901, 13o, identification number 3245).

Z/ See the World Health Organization's (WHO) "Laboratory BiosafetvHanual", 1983 Edition, and Directive 90/679/EEC (Official Journal of theEuropean Communities, No. L 374 of 31 December 1990, p. 1); they are notinterchangeable with the packing groups in accordance with, e.g. Appendix A.5.

2/ See also Directive 90/219.'EEC, Official Journal of the EuropeanCommunities No. L 117 of 8 May 1990, page 1.

Vol. 1845, A-8940


2650 NOTE 4: Genetically modified organisms, which are known or

(cont'd) suspected to be dangerous to humans, animals or the environment,shall be carried in accordance with conditions specified by thecompetent authority of the country of origin.

(5) Substances and mixtures of substances of this Class shall be

considered as solids for the packaging provisions of marginals 2654and 2655 as long as they do not contain free liquid at a temperature

of less than 45 oC.

(6) "Biological products" are:

- finished biological preparations for human or veterinary usemanufactured in accordance with the requirements of national

public health authorities and moving under special approval or

licence from such authorities, if required; or

- biological products transported prior to licensing forresearch or development purposes; or

- finished preparations for use in the experimental treatment

of humans or animals and manufactured in accordance with therequirements of national public health authorities.

They also cover unfinished biological products prepared in

accordance with procedures of specialized government agencies.

Diagnostic specimens are any human or animal material including, butnot limited to, excreta, secreta, blood and its components, tissue

and tissue fluids being transported for purposes of diagnosis or

research, but excluding live infected animals.

NOTE: "Biological products" and "diagnostic specimens" are notconsidered as substantes of this Class if they are known not to

contain infectious substances.

(7) Live vertebrate or invertebrate animals shall not be used to

carry an infectious agent unless the agent cannot be carried by any

other means. Such animals shall be packed, marked, indicated, andcarried in accordance with the relevant regulations governing the

carriage of animals. A/

(8) For the carriage of substances of this Class, the maintenanceof a specified temperature may be necessary.

4/ Such regulations are contained in, e.g., Directive 91/628/EEC (Official

Journal of the European Communities Io. 1 340 of 11 December 1992, p. 17) and inthe Recommendations of the Council of E,,rope (Minlster-al Committee) on the

carriage of certain animal species.

Vol. 1845, A-8940


2651 A. Infectious substances with high risk Potential

1. 2814 Infectious substance. affectino humans.2900 Infectious substance. affecting animals only.

NOTE It Substances which, in accordance with marginal 2650 (4), areassigned to risk group IV, shall be assigned to this item.

NOTE 2t Special conditions of packing are applicable to thesesubstances (see marginals 2653 and 2654).

2 2814 Infectious substance. affecting humans,2900 Infectious substance, affecting animals only.

NOTE Is Substances which, in accordance with marginal 2650 (4), areassigned to risk group III, shall be assigned to this item.

NOTE 2. Special conditions of packing are applicable to thesesubstances (see marginals 2653 and 2654).

a. other infectious substances

3* (b) 2814 Infectious substance. affecting humans,2900 Infectious substance. affecting animals only.

NOTE: Substances which, in accordance with marginal 2650 (4), areassigned to risk group II, shall be assigned to this item.

4o (b) 3291 Clinical waste. unsoecified, n.o.e.

NOTE Is Unspecified wastes resulting from medical/veterinarytreatment of humans/animals or from biological research, and whichare unlikely to contain substances of this Class shall be assignedto this item.

NOTE 2: Specified wastes shall be assigned to 1*, 2* or 3*.

NOTE 3t Decontaminated clinical wastes or wastes resulting frombiological research which previously contained infectious substancesare not subject to the provisions of this Class.

C. Empty usckeaiSns

11 Uncleaned emptv packaoinos, including empty intermediate bulkcontainers 1BC), emptv tank vehicles. emoty demountable tanksand emoty tank-containers, uncleaned, which have containedsubstances of Class 6.2 (see marginal 2672).

Vol. 1845, A-8940

United Nations - Treaty Series & Nations Unies - Recueil des Traitis

2. Provisions

A. Packages

2652 1. General conditions of oacking

(1) Packagings shall satisfy the conditions of Appendix A.5, unless

special conditions for the packing of certain substances are

prescribed in marginals 2653 and 2656.

Intermediate bulk containers (IBCs) shall satisfy the conditions of

Appendix A.6.

(2) In accordance with the provisions of marginals 2650 (3) and

3511 (2) or 3611 (2), the following shall be used:

packagings of packing group II or I, marked with the letter "Y" or

"X", or IBCs of packing group II, marked with the letter "Y" fordangerous substances classified under the letter (b) of each item;

NOTE: For the carriage of substances of Class 6.2 in tank-vehicles,demountable tanks or tank-containers see Annex B.

2. Special conditions for gackino of certain substances

2653 (1) Packagings for substances of 1o and 20 shall include thefollowing essential elements:

(a) An inner packaging comprising:

a leakproof primary receptacle;

a leakproof secondary packaging;

absorbent material placed between the primary receptacleand the secondary packaging: if several primary

receptacles are placed in a single secondary packaging,they shall be individually wrapped so as to prevent

contact between them. The absorbent material, such ascotton wool,shall be in sufficient quantity to absorb theentire contents of the primary receptacles.

Whatever the intended temperature of the consignment, the primaryreceptacle or the secondary packaging shall be capable of

withstanding without leakage an internal pressure producing apressure differential of not less than 95 kPa (0.95 bar) andtemperatures in the range -40 o C to +55 o C.

NOTE: Inner packagings containing infectious substances shall not

be consolidated in an outer packaging with other types of goods.

Vol. 1945, A-8940

1995


2653 (1) (b) An outer packaging of adequate strength for its capacity,(cont'd) mass and intended use, and with a minimum external

dimension of 100 mm.

(2) Packagings conforming to paragraph (1) shall be tested in

accordance with the provisions of marginal 2654; the packaging

design type shall be one permitted by the competent authority.Every packaging manufactured in accordance with the approved designtype shall be marked in accordance with marginal 3512.

Tests for oackagings in accordance with marginal 2653

2654 (1) Other than for packagings for live animals and organisms,samples of each packaging shall be prepared for testing as describedin paragraph (2) and then subjected to the tests in paragraphs (3)

to (5). If the nature of the packaging makes it necessary,equivalent preparation and tests are permitted, provided that thesemay be demonstrated to be at least as effective.

(2) Samples of each packaging shall be prepared as for carriage,

except that the substance to be carried shall be replaced by water,or, where conditioning at -18 "C is specified, by a mixturewater/antifreeze. Each primary receptacle shall be filled to 98%capacity.

(3) Packagings prepared as for carriage shall be subjected to thetests in the table, which, for test purposes, categorizes packagingsaccording to their material characteristics. For outer packagings,the headings in the table relate to:

fibreboard or similar materials whose performance may berapidly affected by moisture;

plastics which may embrittle at low temperature; and

other materials such as metal whose performance is not affectedby moisture or temperature.

If a primary receptacle and a secondary packaging (see marginal 2653(1) (a)) are made of different materials, the material of theprimary receptacle determines the appropriate test. In instanceswhere a primary receptacle is made of two materials, the materialmost liable to damage shall determine the appropriate tests.

Vol. 1845. A-8940


Table

Material of Tests required

Outer packaging Inner packaging In accordance Inwith (3), letter accordance

with (4)

Fibre- Plastics Other Plastics Other (a) (b) (c) (d)board

x x x x When xX x X dry X

x x x ice xx x x is x

x X x used xX X X x

(a) Samples shall be subjected to free-fall drops on to arigid, non-resilient, flat, horizontal surface from a height of 9 m.Where the samples are in the shape of a box five shall be dropped insequence:

one flat on to the bottom,

one flat on to the top,

one flat on to the long side,

one flat on to the short side,one on to a corner.

Where the samples are in the shape of a drum,in sequence:

one diagonally on to the top chime, withdirectly above the point of impact,

three shall be dropped

the centre of gravity

one diagonally on to the base chilie,

one flat on to the side.

Following the appropriate drop sequence, there shall be no leakagefrom the primary receptacle(s) which shall remain protected byabsorbent material in the secondary packaging.

(b) The samples shall be fully immersed in water for a periodof at least 5 minutes and then allowed to drain for not more than30 minutes at 23 oC and 50 ± 2% relative humidity. It shall then besubjected to the test described in (a).

Vol 1845, A-8940

2654 (3)(cont'd)


2654 (3) (c) The samples shall be conditioned in an atmosphere

(cont'd of -18 oC or less for a period of at least 24 hours and within15 minutes of removal from that atmosphere be subjected to the test

described in (a). Where the samples contains dry ice, the

conditioning period may be reduced to four hours.

(d) Where the packaging is intended to contain dry ice, a test

additional to that specified in (a) or (b) or (c) shall be carried

out. One sample shall be stored so that all the dry ice dissipates

and then be subjected to the test described in (a).

(4) Packagings with a gross mass of 7 kg or less shall be subjected

to the tests described in (a) below and packagings with a gross mass

exceeding 7 kg to the tests in (b) below.

(a) Samples shall be placed on a level hard surface. A

cyliodrical steel rod with a mass of at least 7 kg, and a diameter

not exceeding 38 mm, and whose impact end edges have a radius not

exceeding 6 mm, shall be dropped in a vertical free fall from a

height of I m, measured from the impact end to the impact surface ofthe sample. One sample shall be placed on its base. A second

sample shall be placed in an orientation perpendicular to that used

for the first. In each instance, the steel rod shall be aimed toimpact the primary receptacle. Following each impact, penetrationof the secondary packaging is acceptable, provided that there is noleakage from the primary receptacle(s).

(b) Samples shall be dropped on to the end of a cylindricalsteel rod. The rod shall be set vertically in a level hard surface.

It shall have a diameter of 38 mm and the edges of the upper end a

radius not exceeding 6 mm. The rod shall protrude from the surface

a distance at least equal to that between the primary receptacle(s)

and the outer surface of the outer packaging with a minimum of

200 mm. One sample shall be dropped in a vertical freefall from a

height of I m, measured from the top of the steel rod. A second

sample shall be dropped from the same height in an orientationperpendicular to that used for the first. In each instance, the

packaging shall be so orientated that the steel rod would penetrate

the primary receptacle(s). Following each impact, penetration of

the secondary packaging is acceptable, provided that there is no

leakage from the primary receptacle(s).

Vol. 1845. A-8940


2654 (5) As long as an equivalent level of performance is(cont'd) maintained, the following variations in the primary

receptacles placed within the secondary packaging are allowedwithout the need for further testing of the completed packaging:

Primary receptacles of equivalent or smaller size as compared to thetested primary receptacles may be used provided:

(a) the primary receptacles are of similar design to the primaryreceptacle tested (e.g. rounded, rectangular);

(b) the material of construction of the primary receptacles(e.g. glass, plastics, metal) has a resistance to impact andstacking pressure equivalent to or better than that of theprimary receptacles initially tested;

(c) primary receptacles have the same or smaller openings andthe closure is of equivalent design (e.g. screw-threadedplug, bung);

(d) sufficient additional cushioning material is used to fill upempty space and to prevent significant movement of theprimary receptacles; and

(e) primary receptacles are oriented within the secondary

packagings in the same manner as in the tested package.

2655 (1) Substances classified under 3' (b) and 4 (b) shall bepacked in:

(a) steel drums conforming to marginal 3520; or

(b) aluminium drums conforming to marginal 3521; or

(c) steel jerricans conforming to marginal 3522; or

(d) plastics drums or jerricans conforming tomarginal 3526; or

(e) composite packagings (plastics material) conforming to

marginal 3537; or

(f) combination packagings conforming to marginal 3538; or

(g) composite packagings (glass, porcelain or stoneware)conforming to marginal 3539; or

Vol. 1845. A-8940

210 United Nations - Treaty Series - Nations Unies - Recueil des Trait~s 1995

2655 (h) metal IBCs conforming to marginal 3622; or

(cont'd)(i) rigid plastics IBCs conforming to marginal 3624; or

(j) reserved)

(k) composite IBCs with plastics inner receptacles conforming

to marginal 3625, with the exception of IBCs of types

IIHZ2 and 31HZ2.

(2) Solid substances within the meaning of marginal 2650(5) may

also be packed in plywood drums conforming to marginal 3523 or in

fibre drums conforming to marginal 3525, if necessary with one or

more leakproof inner bags.

2656 Biological products and diagnostic specimens of I* to 3' where a

relatively low probability exists that infectious substances are

present e.g. for routine screening tests or initial diagnosis, must

meet all the provisions of this class except where the following

conditions are met:

(1) The primary receptacles do not contain more than 50 ml for

biological products, 100 ml for diagnostic specimens;

(2) The outer packaging does not contain more than:

50 ml for biological products when fragile primary receptacles

are used;

100 ml for biological products when other than fragile primary

receptacles are used;

500 ml for diagnostic specimens.

(3) The primary receptacles are leakproof; and

(4) The packaging is in accordance with the provisions of this

class; however it need not be subjected to the tests.

2657 When substances of this Class are carried in deeply refrigeratedliquid nitrogen, the inner packagings shall conform tothe

provisions for this Class and the containers for the nitrogen shall

conform to the provisions of Class 2.

2658 (1) The openings of primary receptacles for liquids of i' and 2°

shall be closed so as to be leakproof by means of two devices placed

in series, one of which shall be screw-threaded or secured in an

eouivalent manner.

Vol. 1845. A-8940


2658 (2) Receptacles for substances of 3" and 4" which evolve(cont'd) gases and which are carried at ambient temperature of

more than 15 'C shall be fitted with a specific pathogen-tight ventin the lid, which shall be protected against external mechanicalstresses.

With reusable receptacles, the filter of the vent shall be replaced

before refilling.

(3) Plastics or fibreboard packagings intended for the carriage ofwastes of 4' shall be resistant and if the wastes contain sharpobjects, shall be impenetrable to such objects.

(4) The closure of packagings for substances of 4" shall be soconstructed that they are hermetically closed after filling and sodesigned that any subsequent opening is immediately evident.

2659-2660

3. Mixed packing



(2) Substances of 1', 2" and 3" may be packed together in acombination packaging conforming to marginal 3538, if the package istested and approved in accordance with the provisions for substancesof ]" and 2.

(3) Substances of Class 6.2 shall not be packed together withsubstances and articles of other classes, nor with goods not subjectto the provisions of ADR. This does not apply to biologicalproducts and diagnostic specimens which are packed in accordancewith marginal 2656 or to substances being carried as coolants,e.g. ice, dry ice or deeply refrigerated liquid nitrogen.

(4) The provisions of marginals 2001(7), 2002(6) and (7) and 2652shall be observed.


Vol 1845, A-8940


4. Markino and danger labels on oackages (See Appendix A.9)

Marking

2662 (1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument, preceded by the letters "UN".

Danger labels

(2) Packages containing substances of this Class shall bear a labelconforming to model No. 6.2.

(3) Packages containing substances of this Class carried in deeplyrefrigerated liquid nitrogen shall, in addition, bear a labelconforming to model No. 2.

(4) Packages containing substances of 3" and 4' in fragilereceptacles which are not visible from the outside shall, inadditiob, bear on two opposite sides a label conforming tomodel No. 12.

(5) Packages containing liquid substances of 3" in receptacles theclosures of which are not visible from the outside, as well aspackages containing vented receptacles and vented receptacleswithout outer packaging, shall, in addition, bear on two oppositesides a label conforming to model No. 11.

2663


2664 The description of the goods in the transport document shall conformto one of the identification numbers and names underlined inmarginal 2651, followed bythe biological name of the substance 5/for substances of I to 3.

(1) If the infectious substance is a genetically modifiedsubstance, the words "genetically modified micro-organisms shall beadded.

(2) For biological products and diagnostic specimens which areoffered for transport under the conditions of marginal 2656, thedescription of the goods shall be: "Biological product/diagnosticspecimen, containing ... " the infectious substance determining theclassification under 1', 2" or 3" to be entered.

/The biological name given shall normally be that used in reference books,regularly appearing publications and scientific and technical texts. Trade namesshall not be used for this purpose.

Vol. 1845, A-8940

United Nations - Treaty Series - Nations Unies - Recueil des Traits

2664 (2) The description of the goods shall be followed by the(cont'd) particulars of the Class. the item number, together with

the letter, if any, in the list of substances and the initials "ADR"(or "EMD"), e.g. 6.2, 3' (b) ADR.

For the carriage of wastes [see marginal 2002(8)] the description of

the goods shall be: "waste, containing ....,. the component(s)

determining-the classification of the waste under marginal 2002(8)to be entered under its/their chemical or biological name(s),

e.g.: "Waste, containing 2814. Infectious substance, affectinghumans, Marburg virus, 6.2, 2' ADR".

For the carriage of solutions or mixtures (such as preparations and

wastes) containing two or more components subject to ADR, in general

not more than the two components which most predominantly contribute

to the danger(s) of the solutions or mixtures need be shown. For

wastes of 4', the description underlined is sufficient: "3291Clinical Waste, unspecified, n.o.s. 6.2, 4' (b), ADR".

For the carriage of easily perishable substances, appropriate

information shall be provided, e.g.: "Cool at +2/+4 'C" or "carry

in frozen state" or "do not freeze".

2665-

2671

C. Emotv nackaainas

2672 (1) Empty packagings, including empty IBCs, uncleaned, of 11' shallbe closed in the same manner and with the same degree ofleakproofness as if they were full.

(2) Empty packagings, including empty IBCs, uncleaned, of 11" shallbear the same danger labels as if they were full.

(3) The description in the transport document shall conform to one

of the descriptions underlined under 11, e.g. "Empty packagings,6.2, I', ADR". In the case of empty tank-vehicles, empty

demountable tanks, empty tank-containers and empty small containers,

uncleaned, this description shall be completed by adding the words

"Last load", together with the name and Item number of the goods

last loaded, e.g.: "Last load: 2900 Infectious substance, affecting

animals, 3" (b)".

2673D. Other orovisions

2674 Other provisions for substances of this Class which are enacted for

reasons other than those of safety, are not affected (e.g. those

concerning impor. and export, marketing or distribution, protectionat work, veterinary purposes).

Vol. 1945, A-8940

214 United Nations - Treaty Series 9 Nations Unies - Recueii des Traitks 1995

E. Transitional provisions

2675 Substances of Class 6.2 may be carried until 31 December 1995 inaccordance with the provisions applicable for Class 6.2 until

31 December 1994. In such cases, the transport document shall bearthe inscription: "Carriage in accordance with the ADR in forcebefore 1 January 1995".

2676-2699"

Vol. 1845, A-8940


CLASS 7. RADIOACTIVE MATERIAL

2700 (1) Footnote 1/, Amend as follows:

1/ The provisions of Class 7 are based on the followingprinciples and provisions of the International Atomic EnergyAgency (IAEA).

"Regulations for the Safe Transport of Radioactive Material,Safety Series No. 6, 1985 Edition, (As Amended 1990) which alsoincludes the general principles for Radiation Protection.

Explanations and further information about these regulations canbe found in the following documents:

1. IAEA 'Advisory Material for the IAEA Regulations for TheSafe Transport of Radioactive Materials' (1985 Edition)Safety Series No. 37, Third Edition (As Amended 1990).

2. IAEA 'Explanatory Material for the IAEA Regulations forthe Safe Transport of Radioactive Materials' (1985Edition) Safety Series No. 7, Second Edition (As Amended1990).

3. IAEA 'Basic Safety Standards for Radiation Protection'Safety Series No. 9, 1982 Edition.

4. IAEA 'Emergency Response Planning and Preparedness forTransport Accidents Involving Radioactive Material'Safety Series No. 87, 1988 Edition.

5. IAEA 'Schedule of Requirements for the Transport ofSpecified Types of Material Radioactive Consignments'Safety Series No. 80 (As Amended 1990)."

2700 (2) 2. In the second line after "uranlum-238", amend "." to "Z"

and after "thorium-232", amend "." to ":".

7. In the last line delete "transport and".

9. In the second line after "of a", insert the word "large".

Vol. 1845, A-8940


2700 14. Under the title "Package", insert as follows:(cont'd)

"Package shall mean the packaging with its radioactivecontents as presented for transport. Package andpackaging performance standards, in terms of retention ofintegrity of containment and shielding, depend upon thequantity and nature of the radioactive materialtransported."

14.(b) (1) After the words "(see marginal 3732)" add thesentence "and, in addition, for the specific designprovision (see marginal 3733)".

17. In the last line amend "(or millirem)" to"(millirem)"

2702 3. In the title amend "Package Maximum Radiation Level" to"Maximum Radiation Level".

In the second line after "(0.5 mrem/h) at", insert thesentence "any point on".

4. In the second line after "wagons/vehicles", insert thewords "containers, tanks".

5.(a) (English only)Change "(10-6 uCi/cm2)" to "(10 -6 pCi/cm2 )".

5.(b)(English only)

Align the word "(b)" with word "(a)".

2703 3. Delete "Package" in the title.

3.(a) (i) Change "at the surface of the package, and" to "at

any point on any external surface, and".

3.(b) (English only)In the second line after "2 mSv/h", insert "(200mrem/h)".

3.(b) (i) Change "there is" to "the wagon/vehicle is equippedwith".

Vol 1845, A-8940

1995


2703 4. In the third line after "wagons/vehicles", insert(cont'd) "containers, tanks".

4.(a) and (b) Insert "also" after "which".

5. In the second line after "contaminated", insert thesentence "above the limits in paragraph 4, or which showa surface radiation level in excess of 5 gSv/h(0.5 mrem/h)".

7.(a) Change to: "... conforming to models Nos. 1, 1.4, 1.5,

1.6 or 01".

8.(a) (iv) (English only)

Align "fissile, containing more)" in the UN number 2977.

8.(a) (vi) Becomes (vii).

Insert a new (vi) as follows: "Each package except tankcontainers and overpacks shall be clearly and durably marked withthe identification number of the goods to be entered in thetransport document, preceded by the letters 'UN'".

8.(b) (iii) Delete "with a capacity of more than 3,000 litres"and insert "as well as vehicles and containers forcarriage in bulk".

2704 Schedules 1 to 13Item 3, delete "Package" in the title.

Schedule 1. 8.(a) (ill: (English only)

Replace "radioactive" with "Radioactive".

Schedule 1. 8.(a) (i): Amend as follows:

"Marking: see marginal 2702.Labelling: No provisions."

Schedule 2. 8.(b)Replace "No provisions" with "See marginal 2702".

Schedule 3. 8.(a)Replace "No provisions" with "See marginal 2702".

Vol. 1845, A-8940


2704 Schedule 4. 8.(a) (i): Amend as follows:

(cont'd)"Marking: see marginal 2702.

Labelling: No provisions."

Schedule 6. 2.(cl: Table 4 (English only)Replace "INUDSTRIAL" with "INDUSTRIAL"

Schedule 7: (English only):Align NOTE 1, NOTE 2, NOTE 3 as in Schedule 6.

Schedule 9. 2.(b)In the third line after "loss of shielding", insert "integrity".

Schedule 9. 1O.(b) (Hi): (English only)

In the third line replace the UN number "2892" with "2982".

Schedule 10. NOTE IIn the third line after "lose its shielding", insert "integrity".

Schedule 10: (English only)Align NOTE 2, NOTE 3, as in Schedule 6.

Schedule 10. 2.(b) (iIn the third line after "loss of shielding", insert "integrity".

Schedule 10. 2.(b) (ii): (English only)In the second line replace "containment integrity and shielding"with "containment and shielding integrity".

Schedule 10. 8.(b) (iv)Add: "shown in marginal 2705(5)" after "trefoil".

Schedule 10. 12.(b): (Eoglish only)In the first line after T'average", insert "surface".

Schedule 11. NOTE 1

In the third line after "lose its shielding", insert "integrity".

Schedule 11. 2.(a): (English only)Align the whole subparagraph.

Schedule 11. 2.(b) (ii): (English only)In the second line replace "containment integrity and shielding"with "containment and shielding integrity".

Vol. 1945, A-8940

1995 United Nations - Treaty Series e Nations Unies - Recuell des Trait6s 219

2704 Schedule 11. 8.(b) (iv)

(cont'd) Add: "shown in marginal 2705(5)" after "trefoil".

Schedule 11. 12.(cl

In the second and third line change "and as far as practicable"

to "for which".

Schedule 12. 2.(al (ii)

In the first line change "Hydrogenous" to "Homogeneoushydrogenous".

Schedule 12. 2.(a) (iii)

In the last line after "arrangement", add "within the package".

Schedule 12. 6.In the second line change "contents" to "material".

Schedule 12. 8.(b)In the first line change "plainly" to "legibly".

Schedule 12. 8.(b) M

In the first line replace "Type" to "TYPE" (three times).

2705 (2) Insert a new paragraph (2) to read as follows:

"(2) Each package, except tanks, containers, overpacksand excepted packages of schedules I to 4, shall be

clearly and durably marked with the identification numberof the goods to be entered in the transport document

preceded by the letters 'UN'".

Renumber paragraphs (2) to (4) as paragraphs (3) to (5).

2705 (4) (Renumbered (5)). In the last line change "in models Nos. 7A

to 7D" to "below" and -dd the figure below:

Vol. 1845, A-8940


60"

- -X/2

5X

Leuic trefoil :ymbol with proporiow baitd on a cetral circle ofradius X. 1e minimumdowhr ite of X &hal be 4 mM

2707 In the title, insert "containers for carriage in bulk" after"Additional labelling of".

2709 (b) Replace the sentence "the name or symbol of eachradionuclide; or the most significant radionuclide;"with "the name or symbol of each radionuclide or,for mixture of radionuclides, an appropriate generaldescription or a list of the most restrictivenuclides;".

(b) (i) In the last line, delete "and".

Vol. 1845, A-8940


2712 (5) Table 10

Delete the references "10/" and "1/" from the Table 10.Delete the references LV and II/ below Table 10.

2713 (1) (a) (i) Change "there is" to "the vehicle is equippedwith".

(1) Delete the last paragraph initiating with:"If the exclusive use

2716 (English only)

In the first column and second row change "a," to "A,".

CLASS 8: Replace marginals 2800 to 2899 by the following:

"CLASS 8. CORROSIVE SUBSTANCES


2800 (1) Among the substances and articles covered by the title ofClass 8, those which are listed in marginal 2801 or are coveredby a collective heading in that marginal are subject to theconditions set out in marginals 2800 (2) to 2822 and to theprovisions of this Annex and of Annex B. They are thenconsidered as substances and articles of ADR.

NOTE: For the quantities of substances listed in marginal 2801which are not subject to the "provisions for this Class", eitherin this Annex or in Annex B, see marginal 2801a.

(2) The title of Class 8 covers substances which by chemicalaction attack epithelial tissue - of skin or mucous membranes -with which tey are in .contact, and substances which in the eventof leakage are capable of damaging or destroying other goods, ormeans of transport, and may also cause other hazards. The titleof this Class also covers other substances which form a corrosiveliquid only in the presence of water, or which produce corrosivevapour or mist in the presence of natural moisture of the air.

Vol. 1845. A-8940


2800 (3) (a) Substances and articles of Class 8 are subdivided as(cont'd) follows:

A. Acid substances;

B. Basic substances;

C. Other corrosive substances;

D. Articles containing corrosive substances;

E. Empty packagings.

(b) Substances and articles of Class 8 which areclassified under the various items of marginal 2801other than substances of 6, 14" and 15" shall beassigned to one of the following groups designatedby the letter (a), (b) or (c) according to theirdegree of corrosivity:

(a): highly corrosive;

(b): corrosive;

(c): slightly corrosive.

(c) Allocation of substances to groups (a), (b) or (c)has been on the basis of experience taking into

account such additional factors as inhalation risk1/ and reactivity with water (including theformation of dangerous decomposition products). Thedegree of-corrosivity of substances not specificallynamed, including mixtures, can be judged by thelength of time of contact necessary to produce fullthickness destruction of human skin.

J/ A substance or preparation meeting the criteriaof Class 8 having an inhalation toxicity of dusts andmists (LC..) in the range of group (a), but toxicitythrough oral ingestion or dermal contact only in therange of group (c) or less, shall be allocated to

Class 8.

Vol. 1845, A-8940


2800 (c) Substances which are Judged not to cause full(cont'd) (cont'd) thickness destruction of human skin shall still be

considered for their potential to cause corrosion tocertain metal surfaces. In making this grouping,account should be taken of human experience ininstances of accidental exposure. In the absence ofhuman experience, the grouping should be based ondata obtained from animal experiments in accordancewith OECD Guideline 404. 2/

(d) Substances that cause full thickness destruction ofintact skin tissue within an observation period upto 60 minutes starting after the exposure time of 3minutes or less are substances of group (a).

(e) Substances that cause full thickness destruction ofintact skin tissue within an observation period upto 14 days starting after the exposure time of morethan 3 minutes but not more than 60 minutes aresubstances of group (b).

(f) The following are substances of group (c):

substances that cause full thicknessdestruction of intact skin tissue within anobservation period up to 14 days startingafter the exposure time of more than60 minutes but not more than 4 hours;

substances which are judged not to cause fullthickness destruction of intact skin tissue,but which exhibit a corrosion rate on steel oraluminium surfaces exceeding 6.25 mm a year ata test temperature of 55 *C. For the purposesof testing steel, type P3 (ISO 2604 (IV);1975) or a similar type, and for testingaluminium, non-clad types 7075-T6 or AZ5GU-T6shall be used.

2/ OECO Guidelines for Testing of Chemicals, No. 404"Acute Dermal Irritation/Corrosion" (1992).

Vol. 1845, A-8940

1995


2800 (4) If substances of Class 8, as a result of admixtures, come(cont'd) into different categories of risk from those to which the

substances specifically named in marginal 2801 belong, thesemixtures or solutions shall be assigned to the items and groupsto which they belong on the basis of their actual degree ofdanger.

NOTE: For the classification of solutions and mixtures (such aspreparations and wastes), see also marginal 2002 (8).

(5) On the basis of the criteria set out in (3), it may also be

determined whether the nature of a solution or a mixturespecifically named or containing a specifically named substanceis such that the solution or mixture is not subject to theprovisions for this class.

(6) For the packaging requirements of marginals 2805 (2),2806 (3) and 2807 (3), substances and mixtures of substanceshaving a melting point above 45 *C are considered to be solids.

(7) (a) Flammable corrosive liquids having a flashpointbelow 23 *C, other than substances of 54' (a) and

68' (a), are substances of Class 3 (see marginal 2301,

items 21' to 26").

(b) Flammable, slightly corrosive liquids having aflashpoint between 23 "C and 61 *C, are substances ofClass 3 (see marginal 2301, 33").

(c) Corrosive substances which are highly toxic byinhalation, as defined in marginal 2600 (3), aresubstances of Class 6.1 (see marginal 2601).

(8) The chemically unstable substances of Class 8 are to beaccepted for carriage only if the necessary steps have been taken

to prevent their dangerous decomposition or polymerization duringcarriage. To this end it should in particular be ensured thatreceptacles do not contain any substance liable to promote thesereactions.

(9) 1910 calcium oxide and 2812 sodium aluminate, identificationnumbers assigned in the United Nations Recommendations on theTransport of Dangerous Goods, are not subject to the provisions

of ADR.

Vol. 1845, A-8940


2800 (10) The flashpoint referred to below shall be determined in the(cont'd) manner described in Appendix A.3.

A. Acid substances

2801 INORGANIC SUBSTANCES

1" Sulphuric acid and similar substances:

(a) 1829 sulohur trioxide. inhibited (sulphuricanhydride, inhibited), 1831 sulphuric acid. fumina

(oleum), 2240 chromosulohuric acid;

(b) 1794 lead sulohate with more than 3% free acid,

1830 sulphuric acid with more than 51% acid,

1832 sulohuric acid. spent, 1833 sulohurous acid,1906 sludge acid, 2308 nitrosylsulohuric acid,2583 alkvlsulphonic acids, solid with more than 5%

free sulphuric acid or 2583 arvlsulohonic acids.

soLid with more than 5% free sulphuric acid, M584alkylsulohonic acids, liauid with more than 5% free

sulphuric acid or 2584 arylsulohonic acids. liquidwith more than 5% free sulphuric acid, Z7Msulphuric acid with not more than 51% acid or 2796battery fluid. acid, 2837 bisulohates. aqueoussolution (hydrogensulphate, aqueous solution).

NOTE 1: 2585 alkylsulphonic or arylsulphonic acids,

solid and 2586 alkylsulphonic or arylsulphonic acids,liquid with not more than 5% free sulphuric acid are

substances of item 34".

NOTE 2: Lead sulphate with not more than 3% free acid isnot subject to the provisions of ADR.

NOTE 3: Chemically unstable mixtures of sulphuric acid,

spent, are not to be accepted for carriage.

(c) 2837 bisulohates. aoueous solution(hydrogensulphate, aqueous solution).

Vol 1845, A-8940


2801 2 Nitric acids:(cont'd)

(a) 1. 2031 nitric acid, other than red fuming, withmore than 70% acid.

2. 2032 nitric acid. red fuming;

(b) 2031 nitric acid, other than red fuming, with not

more than 70% acid.

3" Nitrating acid mixtures:

(a) 1796 nitrating acid mixture with more than 50%nitric acid, 1826 nitrating acid mixture. spent with

more than 50% nitric acid;

(b) 1796 nitrating acid mixture with not more than 50%nitric acid, 1826 nitrating acid mixture, spent with

not more than 50% nitric acid.

NOTE 1: 1798 nitrohydrochloric acid is not to be

accepted for carriage.

NOTE 2: Chemically unstable mixtures of nitrating acidor mixtures of residual sulphuric and nitric acids, not

denitrated, are not to be accepted for carriage.

4 Perchloric acid solution:

(b) 1802 perchloric acid with not more than 50% acid, by

mass in aqueous solution.

NOTE 1: 1873 perchloric acid aqueous solution with morethan 50% but not more than 72% pure acid, by mass aresubstances of Class 5.1 (see marginal 2501, item 3" (a)).

NOTE 2: Perchloric acid aqueous solution with more than

72% pure acid, by mass, or mixtures of perchloric acidwith any liquid other than water, are not to be accepted

for carriage.

Vol. 1845, A-8940


5 Aqueous solutions of hydrogen halides, with the exception

of hydrofluoric acid:

(b) 1787 hydriodic acid, 1788 hydrobromic acid, *789hydrochloric acid;

(c) 1787 hydriodic acid, 1788 hydrobromic acid, 1789hydrochloric acid, 1840 zinc chloride solution,

2580 aluminium bromide solution, 2581 aluminiumchloride solution, 2582 ferric chloride solution(iron trichloride solution).

NOTE: Hydrogen bromide, anhydrous and hydrogen chloride,anhydrous are substances of Class 2 [see marginal 2201,3" (at) and 5' (at)].

6 Hydrogen fluoride and hydrofluoric acid solutions with

more than 85% hydrogen fluoride:

1052 hvdroaen fluoride, anhydrous, 1790 hydrofluoric acid

with more than 85% hydrogen fluoride.

NOTE: Special packing provisions are applicable to these


7" Solutions of hydrogen fluoride with not more than 85%

hydrogen fluoride:

(a) 1786 hydrofluoric acid and sulohuric acidmixture,1790 hydrofluoric acid with more than 60%

but ot- more than 85% hydrogen fluoride;

(b) 1790 hydrofluoric acid with not more than 60%

hydrogen fluoride, 2817 ammonium hvdrooendifluoride

solution (ammonium bifluoride solution);

(c) 2817 ammonium hvdrooendifluoride solution (ammonium

bifluoride solution).

Vol. 1845, A-8940


2801 8" Fluoro-acid substances:(cont'd)

(a) 1777 fluorosulohonic acid;

(b) 1757 chromic fluoride solution, I7difluoroohosohoric acid. anhydrous, 1775 fluoroboricacid, 1776 fluoroohosohoric acid. anhydrous,1778 fluorosilicic acid, 1782 hexafluoroohosohoric

(c) 1757 chromic fluoride solution.

9 Solid fluorides and other solid fluorinated substanceswhich, in contact with moist air or water, emit hydrogenfluoride:

(b) 1727 ammonium hvdrooendifluoride. solid, 175chromic fluoride, solid, 1811 ootassiumhydrogendifluoride (potassium bifluoride), 2439sodium hydroaendifluoride (sodium bifluoride),1740 hydrogendifluorides. n.o.s.;

(c) 1740 hydrooendifluorides. n.o.s.

NOTE: 2505 ammonium fluoride, 1812 potassium fluoride,1690 sodium fluoride, 2674 sodium fluorosilicate and2856 fluorosilicates, n.o.s. are substances of Class 6.1

(see marginal 2601, 63" (c), 64' (c) or 87" (c)].

I0, Liquid fluorides and other liquid fluorinated substanceswhich, in contact with moist air or water, emit hydrogenfluoride:

(b) 1732 antimony pentafluoride, 2851 boron trifluoridedihvdrate

NOTE: 1745 bromine pentafluoride, 1746 bromine

trifluoride and 2495 iodine pentafluoride are substancesof Class 5.1 (see marginal 2501, 5").

II* Solid halides and other solid halogenated substances,with the exception of fluorine compounds, which, in

contact with moist air or water, emit acid fumes:

Vol 1945, A-8940


2801 (b) 1725 aluminium bromide. anhydrous, 1726 aluminium(cont'd) chloride anhydrous, 1733 antimony trichloride,

1806 ohosohorus Dentachloride, 1939 ohosohorus

oxybromide, 2691 ohosphorus oentabromide, Z869titanium trichloride mixture

NOTE: Solid hydrated forms of aluminium bromide andaluminium chloride are not subject to the provisions ofADR.

(c) 1773 ferric chloride. anhydrous (iron (III)chloride, anhydrous), 2331 zinc chloride. anhydrous,2440 stannic chloride oentahvdrate, 2475 aynadiumtrichloride, 2503 zirconium tetrachloride,

2508 molybdenum oentachloride, 2802 cooper chloride,

2869 titanium trichloride mixture.

NOTE: Ferric chloride hexahydrate is not subject to theprovisions of ADR.

12" Liquid halides and other liquid halogenated substances,with the exception of fluorine compounds, which, in

contact with moist air or water, emit acid fumes:

(a) 1754 chlorosulohonic acid with or without sulphurtrioxide, 1758 chromium oxvchloride (chromyl

chloride), 1809 ohosohorus trichloride, 1828 sulohurchlorides, 1834 sulohuryl chloride, 1836 thionylc , 2444 vanadium tetrachloride, 2692 boron

tribromide (boron bromide), 2879 seleniumoxychloride;

(b) 1730 antimonv oentachloride. liouid, 1731 antimonyoentachloride solution, 1792 iodine monochloride,1808 ohosohorus tribromide, 1810 phosohorus

oxvchloride (phosphoryl chloride), Ij8Mpvrosulohurvl chloride, 1818 silicon tetrachloride,1827 stannic chloride, anhydrous, 183

thioohosohorvl chloride, 1838 titanium

tetrachloride, 2443 vanadium oxvtrichloride;

(c) 1731 antimony Dentachloride solution

Vol. 1845, A-8940


2801 13* Solid hydrogen sulphates:

(cont'd)(b) 2506 ammonium hvdrooen sulohate (ammonium

bisulphate), 2509 potassium hydrogen sulphate

(potassium bisulphate).

14* Bromine or bromine solutions:

1744 bromine or 1744 bromine solution.

NOTE: Special packing provisions are applicable to these


15, Inorganic acid substance in molten form:

2576 ohosohorus oxvbromide. molten.

16*. Solid inorganic acid substances and mixtures of thesesubstances (such as preparations and wastes) which cannotbe classified under other collective headings:

(a) 1905 selenic acid,3260 corrosive solid, acidic. inorganic. n.o.s.;

(b) 1807 ohosohorus nentoxide (phosphoric acid,anhydrous), t260 corrosive solid, acidic. inorganic.n.o.s.;"

(c) 2507 chloroolatinic acid. solid, 2578 phosohorust , 2834 ohosohorous acid, 2865 hvdroxvlamine

sulphate, 2967 sulohamic acid,3260 corrosive solid. acidic. inorganic. n.o.s.

17" Liquid inorganic acid substances and solutions andmixtures of these substances (such as preparations andwastes) which cannot be classified under other collective

headings:

(a) 3264 corrosive liouid. acidic. inoroanic. n.o.s.;

(b) 1755 chromic acid solution,3264 corrosive liguid. acidic. inorganic. n.o.s.;

Vol. 1845, A-8940


2801 (c) 1755 chromic acid solution, 1805 ohosohoric acid,(cont'd) 2693 bisulohites. aaueous solution. n.o.s.,

3264 corrosive liouid. acidic. inoroanic. n.o.s.

NOTE: 1463 chromium trioxide, anhydrous (chromic acid,solid) is a substance of Class 5.1 [(see marginal 2501,31" (b)].

ORGANIC SUBSTANCES

31" Solid carboxylic acids and anhydrides and solidhalogenated carboxylic acids and anhydrides:

(b) 1839 trichloroacetic acid, 1938 bromoacetic acid;

(c) 2214 ohthalic anhydride with more than 0.05% ofmaleic anhydride, 2215 maleic anhydride,2698 tetrahYdroohthalic anhydrides with more than0.05% of maleic anhydride, 2823 crotonic acid.

NOTE 1: Phthalic anhydride and tetrahydrophthalicanhydrides with not more than 0.05% of maleic anhydrideare not subject to the provisions of this class.

NOTE 2: Phthalic anhydride with not more than 0.05% ofmaleic anhydride carried or handed over for carriage inthe molten state at a temperature above its flashpoint isa substance of Class 3 (see marginal 2301, 61").

32" Liquid carboxylic acids and anhydrides and liquidhalogenated carboxylic acids and anhydrides:

(a) 2699 trifluoroacetic acid;

(b) 1. 1764 dichloroacetic acid, 1779 formic acid,1940 thioglycolic acid, 2564 trichloroaceticacid solution, 2790 acetic acid solutionwith not less than 50% but not more than 80%acid, by mass;

2. 1715 acetic anhydride, 2218 acrylic acid.inhibited, 2789 acetic acid. glacial or 278acetic acid solution, with more than 80%acid, by mass;

Vol. 1845, A-8940


2801 (c) 1848 oroolonic acid, 2496 oronionic anhydride,(cont'd) 2511 2-chloroorooionic acid, 2531 methacrylic acid.

inhibited, 2564 trichloroacetic acid solution,2739 butyric anhydride, 2790 acetic acid solution withmore than 25 % but less than 50 % acid, by mass,2820 butyric acid, 2829 caproic acid.

NOTE: Acetic acid solutions with not more than 25% pure acid

by mass, are not subject to the provisions of ADR.

33" Complex compounds of boron trifluoride:

(a) 2604 boron trifluoride diethvl etherate (borontrifluoride ether complex);

(b) 1742 boron trifluoride acetic acid comolex, 1743 borontrifluoride oropionic acid comolex.

NOTE: 2965 boron trifluoride dimethyl etherate is asubstance of Class 4.3 (see marginal 2471, 2" (b)).

34' Alkylsulphonic and arylsulphonic acids and alkylsulphuricacids:

(b) 1803 ohenolsulohonic acid. liguid,2305 nitrobenzenesulohonic acid, 2571 alkylsulohuric

(c) 2585 alkylsulohonlc acids, solid with not more than 5%free sulphuric acid or 2585 arylsulohonlc acids, solidwith not more than 5% free sulphuric acid,2586 alkylsulohonic acids, liouid with not more than 5%free sulphuric acid or 2586 arylsulohonic acids, liouidwith not more than 5% free sulphuric acid.

NOTE: 2583 alkylsulphonic or arylsulphonic acids, solid and2584 alkylsulphonic or arylsulphonlc acids, liquid with morethan 5% free sulphuric acid are substances of I* (b).

Vol. 1845. A-8940


2801 35" Organic acid halides:(cont'd)

(b) 1. 1716 acetvl bromide, 1729 anisoyl chloride,1736 benzovl chloride, 1765 dichloroacetvl chloride,

1780 fumarvl chloride, 1898 acetvl iodide,2262 dimethylcarbamoyl chloride,2442 trichloroacetyl chloride, 2513 bromoacetvl

bromide, 2577 ohenvlacetvl chloride,2751 diethvlthionhosohorvl chloride,

2798 ohenvlnhoshorus dichloride,2799 ohenvlohosohorus thiodichloride.

2. 2502 valervl chloride;

(c) 2225 benezenesulohonvl chloride.

36' Alkyl and aryl chlorosilanes having a flashpoint above 61 'C:

(b) 1728 amvltrichlorosilane,1753 chloroohenvltrichlorosilane,1762 cvclohexenvltrichlorosilane,1763 cvclohexvltrichlorosilane,1766 dichloroohenvltrichlorosilane,1769 diohenvldichlorosilane,

1771 dodecvltrichlorosilane,1781 hexadecvltrichlorosilane,1784 hexyltrichlorosilane, 1799 nonvltrichlorosilane,1800 octadecvltrichlorosilane,1801 octvltrichlorosilane, 1804 ohenvltrichlorosilane,2434 dibenzvldichlorosilane,

2435 ethylohenvldichlorosilane,2437 methvlohenvldichlorosilane,

2987 chlorosilanes. corrosive. n.o.s.

NOTE: Chlorosilanes which emit flammable gases in contactwith water or moist air are substances of Class 4.3 (seemarginal 2471, 1').

37" Alkylchlorosilanes and arylchlorosilanes, having a flashpoint

between 23 *C and 61 *C inclusive:

(b) 1724 alkyltrichlorosilane. stabilized,1747 butvltrichlorosilane, 1767 diethvldichlorosilane,

1816 oroovltrichlorosilane,2986 chlorosilanes. corrosive, flammable. n.o.s.

Vol. 1845. A-8940


2801 NOTE: Chlorosilanes which emit flammable gases in contact

(cont'd) with water or moist air are substances of Class 4.3 (seemarginal 2471, 1").

38' Alkylphosphoric acids:

(c) 1718 butyl acid phosphate, 1793 isooroovl acidohosohate, 1902 diisooctyl acid phosohate, 2819 amylacid ohosphate.

39' Solid organic acid substances and mixtures of thesesubstances (such as preparations and wastes) which cannot beclassified under other collective headings:

(a) 2430 alkylohenols. solid, n.o.s. (including C2-C,2homologues),3261 corrosive solid. acidic. organic. n.o.s.;

(b) 2430 alkvlohenols. solid, n.o.s. (including C2 -C,2homologues), 2670 cvanuric chloride,3261 corrosive solid. acidic. oroanic. n.o.s.;

(c) 2430 alkvlphenols, solid, n.o.s. (including C2 -C,2homologues),3261 corrosive solid. acidic. organic. n.o.s.

40" Liquid organic acid substances and solutions and mixtures ofthese substances (such as preparations and wastes) whichcannot be classified under other collective headings:

(a) 3145 alkvlohenols, liouid. n.o.s. (including C2-C,2homologues),3265 corrosive liouid. acidic, oroanic. n.o.s.;

(b) 3145 alkvlphenols. liquid. n.o.s. (including C,-C, 2homologues),3265 corrosive liouid. acidic, organic, n.o.s.;

(c) 3145 alkylhenols. liguid. n.o.s. (including C2 -C1 2

homologues),3265 corrosive liauid, acidic. oroanic. n.o.s.

Vol. 1845, A-8940


B. Basic substances

INORGANIC SUBSTANCES

2801 41 Basic solid compounds of alkali metals:

(cont'd)(b) 1813 potassium hydroxide. solid (caustic potash),

1823 sodium hydroxide. solid (caustic soda), 1825 sQdium

mnoxide (sodium oxide), 2033 ootassium monoxide(potassium oxide), 2678 rubidium hydroxide, 2680 lithium

hydroxide monohydrate, 2682 caesium hydroxide;

(c) 1907 soda lime with more than 4% sodium hydroxide,3253 disodium trioxosilicate oentahydrate (sodium

metasilicate pentahydrate).

NOTE: Soda lime with not more than 4% sodium hydroxide is

not subject to the provisions of ADR.

42" Solutions of alkaline substances:

(b) 1814 potassium hydroxide solution (potash lye),1819 sodium aluminate solution, 1824 sodium hydroxide

solution (soda lye), 2677 rubidium hydroxide solution,2679 lithium hydroxide solution, 2681 caesium hydroxide

soluion, 2797 battery fluid, alkali,1719 caustic alkali, liouid. n.o.s.;

(c) 1814 potassium hydroxide solution (potash lye),

1819 sodium aluminate solution, 1824 sodium hydroxide

solution (soda lye), 2677 rubidium hydroxide solution,2679 lithium hydroxide solution, 2681 caesium hydroxide

1719 caustic alkali liouid, n.o.s.

43* Ammonia solutions:

(c) 2672 ammonia solution, relative density between 0.88 and0.957 at 15 'C in water with more than 10% but not more

than 35% ammonia.

NOTE 1: Ammonia solutions with more than 35% ammonia are

substances of Class 2 [see marginal 2201, 9" (at)].

Vol. 1845, A-8940


2801 NOTE 2: Ammonia solutions with not more than 10% ammonia are

(cont'd) not subject to the provisions of ADR.

44" Hydrazine and its aqueous solutions:

(a) 2029 hydrazine. anhydrous;

(b) 2030 hvdrazine hydrate or 2030 hydrazine. aoueous

solution with not less than 37% but not more than 64%hydrazine, by mass;

NOTE: 3293 hydrazine, aqueous solution with not more than

37% hydrazine, by mass, is a substance of Class 6.1 (seemarginal 2601, 65" (c)].

45" Sulphides and hydrogen sulphides and their aqueous solutions:

(b) 1. 1847 potassium sulohide. hydrated with not less than30% water of crystallization, 1849 sodium sulohide.

hydrated with not less than 30% water, 2818 ammoniumDolysulphide solution, 2949 sodium hydrosulohide.

hydrated with not less than 25% water of

crystallization;

2. 2683 ammonium sulphide solution;

(c) 2818 ammonium Dolysulphide solution.

NOTE: 1382 anhydrous potassium sulphide and 1385 anhydrous

sodium sulphide and their hydrates with less than 30% water

of crystallization, and 2318 sodium hydrosulphide with lessthan 25% water of crystallization are substances of Class 4.2

(see marginal 2431, 13" (b)].

46" Solid inorganic basic substances and mixtures of these

substances (such as preparations and wastes) which cannot be

classified under other collective headings:

(a) 3262 corrosive solid, basic. inorganic. n.o.s.;

(b) 3262 corrosive solid, basic, inorganic. n.o.s.;

(c) 3262 corrosive solid, basic. Inorganic. n.o.s.

Vol. 1845, A-8940


2801 47" Liquid inorganic basic substances and solutidns and mixtures

(cont'd) of these substances (such as preparations and wastes) which

cannot be classified under other collective headings:

(a) 3266 corrosive liquid. basic. inorganic. n.o.s.;

(b) 3266 corrosive liquid. basic. inorganic. n.o.s.;

(c) 3266 corrosive liquid, basic. inorganic, n.o.s.

ORGANIC SUBSTANCES

51' Tetra-alkylammonium hydroxides:

(b) 1835 tetramethylammonium hydroxide.

52" Solid amines and polyamines:

(a) 3259 amines. solid, corrosive. n.o.s. or

3259 polvamines. solid, corrosive. n.o.s.;

(b) 3259 amines. solid, corrosive. n.o.s. or3259 polvamines, solid, corrosive. n.o.s.;

(c) 2280 hexamethylenediamine. solid, 2579 piperazine

(diethylenediamine), 3259 amines, solid, corrosive.

n.o.s. or

3259 oolvamines. solid, corrosive. n.o.s.

53" Liquid amines and polyamines or amino-alcohols, highly

corrosive or corrosive, having a flashpoint above 61 *C:

(a) 2735 amines. liauid, corrosive. n.o.s. or

2735 polvamines. liauid. corrosive. n.o.s.;

(b) 1761 cuoriethvlenediamine solution,

1783 hexamethvlenediamine solution,

2079 diethylenetriamine, 2259 triethvlenetetramine,2735 amines. liouid, corrosive. n.o.s. or

2735 oolvamines. liouid, corrosive. n.o.s.;

Vol. 1845, A-8940


2801 (c) 1761 cuoriethylenediamine solution,

(cont'd) 1783 hexamethylenediamine solution,

2269 3.3'-iminodioroovlamine (bisaminoproylamine,

dipropylenetriamine), 2289 isoohoronediamine,

2320 tetraethvleneoentamine,2326 trimethylcyclohexylamine,

2327 trimethvlhexamethvlenediamines, 2491 ethanolamine,2491 ethanolamine solution, 2542 tributylamine,

2565 dicyclohexylamine, 2815 N-aminoethvloioerazine,3055 2-(2-aminoethoxv)ethanol,

2735 amines. liauid. corrosive. n.o.s. or

2735 oolvamines. liouid, corrosive. n.o.s.

54' Liquid amines and polyamines, highly corrosive or corrosive,flammable having a boiling point greater than 35 *C:

(a) 2734 amines. liquid, corrosive, flammable. n.o.s. or

2734 oolvamines. liauid. corrosive, flammable. n.o.s.;

(b) 1604 ethylenediamine, 2051 2-dimethylaminoethanol,

2248 di-n-butvlamine, 2258 1.2-oroovlenediamine,2264 dimethvlcvclohexvlamine, 2357 cyclohexylamine,

2619 benzvldimethvlamine,

2685 N.N-diethvlethvlenediamine,2734 amines. liquid, corrosive, flammable. n.o.s. or

2734 polyamines. liouid. corrosive, flammable. n.o.s.

55" Solid organic basic substances and mixtures of these

substances (such as preparations and wastes) which cannot be


(a) 3263 corrosive solid, basic. oraanic. n.o.s.;

(b) 3263 corrosive solid, basic, organic. n.o.s.;

(c) 3263 corrosive solid, basic. organic. n.o.s.

56" Liquid organic basic substances and solutions and mixtures of

these substances (such as preparations and wastes) which


(a) 3267 corrosive liauid. basic. organic. n.o.s.;

(b) 3267 corrosive liquid. basic. organic. n.o.s.;

Vol 1845, A-8940

1995 United Nations - Treaty Series a Nations Unies - Recueil des Traitks 239

2801 (c) 3267 corrosive liauid, basic, organic. n.o.s.(cont'd)

C. Other corrosive substances

61 Chlorite and hypochlorite solutions:

(b) 1791 hYoochlorite solution with not less than 16%available chlorine, 1908 chlorite solution, with notless than 16% available chlorine;

(c) 1791 hvoochlorite solution with more than 5% but lessthan 16% available chlorine, 1908 chlorite solution,with more than 5% but less than 16% available chlorine.

NOTE 1: Chlorite and hypochlorite solutions with not morethan 5% available chlorine are not subject to the provisionsof ADR.

NOTE 2: Solid chlorites and hypochlorites are substances ofClass 5.1 (see marginal 2501, 14, 15" and 29").

62" Chlorophenolates and phenolates:

(c) 2904 chloroohenolates, liauid or 2904 ohenolates.

liguid, 2905 chloroohenolates. solid or 2905 ohenolates.

solid.

63" Formaldehyde solutions:

(c) 2209 formaldehyde solution with not less than 25%formaldehyde.

NOTE 1: 1198 formaldehyde solutions, flammable aresubstances of Class 3 (see marginal 2301, 33" (c)).

NOTE 2: Formaldehyde solutions, non-flammable, with less

than 25% formaldehyde are not subject to the provisions ofADR.

64' Chloroformates and chlorothioformates:

(a) 1739 benzvl chloroformate;

(b) 2826 ethyl chlorothioformate.

Vol. 145. A-8940


2801 NOTE: Chloroformates having predominantly toxic properties

(cont'd) are substances of Class 6.1 (see marginal 2601, 10, 17, 27"and 28').

65" Solid corrosive substances and mixtures of these substances(such as preparations and wastes) which cannot be classified

under other collective headings:

(a) 1759 corrosive solid. n.o.s.;

(b) 1770 diohenvlmethvl bromide,

1159 corrosive solid. n.o.s.,3147 dye. solid, corrosive. n.o.s. or 3147 dye

intermediate. solid, corrosive. n.o.s.;

3244 solids containina corrosive liquid. n.o.s.

NOTE: Mixtures of solids not subject to the provisions ofADR and corrosive liquids may be carried under number 3244,

without being subject to the classification criteria of

marginal 2800 (3), provided there is no free liquid visible

at the time the substance is loaded or at the time the

transport unit is closed. Each packaging shall correspond to

a design type which has passed the leakproofness test for

group (b) level.

(c) 2803 gallium,1759 corrosive solid. n.o.s.,3147 dye. solid, corrosive. n.o.s. or 3147 dye

intermediate. solid, corrosive. n.o.s.

NOTE: Special conditions of packing are applicable to

2803 gallium [see marginal 2807 (4)].

66" Liquid corrosive substances and solutions and mixtures of

these substances (such as preparations and wastes) which


(a) 1760 corrosive liouid. n.o.s.,1903 disinfectant, liouid. corrosive. n.o.s.;

Vol. 1845, A-8940


2801 (b) 2226 benzotrichloride (trichloromethylbenzene),(cont'd) 2705 I-oentol (3-methyl-2-pentene-4-yne-l-ol),

3066 paint (including paint, lacquer, enamel, stain,shellac, varnish, polish, liquid filler and liquidlacquer base) or 3066 paint related material includingpaint thinning or reducing compound,1760 corrosive liouid. n.o.s.,1903 disinfectant. liouid, corrosive. n.o.s.,2801 dye. liquid, corrosive. n.o.s. or 2801 dyeintermediate. liouid, corrosive. n.o.s.;

(c) 2809 mercury, 3066 paint (including paint, lacquer,enamel, stain, shellac, varnish, polish, liquid fillerand liquid lacquer base) or 3066 oaint related materialincluding paint thinning or reducing compound,1760 corrosive liouid, n.o.s.,1903 disinfectant. liquid. corrosive. n.o.s.,2801 dye, liouid, corrosive, n.o.s. or 2801 dyeintermediate. liouid, corrosive, n.o.s.

NOTE 1: Special conditions of packing are applicable to2809 mercury (see marginal 2807 (4)).

NOTE 2: Any substance of AOR specifically listed by nameunder other items may not be carried under the entries for3066 paint or 3066 paint related material.

Substances carried under these entries may contain 20% orless nitrocellulose provided the nitrocellulose contains notmore than 12.6% nitrogen.

67" Solid corrosive tubstances and mixtures of these substances,(such as preparations and wastes), flammable, which cannot beclassified under other collective headings:

(a) 2921 corrosive solid, flammable, n.o.s.;

(b) 2921 corrosive solid, flammable. n.o.s.

68" Liquid corrosive substances and solutions and mixtures ofthese substances, (such as preparations and wastes),flammable, having a boiling point greater than 35 "C, whichcannot be classified under other collective headings:

Vol. 1845, A-8940

1995

242 United Nations - Treaty Series e Nations Unies - Recueil des Traitks

2801 68" (a) 2920 corrosive liouid. flammable. n.o.s.;(cont'd) (cont'd)

(b) 2920 corrosive liquid. flammable. n.o.s.

69' Solid corrosive substances and mixtures of these substances,self-heating, (such as preparations and wastes) which cannot

be classified under other collective headings:

(a) 3095 corrosive solid, self-heating. n.o.s.;

(b) 3095 corrosive solid, self-heating. n.o.s.

70" Liquid corrosive substances and solutions and mixtures ofthese substances., self-heating, (such as preparations andwastes), which cannot be classified under other collectiveheadings:

(a) 3301 corrosive liquid. self-heating, n.o.s.;

(b) 3301 corrosive liquid, self-heating. n.o.s.

71' Solid corrosive substances and mixtures of these substances,(such as preparations and wastes) which, in contact with

water, emit flammable gases, and which cannot be classified

under other collectiye headings:

(a) 3096 corrosive solid, water-reactive. n.o.s.;

(b) 3096 corrosive solid, water-reactive. n.o.s.

NOTE: The term "Water-reactive" denotes a substance which, in


72" Liquid corrosive substances and solutions and mixtures ofthese substances (such as preparations and wastes) which, incontact with water, emit flammable gases and which cannot beclassified under other collective headings:

(a) 3094 corrosive liquid, water-reactive. n.o.s.;

(b) 3094 corrosive liquid, water-reactive. n.o.s.

NOTE: The term "water-reactive" denotes a substance which, in


Vol. 1845, A-8940

1995 United Nations - Treaty Series e Nations Unies - Recueil des Traitas 243

2801 73" Solid corrosive substances and mixtures of these substances,

(cont'd) oxidizing, (such as preparations and wastes) which cannot be


(a) 3084 corrosive solid, oxidizing. n.o.s.;

(b) 3084 corrosive solid, oxidizing. n.o.s.


these substances, oxidizing, (such as preparations and

wastes) which cannot be classified under other collective

headings:

(a) 3093 corrosive liquid, oxidizino. n.o.s.;

(b) 3093 corrosive liouid, oxidizing. n.o.s.

75" Solid corrosive substances and mixtures of these substances,

toxic (such as preparations and wastes) which cannot be


(a) 2923 corrosive solid, toxic, n.o.s.;

(b) 2923 corrosive solid, toxic. n.o.s.;

(c) 2923 corrosive solid, toxic. n.o.s.


these substances, toxic, (such as preparations and wastes)

which cannot be classified under other collective headings:

(a) 2922 corrosive liauid. toxic. n.o.s.;

(b) 2922 corrosive liauid, toxic. n.o.s.;

(c) 2922 corrosive liouid, toxic. n.o.s.

0. Articles containing corrosive substances

81* Batteries:

(c) 2794 batteries. wet. filled with acid, electric storage,

2795 batteries, wet. filled with alkali, electric

storage,

Vol. 1845. A-8940


2801 81" 2800 batteries, wet. non-spillable, electric storage,(cont'd) (cont'd) 3028 batteries. dry containing potassium hydroxide

sojjd, electric storage.

NOTE 1: Special conditions of packing are applicable tothese articles [see marginal 2807 (5)]

NOTE 2: Batteries (identification number 2800) can beconsidered as non-spillable provided that they are capable ofwithstanding the vibration and pressure differential testsgiven below, without leakage of battery fluid.

Vibration test: The battery is rigidly clamped to theplatform of a vibration machine and a simple harmonic motionhaving an amplitude of 0.8 mm (1.6 mm maximum totalexcursion) is applied. The frequency is varied at the rateof 1 Hz/min between the limits of 10 Hz to 55 Hz. The entirerange of frequencies and return is traversed in 95 ± 5minutes for each mounting position (direction of vibration)of the battery. The battery is tested in three mutuallyperpendicular positions (to include testing with fillopenings and vents, if any, in an inverted position) forequal time periods.

Pressure differential test: Following the vibration test,the battery is stored for six hours at 24 *C + 4 *C whilesubjected to a pressure differential of at least 88 kPa. Thebattery is tested in three mutually perpendicular positions(to include testing with fill openings and vents, if any, inan inverted position) for at least six hours in eachposition.

82" Other articles containing corrosive substances:

(b) 1774 fire extinguisher charges, corrosive liquid,2028 bombs. smoke. non-explosive with corrosive liquid,

without initiating device.

Vol 1845, A-8940


E. Empty packagings

91" Empty packaginas, including empty intermediate bulkcontainers (IBCs), emoty tank-vehicles, empty demountable

tanks, emptv tank-containers, uncleaned, as well as emptvehicles for carriage in bulk and emoty small bulk

containgU, uncleaned, having contained substances ofClass 8.

2801a Neither the provisions of this class contained in this Annex northose contained in Annex B are aplicable to:

(1) Substances of I* to 5, 7* to 13, 16, 17' , 31 to 47', 51"to 56' and 61" to 76', carried in conformity with the followingprovisions:

(a) Substances classified under (a) of each item:

Liquids: not more than 100 ml per inner packaging andnot more than 400 ml per package;

Solids: not more than 500 g per inner packaging andnot more than 2 kg per package.

(b) Substances classified under (b) of each item:

Liquids: not more than I litre per inner packagingand not more than 4 litres per package;

Solids: not more than 3 kg per inner packaging andnot more than 12 kg per package.

(c) Substances classified under (c) of each item:

Liquids: not more than 3 litres per inner packaging

and not more than 12 litres per package;

Solids: not more than 6 kg per inner packaging andnot more than 24 kg per package.

These quantities of substances shall be carried in combinationpackagings which at least meet the conditions of marginal 3538.

The "General conditions of packing" of marginal 3500 (1), (2) and(5) to (7) shall be observed.

Vol. 1845, A-8940


2801a (2) Non-spillable batteries with identification number 2800 of(cont'd) 81" if at temperature of 55 *C, the electrolyte will not flow from

a ruptured or cracked case and there is no free liquid to flow andif when packaged for carriage, the terminals are protected fromshort circuits.

(3) Manufactured articles or instruments containing not more than

I kg mercury of 66" (c).

2. Provisions

A. Packages

1. General conditions of nackinq

2802 (1) Packagings shall satisfy the conditions of Appendix A.5,unless special conditions for the packing of certain substances areprescribed in marginals 2803 to 2808.

(2) Intermediate bulk containers (IBCs) shall satisfy theconditions of Appendix A.6.

(3) In accordance with the provisions of marginals 2800(3)(b) and3511(2) or 3611(2) respectively the following shall be used:

- packagings of packing group I, marked with the letter "X",for the highly corrosive substances classified under theletter (a) of each item;

- packagings of packing group II or I, marked with the letter".Y" or "X", or IBCs of packing group II, marked with theletter "Y", for the corrosive substances classified under theletter (b) of each item;

- packagings of packing group III, II or I, marked with theletter "Z", "Y" or "X", or IBCs of packing group III or II,marked with the letter "Z" or "Y", for the slightly corrosivesubstances classified under the letter (c) of each item.

NOTE: For the carriage of substances of Class 8 in tank-vehicles,demountable tanks or tank-containers, and for the carriage in bulkof solids of this Class, see Annex B.

Vol. 1845, A-8940


2. Soecial conditions for packing of certain substances

2803 Hydrogen fluoride, anhydrous and hydrofluoric acid solutioncontaining more than 85% hydrogen fluoride of 6* shall be packed inpressure receptacles made of carbon steel or suitable alloy steel.The following pressure receptacles shall be permitted:

(a) cylinders having a capacity not exceeding 150 litres;

(b) receptacles having a capacity of not less than 100 litres andnot more than 1,000 litres (for example, cylindricalreceptacles fitted with rolling hoops or receptacles mountedon skids).

The pressure receptacles shall satisfy the relevant requirements ofClass 2 (see marginals 2211, 2213(l) and (2), 2215, 2216 and 2218).The wall thickness of the pressure receptacles shall not be lessthan 3 mm.

Before being used for the first time, pressure receptacles shall besubjected to a hydraulic pressure test at a pressure of not lessthan 1 MPa (10 bar) gauge pressure. The pressure test shall berepeated every eight years and shall be accompanied by an internalinspection of the pressure receptacles and a check of theirequipment. In addition, the resistance of the pressure receptaclesto corrosion shall be checked by means of suitable instruments(e.g. by ultrasound), and the condition of the equipment verified,every two years.

The tests and inspections shall be carried out under thesupervision of an expert approved by the competent authority.

The maximum mass of the contents per litre of capacity for hydrogenfluoride, anhydrous or hydrofluoric acid solution shall notexceed 0.84kg.

2804 (1) Bromine and bromine solution of 14" shall be packed in glassinner packagings, containing not more than 2.5 litres each, or inpolyvinylidene fluoride (PVDF) inner packagings containing not morethan 15 litres each which shall be placed in combination packagingsconforming to marginal 3538. The combination packaging!-shall betested and approved in accordance with Appendix A.5 for packinggroup I.

Vol. 1845, A-8940


2804 (2) Bromine containing less than 0.005% water, or between 0.005%

(cont'd) and 0.2% water, provided that in the latter case measures are taken

to prevent corrosion of the lining of the receptacles, may also be

carried in receptacles satisfying the following conditions:

(a) the receptacles shall be made of steel and be equipped

with a leakproof lining made of lead or of some other

material affording equivalent protection and with a

hermetic closure; receptacles made of monel metal or

nickel, or with a nickel lining, shall also be

permitted;

(b) the capacity of the receptacles shall not exceed450 1itres.;

(c) the receptacles shall not be filled to more than 92% oftheir capacity or more than 2.86 kg per litre of

capacity;

(d) the receptacles shall be welded and designed for a

calculation pressure of not less than 2.1 MPa (21 bar)

gauge pressure. The materials and workmanship shall in

other respects meet the relevant requirements of Class 2

(see marginal 2211(l)]. The initial test of unlined

steel receptacles shall be subject to the provisions of

Class 2 [see marginals 2215(l) and 2216(1)];

(e) the closures shall project as little as possible from

the receptacle and be fitted with protective caps. The

closures and caps shall be fitted with gaskets made of a

material not capable of being attacked by bromine. The

closures shall be in the upper part of the receptacles

in such a manner that they can In no case be in

permanent contact with the liquid phase;

(f) the receptacles shall be provided with fittings enabling

them to stand stably upright, and with lifting

attachments (rings, flanges, etc.) at the top, which

shall be tested at twice the working load.

Vol 1845, A-8940


2804 (3) Before being put into service, receptacles in conformity(cont'd) with (2) above shall be subjected to a leakproofness test at a

pressure of at least 200 kPa (2 bar) gauge pressure. Theleakproofness test shall be repeated every two years and shall be

accompanied by an internal inspection of the receptacle and a checkof its tare. The test and the inspection shall be carried out

under the supervision of an expert approved by the competentauthority.

(4) Receptacles in conformity with (2) shall bear, in clearly

legible and durable characters:

- the name of the manufacturer or the manufacturing mark andthe number of the receptacle,

- the word "Bromine",

- tare mass of the receptacle and the permissible maximum mass

of the filled receptacle,

- date (month, year) of the initial test and of the latest

periodical test,

- stamp of the expert who carried out the tests and

inspections.

2805 (1) Substances classified under (a) of the various items shall be

packed in:

(a) non-removable head steel drums conforming to

marginal 3520, or

(b) non-removable head aluminium drums conforming to

marginal 3521, or

(c) non-removable head steel jerricans conforming to

marginal 3522, or

(d) non-removable head plastics drums of a capacity not

exceeding 60 litres or non-removable head plastics

jerricans conforming to marginal 3526, or


marginal 3537, or

Vol. 1845, A-8940


2805 (f) combination packagings with inner packagings of glass,

(cont'd) plastics or metal conforming to marginal 3538, or

(g) composite packagings (glass, porcelain or stoneware)conforming to marginal 3539.

NOTE 1: to (d). The permissible period of use for packagings

intended for the carriage of nitric acid of 2'(a) and hydrofluoric

acid solution of 7"(a) shall be two years from the date of their

manufacture.

NOTE 2: to (f) and (g). Inner packagings or receptacles of

glass shall not be permitted for fluorides of 7"(a), 8"(a) or

33"(a).

(2) Solid substances within the meaning of marginal 2800(5) may

also be packed in:

(a) removable head drums conforming to marginals 3520 for

steel, 3521 for aluminium, 3523 for plywood, 3525 forfibreboard, or 3526 for plastics material, or in

removable head jerricans conforming to marginals 3522

for steel or 3526 for plastics material, if necessary

with one or more sift-proof inner bags; or

(b) combination packagings conforming to marginal 3538, withone or more sift-proof inner bags.

2806 (1) Substances classified under (b) of the various items shall be

packed in:

(a) steel drums conforming to marginal 3520, or

(b) aluminium drums conforming to marginal 3521, or

(c) steel jerridans conforming to marginal 3522, or

(d) plastics drums or plastics jerricans conforming to

marginal 3526, or


marginal 3537, or

(f) combination packagings conforming to marginal 3538, or

Vol. 1845, A-8940


2806 (g) composite packagings (glass, porcelain or stoneware)(cont'd) conforming to marginal 3539.

NOTE 1: to (a), (b), (c) and (d). Simplified conditions are

applicable to removable head drums and jerricans for viscoussubstances having a viscosity of more than 200 mm2/s at 23 'C andfor solid substances (see marginals 3512, 3553, 3554 and 3560).

NOTE 2: to (d). The permissible period of use for packagingsintended for the carriage of nitric acid containing more than 55%pure acid of 2"(b) and hydrofluoric acid solution of 7"(b) shall betwo years from the date of their manufacture.

NOTE 3: to (f) and (g). Inner packagings or receptacles of glass

shall not be permitted for fluorides of 7°(b), 8"(b), 9°(b), 10(b)or 33'(b).

(2) Substances classified under (b) of the various itemswhich have a vapour pressure at 50 "C of not more than 110 kPa

(1.10 bar) may also be packed in metal IBCs conforming tomarginal 3622, rigid plastics IBCs conforming to marginal 3624 orcomposite IBCs with rigid plastics inner receptacle conforming tomarginal 3625.

(3) Solid substances within the meaning of marginal 2800(5) mayalso be packed in:

(a) drums conforming to marginals 3523 for plywood or 3525for fibreboard, if necessary with one or more sift-proof

inner b.ags, or

(b) water-resistant bags conforming to marginals 3533 fortextile material, 3534 for woven plastics material, 3535for plastics film or 3536 for water-resistant paper,provided the goods are carried as a full load or thebags are secured on pallets, or

(c) composite IBCs with plastics inner receptacle conformingto marginal 3625, fibreboard IBCs conforming tomarginal 3626 or wooden IBCs conforming to

marginal 3627, or

Vol. 1845, A-8940


2806 (d) flexible IBCs conforming to marginal 3623 with the(cont'd) exception of IBCs of types 13H1, 13LI and 13M1, and

provided that the goods are carried as a full load orthe flexible IBCs are loaded on pallets.

(4) Articles of 82" shall be packed as follows:

(a) fire extinguisher charges, corrosive liquid, in woodenboxes conforming to marginals 3527, 3528 or 3529, orfibreboard boxes conforming to marginal 3530, orexpanded plastics boxes of type 4HI conforming tomarginal 3531.

(b) bombs, smoke, non-explosive with corrosive liquid,without initiating device, individually with cushioningmaterial in boxes, tubes or partitioned compartments ineither wooden boxes conforming to marginals 3527, 3528

or 3529, or steel boxes of type 4A conforming tomarginal 3537.

2807 (1) Substances classified under (c) except gallium of 65"(c) andmercury of 66"(c), of the various items shall be packed in:

(a) steel drums conforming to marginal 3520, or

(b) aluminium drums conforming to marginal 3521, or

(c) steel jerricans conforming to marginal 3522, or

(d) plastics drums or plastics jerricans conforming tomarginal 3526, or

(e) composite packagings (plastics material) conforming tomarginal 3537, or

(f) combination packagings conforming to marginal 3538, or

(g) composite packagings (glass, porcelain or stoneware)

conforming to marginal 3539, or

(h) light gauge metal packagings conforming to marginal

3540.

Vol. 1845. A-8940


2807 NOTE: to (a), (b), (c), (d) and (h). Simplified conditions are(cont'd) applicable to removable head drums, jerricans and light gauge metal

packagings for viscous substances having a viscosity of more than200 mm'/s at 23 *C and for solid substances (see marglnals 3512,3552 to 3554 and 3560).

(2) Substances classified under (c) except gallium of 65"(c) andmercury of 66"(c), of the various items which have a vapourpressure at 50 *C of not more than 110 kPa (1.10 bar) may also be

packed in metal IBCs conforming to marginal 3622, rigid plasticsIBCs conforming to marginal 3624 or composite IBCs with rigidplastics inner receptacle conforming to marginal 3625.

(3) Solid substances within the meaning of marginal 2800(5) mayalso be packed:

(a) in drums conforming to marginals 3523 for plywood, or3525 for fibreboard, if necessary with one or more sift-

proof inner bags, or

(b) in water-resistant bags conforming to marginals 3533 for

textile material, 3534 for woven plastics material or3535 for plastics film or 3536 for water-resistantpaper, or

(c) in flexible IBCs conforming to marginal 3623 with the

exception of IBCs of types 13H1, 13L1 and 13M1 or in

composite IBCs with flexible plastics inner receptacleconforming to marginal 3625 or in fibreboard IBCsconforming to marginal 3626 or wooden IBCs conforming tomarginal 3627.

(4) (a) Gallium of 65'(c) and mercury of 66"(c) shall be packedin combination packagings conforming to marginal 3538.

These combination packagings may consist of glass,porcelain, stoneware or plastics inner packagings,maximum net quantity of 10 kg. The following outerpackagings may be used:

Vol. 1845. A-8940


2807 natural wood boxes conforming to marginal 3527; plywood(cont'd) boxes conforming to marginal 3528; reconstituted wood

boxes conforming to marginal 3529; fibreboard boxesconforming to marginal 3530; plastics boxes conformingto marginal 3531 removable head steel drums conformingto marginal 3520; removable-head steel jerricansconforming to marginal 3522; plywood drums conforming tomarginal 3523; fibre drums conforming to marginal 3525;or in removable head plastics drums conforming tomarginal 3526.

(b) Mercury may also be packed in welded steel bottles withinner vaulted bottoms as single packagings. The closureshall be a bolt with a conical thread and the openingshall not exceed 20 mm.

(5) (a) Articles of 81, except batteries, wet, non-spillable,shall be fastened with inert cushioning material or inan equivalent manner in wooden boxes or in rigidplastics boxes or in a wooden slatted crate. Batteriesshall be insulated against short-circuiting.

(b) Non-spillable type batteries (identification number2800) shall be protected against short-circuits andshall be securely packed in strong outer packagings.

NOTE: Non-spillable batteries which are an integral part of, andnecessary for, the operation of mechanical or electronic equipment,shall be securely fastened in the battery holder on the equipmentand protected in such a manner as to prevent damage and short

circuits.

(c) Articles of 81" may bg carried on pallets. They shall bestacked and adequately secured in tiers separated by a layerof non-conductive material. Battery terminals shall not, inany case, support the weight of other superimposed elements.

Batteries shall be isolated in such a manner as to prevent

short-circuits. Each battery need not be marked and labelledif the pallet load bears a marking and a danger label.

2808 Packagings, including IBCs, containing 1791 hypochlorlte solutionof 61' shall be fitted with a vent conforming to marglnals 3500(8)or 3601(6) respectively.

Vol. 1845, A-8940


2809 Molten phosphorus oxybromide of 15' may be carried only intank vehicles (see Appendix B.la) or in tank-containers (see

Appendix B.Ib).

28103. Mixed oacking



(2) Substances of different items of this Class in quantities not

exceeding, per inner packaging, 3 litres for liquids and/or 5 kg

for solids, may be packed together and/or with goods not subject to

the provisions of ADR [see marginal 2800(8)], in a combination

packaging conforming to marginal 3538 provided they do not react

dangerously with one another.

(3) Substances of 4" shall not be packed together with other

goods, except with substances of 3" of Class 5.1, marginal 2501.

Substances of 6" and 14" shall not be packed together with othergoods.

(4) Substances classified under (a) of the various items shall

not be packed together with substances and articles of classes 1

and 5.2 and material of class 7.

(5) Except as otherwise specially provided, liquid substances

classified under (a) of the various items, in quantities not

exceeding 0.5 litre per inner packaging and 1 litre per package,

and substances classified under (b) or (c) of the various items, in

quantities not exceeding, per inner packaging, 3 litres for liquids

and/or 5 kg for solids, may be packed together in a combination

packaging conforming to marginal 3538 with substances or articles

of other Classes, provided that mixed packing is also permitted for

the substances and articles of these Classes, and/or with goods

which are not subject to the provisions of AOR [see marginal

2800 (8)], provided they do not react dangerously with one another.


(a) combustion and/or giving off considerable heat,

(b) emission of flammable and/or toxic gases,

(c) formation of corrosive liquids,

Vol. 1845, A-8940


2811 (d) formation of unstable substances.(cont'd)

(7) The mixed packing of acid substances with basic substances ina package shall not be permitted if the two substances are packedin fragile packagings.

(8) The provisions of marginals 2001(7), 2002(6) and (7) and 2802shall be complied with.


4. Marking and danger labels on packages

2812 Marking

(1) Each package shall be clearly marked with the identificationnumber of the goods to be entered in the transport document,preceded by the letters "UN".

Danger labels

(2) Packages containing substances or articles of Class 8 shall

bear a label conforming to model No. 8.

(3) Packages containing substances of 32"(b)2., 33"(a), 35"(b)2.,37, 54', 64"(b) and 68' shall, in addition bear a label conforming

to model No. 3.

(4) Packages containing substances of 44'(a) and 45"(b)2. shallin addition bear labels conforming to models Nos. 3 and 6.1.

(5) Packages containing substances of 67" shall in addition beara label conforming to model No. 4.1.

(6) Packages containing substances of 69" and 70" shall inaddition bear a label conforming to model No. 4.2.

(7) Packages containing substances of 71" and 72" shall inaddition bear a label conforming to model No. 4.3.

(8) Packages containing substances of 3"(a), 4, 73" and 74"shall in addition bear a label conforming to model No. 05.

Vol. 1845, A-8940


2812 (9) Packages containing substances of 2"(a)2. shall in addition(cont'd) bear labels conforming to models Nos. 05 and 6.1.

(10) Packages containing substances listed below shall in additionbear a label conforming to model No. 6.1:

Item number Substance Substance

identificationnumber

]*(a) 1831 Sulphuric acid, fuming (oleum)

6 All substances

7" All substances

9'(b) 1811 Potassium hydrogendifluoride

(potassium bifluoride)

10(b) 1732 Antimony pentafluoride

12"(a) 1809 Phosphorus trichloride

2879 Selenium oxychloride

14" All substances

44"(b) All substances

45"(b)1. and 2818 Ammonium polysulphide solution(c)

53"(b) and (c) 1761 Cupriethylenediamine solution

75* All substances

76" All substances

(11) Packages containing fragile receptacles not visible from theoutside shall in addition bear on two opposite sides a label

conforming to model No. 12.

(12) Packages containing liquids in receptacles, the closures ofwhich are not visible from the outside, as well as packages

containing vented receptacles or vented receptacles without outer

packaging, shall in addition bear on two opposite sides a labelconforming to model No. 11.

2813-

Vol. 1845, A-8940


B. Particulars in transoort document

2814 The description of the goods in the transport document shall

conform to one of the substance identification numbers and one of

the names underlined in marginal 2801.

If the substance is not mentioned by name but is assigned to an

n.o.s. entry the description of the goods shall consist of the

identification number and the n.o.s. designation, followed by the

chemical or technical name. /

The description of the goods shall be followed by oarticulars of

the Class. the item number. the letter if applicable, and the

initials "ADR" (or "RID"), e.g. "8, 1"(a), ADR".

For the carriage of wastes (see marginal 2000(5)) the description

of the goods shall be: "Waste, containing ... ", the component(s)

which has/have been used for the classification of the waste under

marginal 2002(8) to be entered under its/their chemical name(s),

e.g. "Waste containing 1824 sodium hydroxide solution, 8, 42*(b)

ADR".

For the carriage of solutions or mixtures (such as preparations and

wastes) containing several components subject to the ADR, it will

not in general be necessary to refer to more than two components

which predominantly contribute to the danger or dangers of the

solutions and mixtures.

For the carriage of solutions and mixtures containing only one

component subject to the provisions of ADR, the words "solution" or"mixture" should be added as part of the name in the transport

document (see marginal 2002(8)).

When a solid substance is handed over for carriage in the molten

state, the description of the goods shall be completed by the word'molten", unless it is already included in the name.

3J The technical name shall be a name currently used in scientific and

technical handbooks, journals and texts. Trade names shall not be used for

this purpose.

Vol. 1845, A-8940


2814 If a solution or mixture specifically named or containing a(cont'd) specifically named substance is not subject to the conditions of

this Class, In accordance with marginal 2800(5), the consignor mayenter in the transport document: "Not Goods of Class 8".

2815-2821

C. Emuty oackagings

2822 (1) Uncleaned empty packagings, including empty IBCs, of 91"shall be closed in the same manner and with the same degree ofleakproofness as if they were full.

(2) Uncleaned empty packagings, including empty IBCs, of 91"shall bear the same danger labels as if they were full.

(3) The description in the transport document shall conform toone of the names underlined in 91", e.g. "Empty packagings, 8, 91,ADR".

In the case of empty tank-vehicles, empty demountable tanks, emptytank-containers and empty small bulk containers, uncleaned, thisdescription shall be completed by adding the words "Last load"together with the name and item number of the goods last loaded,e.g. "Last load: 1830 sulphuric acid, 1*(b)".

2823-

2824


2825 Substances of class 8 may be carried until 30 June 1995 inaccordance with the requirements for Class 8 applicable until 31December 1994. The transport document shall, in such cases, bearthe inscription "Carriage in accordance with the ADR in force

before 1 January 1995".

2826-2899"

Vol 1845. A-8940

260 United Nations - Treaty Series 9 Nations Unies - Recueil des Trait~s 19

CLASS 9 MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES

2901 Insert the following new item

"8' Motor vehicle components

(c) 3268 air bag inflators. 3268 air bag modules.3268 seat-belt ore-tensioners or3268 seat-belt modules

NOTE 1: This item applies to articles which may be classified in

Class 1 in accordance with marginal 2100(2)(b), which are used aslife-saving vehicle air bags or seat-belts, when carried as

component parts and when the 'air bag inflators', 'seat-beltpre-tensioners', 'air bag modules' or 'seat-belt modules' packaged

as for carriage have been tested in accordance with testseries 6(c) of part I of the recommendations on the transport of

dangerous goods, tests and criteria, ?./ with no explosion of the

device, no fragmentation of device casings, and no projectionhazard or thermal effect, which would significantly hinder

firefighting or other emergency response efforts in the immediate

vicinity.

NOTE 2: Such air bags or seat-belts installed in vehicles or in

completed vehicle components such as steering columns, door panels,

etc. are not subject to thd provisions of ADR."

"F. Environmentally hazardous substances

NOTE: Assignment of a substance to 11" or 12" shall be as

indicated in Appendix A.3, section G, marginals 3390 to 3396.

11" Liquid substances pollutant to the aquatic environment and

solutions and mixtures of such substances (such as preparations andwastes), which cannot be classified in the other classes, or in

items 1" to 8, 13" and 14' of this Class.

Z/ Recommendations on the Transport of Dangerous Goods, Tests and

Criteria (Second edition), published by the United Nations Organization under

the symbol ST/SG/AC.1O/11/Rev.1.

Vol. 1845, A-8940


2901(cont'd)

(c) 3082 Environmentally hazardous substance, liauid, n.o.s., such as:

alcohol C6-C,7 (secondary) poly (3-6) ethoxylatealcohol C,2-C15 poly (1-3) ethoxylatealcohol C,3-C,. poly (1-6) ethoxylatealpha-cypermethrinbutyl benzyl phthalatechlorinated paraffins (C,0-C13 )1-chlorooctanecresyl diphenyl phosphatecyfluthrindecyl acrylatedi-n-butyl phthalate1,6-dichlorohexanediisopropylbenzenesisodecyl acrylateisodecyl diphenyl phosphateisoctyl nitratemalathionresmethrintriaryl phosphatestricresyl phosphatestriethylbenzenetrixylenyl phosphate

12" Solid substances pollutant to the aquatic environment and mixturesof such substances (such as preparations and wastes) which cannotbe classified in the other classes, or in items I to 8, 13" and

14' of this Class.

(c) 3077 Environmentally hazardous substance. solid. n.o.s., suchas:

chlorohexidinechlorinated paraffins (C,0-C13 )p-dichlorobenzenediphenyldiphenyl etherfenbutatin oxidemercurous chloride (calomel)tributyltin phosphatezinc bromide

Vol. 1945, A-8940


2901(cont'd) 13" Genetically modified micro-organisms.

NOTE 1: Genetically modified micro-organisms are micro-organisms in which the genetic material has been deliberatelyaltered by technical means or by such means that cannot occurnaturally.

NOTE 2: Genetically modified micro-organisms which areinfectious are substances of Class 6.2 (see marginal 2651,items I* to 3, identification numbers 2814 and 2900).

NOTE 3: Genetically modified micro-organisms within themeaning of this item are those which are not dangerous forhumans and animals, but which could alter animals, plants,

microbiological substances and ecosystems in such a way as

cannot occur naturally.

(b) 3245 Genetically modified micro-organisms

NOTE 1: Genetically modified micro-organisms which havereceived a consent for deliberate release into the

environment, _/ are not subject to the provisions of this

Class of ADR.

NOTE 2: For the purpose of the packaging requirements ofmarginal 2903, substances and mixtures of substances aredeemed to be solids if they do not contain free liquid at atemperature less than 45 *C.

NOTE 3: Live vertebrate or invertebrate animals shall not beused to carry substances classified under this item unlessthe substance can be carried in no other way.

I/ See in particular Part C of Directive 90/220/EEC (Official Journal ofthe European Community, No. L 117, of 8 May 1990, pp. 18 to 20), which sets

out the authorization procedures for the European Community.

Vol 1845, A-8940


2901 14" Genetically modified oroanisms

(cont'd)NOTE: Genetically modified organisms, which are known or

suspected to be dangerous to the environment shall be carried

in accordance with conditions specified by the competent

authority of the country of origin."

Replace the existing heading "F. Empty packagings" by "G.

Empty packagings", and "11"' by "21"".

2901a (1) First sentence, replace "of 1, 2" and 4"" by "of 1, 2, 4"

and 11" to 13"".

2903 Amend (2)(c) and add a new (2)(d) as follows:

"(c) in composite IBCs with flexible plastics inner receptacle

conforming to marginal 3625, fibreboard IBCs conforming to

marginal 3626 or wooden IBCs conforming to marginal 3627, or

(d) in flexible IBCs conforming to marginal 3623 with the

exception of IBCs of types 13H1, 1311 and 13MI, provided that

the goods are carried as a full load or the flexible IBCs are

loaded on pallets."

2904 Add a new paragraph (4) as follows:

"(4) Articles of 8"(c) shall be packed in combination packagings

conforming to marginal 3538 and to a design type tested and

approved for packing group III".

2908 (new) "(1) If substances of 13* are carried in deeply refrigerated

nitrogen, the inner packagings shall conform to the provisions of

this Class and the receptacles for the nitrogen shall satisfy the

provisions of Class 2.

(2) Live animals in accordance with 13, NOTE 3, shall be packed,

marked, described and carried in accordance with the relevant

regulations for the carriage of animals J/".

2911 In paragraphs (2) and (3), after "items of Class 9", add "except

substances of 13"", and replace the word "receptacle" by "inner

packaging".

4/ See footnote 4/ in marginal 2650(7).

Vol. 1845, A-8940

264 United Nations - Treaty Series 9 Nations Unies - RecueiU des Traitis 1995

2911 New paragraph (5):(cont'd)

"(5) Substances of 13" shall not be packed together in acombination packaging conforming to marginal 3538 with other goods.This shall not apply to substances added as coolants, e.g. ice, dryice or deeply refrigerated liquid nitrogen."

Paragraphs (5) and (6) become (6) and (7).

2912 Insert the following new paragraph (1) under "MarrkiJng":

"(1) Each package shall be clearly and durably marked with theidentification number of the goods to be entered in the transportdocument, preceded by the letters 'UN'."

Paragraphs (1) to (4) are renumbered (2) to (5).

In paragraph (3) (renumbered (4)), replace "55 "C" by "61 "C".

Insert a new paragraph (6)

"(6) New packages containing substances of 13" carried in deeplyrefrigerated nitrogen shall also bear a label conforming to model

No. 2."

Paragraphs (5) and (6) become paragraphs (7) and (8).

2914 (1) In the first sentence, add "- except for substances of 14 -"

after "identification numbers".

Vol. 1845, A-8940


2914 (1) Insert after the first sentence:

(cont'd)"If the substance is not mentioned by name, but is assignedto an n.o.s. entry, the description of the goods shall

consist of the identification number and the n.o.s.

designation, followed by the chemical or technical Vf name of

the substance, or for substances of 13", by the biological

name 5_/ of the substance.

5/ The technical or biological name shall be a name currently used in

scientific and technical handbooks, journals and texts. Trade names shall not

be used for this purpose. In the case of pesticides, the name to be enteredshould be that given in Standard ISO 1750: 1981 if listed.

In the second part of paragraph (1), replace "see marginal

2000 (4)" with "see marginal 2000 (5)".

At the end of paragraph (1), add:

"For solutions and mixtures containing only one component

subject to the provisions of ADR, the words 'solution' or'mixture' shall be added as part of the name in the transport

document (see marginal 2002(8)].

When a solid substance is handed over for carriage in themolten state, the description of the goods shall be completed

by the word 'molten', unless it is already included in the

name.

For the carriage of easily perishable substances of 13"appropriate information shall be given, e.g.: 'Cool at+2"/+4 'C' or 'Carry in frozen state' or 'Do not freeze'.'

2921 Replace "11" by "21"" five times."

Vol. 1845, A-8940


PART III

APPENDICES TO ANNEX A

APPENDIX A.1

3102 The beginning should read as follows: "Conditions relating tonitrated cellulose mixtures of class 4.1.

(1) Nitrocellulose of marginal 2401, 24' (a), heated for half anhour ....... (remainder unchanged).

Insert new marginal 3103 and 3104 to read as follows:

Conditions relating to self-reactive substances of Class 4.1

Testing for assignment under Section E of marginal 2401

3103 "Self-reactive substances of items 31] to 50" can only be acceptedfor carriage and when the relevant criteria in Parts II and III of

the 'Recommendations on the Transport of Dangerous Goods: Testsand Criteria' (second edition published by the United NationsOrganization under the reference (ST/SG/AC.10/11/Rev.1) are met.The principles for classification of self-reactive substances aregiven in marginal 3104. The test selected for determining the

self-accelerating decomposition temperature (SADT) shall beconducted in a manner which is representative, both in size andmaterial, of the package to be carried.

Princioles for classification of self-reactive substances ofClass 4.1

3104 (1) A self-reactive substance or self-reactive substanceformulation shall be regarded as possessing explosive propertieswhen in laboratory testing it is liable to detonate, to deflagraterapidly or to show a violent effect when heated under confinement.

(2) The following principles shall be applied to theclassification of a self-reactive substance and self-reactivesubstance formulation not listed in marginal 2401:

Vol. 1845, A-8940

1995


3104 (a) any self-reactive substance or self-reactive substance(cont'd) formulation which can detonate or deflagrate rapidly, as packaged

for carriage, shall be prohibited from carriage in that packagingunder Class 4.1 (defined as self-reactive substance type A, exitbox A of figure 1);

(b) any self-reactive substance or self-reactive substanceformulation possessing explosive properties and which, as packagedfor carriage, neither detonates nor deflagrates rapidly, but isliable to undergo a thermal explosion in that packaging, shall alsobear a label conforming to model No. 01. Such a self-reactivesubstance may be packaged in amounts of up to 25 kg unless themaximum quantity has to be limited to a lower amount to precludedetonation or rapid deflagration in the package (defined asself-reactive substance type 8, exit box B of figure 1);

(c) any self-reactive substance or self-reactive substanceformulation possessing explosive properties may be carried withouta label conforming to model No. 01 when the substance as packaged(maximum 50 kg) for carriage cannot detonate or deflagrate rapidlyor undergo a thermal explosion (defined as self-reactive substancetype C, exit box C of figure 1);

(d) any self-reactive substance or self-reactive substanceformulation which in laboratory testing:

- detonates partially, does not deflagrate rapidly and shows noviolent effect when heated under confinement; or

- does not detonate at all, deflagrates slowly and shows noviolent effect when heated under confinement; or

- does not detonate or deflagrate at all and shows a mediumeffect when heated under confinement

may be accepted for carriage in packages containing not more than50 kg (defined as self-reactive substance type D, exit box 0 offigure 1).

Vol. 1845. A-8940


3104 (e) any self-reactive substance or self-reactive substance

(cont'd) formulation which, in laboratory testing, neither detonates nor

deflagrates at all and shows low or no effect when heated under

confinement may be accepted for carriage in packages containing not

more than 400 kg/450 litres (defined as self-reactive substancetype E, exit box E of figure 1);

(f) any self-reactive substance or self-reactive substance

formulation which, in laboratory testing, neither detonates in the

cavitated state nor deflagrates at all and shows only a low or no

effect when heated under confinement as well as low or no explosivepower may be accepted for carriage in IBCs (defined as self-reactive substance type F, exit box F of figure 1);

(g) any self-reactive substance or self-reactive substanceformulation which, in laboratory testing, neither detonates in the

cavitated state nor deflagrates at all and shows no effect whenheated under confinement, nor any explosive power shall not be

considered as a self-reactive substance of Class 4.1, provided that

the formulation is thermally stable (self-accelerating

decomposition temperature is 60 'C to 75 °C for a 50 kg package)and any compatible diluent meets the requirements of marginal

2400(19) (defined as self-reactive substance type G, exit box G of

figure 1). If the formulation is not thermally stable or a

compatible diluent having a boiling point less than 150 "C is used

for desensitization, the formulation shall be defined as a

self-reactive substance type F.

Vol. 1845, A-8940


FIGURE I

Classification and flow chart scheme forself-reactive substances

.1 0

L,-

Vol 1845, A-8940


3104 (3) Paragraph (2) refers only to those properties of(cont'd) self-reactive substances which are decisive for classification. A

flow chart, presenting the classification principles in the form of

a graphically arranged scheme of questions concerning the decisiveproperties together with the possible answers, is given infigure 1. These properties shall be determined experimentally in

accordance with marginal 3102."

Existing marginals 3103 and 3104 are renumbered 3105 and 3106.References to marginals 3103 and 3104 in marginals 2501 to 2599should be renumbered accordingly.

The existing "figure 1" is renumbered as "figure 2".


Ammunition. practice, insert "30"/0488"

Ammunition, smoke, with or without burster, expelling charge orpropelling charge. Sentence 1 to read: "Ammunition containing a

smoke-producing substance such as chlorosulphonic acid mixture ortitanium tetrachloride; or a smoke-producing pyrotechniccomposition based on hexachloroethane or red phosphorus."

Add:

"Articles. explosive. extremely insensitive (Articles [EE) 50'/0486

Articles containing only extremely insensitive detonatingsubstances (EIDS) which demonstrate a negligible probability ofaccidental initiation or propagation under normal conditions oftransport, and which have passed Test Series 7."

Cartridoes. small arms: delete "15'/0328;"insert: "27"/0417"

after "cartridges. small arms" insert the following new

description:

"Cartridges, for weapons. blank 27'/0327; 37"/0338; 47"/0014

Vol. 1845, A-8940

1995 United Nations - Treaty Series e Nations Unies - Recueil des Traitks

3170 Ammunition consisting of a closed cartridge case with a centre or(cont'd) rim fire primer and a charge of smokeless or black powder. The

cartridge cases contain no projectiles. The cartridges aredesigned to be fired from weapons with a calibre of at most 19.1 mmand serve to produce a loud noise and are used for training,saluting, propelling charge, starter pistols," etc.

Charges. propelling. for rocket motors:

Delete "for rocket motors" in the title.

Insert: "37'/0491".

Description to read:

"Articles consisting of a propellant charge in any physical form,with or without a casing, as a component of rocket motors or forreducing the drag of projectiles."

Charges. propelling, for rocket motors, composite mixture: delete

the whole entry.

Add the following new description after "Charges. suoolementary.explosive"

"Comoonents. explosive train, n.o.s. 1*/0461; 13"/0382; 35"/0383;47"/0384

Articles containing an explosive designed to transmit detonation ordeflagration within an explosive train."

Cord. detonating, flexible: description to read:

"Article consisting of a core of detonating explosive enclosed inspun fabric and a plastics or other covering. The covering is not

necessary if the spun fabric is sift-proof."

Explosive. blasting. Tvoe A: in the penultimate sentence, delete

the word "plastic" and change "may" to "shall"

Vol. 1845, A-8940

271


3170 "Hexatonal. cast 4"/0393

(cont'd)amend to read "Hexotona] 4"/0393"

IexiJlite dry or wetted ... 4'/0118amend to read "Hexolite (hexotol), dry or wetted ... 4/0118"

Jet perforating guns. charoed, oil well, without detonator: insert

"39/0494"

Add: "Octonal 4"/0496

Substance consisting of an intimate mixture ofcyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) andaluminium."

Powder cake (powder paste), wetted ... with not less than 35%

water, by mass ...

replace "35%" with "25%".

Powder. smokeless

delete "generally"

Add: "Prooellant. liouid 2'/0497, 26"/0495

Substance consisting of a deflagrating liquid explosive, used for

propulsion.

Propellant. solid 2'/0498, 26"/0499

Substance consisting of a deflagrating solid explosive, used forpropulsion."

Signals, railway track. exolosive: insert: "307/0492; 43"/0493"

Sijgnals, smoke with explosive sound unit: delete the whole entry.

Signals. smoke without explosive sound device: delete the wholeentry.

Vol 1845, A-8940


3170 After "Signals. hand" insert the following new description:(cont'd)

" Signals. smoke 9'/0196; 19"/0313; 30"/0487; 43'/0197

Articles containing pyrotechnic substances which emit smoke. Inaddition they may contain devices for emitting audible signals.'

After "Sounding devices, exglosive" (second entry) insert the

following new description:

"Substances. exglosive, very insensitive (Substances, EVI 487/042)

Substances presenting a mass explosion hazard but which are soinsensitive that there is very little probability of initiation orof transition from burning to detonation under normal conditions oftransport, and which have passed Test Series 5."

Vol. 1845, A-8940


APPENDIX A.3

3300 (2) Replace "IP J/ 170/90" by "IP 1/ 170/94"

3301 (a) Replace "IP 1/ 33/59" by "IP 1/ 170/94".

3302 Replace "(21 "C, 55 °C and 100 "C respectively)" with "(23 *C and

61 *C respectively)".

3304 Add a new marginal as follows:

"Method of testing for combustibility

3304 (1) The method describes a procedure for determining whether thesubstance, when heated under the test conditions and exposed to anexternal source of flame applied in a standard manner, sustainscombustion.

(2) Principle of the method: a metal block with a concavedepression (test portion well) is heated to a specifiedtemperature. A specified volume of the substance under test istransferred to the well and its ability to sustain combustion isnoted after application and subsequent removal of a standard flameunder specified conditions.

(3) Apparatus: A combustibility tester consisting of a block ofaluminium alloy or other corrosion-resistant metal of high thermalconductivity is used. The block has a concave well and a pocketdrilled to take a thermometer. A small gas jet assembly on aswivel is attached to the block. The handle and gas inlet for thegas jet may be fitted at any convenient angle to the gas jet. Asuitable apparatus is shown in figure I and the essentialdimensions are given in figures 1 and 2.

The following equipment is needed:

(a) fIaLW, for checking that the height of the centre of thegas jet above the top of the test portion well is 2.2 mm(see figure 1);

Vol. 1845, A-8940


3304 (b) Thermometer, mercury in glass, for horizontal operation,(cont'd) with a sensitivity not less than I mm/ *C, or other measuring

device of equivalent sensitivity permitting reading at 0.5 "Cintervals. When in position in the block, the thermometer bulbshould be surrounded with thermally conducting thermoplasticcompound;

(c) Hotolate, fitted with a temperature-control device.(Other types of apparatus with suitable temperature-controlfacilities may be employed to heat the metal block);

(d) stopwatch, or other suitable timing device;

(e) Syringe, capable of delivering 2 ml to an accuracy of± 0.1 ml; and

(f) Fuel source, butane test fuel.

(4) Sampling: The sample shall be representative of thesubstance to be tested and shall be supplied and kept in a tightlyclosed container prior to test. Because of the possibility of lossof volatile constituents, the sample shall receive only the minimumtreatment to ensure its homogeneity. After removing each testportion, the sample container shall be immediately closed tightlyto ensure that no volatile components escape from the container; ifthis closure is incomplete, an entirely new sample should be taken.

(5) Procedure: Carry out the determination in triplicate.

WARNING - Do not carry out the test in a small confined area (forexample a glove box), because of the hazard of explosions.

(a) It is essential that the apparatus is set up in acompletely draught-free area (see warning) and in the absence ofstrong light, to facilitate observation of flash, flame, etc.

(b) Place the metal block on the hotplate or heat the metalblock by other suitable means so that its temperature, as indicatedby the thermometer placed in the metal block, is maintained at thespecified temperature with a tolerance of ± I *C. The testtemperature is 60.5/75 *C [(see (h)]. Correct this temperature for

Vol. 1845, A-8940


3304 the difference in barometric pressure from the standard atmospheric

(cont'd) pressure (101.3 kPa) by raising the test temperature for a highpressure or lowering the test temperature for a lower pressure by

1.0 'C for each 4 kPa difference. Ensure that the top of the metal

block is exactly horizontal. Use the gauge to check that the jet

is 2.2 mm above the top of the well when in the test position.

(c) Light the butane test fuel with the jet away from the

test position (i.e. in the "off" position, away from the well).Adjust the size of the flame so that it is 8 mm to 9 mm high and

approximately 5 mm wide.

(d) Using the syringe, take from the sample container at

least 2 ml of the sample and rapidly transfer a test portion of

2 ml ± 0.1 ml to the well of the combustibility tester and

immediately start the timing device.

(e) After a heating time of 60 s, by which time the test

portion is deemed to have reached its equilibrium temperature, andif the test fluid has not ignited, swing the test flame into the

test position over the edge of the pool of liquid. Maintain it in

this position for 15 s and then return it to the "off" positionwhile observing the behaviour of the test portion. The test flame

should remain alight throughout the test.

(f) For each test observe and record:

(i) whether there is ignition and sustained combustion

or flashing, or neither, of the test portionbefore the test flame is moved into the test

position;

(ii) whether the test portion ignites while the testflame is in the test position, and, if so, how

long combustion is sustained after the test flame

is returned to the "off" position.

(g) If sustained combustion interpreted in accordance withparagraph (6) is not found, repeat the complete procedure with new

test portions, but with a heating time of 30 s.

Vol. 1845, A-8940


3304 (h) If sustained combustion interpreted in accordance with(cont'd) paragraph (6) is not found at a test temperature of 60.5 "C, repeat

the complete procedure with new test portions, but at a test

temperature of 75 "C.

(6) Interpretation of observations: The substance shall beassessed as sustaining combustions if, for either of the heatingtimes, one of the following occurs with either of the testportions:

(a) When the test flame is in the "off" position, the test

portion ignites and sustains combustion;

(b) The test portion ignites while the test flame is in thetest position, maintained for 15 s, and sustains combustion formore than 15 s after the test flame has been returned to the "off"position;

Intermittent flashing shall not be interpreted assustained combustion. Normally, at the end of 15 s, the combustionhas either clearly ceased or continues. In cases of doubt, thesubstance shall be deemed to sustain combustion;

(c) Substances are considered not to sustain combustion iftheir fire point according to ISO 2592:1973 is greater than 100 "Cor if they are water miscible solutions with a water content ofmore than 90% by mass.

Vol 1845. A-8940


Design and dimensions of the test apparatusfor determining the comustiblity offallabe liouLds

Dimensions in millimetres

Ther=c=e :a-

Test gas jet

Test portion we!!

figure . '-'Combustibility tester

CLmensions Ln ailli=etres

Butane gas nle,

Test flameE. : .5

1 1

figure por2Tsn "Je m

F~gure 2 - Tear. gas jet; and C'lame

Vol. 1845, A-8940


Add the following new Section G:

"G. Test for determining the ecotoxicity. oersistence andbioaccumulation of substances in the'aquatic environment forassignment to Class 9

NOTE: The test methods used shall be those adopted by the OECD and

the European Committees. If other methods are used, they shall beinternationally recognized, be equivalent to the OECD/EC tests andbe referenced in test reports.

3390 Acute toxicity for fish

The object is to determine the concentration which causes 50%mortality in the.test species; this is the (LC5 0 ), value, namely,the concentration of the substance in water which will cause thedeath of 50% of a test group of fish during a continuous period oftesting of at least 96 hours. Appropriate types of fish include:striped brill (Brachvdanio rerto), fathead minnow (Pimeohales

promelas and rainbow trout (Oncorhvnchus mvkiss).

The fish are exposed to the test substance added to the water invarying concentrations (+I control). Observations are recorded atleast every 24 hours. At the end of the 96-hour activity and, ifpossible, at each observation, the concentration causing the death

of 50% of the fish is calculated. The no observed effect

concentration (NOEC) at 96 hours is also determined.

3391 Acute toxicity for daohnia

The object is to determine the effective concentration of the

substance in water which renders 50% of the daphnia unable to swim(EC6 ). The appropriate test organisms are daohnia magna anddaphnia pulex. The daphnia are exposed for 48 hours to the testsubstance added to the water in varying concentrations. The noobserved effect concentration (NOEC) at 48 hours is also

determined.

Vol. 1845. A-8940


3392 Aloal growth inhibition

The object is to determine the effect of a chemical on the growthof algae under standard conditions. The change in biomass and therate of growth with algae under the same conditions, but withoutthe presence of the test chemical, are compared over 72 hours. Theresults are expressed as the effective concentration which reducesthe rate of algal growth by 50%, IC.,, and also the formation ofthe biomass, ICsob.

3393 Tests for ready biodegradability

The object is to determine the degree of biodegradation under

standard aerobic conditions. The test substance is added in lowconcentrations to a nutrient solution containing aerobic bacteria.The progress of degradation is followed for 28 days by determiningthe parameter specified in the test method used. Severalequivalent test methods are available. The parameters includereduction of dissolved organic carbon (DOC), carbon dioxide (C02 )generation of oxygen (O) depletion.

A substance is considered to be readily biodegradable if within notmore than 28 days the following criteria are satisfied - within10 days from when degradation first reaches 10%:

Reduction of DOC: 70%Generation of CO, 60% of theoretical CO2 productionDepletion of 02 60% of theoretical 02 requirement.

The test may be continued beyond 28 days if the above criteria arenot satisfied, but the result will represent the inherentbiodegradability of the test substance. For assignment purposes,the "ready" result is normally required.

Where only COD and BOD5 data are available, a substance isconsidered to be readily biodegradable if the ratio of BOD5 to CODis greater than or equal to 0.5.

Vol. 1845, A-8940


3393 BOD (Biochemical Oxygen Demand) is defined as the mass of dissolved(cont'd) oxygen required by a specific volume of solution of the substance

for the process of biochemical oxidation under prescribedconditions. The result is expressed as grams of BOO per gram oftest substance. The normal test period is five days using anational standard test procedure.

COD (Chemical Oxygen Demand) is a measure of the oxidizability of a

substance, expressed as the equivalent amount in oxygen of anoxidizing reagent consumed by the substance under fixed laboratoryconditions. The results are expressed in grams of COD per gram of

substance. A national standard procedure may be used.

3394 Tests for bioaccumulation ootential

(1) The object is to determine the potential for bioaccumulationeither by the ratio at equilibrium of the concentration (c) of a

substance in a solvent to that in water or by the bioconcentration

factor (BCF).

(2) The ratio at equilibrium of the concentration (c) of asubstance in a solvent to that in water is normally expressed as alog,,. The solvent and water shall have negligible miscibility and

the substance shall not ionize in water. The solvent normally used

is n-octanol.

In the case of n-octanol and water, the result is:

log P.. - log.0 [Co/CJ]

where P._ is the partition coefficient obtained by dividing theconcentration of the substance in n-octanol (C.) by theconcentration of the substance in water (C.). If log/Po. t 3 then

the substance has a potential to bioaccumulate.

(3) The bioconcentration factor (BCF) is defined as the ratio-ofthe concentration of the test substance in the test fish (c,) tothe concentration in the test water (c.) at steady state:

BCF - (c,)/(c.).

Vol. 1845, A-8940


3394 The principle of the test involves exposing fish to a solution or

(cont'd) dispersion at known concentrations of the test substance in water.

Continuous flow, static or semi-static procedures may be used

according to the test procedure selected, based on the propertiesof the test substance. Fish are exposed to the test substance over

a given period of time, followed by a period of no further

exposure. During the second period, measurements are made of the

rate of increase in the water of the test substance (i.e. the rateof excretion or depuration).

(Full details of the various test procedures and the calculation

method for the BCF are given in the OECD Guidelines for Testing of

Chemicals, methods 305A to 305E, 12 May 1981).

(4) A substance may have a log P,. greater than 3 and a BCF less

than 100 which would indicate little or no potential to

bioaccumulate. In cases of doubt, the BCF value takes precedence

over log Po., as indicated in the flow chart shown in marginal

3396.

3395 Ciei

A substance may be regarded as a pollutant to the aquatic

environment if it satisfies one of the following criteria:

The lowest of the values of the 96 hour LC,, for fish, the 48-hour

EC.. for daphnia or the 72 hour IC5 for algae

- is less than or equal to 1 mg/L;

- is greater than I mg/L but less than or equal to 10 mg/L, and

the substance is not readily biodegradable;

- is greater than 1 mg/L but less than or equal to 10 mg/L, and

the log P.. is greater than or equal to 3.0 (unless the

experimentally determined BCF is less than or equal to 100).

Vol 1845. A-8940


Procedure to be followed

. Lowest value of 96 hour LC,. 48. hour ZC3 or 72 hour IC* as

appropriate.

BCF - bloconcencratLon factor.

Vol. 1845, A-8940

3396


APPENDIX A.5

3500 In the NOTE before Section I, insert "6.2" before "8 or 9".

(1) After "particularly by" add: "vibration or"

(6) After "one another", add:

"and cause:

(a) combustion and/or evolution of considerable heat;

(b) emission of flammable, and/or toxic gases;

(c) the formation of corrosive substances; or

(d) the formation of unstable substances.

shall no( be placed .........

(9) After "New", add:

"remanufactured,..."

Vol. 1845. A-8940


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Vol. 1845, A-8940

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3500 (12) Renumber this paragraph as paragraph (14) and insert two new(cont'd) paragraphs (12) and (13) as follows:

"(12) Packagings used for solids which may become liquid attemperatures likely to be encountered during carriage shall also becapable of containing the substance in the liquid state.

(13) The packagings shall be manufactured and tested under aquality assurance programme which satisfies the competent authorityin order to ensure that each manufactured packaging meets therequirements of this appendix."

3510 (1) Replace the definition of boxes as follows:

"Boxes:

packagings with complete rectangular or polygonal faces, madeof metal, wood, plywood, reconstituted wood, fibreboard,plastics or other suitable material. Small holes forpurposes such as ease of handling or opening, or to meet

classification requirements, are permitted as long as they donot compromise the integrity of the packaging during

carriage;"

Add the following definitions:

"Reconditioned oackaaings include metal drums that are:

(i) cleaned to original materials of construction, with all

former contents, internal and external corrosion, andexternal coatings and labels removed;

(ii) restored to original shape and contour, with chimes (ifany) straightened and sealed, and all non-integralgaskets replaced; and

(iii) inspected after cleaning but before painting, with

rejection of packagings with visible pitting,significant reduction in material thickness, metal

fatigue, damaged threads or closures, or other

significant defects."

Vol. 1845, A-8940


3510 "Remanufactured packaging include metal drums that:

(cont'd)(i) are produced as a UN type from a non-UN type;

(ii) are converted from one UN type to another UN type; or

(iii) undergo the replacement of integral structuralcomponents (such as non-removable heads).

Remanufactured packagings are subject to the samerequirements of this Appendix that apply to a new packagingof the same type."

"Reused nackagings:

packagings which have been examined and found free of defectsaffecting the ability to withstand the performance test; theterm includes those which are refilled with the same orsimilar compatible contents and are carried withindistribution chains controlled by the consignor of theproduct;"

(3) Insert the following:

"Sift-proof oackaoinos:

packagings impermeable to dry contents including fine solidmaterial produced during carriage."

3511 (1) Amend the word "type" to read "kind".

3512 Add the following note at the beginning of marginal 3512:

"NOTE The marking indicates that the packaging which bears itcorresponds to a successfully tested design type and that itcomplies with the provisions of this Appendix which are related tothe manufacture, but not to the use, of the packaging. In itself,therefore, the mark does not necessarily confirm that the packagingmay be used for any substance: generally the type of packaging(e.g. steel drum), its maximum capacity and/or mass, and anyspecial requirements are specified for each substance in theappropriate packaging marginals in the classes."

Vol. 1845, A-8940

288 United Nations - Treaty Series * Nations Unies - Recueil des Traitks 1'

3512 (1) Replace the first sentence with the following:

(cont'd)"Each packaging shall bear markings which are durable, legible and

placed in a location and of such a size relative to the packagingas to be readily visible. For packages with a gross mass of more

than 30 kg, the markings or a duplicate thereof shall appear on the

top or on a side of the packaging. Letters, numerals and symbols

shall be at least 12 mm high, except for packagings of 30 litres or30 kg capacity or less, when they shall be at least 6 mm in height

and for packagings of 5 litres or 5 kg or less when they shall be

of an appropriate size. The marking ..." (remainder unchanged).

(c) (ii) Second sentence: After "inner packagings", insert "andfor light gauge metal packagings, removable head, intended for

substances of Class 3, 5'(c)".

(iii) Add the following:

"(iii) for packagings intended to contain substances of

Class 6.2, 1* and 2, 'Class 6.2' shall be used instead of theinformation required in (i) or (ii);"

(d) After "inner packagings", insert: "and for light gauge metal

packagings, removable head, intended for substances of

Class 3, 5" (c)".

(2) Replace the existing text by the following:

"(2) Every reusable packaging liable to undergo a reconditioningprocess which might obliterate the packaging markings shall bear

the marks indicated in (1) (a) to (e) in a permanent form. Marks

are permanent if they are able to withstand the reconditioningprocess (e.g. embossed). For packagings other than metal drums of

a capacity greater than 100 litres, these permanent marks mayreplace the corresponding durable markings prescribed in (1). Inaddition to the durable markings prescribed in (1), every new metal

drum of a capacity greater than 100 litres shall, bear the marks

described in (1) (a) to (e) on the base, with an indication

VoI. 1845, A-8940


3512 of the nominal thickness of at least the metal used in the body(cont'd) (in mm, to 0.1 mm), in permanent form (e.g. embossed). When the

nominal thickness of either head of a metal drum is thinner than

that of a body, the nominal thicknesses of the top head, body, andbottom head shall be marked on the bottom in a permanent form

(e.g. embossed), for example '1.0 - 1.2 - 1.0' or '0.9 - 1.0 -1.0'. Nominal thicknesses of metal shall be determined accordingto the appropriate ISO standard, e.g. ISO 3574 : 1986 steel drums.

The marks indicated in (1) (f) and (g) shall not be applied in a

permanent form (e.g. embossed) except as provided for below.

For remanufactured metal drums, if there is no change to the

packaging type and no replacement or removal of integral structuralcomponents, the required markings need not be permanent(e.g. embossed). Every other remanufactured metal drum shall bearthe markings in (1) (a) to (e) in a permanent form (e.g. embossed)on the top head or side.

Metal drums made from materials (e.g. stainless steel) designed to

be reused repeatedly may bear the markings indicated in (1) (f) and(g) in a permanent form (e.g. embossed)."

(4) Add a new sub-paragraph as follows:

"(4) When, after reconditioning, the markings required by (1) (a)

to (d) no longer appear on the top head or the side of a metal

drum, the reconditioner shall apply them in a durable form followedby the markings required in (h), (i) and (j). These markings shallnot identify a greater performance capability than that for which

the original design type has been tested and marked."

(5) Amend as follows:

"(5) The letters 'V" or "W" may follow the packaging code. Theletter "V' signifies a'special packaging [see 3558 (5)]. The

letter "W" signifies that the packaging, although of the same typeindicated by the code, is manufactured to a specification different

to that in section III and is considered equivalent under the

provisions of 3500(14)."

(7) Third example: For "4A1W" read "4AW".

Vol. 1845, A-8940


35]2 (7) Last example: After "200 mm2 /s", add: "and for substances

(cont'd) of Class 3, 5"(c).

Add the following examples:

"For a remanufactured steel drum intended to transport liquids:

OA2/Y/100/91 (a), (b), (c), (d) and (e)

USA/MM5 (f) and (g)"

"For fibreboard box intended to contain substances of 1" and 2" of

Class 6.2:

4G/Class 6.2/S/92 (a) (i), (b), (c) (iii),

SP-9969-ERIKSSON (d), (e), (f), (g)"

"For fibreboard box intended to contain inner packagings or solids:

4G/Y145/S/83 (a), (b), (c), (d), (e)

NL/VL823 (f) and (g)

Change the table headings as follows:

"Kind Material Category Code Marginal"

Delete "4AI, 4A2, 4B] and 4B2" and insert instead:

"4A and 4B"

(b) After the word "plastics" insert the following:

"or other suitable material"

(b) Amend as follows:

"(b) Unless otherwise approved by the competent authority, the

period of use permitted for the transport of dangerous

substances shall not exceed five years, from the date of the

manufacture of the packaging, except where a shorter period

of use is prescribed because of the nature of the substance

to be transported."

3514

3525

3526

Vol. 1845, A-8940

1995


3527 (a) Add a second paragraph as follows:

"Fastenings shall be resistant to vibration experienced under

normal conditions of carriage. End grain nailing shall be avoidedwhenever practicable. Joins which are likely to be highly stressed

shall be made using clenched or annular ring nails or equivalentfastenings."

3530 (b) After "wood" in the first sentence, add:


and after "wooden battens" in the second sentence add:


(c) Renumber the last sentence as paragraph (d)

(d) Renumber the existing paragraph (d) as paragraph (e)

3532 Amend as follows the packaging codes:

"4A steel

4 aluminium"

(b) Delete "4A2 and 42"


"(b) To prevent the entry of moisture, a bag of four plies or more

shall be made waterproof by the use of either a waterresistant ply as one of the two outermost plies or a waterbarrier made of a suitable protective material between thetwo outermost plies; a bag of three plies shall be madewaterproof by the use of a water resistant ply as theoutermost ply. Where there is a danger of the containedsubstance reacting with moisture or where it is packed damp,water resistant ply or barrier shall also be placed next tothe substance. Joins and closures shall be waterproof."

Vol. 1845, A-8940


3550 (2) Add a new last sentence as follows:

"A packaging design type is defined by the design, size, materialand thickness, manner of construction and packing, but may includevarious surface treatments. It also includes packagings which

differ from the design type only in their lesser design height."

(3) Add a-final sentence as follows:

"For such tests on paper or fibreboard packagings, preparation at

ambient conditions shall be considered equivalent to therequirements of marginal 3551(3)."

(6) Add as follows:

"(6) The competent authority may permit the selective testing ofpackagings that differ only in minor respects from a tested type,e.g. smaller sizes of inner packagings or inner packagings of lowernet mass; and packagings such as drums, bags and boxes which areproduced with small reductions in external dimension(s.)"

(7) Add as follows:

"(7) Provided the validity of the test results is not affected andwith the approval of the competent authority, several tests may bemade on one sample."

3551 (1) Amend to read as follows:

"Tests shall be carried out on packagings and packages prepared asfor despach, including inner packagings of combination packagings.Ineer or single receptacles or packagings shall be filled to notless than 95% of their maximum capacity for liquids or 98% forsolids. For combination..packagings where the inner packaging isdesigned to carry liquids and solids, separate testing is requiredfor both liquid and solid contents. The substances or articles tobe transported in the packagings may be replaced by other

substances or articles except where this would invalidate theresults of the tests. For solids, when another substance ... "

(remainder unchanged).

Vol 1845. A-8940


355) (3) Add the following NOTr:

(cont'd)"NOTF: Average values shall fall within these limits. Short term

fluctuations and measurement limitations may cause individual

measurements to vary by up to +/-5% relative humidity without

significant impairment of test reproducibility."

(5) Add as follows, before the NOTE:

"Where the behaviour of the plastics material has been established

by other means, the above compatibility test may be dispensed with.

Such procedures shall be at least equivalent to the above

compatibility test and be recognized by the competent authority."

3552 (]) Add immediately following the table:

"Where more than one orientation is possible for a given drop test,

the orientation most likely to result in failure of the packaging

shall be used."

(?) Replace the main text with the following:

"The temperature of the test sample and its contents shall be

reduced to -18 "C or lower for the following packagings:

(a) plastics drums (see 3526);

(h) plastics jerricans (see 3526);

(c) plastics boxes other than expanded polystyrene boxes

(see 3531);

(d) composite packagings (plastics material) (see 3537);

(e) combination packagings with plastics inner packagings (see

marginal 3538);

(f) textile bags with inner plastics liner (see 3533);

Vol. 1845. A-8940

293

294 United Nations - Treaty Series a Nations Unies - Recueil des Traitis 1995

3552 (g) woven plastics bags (see 3534), and

(cont'd)(h) plastics film bags (see 3535).

Where the test samples are prepared in this way, the conditioningin marginal 3551(3) may be waived. Test liquids shall be kept inthe liquid state by the addition of anti-freeze if necessary."

(4) (c) Add at the end: "and for substances of Class 3, 5" (c)"

3553 (1) After "200 mm2/s", add: "light gauge metal packagings,removable head, intended for substances of Class 3, 5* (c)".

(4) Amend the text as follows:

"The test samples including their closures shall be restraincdunder water for 5 minutes while an internal air pressure isapplied, the method of restraint shall not affect the results nfthe test. Other methods at least equally effective may be used."

3554 (1) After "200 mm'/s", add: "light gauge metal packagings,removable head, intended for substances of Class 3, 5" (c)".

3555 (3) Replace the existing text with the following:

"Test Method:

The test sample shall be subjected to a force applied to the topsurface of the test sample equivalent to the total weight ofidentical packages which might be stacked on it during carriage.

The duration of the test shall be 24 hours, except that plasticsdrums and jerricans in accordance with marginal 3526, and compositepackagings 6HHI and 6HH2 in accordance with marginal 3537, intendedfor liquids, shall be subjected to the stacking test for a periodof 28 days at a temperature of not less than 40 'C.

The minimum height of the stack including the test sample shall be

3 metres.

Vol. 1845. A-8940


3555 For the test in accordance with marginal 355] (5), the original

(cont'd) filling substance shall be used. For the test in accordance withmarginal 355] (6), a stacking test shall be carried out with a

standard liquid.

Where the contents of the test samples are non-dangerous liquidswith relative density different from that of the liquid to be

carried, the force shall be calculated in relation to the latter."

(4) Amend and move the existing footnote &/ to become a new finalsentence in paragraph (4) as follows:

"Stacking stability shall be considered sufficient when, after thestacking test, and in the case of plastics packagings, aftercooling to ambient temperature, two filled packagings of the sanrtypp placed on each test sample maintain their position for onehour. "

3556 In the title, replace "55 'C" by "6] °C".

3558 Add the following new paragraphs (4) and (5):

(4) Add as follows:

"(4) Where an outer packaging of a combination packaging has beensuccessfully tested with different types of inner packagings, avariety of such different inner packagings shall also be assembledin this outer packaging. In addition, provided an equivalent level

of performance is maintained, the following variations in inner

packagings are allowed without further testing of the package:

(a) Inner packagings of equivalent smaller size shall be usedprovided:

(i) The inner Oackagings are of similar design to the testedinner packagings (e.g. shape - round, rectangular etc;);

(ii) The material of construction of the inner packagings(glass, plastics, metal etc.) offers resistance toimpact and stacking forces equal to or greater than that

of the originally tested packaging;

Vol. 1845, A-8940

1995


3558 (iii) The inner packagings have the same or smaller openings(cont'd) and the closure is of similar design (e.g. screw cap,

friction lid, etc.);

(iv) Sufficient additional cushioning material is used totake up void spaces and to prevent significant movementof inner packagings; and

(v) Inner packagings are oriented within the outer packaging

in the same manner as in the tested package.

(b) A lesser number of the tested inner packagings, or of theilternative types of inner packagings identified in (a)above, shall be used provided sufficient cushioning is addedto fill the void space(s) and to prevent significant movementof the inner packagings."

(5) Add as follows:

"(5) Articles or inner packagings of any type for solids orliquids shall be assembled and presented for carriage without

testing in an outer packaging under the following conditions:

(a) The outer packaging shall have been successfully tested inaccordance with marginal 3552 with fragile (e.g. glass) innerpackagings containing liquids using the packing group I dropheight.

(b) The total combined gross mass of inner packagings shall notexceed one half of the gross mass of inner packagings used

for the drop test in (a) above.

(c) The thickness of the cushioning material between innerpackagings and between inner packagings and the outside ofthe packaging shall not be reduced below the correspondingthickness in the originally tested packaging; and if a singleinner packaging was used in the original test, the thicknessof the cushioning between inner packagings shall not be lessthan the thickness of cushioning between the outside of thepackaging and the inner packaging in the original test. Ifeither fewer or smaller inner packagings are used (ascompared to the inner packagings used in the drop test)

Vol. 1845. A-8940


3558 sufficient additional cushioning material shall be used to(cont'd) take up void spaces.

(d) The outer packaging shall have passed successfully the

stacking test in marginal 3555 while empty. The total massof identical packages shall be based on the combined mass of

the inner packagings used for the drop test in (a) above.

(e) Inner packagings containing liquids shall be completelysurrounded with a 2ufficient quantity of absorbent material

to absorb the entire liquid contents of the inner packagings.

(f) If the outer packaging is intended to contain inner

packagings for liquids and is not leakproof, or is intended

to contain inner packagings for solids and is not sift-proof,a means of containing any liquid or solid contents in the

event of leakage shall be provided in the form of a leakproofliner, plastics bag or other equally efficient means of

containment. For packagings containing liquids, theabsorbent material required in (e) above shall be placedinside the means of containing liquid contents.

(g) Packagings shall be marked in accordance with marginal 3512

as having been tested to Packing Group I performance forcombination packagings. The marked gross mass in kilograms

shall be the sum of the mass of the outer packagings plus onehalf of the mass of the inner packaging(s) as used for the

drop test referred to in (a) above. The mark shall contain aletter "V" in accordance with marginal 3512 (5) as being a

special packaging."


"A test report containing at least the following particulars shallbe drawn up and shall be available to the users of the packaging:

1. to 6. unchanged;

7. Maximum capacity;

8. Characteristics of test contents, e.g. viscosity and relativedensity for liquids and particle size for solids;

9. to 13. unchanged;

Vol. 1845. A-8940

298 United Nations - Treaty Series * Nations Unies - Recueil des Traits

3559 14. A unique test report identification;

(cont'd)15. Date of the test report;

16. The test report shall be signed with the name and status of

the signatory."

Delete final sentence and replace as follows:

"The test report shall contain statements that the packagingprepared as for carriage was tested in accordance with the

appropriate provisions of Appendix A.5 and that any use of otherpackaging methods may render it invalid. A copy of the test reportshall be available to the competent authority."

3560 In the hading "B.", insert: ", remanufactured" after "new".

(1) Second indent; amend the beginning as follows:

"after remanufacturing or reconditioning, ... " (remainder

unchanged).

Insert the following after the second indent:

"For this test, packagings need not have their own closures fitted.

The inner receptacle of composite packagings may be tested without

the outer packaging provided the test results are not affected."

3571 Delete this marginal and "SECTION V Transitional period".

3571-3599

Vol. 1945. A-8940


ANNEX TO APPENDIX A.5

SECTION I

(d) Amend the specifications of white spirit as follows:

"boiling range 160-220 *C; relative density 0.78-0.80;flashpoint >50 "C; aromatic content 16-21%."

(e) Amend the specification of nitric acid as follows:

"Nitric acid in a concentration of not less than 55% shall be

used."

SECTION II

CLASS 3

Amend title A to read as follows:

"A. Substances having a flashpoint below 23 *C, not toxic, notcorrosive"

Under 5". read "Viscous substances" (delete ": Certain colours

for rotogravures and for leathers").

Amend title B to read as follows:

"B. Substances having a flashpoint below 23 *C and toxic"

Under 17" (b), delete the synonym "(methyl alcohol)".

Replace title D by title E as follows:

"E. Substances having a flashpoint between 23 "C and 61 "C

inclusive which might be slightly toxic or slightly corrosive"

Delete 32" (c) and substances listed under 32" (c).

Replace "33" (c)" by "(34" (c)".

Vol. 1845, A-8940


CLASS 6.1

Replace the text under class 6.1 by the following:

"B. Organic substances which have a flashpoint of 23 'C or above

or non-flammable organic substances.

12" Nitrogenous substances having a flashpoint above 61 *C:

(b) aniline Acetic acid

14" Oxygenated substances having a flashpoint above 61 *C:

(e) ethylene glycol monobutyl ether Acetic acid

furfuryl alcohol Acetic acid

phenol solution Acetic acid

27" Corrosive toxic organic substances, articles containingcorrosive toxic organic substances (such as preparations andwastes), which cannot be classified under other collectiveheadings

(b) cresols or cresylic acid Acetic acid"

Insert a new text for class 6.2 as follows:

CLASS 6.2

"I" - 4' All infectious substances considered

to be liquids in accordance withmarginal 2650 (5) Water"

Amend the text for class 8 as follows:

CLASS 8

"A. Acid substances

Inorganic acids

1 (b) Sulphuric acid Water

Sulphuric acid, spent Water

Vol. 1845, A-8940

1995 United Nations - Treaty Series - Nations Unies - Recueil des Trait~s 301

2' (b) Nitric acid with not morethan 55% acid

4" (b) Perchloric acid with not morethan 50% acid, by mass in aqueoussolution

5" (b) Hydrochloric acid with not more

and (c) than 36% pure acidHydrobromic acidHydriodic acid

7" (b) Hydrofluoric acid with not morethan 60% hydrogen fluoride I/

8" (b) Fluoroboric acid with not more

than 50% pure acidFluorosilicic acid

(hydrofluorosilicic acid)

17° (b) Chromic acid solution with not more

and (c) than 30% pure acid

17" (c) Phosphoric acid

Organic substances

32" (b) Acrylic acid, formic acid, aceticacid, thioglycolic acid

32° (c) Methacrylic acid, propionic acid

40" (c) Alkylphertols, liquid

Nitric acid

Nitric acid

Water

Water

Water

Water

Nitric acid

Water

Acetic acid

Acetic acid

Acetic acid

I/ Maximum 60 litres; permissible period of use two years.

Vol. 1845, A-8940


B. Basic substances

Inorganic substances

42' (b) Sodium hydroxide solution,and (c) potassium hydroxide solution

43" (c) Ammonia solution

44" (b) Hydrazine, aqueous solutions withnot more than 64% hydrazine, by mass

C. Other corrosive substances

61' (c) Chlorite and hypochlorite solutions 2.

63' (c) Formaldehyde solutions

Water

Water

Water

Nitric acid

Water"

L/ Test to be carried out only with vent. If the test is carried outwith nitric acid as the standard liquid, an acid-resistant vent shall be used.For hypochlorite solutions, vents of same design type, resistant tohypochlorite (e.g. of silicone rubber) but not resistant to nitric acid, arealso permitted.

Vol. 1845, A-8940


APPENDIX A.6

3600 (a) Amend as follows:

"(a) has a capacity of:

(i) not more than 3.0 m3 (3,000 litres) for solids andliquids of Packing Groups II and I1;

(ii) not more than 1.5 m3 for solids of Packing Group I

when packed in flexible, rigid plastics,composite, fibreboard and wooden IBCs;

(iii) not more than 3.0 m3 for solids of Packing Group Iwhen packed in metal IBCs;"

3601 (3 Replace the word "reconditioned" with "repaired".

3610 (1) Replace the definition of a flexible IBCs as follows:

"Flexible IBCs consist of a body constituted of film, woven fabricor any other flexible material or combinations thereof, and if

necessary an inner coating or liner, together with any appropriate

service equipment and handling devices."

(2) In the definition of "Liner", before the word "fibreboard" add"flexible".

Replace the definition of "Body" with the following:

"Body (for all categories of IBC other than composite IBCs) meansthe receptacle proper, including openings and their closures, butdoes not include service equipment (see below)."

3611 (2) Insert after "i.e.":

"X for substances of Packing groups I, II and III (IBCs for solidsonly)".

3612 (1) (c) Amend text in brackets to read "(X, Y or Z)".

Add an example of a Packing Group I IBC:

Vol 1845. A-8940


I]C/X/0 93 For a wooden IBC.for solids withS/Aurigny 9876 an inner liner and authorized for3000/910 Packing Group I solids."

(3) Delete

3621 (9) Replace the word "reconditioned" with "repaired".

3623 (10) Add a new subparagraph (10) as follows:

"(10) The liner shall be made of a suitable material. The strengthof the material used and the construction of the liner shall beappropriate to the capacity of the IBC and the intended use. Joinsand closures shall be sift-proof and capable of withstandingpressures and impacts liable to occur under normal conditions ofhandling and carriage."


"(7) Unless otherwise approved by the competent authority, theperiod of use permitted for the transport of dangerous liquidsshall not exceed five years from the date of manufacture of thereceptacle of the IBC except where a shorter period of use isprescribed because of the nature of the liquid to be transported."

3625 (4) (i) Delete the words "body of",


"(6) Unless otherwise approved by the competent authority, theperiod of use permitted for the transport of dangerous liquidsshall not exceed five years from the date of manufacture of thereceptacle of the IBC except where a shorter period of use isprescribed because of the nature of the liquid to be transported."

3650 (4) (b) Replace the text with the following:

"(b) where the substances to be carried have a relative densityexceeding 1.2, the drop heights shall be calculated on the basis ofthe relative density (d) of the substance to be carried rounded upto the first decimal as follows:

Vol. 1945, A-8940


3650(cont'd)

3656

3657

3658

Vol. 1845, A-8940

Packing Group I Packing Group II Packing Group III

d x 1.5 m d x 1.0 m d x 0.67 m

(2) Add the following:

"For this test the IBC need not have its closures fitted. The

inner receptacle of composite IBCs may be tested without the outer

packaging provided the test results are not affected."

(4) (a) Replace the text with the following:

"1. For IBCs of types 21A, 218 and 21N, for Packing Group I

solids, a 250 kPa (2.5 bar) gauge pressure;

2. For IBCs of types 21A, 218, 21N, 31A, 31B and 31N, for Packing

Group I or III substances, a 200 kPa (2 bar) gauge pressure;

3. In addition, for IBCs of types 31A, 31B and 31N, a 65 kPa

(0.65 bar) gauge pressure. This test shall be performed before

the 2 bar test."

(5) Replace the text as follows for metal IBCs:

"For IBCs of types 21A, 218, 21N, 31A, 31B and 31N, when subjected

to the test pressure specified in 4 (a) (1) or (2): no leakage.

For IBCs of types 31A, 31B and 31N, when subjected to the test

pressure specified in 4 (a) 3: neither permanent deformation which

would render the IBC unsafe for carriage, nor leakage."

(3) Add the following new text:

"IBCs of 0.45 m3 or less capacity shall also be subject to a drop

test on the most vulnerable part other than the part of the base of

the IBC tested in the first drop (for metal IBCs); on the most

vulnerable side (for flexible IBCs); flat on a side, flat on the

top and on a corner (for all other types of IBC). The same or

different IBCs may be used for each drop."

306 United Nations - Treaty Series & Nations Unies - Recueil des Traitks 1995

3658 (4) Replace the table with the following:(cont'd)


1.8 m 1.2 m 0.8 m

3659 (4) Replace the table with the following:


1.8 m 1.2 m 0.8 m

3661 Delete existing text and replace with new text as follows:

"(1) A test report containing at least the following particularsshall be drawn up and shall be available to the users of the IBC:

1. Name and address of the test facility;

2. Name and address of the applicant (where appropriate);

3. A unique test report identification;

4. Date of the test report;

5. Manufacturer of the IBC;

6. Description of the IBC design type (e.g. dimensions,materials, closures, thickness, etc.), including method ofmanufacture (e.g. blow moulding) and which may includedrawing(s) and/or photograph(s);

7. Maximum capacity;

8. Characteristics of test contents, e.g. viscosity andrelative density for liquids and particle size for solids;

9. Test descriptions and results;

10. The test report shall be signed with the name and statusof the signatory.

Vol. 1845, A-8940


3661 (2) The test report shall contain statements that the IBC prepared(cont'd) as for carriage was tested in accordance with the appropriate

provisions of Appendix A.6 and that the use of other packagingmethods or components may render it invalid. A copy of the testreport shall be available to the competent authority."

3662 (1) After "31HZ2," amend the text as follows:

"... 31HZ2 shall successfully undergo the leakproofness test, andbe capable of meeting the appropriate levels according tomarginal 3656(3) before they are used for carriage for the first

time."

(2) Replace "after any reconditioning" with "after any repair,before it is reused for carriage",


"All metal IBC, all rigid ... (existing text) ... put into service,and thereafter at intervals not exceeding five years, with regardto ... (existing text)".

Vol. 1845, A-8940

307


APPENDIX A.7

3700

Replace:

"29 9

Au

with11,199Au

.z43cm

with,,z4cm

,,17 5ybwith"1 7 syb

,,2 .7Bk

with,,2. 7Bk

Berkelium(97)

Berkelium(97)

200 0.9

200 0.9

3 x 10-4

3 x 10-4

800 0.9

800 0.9

2 x I0"4

2 x 10 - 4

8 x 10"z

8 x10-3";

2"

20";

5 x 10 "

5 x 10-3";

"'z'Xe Xenon(54)with.22 Xe

.,2 3 5

u

with.,2 3 5

u

"U (natural)with

"U (natural)

0.2

4 IC

Unlimited j.'

Unlimited 3a/

Unlimited

Unlimited

5 0.2

00 4

5"

100";

Unlimited

Unlimited

Unlimited"

Unlimited 3.b/";

Vol. 1845, A-8940


3700(cont'd)

"U (enriched 5%or less) Unlimited 3b/ Unlimited 3a/"

with

"U (enriched 5%

or less) Unlimited 3a/ Unlimited 2A/ /";

"U (enriched mor 5%) 10 200 1 x 10- 3 2 x 10- 2"

with"U (enriched more than 5%) 10 200 1 x I0-3 J / 2 x 10-2";

"U (depleted) Unlimited Unlimited"with"U (depleted) Unlimited Unlimited b/";

Insert:

Below the line for 16OW:

"'22 Xe Z/ Xenon (54)0.2 5 0.2 5"

"2 3

Xe 0.2 5 0.2 5"

At the bottom of Table 1 replace reference 1/ as follows:

"J/ The Ci values quoted are obtained by rounding down from theTBq figure after conversion to Ci. This ensures that the magnitude

of A, or A2 in Ci is always less than that in TBq.";

At the bottom of Table 1 change "J/" to "3a/" and add reference I1t/

as follows:

"3b/ These values do not apply to reprocessed uranium".

Table I Minor changes:

Align the figures of the radionuclide 24 8Cm;

Delete the reference Z/ from the line of 175Hf;Delete the symbol "x" from the last column of the 1

3 7Np;

Delete the reference 2/ from the line of 20zPb;Delete the reference _/ from the line 10

4Re-;Delete the reference / from the line of "64 Re;

Vol. 1845, A-8940


3701 (2) In the seventh line after "half-life", insert the word"either".

3702 (1) (a) (i) In the last line change "or" to "and".

(5) In the fifth line after "3703", delete "(1)".

3710 (1) (b) In the second line, replace "its shielding, containmentsystem," with "its shielding and containment,".

(c) Replace the existing paragraph with:

"(c) For each packaging containing fissile material, where, inorder to comply with the provisions of marginal 3741, neutronpoisons are specifically included as components of the package,tests shall be performed to confirm the presence and distributionof those neutron poisons.".

3712 (6) In the second line, after "Table IV", insert "or which showsradiation level in excess of 5gSv/h (0.5 mrem/h)".

In the last line replace "5 /Sv/h" with "5pSv/h" (Only Englishtext).

(7) Replace with the following:

"(7) An overpack, container or vehicle dedicated to the transportof low specific activity material or surface contaminated objectsunder exclusive use shall be excepted from paragraphs (2) and (6)above solely with regard to its internal surface and only for aslong as it remains under that specific exclusive use."

3713 (3) In the last line replace "levels specified in table IV." with"limits specified in Table IV."

(4) In the third line replace "columns 2 and 3 respectively intable V." with "columns 2 and 3 respectively in Table V."

3714 (5) Table VI, in the title of the Table VI delete the word"integrity"

Vol. 1845, A-8940


3715

3718

3719

Vol. 1845, A-8940

(1) (a) In the seventh line change "doe" to "dose"

(3) Table IX

In the first row and third line after "Index" add "(TI)";

In the third row and third line replace "and" with "or";

In the seventh row and third column replace: "Either the sum ofTI's or the larger ofthe TI for radiationcontrol and the TIfor nuclear control"

with: "Either the sum of

the TI's or thelarger of the TI forradiation exposurecontrol or the TI fornuclear criticalitycontrol";

In the eighth row and third line after "control" change "and" to"or" ;

In the tenth row and third line after "control" change "and" to"or".

(c) In the second line, change "transpored" to "transported";

(10) Table X

In the row "More than 1 but not more than 10" change "III-YELLOWand" to "111-YELLOW".

(e) In the last line replace "palce" with "place";

SECTION IV

In the NOTE replace "and the 1988 Supplement" with "(As Amended1990)".


3751 (b) At the end of the line delete "and".

(c) At the end of the paragraph change "Appendix." to "Appendix;

and".

3753 (b) At the end of the third line change "a)" to "(a).

3755 (b) In the first line change "marginal 3705" to "marginal 2705".

3757 (3) (a) After "of time" insert ",related to the shipment,".

Vol. 1845, A-8940

1995 United Nations - Treaty Series 9 Nations Unies - RecueUl des Traitis 313

APPENDIX A.9

(1) After "1.5", add "1.6" and after "6.1, add "6.2". Delete"6. IA .

Add:

"No. 1.6 (black on orange background:division number '1.6' fillingmost of the upper half;compatibility group letter 'N'in the lower half;small figure '1' in bottomcorner);

"No. 6.2 (Symbol of three crescentssuperimposed on a circle)

liable to explosion,division 1.6,"

infectious: to be keptapart in vehicles andat loading, unloading, ortransloading points, fromfoodstuffs, other articles

of consumption and animalfeeds;"

Delete the current text which appears after "No. 6.2" and No. 6.1A.

Danger labels Delete the label No. 6.IA.

Insert:

Additional diagram "No. 1.6" in the same style as Nos. 1.4 and 1.5in the Table of diagrams (see description above):

Insert model No. 6.2 as follows:

Vol. 1845, A-8940

3900

3902


PART I

GENERAL PROVISIONS APPLICABLE TO THE CARRIAGE OF DANGEROUS SUBSTANCES

OF ALL CLASSES

10 Oil In the preamble to the table, amend the first indent, to read:

"- special requirements ... subject, however, to compliance withthe provisions of marginals 10 240 (1) (a) and 21 212" and deletethe words: "- supervision of vehicles (marginals XX 321 of Parts Iand II)".

Amend the table entries as follows:

1. Class 1, "substances" column, in the first line, "maximumtotal quantity of 50 kg", insert:

"48' (UN Nos. 0331 and 0332)".

2. Class 1, "substances" column, in the last line but two,replace "35" to 37', 39" to 41, 43"" by "35" to 43".

3. Class 1, "substances" column, in the last line but one,replace "47" by "46", 47'".

4. Class I, "substances" column, last line (maximum total

quantity of 5 kg), amend to read:

"48' (UN No. 0482)".

Vol. 1845. A-8940


10 011 Amend the table as follows:

5 kg 20 50 100 333 500 1 000 Unlimitedkg kg kg kg kg kg

6, 12', 13" andsubstances of"(a)" of I1,14" to 28" and4W to 57 x

Substances of"(b)" of 11',14" to 28* and X

3 41 to 57"

1"(a), 2"(a) and3"(b), 4"(a) and(b), 5"(a),and 7"(b) X

31"(c) and X34(c)

Other substances x

Vol. 1845, A-8940


10 011(cont'd)

Unlimited

10 (b) and X

2°(c)

6 *(c) and X110 (c)

4.1 210 to 260 X

350, 360,450 , 460 X j/

370 tO 400,470 tO 50* x

20 x

6.2 Substancesof (b) x

60, 140 andsubstancesclassifiedunder (a) X

Substances8 classified

under (b) X

Substancesclassifiedunder (c) X

Substancesor articlesclassifiedunder10 (b), X40 (c) or 50

9 Substancesor articlesclassifiedunder10 (c), 60 Xor 70

110 (c) and X120 (c)

130 (b) xI/ Excru-i-ngthe Rass orf-I 're-f-rigerating- Mance If

Vol 1845, A-8940

1995


10 012 Amend as follows:

1. Existing text becomes paragraph (]).

2. Add a new paragraph (2) as follows:

"(2) Where consignments from more than one consignor are carriedin the same transport unit, the transport documents accompanyingthese consignments need not bear the inscription mentioned inparagraph (I)."

10 013 Delete paragraph (1) and delete "(2)" before the second paragraph.

10 014 Add the following definition: "The term 'base vehicle' means anyincpmplete motor vehicle or its trailer corresponding to a typeapproved in accordance with Appendix B.2".

10 220(2) Amend to read as follows:

"(2) Vehicles carrying liquids having a flash-point of 61 *C orbelow or the flammable substances of Class 2 as defined in marginal2200(3) shall, in addition, comply with the requirements ofmarginals 220 532, 220 533 and 220 584 of Appendix B.2."

10 221(1) Amend to read as follows:

"(1) Motor vehicles (tractors and rigid vehicles) with a maximummass exceeding 16 tons and trailers (i.e. full trailers, semi-trailers, and centre-axle trailers) with a maximum mass exceeding10 tonnes L/ making up the following types of transport unit:

- tank vehicles,

- vehicles carrying demountable tanks or batteries ofreceptacles,

- vehicles carrying tank-containers with a capacity of morethan 3,000 litres, and,

type III transport units, (see marginal 11 204 (3)),

i/ For semi-trailers and centre-axle trailers, the maximum mass refersto the weight transmitted to the ground by the axle or axles of the semi-trailer or centre-axle trailer, when that trailer is coupled to the drawingvehicle and carrying its maximum load.

Vol. 1845. A-8940

317


10 221 (1) first registered after 30 June 1993, shall be fitted with an anti-(cont'd) lock-braking system, the performance of which shall meet the

provisions of marginals 220 520 and 220 521 of Appendix B.2.

10 221 (2) Amend to read as follows:

"(2) Each transport unit of a type specified in paragraph (1)above, which includes a motor vehicle and/or trailer of a typespecified in (1) above, shall be fitted with an endurance brakingsystem meeting the requirements of marginals 220 522 and 220 535 ofApppendix B.2".

10 221 (3) Amend to read as follows:

"(3) Each transport unit of a type specified in paragraph (1)above in service after 31 December 1999 shall be equipped with thedevices referred to in paragraphs (1) and (2)".

10 240 (1) (b) Add at the end of paragraph:

"Motor vehicles with a permissible maximum laden weight of lessthan 3.5 tonnes may be equipped with a portable fire extinguisherof a minimum capacity of 2 kg of powder."

(3) Amend the first sentence as follows:

"The portable fire extinguishers conforming to the provisions of

paragraph (1) above shall be fitted with a seal verifying that theyhave not been used."

10 251 Read as follows:

"The requirements concerning the electrical equipment set out inmarginal 220 511 of Appendix B2 shall apply to every transport unitcarrying dangerous substances for which an approval according tomarginals 10 282 or 10 283 is required. The requirements inmarginal 220 512 to 220 516 of Appendix B.2 shall apply only to thefollowing vehicles:

(a) Transport units carrying tanks (fixed or demountable) or

batteries of receptacles transporting either liqu:ds having aflashpoint of 61" C or below, or inflammable substances ofClass 2 as defined in marginal 22Q0 (3). Transport unitscarrying tanks (fixed or demountable) transporting diesel

Vol. 1845, A-8940


10 251 fuel, gas-oil or heating oil light, with the identification(cont'd) number 1202, registered before I July 1995 and not conforming

to this marginal, may, however, be used;

(b) Transport units intended for the carriage of explosives andhaving to comply with the requirements set out inmarginal 11 204 (3) for transport units of type III."

10 261 Add a new marginal 10 261 as follows:

"10 261 (1) Motor vehicles (tractors and rigid vehicles) witha maximum mass exceeding 12 tonnes that will beregistered for the first time after 1 July 1995, shallbe equipped with a speed limitation device in accordancewith marginal 220 540 of Appendix B.2.

(2) The requirements of paragraph (1) above are alsoapplicable to vehicles with the same characteristicsregistered between 1 January 1988 and 1 July 1995, asfrom 1 July 1996."

10 281 Add a new paragraph 10 281 under the title "Approval of vehicles"as follows:

"At the request of the manufacturer or his duly accreditedrepresentative, base vehicles of new motor vehicles and theirtrailers which are subject to approval according tomarginals 10 282 and 10 283, may be type approved by a competentauthority in accordance with Appendix B.2. This type-approvalshall be accepted as ensuring the conformity of the base vehiclewhen the approval of the complete vehicle is obtained, providedthat no modificatiorrof the base vehicle alters its validity."

10 282 (2) Delete the last sentence.

10 315 Delete the second and third sentences of paragraph (3).

Paragraph (3) would then read:

(3) By means of appropriate endorsements on his certificate madeevery five years by the competent authority or by any organizationrecognized by that authority, a vehicle driver shall be able toshow that he has, in the year before the date of expiry of hiscertificate, completed a refresher training course and has passed atest approved by that authority."

Vol. 1845, A-8940

1995


10 315 Insert the following new paragraph (6):

"(6) The certificate shall be prepared in the language or one ofthe languages of the country of the competent authority whichissued the certificate or recognized the issuing organization and,

if this language is not English, French or German, also in English,French or German, except where otherwise provided by agreements

concluded between the countries concerned with the transport

operation."

Existing paragraphs (6) and (7) to be renumbered (7) and (8).

10 321 Replace at the beginning of the text "transport units" with"vehicles".

10 353 (2) Replace "55 C" with "61 C"

10 374 Delete.

10 381 (2) Delete the new (e) (see TRANS/WP.15/126/Add.12).

10 385 Add:"(f) The measures to be taken to avoid or minimize damage in

the event of spillage of substances considered to be pollutant tothe aquatic environment in addition to the hazards indicated by thedanger labels."

10 414 (1) Read as follows:

"(1) The various components of a load comprising dangeroussubstances shall be properly stowed on the vehicle and secured byappropriate means to prevent them from being significantly

displaced in relation to each other and to the walls of thevehicle. The load may be protected, for example, by the use ofside wall fastening straps, sliding slatboards and adjustablebrackets, air bags and anti-slide locking devices. The load is

also sufficiently protected within the meaning of the firstsentence if each layer of the whole loading space is completelyfilled with packages."

(2) Delete this paragraph.

Renumber paragraphs (3) to (5) as paragraphs (2) to (4).

Vol 1845, A-8940


10 416 Insert a new marginal 10 416, as follows:

"Prohibition of smoking

10 416 Smoking shall be prohibited during handling operations

in the vicinity of vehicles and inside the vehicles."

10 417 Replace "55 C" with "61* C".

10 500 (2) Amend the beginning of the sentence to read:

"(2) Tank-vehicles or transport units having one or more tankscarrying dangerous goods covered by Appendix B5 shall ... "


(3) Insert a new paragraph (3) as follows:

"(3) Transport units and containers carrying dangerous solid

substances in bulk covered by Appendix B5 shall in addition displayon the sides of each transport unit or container, clearly visibleand parallel to the longitudinal axis of the vehicle,orange-coloured plates identical with those prescribed inparagraph (1). These orange-coloured plates shall bear theidentification numbers prescribed for each of the substancescarried in bulk in the transport unit or in the container."

Renumber existing paragraphs (3) to (12) as (4) to (13).


"(4) For containers carrying dangerous solid substances in bulk

and for tanks containers, the plates prescribed in paragraphs (2)and (3) may be replaced .... the provisions of last sentence ofparagraph (6) concerning resistance to fire shall not apply."(remainder unchanged).

(5) Read as follows:

"(5) For transport units carrying only one of the substances

listed in Appendix B5, the orange-coloured plates prescribed in

paragraphs (2) and (3) shall ..." (remainder unchanged).

Vol. 1845, A-8940

322 United Nations - Treaty Series - Nations Unies - Recueil des Traitas

10 500 (7) Add at the end of text:(cont'd)

"and empty bulk vehicles and empty bulk containers, uncleaned".

(8) Add at the end of text:

"If plates are covered, the covering shall be total and remaineffective after 15 minutes' engulfment in fire."


"(10) Bulk containers, tank-containers and batteries(remainder unchanged).


"(11) Bulk vehicles and vehicles with fixed ..." (remainderunchanged).


"(12) The requirements of marginal 10 500 (10) and (11) are alsoapplicable to empty fixed or demountable tanks, tank-containers andbatteries of receptacles, uncleaned and not degassed and empty bulkvehicles and empty bulk containers, uncleaned."

10 602 Insert the following text after the first sentence:

"The period of validity of the temporary derogation shall be notmore than five years from the date of its entry into force. Thetemporary derogation shall automatically come to an end from thedate of the entry into force of a corresponding amendment to thisannex".

Vol 1845. A-8940

1995


PART II

SPECIAL PROVISIONS APPLICABLE TO THE CARRIAGE OF DANGEROUS SUBSTANCES OF

CLASSES 1 TO g SUPPLEMENTING OR AMENDING THE REQUIREMENTS OF PART I

Class 1: Exolosive substances and articles

11 204 (2) Amend (b), (c) and (d) as follows:

"(b) Engine and exhaust system

The engine and the exhaust system shall comply with therequirements of marginals 220 533 and 220 534 of Appendix B.2.

(c) Fuel tanks

The fuel tank shall comply with the requirements of marginal 220

532 of Appendix B.2.

(d) Driver's cab

The material used in the construction of the driver's cab shallcomply with the requirements of marginal 220 531(l) of Appendix B.2Auxiliary heating appliances shall comply with the requirements ofmarginal 220 536 of Appendix B.2."

11 205 Existing paragraph to become paragraph (1).

Delete NOTE and insert:

"(2) For carriage in containers the provisions ofmarginals 10 118 (3) and 11 118 shall apply. For free-flowing

powdery substances of 2, 4', 8, 26" and 29, and for fireworks of9', 21' and 30', the floor. of a container shall have a non-metallicsurface or covering."

11 211 Insert a new marginal as follows:

"For carriage in containers the provisions of marginals 10 118 (3)and 11 118 shall apply. For free-flowing powdery substances of 2%4, 8', 26' and 29', and for fireworks of 9', 21" and 3C', thefloor of a container shall have a non-metallic surface orcovering."

Vol 1845. A-8940

1995


11 311 Add a new paragraph (3) as follows:

"(3) The presence of a driver's assistant on board shall not be

required in the case of articles of 43" identification No. 0336,

carried in a type I transport unit."

11 401 Read:

"11 401 The total net mass in kg of explosive substance (or in

the case of explosive articles, the total net mass of

explosive substance contained in all the articles

combined) which may be carried on one transport unit

shall be limited as indicated in the table below (see

also marginal 11 403 as regards the prohibition of mixed

loading):

auIa. or.l¢Inpbl. Sit h,. Int aof u*.OhmnIl Ifl 21i. I teed

!*-22" 2S-22" 24.3- 3'-4S 06, 21" 1.* 4." * 52"

Tr...wt Wnt

Ty. 10 oc se o* .. I . 1 M0 .11IWI2WI

Ti.e 22 200 3 soc S CCC 2200 U lltted SCS 0 1.1100t0

1,P. I22 2 00i am 00i 2o is WCC li2 t2 15 MO 1111m.t

X M.. 0IM 3.0o0 kg (4.000 kg In . 2rI1,)"

11 402 Amend end of first sentence to read: "(in the order 1.1, 1.5, 1.2,

1.3, 1.6, 1.4)".

11 403 (1) Amend to read: "... Nos. 1, 1.4, 1.5 or 1.6 ... ".

Add vertical and horizontal columns "N" and at point of

intersections with "C" add "L/, 2/", with "D" add *Z/, j/", with

"E" add "2/, 1/", with !N" add "?/" and with "S" add "x".

Add two new footnotes as follows:

"2/ Different types of 1.6N articles may be transported together

as 1.6N articles only when it is proven by testing or analogy

that there is no additional risk of sympathetic detonation between

the articles. Otherwise they should be treated as hazard

division 1.1."

Vol. 1845, A-8940


11 403 "2/ When articles of compatibility group N are carried with

(cont'd) substances or articles of compatibility groups C, D or E, the

articles of compatibility group N should be considered as having

the characteristics of compatibility group 0."

11 414 Delete.

Marking and labelling

11 500 (1) Add at the beginning: "In addition of the provisions of

marginal 10 500",

Amend to read: "... Nos. 1, 1.4, 1.5 or 1.6 ... "

(2) Amend to read: "... in the order 1.1 (most dangerous), 1.5,1.2, 1.3, 1.6, 1.4 (least dangerous)."

(4) Amend to read: "... 43' No. 0301 and 0303".

Class 2: Gases: comoressed, liguefied or dissolved under oressure

21 240 Delete.

21 403 Amend to read: "... conforming to models Nos. 1, 1.4, 1.5, 1.6 or

01".

21 407 (1), insert a second sentence to read:

"The permission and the notice provided for in (a) and (b)

above respectively shall not be required if the substances are

contained in cylinders, receptacles, 'assemblies of cylinders' orreceptacles conformfing to marginal 2207 having a capacity not

exceeding 1,000 litres as described in marginal 2212 (1) (a), (b),

(d) or (e)."

Class 3: Flammable liouids


"The provisions of marginal 10 321 shall apply to the dangerous

goods listed below in quantities exceeding those specified:

Substances of I' to 5" (a) and (b), 7' (b),

21" to 26" and slightly toxic substancesof 41" to 57": 10 000 kg

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326 United Nations - Treaty Series e Nations Unies - Recueil des Traits 1995

31 321 Substances of 6" and 11" to 19', 27, 28,(cont'd) and toxic or very toxic substances of

4W to 57": 5 000 kg".

31 403 Amend to read: "... conforming to models Nos. 1, 1.4, 1.5, 1.6 or01".

31 410 Delete "or 6.IA"

31 414 Delete.

31 415 Replace "6" and 11' to 20"' by "6', 11" to 19, 27", 28, 32" andthe toxic or very toxic substances of 41" to 57"".


"Vehicles with fixed or demountable tanks and tank-containers

containing or having contained (empty, uncleaned) substances ofthis Class shall bear labels conforming to model No. 3.

Those containing or having contained the substances of this Classlisted in marginal 2312 (3) to (5) shall also bear labels in

accordance with that marginal."

Class 4.1: Flammable solids

41 105 Delete paragraphs (2) and (3), add new paragraphs (2) to (9) to

read as follows:

"(2) Substances of 26" shall be shielded from direct sunlight and

heat during carriage.

(3) Substances of 41" to 50" shall be forwarded so that thecontrol temperatures 'indicated in marginal 2400 (20), given forlisted substances in marginal 2401 and for non-listed substances* inthe approved conditions of carriage [see marginal 2400 (16)], are

not exceeded.

(4) Maintenance of the prescribed temperature is essential for thesafe carriage of many self-reactive substances. In general, there

shall be:

- thorough inspection of the transport unit prior to loading;

Vol. 1845, A-8940


41 105 instructions to the carrier about the operation of the(cont'd) refrigeration system, including a list of the suppliers of

coolant available en route;

- procedures to be followed in the event of loss of control;

- regular monitoring of operating temperatures; and

- provision of a back-up refrigeration system or spare parts.

(5) Any control and temperature sensing devices in therefrigeration system shall be readily accessible and all electricalconnections weather-proof. The temperature of the air space withinthe transport unit shall be measured by two independent sensors andthe output shall be so recorded that temperature changes arereadily detectable. The temperature shall be checked every four tosix hours and logged. When substances having a control temperatureof less than +25' C are carried, the transport unit shall beequipped with visible and audible alarms, powered independently ofthe refrigeration system, set to operate at or below the controltemperature.

(6) If the control temperature is exceeded during carriage, analert procedure shall be initiated involving any necessary repairsto the refrigeration equipment or an increase in the coolingcapacity (e.g. by adding liquid or solid coolant). There shallalso be frequent checking of the temperature and preparations forimplementation of the emergency procedures. If the emergencytemperature (see also marginals 2400 (20) and 2401) is reached, theemergency procedures shall be set in operation.

(7) The suitability of a particular means of temperature controlfor carriage depends on a number of factors. Amongst those to beconsidered are:

- the control temperature(s) of the substance(s) to be carried;

- the difference between the control temperature and theanticipated ambient temperature conditions;

- the effectiveness of the thermal insulation;

- the duration of carriage; and

Vol. 1845, A-8940

327


41 105 - allowance of a safety margin for delays.

(cont'd)

(8) Suitable methods for preventing the control temperature being

exceeded are, in order of increasing capability:

(a) thermal insulation; provided that the initial temperature ofthe self-reactive substance(s) is sufficiently below the

control temperature;

(b) thermal insulation and coolant system; provided that:

- an adequate quantity of non-flammable coolant (e.g.liquid nitrogen or solid carbon dioxide), allowing areasonable margin for delay, is carried or thepossibility of replenishment is assured;

- liquid oxygen or air is not used as coolant;

- there is a uniform cooling effect even when most of the

coolant has been consumed; and

- the need to ventilate the transport unit before entering

is clearly indicated by a warning on the door(s);

(c) thermal insulation and single mechanical refrigeration;

provided that flameproof electrical fittings are used withinthe coolant compartment to prevent ignition of flamnablevapours from the self-reactive substances.

(d) thermal insulation and combined mechanical refrigeration

system and coolant system; provided that:

- the two systems are independent of one another; and

- the requirements (b) and (c) are met;

(e) thermal insulation and dual mechanical refrigeration

system provided that:

- apart from the integral power supply unit, the twosystems are independent of one another;

- each system alone is capable of maintaining adequatetemperature control; and

Vol. 1845, A-8940


41 105 - flameproof electrical fittings are used within the(cont'd) coolant compartment to prevent ignition of inflammable

vapours from the self-reactive substances.

(9) For substances of 41" and 42', one of the following methods oftemperature control described in paragraph (8) shall be used:

- method (c) when the maximum ambient temperature to beexpected during carriage does not exceed the control

temperature by more than 10" C; or

- method (d) or (e).

For substances of 43" to 50, one of the following methods shall be

used:

method (a) when the maximum ambient temperature to bAD

expected during carriage is at least 10" C below thecontrol temperature;

- method (b) when the maximum ambient temperature to be

expected during carriage does not exceed the controltemperature by more than 30" C; or

- method (c), (d) or (e)."

41 204 Amend to read as follows:

"Substances of 31* to 40' shall be loaded in closed or sheetedvehicles. Where, under the provisions of 41 105, substances

are required to be carried in insulated, refrigerated ormechanically-refrigerated vehicles, those vehicles shall satisfy

the provisions of 41 248. -Substances of 41° to 50" contained inprotective packagings filled with a coolant shall be loaded in

closed or sheeted vehicles. If the vehicles used are closed theyshall be adequately ventilated. Sheeted vehicles shall be fittedwith side boards and a tail-board. The sheets of these vehicles

shall be of an impermeable and non-combustible material."

Vol. 1845, A-8940


41 248 Add a new marginal as follows:

*Insulated, refrigerated and mechanically-refrigerated vehicles

41 248 Insulated, refrigerated and mechanically-refrigerated

vehicles used in accordance with the provisions of 41 105 shall

conform to the following conditions:

(a) the vehicle shall be such and so equipped as regards its

insulation and means of refrigeration (see marginal

41 105) that the maximum temperature prescribed in

41 105 is not exceeded. The overall heat transfer

coefficient shall be not more than 0.4 W/m2 K;

(b) the vehicle shall be so equipped that vapours from the

substances or the coolant carried cannot penetrate into

the driver's cab;

(c) a suitable device shall be provided enabling the

temperature prevailing in the loading space to be

determined at any time from the cab;

(d) the loading space shall be provided with vents or

ventilating valves if there is any risk of a dangerous

excess pressure arising therein. Care shall be taken

where necessary to ensure that refrigeration is not

impaired by the vents or ventilating valves;

(e) the refrigerant shall not be flammable; and

(f) the refrigerating appliance of a mechanically-

refrigerated vehicle shall be capable of operating

independently of the engine used to propel the vehicle."


"The provisions of 10 321 shall apply to the dangerous goods listed

below in quantities exceeding those specified:

- substances of 21" to 25': 1,000 kg

- substances of 26": 100 kg

- substances of 31, 32, 43" and 44': 1,000 kg

Vol. 1845, A-8940

1995 United Nations - Treaty Series 9 Nations Unies - Recueil des Traits 331

41 321 substances of 33, 34', 45" and 46': 2,000 kg(cont'd)

substances of 35', 36', 47" and 48': 5,000 kg

substances of 41' and 42': 500 kg.

In addition, vehicles carrying more than 500 kg of substances of41" and 42' shall be subject at all times to supervision to preventany malicious act and to alert the driver and competent authoritiesin the event of loss or fire."


"(I) A transport unit shall carry not more than:

- 5,000 kg of substances of 31" and 32" if its loading space isventilated at the top and the transport unit is insulatedwith heat-resistant material (see marginal 11 204 (3) (a)) or1,000 kg of substances of 31" and 32' if the transport unitdoes not meet these requirements;

- 10,000 kg of substances of 33" and 34";

- 20,000 kg of substances of 35', 36, 37, 38', 39' and 40';

- 1,000 kg of substances of 41' and 42" or 5,000 kg ifinsulated with heat-resistant material;

- 5,000 kg of substances of 43" and 44' or 10,000 kg ifinsulated with heat-resistant material; and

- 20,000 kg of substances of 45', 46', 47', 48', 49' and 50'.

(2) When substances of this Class are carried together in onetransport unit, the limits given in paragraph (1) shall not beexceeded and the total contents shall not exceed 20,000 kg."

41 402 Insert a new marginal 41 402 to read as follows:

"The provisions of marglnals 10 500 and 41 204 shall not apply tothe carriage of substances listed in or covered by 31' to 34" and41" to 44' provided that the substance is packaged in accordancewith packing method PIA, OPIB, OP2A or OP2B, as required, and thequantity per transport unit is limited to 10 kg."

Vol. 1845, A-8940


41 403 Read:

"(1) Packages bearing a label conforming to model No. 4.1 shall

not be loaded together on one vehicle with packages bearing a label

conforming to models Nos. 1, 1.4, 1.5, 1.6 or 01.

(2) Packages bearing labels conforming to models Nos. 4.1 and 01

shall not be loaded together in the same vehicle with packages

bearing a label conforming to models Nos. 1, 1.4, 1.5, 1.6, 2, 3,

4.2, 4.3, 5.1, 5.2, 6.1, 7A, 7B, 7C, 8 or 9."


(1) Packages containing substances of 26' shall be stored only in

cool, well-ventilated places away from heat sources.

(2) Packages containing substances of 4W to 50" shall not be

placed on top of other goods; in addition, they shall be so stowed

as to be readily accessible.

(3) For packages containing substances of 41' to 50, the

specified control temperature shall be maintained during the whole

transport operation, including loading and unloading, as well as

any intermediate stops [see marginal 41 105(2)].

(4) Packages shall be loaded so that a free circulation of air

within the loading space provides a uniform temperature of the

load. If the contents of one vehicle or large container exceed

5,000 kg of flammable solids, the load shall be divided into stacks

of not more than 5,000 kg separated by air spaces of at least

0.05 m."


"Vehicles with fixed- or demountable tanks and tank-containers, as

well as vehicles and containers for the carriage of dangerous solid

substances in bulk, containing or having contained (empty,

uncleaned) substances of this Class shall bear labels conforming to

model No. 4.1.

Those containing or having contained the substances of this Class

listed in marginal 2412 (3) shall also bear labels in accordancewith that marginal."

Vol. 1845, A-8940


Class 4.2: Substances liable to soontaneous combustion

42 105 Insert a new marginal 42 105 as follows:

'Method of dispatch and restrictions on forwarding

42 105 Phosphorus of 22* may be carried only in tank-vehicles,demountable tanks and tank-containers."

42 403 Amend to read: "... conforming to models Nos. 1, 1.4, 1.5, 1.6or 01".

42 414 Delete.


"Vehicles with fixed or demountable tanks and tank-containers, aswell as vehicles and containers for the carriage of dangerous solidsubstances in bulk, containing or having contained (empty,uncleaned) substances of this Class shall bear labels conforming tomodel No. 4.2.

Those containing or having contained the substances of this Classlisted in marginal 2442 (3) to (5) shall also bear labels inaccordance with that marginal."

Class 4.3: Substances which. in contact with water. emit flammable gases

43 111 (1) Delete "15 (c)"

(3) Insert "ferrosilicon of 15" (c)", after "Aluminium dross of13" (c)."

43 403 Amend to read: "... conforming to models Nos. 1, 1.4, 1.5. 1.6 or01.

43 414 Delete the first and second sentences of the paragraph. The thirdsentence becomes the first sentence.


"Vehicles with fixed or demountable tanks and tank-containers, aswell as vehicles and containers for the carriage of dangerous solidsubstances in bulk, containing or having contained (empty,

Vol. 1845, A-8940


43 500 uncleaned) substances of this Class shall bear labels conforming to(cont'd) model No. 4.3.

Those containing or having contained the substances of this

Classlisted in marginal 2482 (3) to (7) shall also bear labels in


Class 5.1: Oxidizing substances

51 105 Insert a new marginal 51 105 as follows:

*Method of dispatch and restrictions on forwarding

51 105 Ammonium nitrate of 20" may be carried only in tank-

vehicles, demountable tanks and tank-containers."


"For carriage of liquids of I' (a):

(1) The provisions of marginals 220 531(2), 220 532 and 220 533 of

Appendix B.2 shall apply;

(2) Unchanged.

(3) Text of existing (4). Existing (3) is deleted.


01".

51 414 Amend to read: "The use of readily flamable materials for stowing

packages in vehicles is prohibited".


"Vehicles with fixed or demountable tanks and tank-containers, aswell as vehicles and containers for'the carriage of dangerous solid



model No. 5.1.

Those containing or having contained the substances of this Class

listed in marginal 2512 (3) shall also bear labels in accordance

with that marginal."

Vol. 1845, A-8940

United Nations - Treaty Series e Nations Unies - Recuel des Traitis

Class 5.2: Organic oeroxides

52 403 (1) Read: "... conforming to models Nos. 1, 1.4, 1.5, 1.6 or 01".

52 403 (2) Read: "... 1, 1.4, 1.5, 1.6, 2, 3, 4.1, 4.2, 4.3, 5.1, 6.1,

7A, 78, 7C, 8 or 9".(cont'd)

52 414 Delete (1) and (2).

Renumber (3) to (6) as (1) to (4), and amend the former (5), as thenew (3) to read:

"(3) For packages containing substances of 11' to 20, the control

temperature shall be maintained during the whole transport

operation, including loading and unloading, as well as anyintermediate stops [see marginal 52 105(1)]."


"Vehicles with fixed or demountable tanks and tank-containers, as

well as vehicles and containers for the carriage of solid dangerous



model No. 5.2.

Those containing or having contained the substances of this Classlisted in marginal 2559 (3) to (4) shall also bear labels inaccordance with that marginal.*

Marginals 61 000 to 70 999: Replace by the following revised

sections:

"Class 6.1: Toxic substances

General

(Only the general provisions of Part I apply)

61 000-61 099

Vol. 1845, A-8940


Section 1: Mode of carriage

61 100-61 110

Carriage in bulk

61 111 (1) Substances of 60° (c) and 3243 solids containing toxic liquidof 65" (b) may be carried in bulk as a full load.

(2) Substances of 60" (c) and 3243 solids containing toxic liquidof 65" (b) shall in such case be carried in sheeted, open vehicles.Vehicles containing 3243 solids containing toxic liquid of 65"(b) in bulk shall be leakproof or rendered leakproof, for exampleby means of a suitable and sufficiently stout inner lining.

(3) Solid wastes containing substances of 60" (c) may be carriedunder the same conditions as the substances themselves. Othersolid wastes classified under the letter (c) of the various itemsmay be carried in bulk only under the conditions ofmarginal 61 118.

61 112-61 117

Carriage in containers

61 118 Containersclassifiedcontainingsheeted orContainers65" (b) in

example by

intended for the carriage in bulk of solid wastesunder (c) of the various items and 3243 solidstoxic liquid of 65' (b) shall have complete walls and behave a cover.containing 3243 solids containing toxic liquid ofbulk shall be leakproof or rendered leakproof, formeans of a suitable and sufficiently stout inner lining.

61 119-61 199

Section 2: Special reouirements to be fulfilled by the means oftransoort and its eouioment

62 200-61 259

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United Nations - Treaty Series & Nations Unies - Recueil des Traitks

Special equipment

61 260 Whenever motor fuel anti-knock mixtures of 31° (a) or receptacleshaving contained them are carried, the driver shall, when he isgiven the transport document, at the same time be given a portableequipment box fitted with a handle and containing:

Three copies of the written instructions specifying theaction to be taken in the event of an accident or incidentoccurring during carriage (see marginal 61 385);

Two pairs of gloves and two pairs of boots made of rubber orsome suitable plastics material;

Two respirators with an activated-charcoal cartridge of 500 cm3

capacity;

A bottle (made of bakelite, for example) containing 2 kg ofpotassium permanganate and bearing the inscription "dissolve inwater before use";

Six fibreboard notices bearing the inscription "DANGER - volatilepoison spilled. Do not approach without respirator" in thelanguage or languages of each of the countries in whose territorycarriage takes place.

This equipment box shall be kept in the driver's cab in a placewhere it can easily be found by the decontamination team.

61 261-

61 299

Section 3: General service grovisions

61 300-

61 301

Action to be taken in the event of accident

61 302 (See marginal 61 385)

Precautions with respect to articles of consumption

61 303 (See marginal 61 410)

Vol. 1845, A-8940

337


61 304-

61 320

Supervision of vehicles

61 321 The provisions of marginal 10 321 shall apply to the dangerous

goods listed below in quantities exceeding those specified:

Substances of 1 to 5" and substances

classified under (a) of all items: 1,000 kg

Substances classified under (b)

of all items: 5,000 kg.

61 322-

61 384

Instructions in writing

61 385 Where motor fuel anti-knock mixtures of 31" (a), or receptacleswhich have contained them, are carried, the text of the written

instructions shall specify, inter alia, the following:

(A) Precautions to be observed

The substance being carried is highly toxic. In the event of

leakage from one of the receptacles the following precautionsshould be taken:

1. Avoid:

(a) Contact with the skin;

(b) Inhalation of vapours;

(c) Introduction of the liquid into the mouth.

2. When drums which are torn open or damaged or wetted withliquid are being handled, the use of the following is

compulsory:

(a) Respirators;

(b) Gloves made of rubber or some suitable plastics

material;

Vol. 1845, A-8940


61 385 (c) Boots made of rubber or some suitable plastics material.(cont'd)

In the event of a serious accident involving obstruction of thepublic highway, it is essential that persons arriving to clear thesite should be warned of the danger incurred.

(B) Action to be taken

All practicable steps, including the use of the notices referred toin marginal 61 260, shall be taken to keep persons at a-distance ofnot less than 15 metres from the site of the accident; the noticescontained in the equipment box shall be set up round the enclosureand onlookers shall be kept away.

The respirators, gloves-and boots will enable one person toapproach the load and verify its condition.

Should any of the drums be torn open, the following should be done:

(a) Additional respirators, gloves and boots with which toequip the workmen should be procured urgently;

(b) Drums still intact should be set aside;

(c) The liquid spilled on the vehicle or on the groundshould be neutralized by copious swilling with an aqueous solutionof potassium permanganate (a neutralizing agent a bottle of whichis kept in the equipment box); the solution is easily prepared bystirring 0.5 kg of permanganate with 15 litres of water in abucket; swilling should be carried out several times, because ittakes 2 kg of potassium permanganate to neutralize completely I kgof the substance being carried.

Where practicable, the best way to decontaminate the area is topour petrol over the spilled fluid and ignite It.

(C) Important notice

In case of accident, one of the first steps which must be taken isto notify by telegram or telephone ... (insert here the address andtelephone numbers of the establishments to be notified in each ofthe countries in whose territory carriage is to take place).

Vol. 1845, A-8940

1995


61 385 A vehicle which has been contaminated with the substance carried(cont'd) shall not be put back into service until it has been decontaminated

under the supervision of a competent person. Any wooden parts ofthe vehicle which have been attacked by the substance carried shallbe removed and burnt.

61 386-61 399

Section 4: Special provisions concernino loadino. unloading and

handling

61 400-61 402

Prohibition of mixed loading on one vehicle

61 403 Packages bearing a label conforming to model No. 6.1 shall not beloaded together on one vehicle with packages bearing a label

conforming to models Nos. 1, 1.4, 1.5, 1.6 or 01.

61 404-

61 406

Places of loading and unloading

61 407 (1) The following operations are prohibited:

(a) Loading or unloading substances of 1' to 5" and anysubstance classified under (a) of other items in a public place in

a built-up area without special permission from the competentauthorities;

(b) Loading or unloading the said substances in a publicplace elsewhere than in a built-up area without prior notice having

been given to the competent authorities, unless the said operations

are justified for serious reasons of safety.

(2) If, for any reason, handling operations have to be carried

out in a public place, then substances and articles of differentkinds shall be separated according to the labels.

61 408-61 409

Vol. 1845, A-8940



61 410 Substances of Class 6.1 shall be kept apart from foodstuffs, other

articles of consumption and animal feeds in vehicles and at places

of loading, unloading or transloading.

61 411-

61 414

Cleaning after unloading

61 415 (1) A vehicle which has been contaminated with substances

of 31" (a) or with a mixture thereof shall not be put back intoservice until it has been decontaminated under the supervision of a

competent person. Any wooden parts of the vehicle which have beenattacked by substancesof 31" (a) shall be removed and burnt.

(2) If substances in this Class have leaked and been spilled in avehicle, it may not be reused until after it has been thoroughly

cleaned and, if necessary, decontaminated. All other goods andarticles carried in the same vehicle shall be examined for possible

contamination.

61 416-61 499

Section 5: Special provisions concerning the operation of

vehicles (tank-vehicles) and containers (tank-containers)


Marking

61 500 (1) Whenever substances of 31' (a) are carried, the vehicle shall

display on each side a warning notice to the effect that, if any

liquid escapes, the greatest caution must be exercised and that the

vehicle must not be approached without respirator, gloves and boots

of rubber or some suitable plastics material.

Labelling

(2) Vehicles with fixed or demountable tanks and tank-containers,

as well as vehicles and containers for the carriage of dangerous

solid substances in bulk, containing or having contained (empty,

Vol. 1845, A-8940


61 500 uncleaned) substances of this Class shall bear labels conforming to(cont'd) model No. 6.1.

Those containing or having contained (empty, uncleaned) thesubstances of this Class listed in marginal 2612 (3) to (10) shall

also bear labels in accordance with that marginal.

61 501-61 508

Halts of limited duration for service requirements

61 509 Halts for service requirements shall so far as possible not be madein residential or urban areas. A halt near such a place may not beprolonged except with the agreement of the competent authorities.

61 510-61 514

Protection against the action of the sun

61 515 During the period April to October inclusive, when a vehiclecarrying hydrogen cyanide of I' is stationary, the packages shall,if the legislation of the country in which the vehicle is halted sorequires, be effectively protected against the action of the sun,e.g. by means of sheets placed not less than 20 cm above the load.

61 516-61 599

Section 6: Transitional orovisions, derooations, and provisionspeculiar to certain countries


61 600-61 999

Class 6.2: Infectious substances

General

(Only the general provisions of Part I apply)62 000-62 099

Vol. 1945, A-8940



62 100-62 104

62 105 Packages containing substances of this Class shall be carried inclosed or covered vehicles

62 106-62 117


62 118 (1) Packages containing substances of this Class may be carriedin small containers.

(2) The mixed loading prohibitions of marginal 62 403 shall alsoapply to the contents of small containers.

62 119-

62 199

Section 2: Special reouirements to be fulfilled by the means oftransport and its eouipment

62 200-62 239

Fire-fighting appliances

62 240 The provisions of marginal 10 240 (1) (b), (3) and (4), shall notapply.

62 241-62 299

Section 3: General service provisions

62 300-62 301

Action to be taken in the event of accident

62 302 (See marginal 62 385)

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344 United Nations - Treaty Series - Nations Unies - Recueil des Traitis 1995


62 303 (See marginal 62 410)

62 304-62 320


62 321 The provisions of marginal 10 321 shall apply to all substances of1', whatever their mass. They shall also apply to substances of 2'whose quantity exceeds a mass of 100 kg. However, the provisionsof marginal 10 321 need not be applied where the loaded compartmentis locked and the packages carried are otherwise protected againstany illicit unloading.

62 322-

62 352

62 353 The provisions of marginal 10 353 shall not apply.

62 354-62 384

Instructions in writing

62 385 The instructions in writing shall also include:

(a) the provision that, in the cases provided formarginal 10 385 (1) (d) the local health or veterinary authorities

shall be informed;

(b) information as to how the substance(s) are to beabsorbed and contained, and how the dangers of the substance(s) of

Class 6.2 are to be eliminated on the spot, e.g. suitabledisinfectants;

(c) information on suitable protective equipment for the

driver.

62 386-62 399

Section 4: Special orovisions concernino loading. unloadingand handling

Vol. 1845, A-8940


62 400-62 402


62 403 (1) Packages bearing a label conforming to model No. 6.2 shallnot be loaded together in the same vehicle with foodstuffs, otherarticles of consumption and animal feeds.

(2) Packages bearing a label conforming to model No. 6.2 shallnot be loaded together in the same vehicle with packages bearing alabel conforming to models Nos. 1, 1.4, 1.5, 1.6 or 01.

62 404-

62 409

Precaution with respect to articles of consumption

62 410 Substances of class 6.2 shall not be loaded together in the samevehicle with foodstuffs, other articles of consumption and animalfeeds (see 62 403(1)). They shall be kept apart from foodstuffs,other articles of consumption and animal feeds at places ofloading, unloading or transloading.

62 411-

62 412 Substances of item 4 shall be filled in tanks or in speciallyequipped vehicles in a manner which avoids risks to humans, animalsand the environment, e.g. by loading in bags or by airtightconnections.

62 413-

Handling and storage

62 414 (1) Packages containing substances of this Class shall be sostowed that they are readily accessible.

(2) When packages of this Class are to be carried at ambienttemperature of not more than 15" C or refrigerated, the temperatureshall be maintained when unloading or during storage.

(3) Packages of this Class shall be stored only in cool placesaway from sources of heat.

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62 415 If substances of this Class have leaked and been spilled in avehicle, it may not be reused until after it has been thoroughlycleaned and, if necessary, disinfected. All goods and articlescarried in such a vehicle shall be checked for possiblecontamination. The wooden parts of the vehicle which have comeinto contact with the substances of items I* and 2" shall beremoved and burnt.

62 416-62 499

Section 5: Soecial orovisions concernina the operation of vehicles

(tank-vehicles) and containers (tank-containers)


Labelling

62 500 Vehicles with fixed tanks or demountable tanks; specially equippedvehicles and tank-containers containing or having contained (empty,

uncleaned) substances of 4', shall bear labels conforming to model

No. 6.2.

62 501-62 508

Halts of limited duration for service requirements

62 509 Halts of vehicles carrying substances of I" and 2" for service,requirements shall so far as possible not be made in residential orurban areas. A halt near such a place may not be prolonged except

with the agreement of the competent authorities.

62 510-62 599

Section 6: Transitional orovisions. derogations and Provisions

peculiar to certain countries


62 600-

70 999"

Vol. 1845, A-8940


Ciass.Z: Radioactive material

71 315 Delete.


"The provisions of marginal 10 321 shall apply to all material, in

whatever mass. In addition, these goods shall be subject at all

times to supervision to prevent any malicious act and to alert the

driver and the competent authorities in the event of loss or fire.

However, the provisions of marginal 10 321 need not be applied

where:

(a) The loaded compartment is locked and the packages

carried are otherwise protected against illicit unloading; and

(b) The dose rate does not exceed 5 pSv/h (0.5 mrem/h) at

any accessible point on the outer surface of the vehicle."

71 374 Delete.


01".

Vol 1845, A-8940


Karginals 81 000 to 90 999: Replace by the following revised sections:

"Class 8: Corrosive substances

General


81 000-81 099


81 100-

81 110

Carriage in bulk

81 111 (1) Lead sulphate of 1 (b), substances of 13" (b) and 3244solids with corrosive liquid of 65" (b) and solid wastes classifiedunder the letter (c) of the various items may be carried in bulk asa full load. The body of the vehicle shall be equipped with asuitable and sufficiently stout inner lining. If the vehicle issheeted the sheet shall be so placed that it cannot touch theload. Vehicles containing substances of 65' (b) (3244) shall beleakproof or rendered leakproof, for example by the means of asuitable and sufficiently stout inner lining.

(2) Solid wastes containing substances of 13" may be carriedunder the same conditions as the substances themselves. Othersolid wastes classified under the letter (c) of the variousitems may only be carried in bulk under the conditions ofmarginal 81 118.

81 112-

81 117


81 118 Containers intended for the carriage in bulk of lead sulphate of1" (b), substances of 13" (b), 3244 solids containing corrosiveliquid of 65' (b) or solid wastes classified under (c) of the

Vol. 1845, A-8940


81 118 various items shall have complete walls and a suitable lining and

(cont'd) be sheeted or have a cover.

Containers containing 3244 solids containing corrosive liquid of65' (b) in bulk shall be leakproof or rendered leakproof, forexample by the means of a suitable and sufficiently stout innerlining.

81 119-81 199

Section 2: Special reouirements to betransnnrt and its enuinmpnt

fulfilled bv the means of

81 200-81 299

81 300-81 320

Sction 3: General service provisions


81 321 The provisions of marginal 10 321 shall apply to the substanceslisted below in quantities exceeding those specified:

81 322-81 399

Substances classified under (a)of all items:

Bromine of 14':

10,000 kg

1,000 kg.

Section 4: Soecial-provisions concerning loading, unloadingand handlin

81 400-81 402


81 403 Packages bearing a label conforming to model No. 8 shall not beloaded together on the same vehicle with packages bearing a labelconforming to models Nos. 1, 1.4, 1.5, 1.6 or 01.

81 404-81 409

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350 United Nations - Treaty Series & Nations Unies - Recueil des Traitis 1995


81 410 Packages bearing labels conforming to model No. 6.1 shall be kept

apart from foodstuffs, other articles of consumption and animal

feeds in vehicles and at places of loading, unloading or

transloading.

81 411-81 412

Cleaning before loading

81 413 Vehicles intended to carry packages containing substances of

2" (a)'2., 3" (a), 4, 73' or 74" shall be carefully cleaned and in

particular be free of all combustible waste (straw, hay, paper,

etc.).


81 415 If substances from packages bearing labels conforming to model

No. 6.1 have leaked and been spilled in a vehicle, it may not be

reused until after it has been thoroughly cleaned and, if

necessary, decontaminated. All other goods and articles carried in

the same vehicle shall be examined for possible contamination.

81 416-81 499

Section 5: Special orovisions concerning the operation of

vehicles (tank-vehicles) and containers (tank-

containers)


Labelling

81 500 Vehicles with fixed or demountable tanks or tank-containers, as.well as vehicles and containers for the carriage of dangerous solid



model No. 8.

Those containing or having contained (empty, uncleaned) the

substances of this Class listed in marginal 2812 (3) to (10) shall

also bear labels in accordance with that marginal.

Vol. 1845, A-8940


81 501-81 599

Section 6: Transitional orovisions. derogations and provisionspeculiar to certain countries


81 600-

90 999"

Class 9: Miscellaneous dangerous substances and articles

91 105 Read:

"Packages containing substances of this Class shall be carried in

closed or covered vehicles."

91 ill Add: "and 12" (c)".

91 118 Add: "and 12' (c)".

91 240 Delete.

91 321 Add:

"Substances classified under (b) of 13': 1,000 kg".

91 385 The current text becomes paragraphe (1).

Add the following paragraph (2):

(2) For substances of 11" and 12", the instructions in writing

shall also include, the measures to be taken to avoid or minimizedamage in the event of spillage of these substances which areconsidered to be pollutant to the aquatic environment."

Add a new paragraph (3) as follows:

(3) For substances of 13", the instructions in writing shall also

include:

Vol. 1845, A-8940


91 385 (a) the provision that, in the case of damage to or leakagefrom a package containing substances of 13, the local health orveterinary authorities shall be informed;

(b) information as to how the substance(s) is/are to be

absorbed and contained, and how the dangers of the substance(s) of13" are to be eliminated on the spot, e.g. suitable disinfectants;

(c) information on suitable protective equipment for thedriver."

91 403 Amend to read: "... conforming to models Nos. 1, 1.4, 1.5. 1.6 or01".

Handling and storage

91 414 (1) Packages containing substances of 13" shall be so stowed that(new) they are readily accessible.

(2) When packages containing substances of 13" are to be carriedrefrigerated, the functioning of the cooling chain shall be ensuredwhen unloading or during storage.

(3) Packages containing substances of 13" shall only be stored incool places away from sources of heat.

91 415 The current text becomes paragraph (1), with the inclusion of ", 1'to 12*", after "Class 9".

Add the following new paragraph (2).

"(2) If a substance of 13" has escaped and has contaminated avehicle, this vehicle may be reused only after it has beenthoroughly cleaned and, if necessary, disinfected. All goods andarticles carried in such a vehicle shall be checked for possiblecontamination. The wooden parts of the vehicle which have comeinto contact with the substances of 13" shall be removed andburnt."

91 500 (2) Amend as follows:

"(2) Vehicles with fixed or demountable tanks and tank-containers,as well as vehicles and containers for the carriage of dangeroussolid substances in bulk, containing or having contained substancesof this Class, with the exception of substances of 4" (c), shallbear labels conforming to model No. 9.

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United Nations - Treaty Series 9 Nations Unies - Recueil des Trait~s

91 500 Those containing or having contained the substances of this Class(cont'd) listed in marginal 2912 (4) to (6) shall also bear labels in


Apoendices B.Ia/B.lb

Note: In the following amendments, the letter X in a marginalnumber indicates that the amendment applies to both appendices(e.g. 21X 310 means "211 310 and 212 310").

211 126 Amend this marginal to read:

"211 126 Shells intended for the carriage of liquids having aflash-point of 61 °C or below or for the carriage of flammablegases, shall be linked to the chassis by means of at least one goodelectrical connection. Any metal contact capable of causingelectrochemical corrosion shall be avoided. Shells shall beprovided with at least one earth fitting clearly marked with thesymbol "..", capable of being electrically connected."

212 126 Replace "55 "C" by "61 *C".

211 174 Insert before the present text the following sentence:

"During loading and unloading of tanks, appropriate measures shallbe taken to prevent the release of dangerous quantities of gasesand vapours."

211 187 Insert the following new marginal 211 187:

"Fixed tanks (tank-vehicles), demountable tanks and batteries ofreceptacles constructed before 1 January 1990 shall, if used after31 December 2004, conform to the provisions of marginal 211 127(5), applicable as from I January 1990, concerning wall thicknessand protection against daMage."

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353

354 United Nations - Treaty Series e Nations Unies - Recueil des Trait~s

21X 310 Amend as follows:

"The following substances of marginal 2301 may be carried in fixed

or demountable tanks/tank-containers:

(a) Propyleneimine, inhibited, of 12%

(b) Substances classified under (a) of 11', 14" to 22, 26" and27", 41" to 57";

(c) Substances classified under (b) of 11, 14' to 27, 41 to57", and substances of 32" and 33*;

(d) Substances of 1 to 5", 31, 34° and 61" (c), with theexception of isopropyl nitrate, n-propyl nitrate andnitromethane of 3" (b)."


"Shells intended for the carriage of inhibited propyleneimine

of 12" shall be designed for a calculation pressure (seemarginal 21X 127 (2)) of not less than 1.5 MPa (15 bar) (gaugepressure)."

21X 331 (Last sentence)after "referred to in

21X 332 (First sentence) [marginal 21X 310 (c)", insert3the words "except those of 33"".

21X 370 (First sentence)

21X 332 Insert a fourth sentence as follows:

"If shells intended for the carriage of substances of 33" arefitted with safety valves, these shall satisfy the requirements ofmarginals 21X 134 and 21X 135."

In the last sentence, replace "55 "C" by "61 "C".

Vol 1845, A-8940

1995


ZIX 371 Amend as follows:

"Tank-vehicles and demountable tanks/tank-containers approved forthe carriage of substances of 11, 12", 14" to 20", 27, 32" and

41 to 57" shall not be used for the carriage of foodstuffs,

articles of consumption or animal feeds."


"211 380 Fixed tanks (tank-vehicles) and demountable tanks

intended for the carriage of substances of 32" and 33' of marginal

2301, built according to the requirements of this Appendixapplicable prior to 1 January 1995, but which do not, however,

conform to the requirements applicable as from I January 1995, may

still be used up to 31 December 2000."


"212 380 Tank-containers intended for the carriage of substancesof 32' and 33" of marginal 2301, built according to the

requirements of this Appendix applicable prior to 1 January 1995,

but which do not, however, conform to the requirements applicable

as from 1 January 1995, may still be used up to 31 December 1999."

21X 471 The beginning should read as follows:

"Shells containing substances of 31' to 33' of marginal 2431 andsubstances of 2*(b), 3'(a) and 3"(b) of marginal 2471


21X 510 (b) Delete "and liquid substances and solutions assimilable under

(a) or (b) of thes~ritems"; delete the words "highly oxidizing or

oxidizing".

21X 510 (d) Delete "and liquid substances and solutions assimilable under

(a) or (b) of these items"; delete the words *slightly oxidizing".

21X 510 (e) Delete "as well as powdery or granular substances assimilableunder (b) or (c) of these items"; delete the words "oxidizing and

slightly oxidizing"..

Vol. 1845, A-894,


Amend the title before marginals 21X 600 to read:

"Class 6.1: Toxic substances

"Class 6.2: Infectious substances".


"(1) The following substances of marginal 2601 may be carried infixed or demountable tanks/tank-containers:

(a) The substances listed by name in 2" to 4';

(b) Highly toxic substances classified under (a) of 6" to 13" -with the exception of isopropyl chloroformate of 10" -, 15" to 17",20, 22, 23, 25" to 28', 31' to 36', 41', 44', 51, 52', 55,61, 65' to 68', 71" to 87" and 90, carried in the liquid state;

(c) Toxic or slightly toxic substances classified under (b) or(c) of 11', 12, 14' to 28", 32' to 36, 41', 44', 51" to 55, 57"to 62', 64" to 68', 71' to 87' and 90', carried in the liquidstate;

(d) Toxic or slightly toxic powdery or granular substancesclassified under (b) or (c) of 12, 14, 17, 19, 21, 23, 25" to27', 32' to 35, 41, 44, 51' to 55, 57' to 68, 71' to 87' and90*.

NOTE: For the carriage in bulk of substances of 60' (c) and

substances of 65' (b) (3243) and solid wastes classified under (c)of the various items, see marginal 61 111.

(2) Substances of marginal 2651, 3" and 4, may be carried infixed or demountable tanks/tank-containers."


"Shells intended for the carriage of substances referred to inmarginal 21X 610(])(a) listed by name under 2* to 4 of marginal2601 shall be designed for a calculation pressure (see marginal 21X127 (2)) of not less than 1.5 MPa (15 bar) (gauge pressure)."

21X 621 Replace "21X 610 (b)" by "21X 610 (1) (b)".

Vol. 1845, A-8940


21X 622 Replace "21X 610 (c)" by "21X 610 (1) (c) and 21X 610 (2)".

Add the following sentence:

"Shells intended for the carriage of chloroacetic acid of 24" (b)

of marginal 2601 shall be provided with an enamel or equivalent

protective lining if the material of the shell is attacked by

chloroacetic acid."

21X 623 Replace "21X 610 (d)" by "21X 610 (1) (d)".

21X 630 Replace "21X 610 (a) and (b)" by "21X 610 (1) (a) and(b)".

21X 631 Replace "21X 610 (c) and (d)" by "21X 610 (1) (c) and (d) and (2)".

21X 6$0 In the first sentence, replace "21X 610 (a), (b) and (c)" by

"21X 610 (1) (a), (b) and (c) and (2)".

211 650 In the second sentence, after "31" (a)", add "of marginal 2601".

21X 651 Replace "21X 610 (d)" by "21X 610 (1) (d)".

21X 670 After "3"", add "of marginal 2601".

21X 671 Replace "21X 610 (a) and (b)" by "21X 610 (1) (a) and (b)".

21X 760 Replace "the trefoil symbol, as shown on labels Nos. 7A to 7D" by

"the trefoil symbol described in marginal 2705(5)."


The following substances of marginal 2801 may be carried in fixed

or demountable tanks/tank-containers;

(a) Substances listed by name in 6" and 14";

(b) Substances classified under (a) of 1', 2, 3, 7, 8, 12",

17", 32", 33", 39, 40, 46', 47, 52" to 56", 64" to 68" and

70", 72" to 76, carried in the liquid state;

(c) Phosphorus oxybromide of 15" and substances classified under

(b) or (c) of I' to 5', 7, 8", 10', 12", 17", 31" to 40",

42" to 47", 51" to 56", 61" to 76", carried in the liquid

state;

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358 United Nations - Treaty Series * Nations Unies - Recuei des Traitks 1

21X 810 (d) Powdery or granular corrosive or slightly corrosive(suite) substances classified under (b) or (c) of 9, 11, 13', 16', 31',

34', 35', 39', 41, 45', 46, 52, 55, 62', 65, 67, 69, 71,73" and 75'.

NOTE: For the carriage in bulk of lead sulphate of I' (b), ofsubstances of 13" (b), and solid wastes and solids containing acorrosive liquid of 65' (b) of identification No. 3244 classifiedunder (c) of the various items, see marginal 81 111.

21X 820 Amend the text to read:

Shells intended for the carriage of substances listed by name in 6"and 14' shall be designed for a calculation pressure (see marginal21X 127 (2)) of not less than 2.1 MPa (21 bar) (gauge pressure).

Shells intended for the carriage of substances of 14o shall be

provided with a lead lining not less than 5 mm thick or anequivalent lining. The requirement of Appendix B.Id shall apply to

the materials and construction of welded shells, intended for the

carriage of substances of 6".

21X 822 Second sentence, delete.

21X 830 Replace "24"' by "14".

2IX 850 Replace "anhydrous hydrofluoric acid or aqueous solutions ofhydrofluoric acid" by "substances". Delete the second

subparagraph.

21X 851 Replace "bromine of 24'" by "substances of 14"".

21X 860 Insert the following new 21X860 as follows:

"Shells intended for the carriage of substances of 6' and 14'

shall bear, in addition to the particulars referred to inmarginal 21X 160, the date (month, year) of the most recentinspection of the internal condition."

2IX 861 Existing 2IX 860 is renumbered 21X 861 and is amended as follows:

"Shells intended for the carriage of inhibited sulphur trioxideof I* (a) and substances of 6' and 14' shall bear in addition, onthe plate referred to in marginal 21X 160, the maximum permissible

load mass in kg of the shell."

Vol. 1845. A-8940



"Shells intended for the carriage of inhibited sulphur trioxide

of I* (a) shall not be filled to more than 88% of their capacity;

those intended for the carriage of substances of 14" shall be

filled to not less than 88% and not more than 92% of their capacityor to 2.86 kg per litre of capacity.

"Shells intended for the carriage of substances of 6" shall not be

filled to more than 0.84 kg per litre of capacity."


"Shells intended for the carriage of substances of 6, 7" and 14"

shall be hermetically-closed (see marginal ZiX 127 (2)) during

carriage and the closures shall be protected with lockable caps."

21X 910 Amend to read:

"Substances of 1', 2, 4" (c), II* and 12" of marginal 2901 may be

carried in fixed or demountable tanks and in tank-containers."

In the NOTE, add "and 12"".


"Shells intended for the carriage of substances of 1, 4, 11" and

12' shall be designed in accordance with the requirements of Part I

of this Appendix."


"Shells intended for the carriage of substances of I", 4"% 11 and

12" shall be subject to the initial and periodic hydraulic pressuretests at the calculation pressure used in their design as definedin marginal 21X 123."

Appendix B.1c

213 010 (e) To read:

"Substances of 1" (b) and (c), 2" (b), 5", 8" (b) and (c), 17" (c),

42", 43" (c) and 61" of Class 8."

Vol. 1t45, A-8940


REPLACE APPENDIX B.2 by the following:

"APPENDIX B.2

UNIFORM PROVISIONS CONCERNING THE CONSTRUCTION OF VEHICLESINTENDED FOR THE CARRIAGE OF DANGEROUS GOODS INCLUDING PROVISIONS

FOR THEIR TYPE APPROVAL WHERE APPROPRIATE

220 000-220 099

Section 1: Scope

220 100 (1) The provisions of this Appendix apply to the construction of

basevehicles of motor vehicles and their trailers intended for the

carriage of dangerous goods, which are subject to approval

according to marginals 10 282, 11 282, 10 283, and to "type II"transport units according to marginal 11 204(2), and to their typeapproval.

(2) For the type-approval of a vehicle type in accordance withmarginal 10 281, all sections of this Appendix shall apply.

(3) In the case of single vehicles which have not been subject to

the type-approval procedure in accordance with marginal 10 281,

only the provisions of section 5 of this Appendix apply.

220 101-

220 199

Section 2: Definitions

220 200 For the purpose of this Appendix:

(1) "Vehicle" means a chassis-cab vehicle, a tractor for semi-trailer

or a trailer-chassis or a trailer with a self-supporting body intendedfor the transport of dangerous goods;

(2) "Vehicle type" means vehicles which do not differ essentially withregard to the constructional features specified in this Appendix.

Vol. 1845, A-8940


Section 3: Application for type-approval

220 300 The application for type-approval of a vehicle type with regard to itsspecific constructional features shall be submitted by the vehiclemanufacturer or by his duly accredited representative.

220 301 The application for type-approval shall be accompanied by the under-mentioned documents in triplicate and by the following particulars

(1) a detailed description of the vehicle type with respect to itsrelevant structure, engine (compression-ignition, positive-ignition),dimensions, configuration and constituent materials;

(2) The type of vehicle according to the dangerous goods which thevehicle is intended to transport, i.e.:

Type EX/JI for vehicles intended for the carriage of explosives astype II transport units (see marginal 11 204);

Type EX/Ill for vehicles intended for the carriage of explosivesas type III transport units (see marginal 11 204);

Type FL for vehicles intended for the carriage of liquids with aflashpoint of not more than 61 "C or flammable gases, infixed tanks, demountable tanks or batteries of receptacles;

Type OX for vehicles intended for the carriage of substances ofclass 5.1, marginal 2501, item 1"(a), in fixed tanks,demountable tanks or batteries of receptacles;

Type AT for vehicles intended for the carriage of dangerous goodsin tank-containers with a capacity of more than 3 000litres, or vehicles other than those of types EX/I, EX/III,FL or OX intended for the carriage of dangerous goods infixed tanks, demountable tanks or batteries of receptacles

(3) drawings of the vehicle; and

(4) particulars of :

(a) the technical maximum mass (kg)

(b) the type(s) of endurance braking system(s)

220 302 A vehicle representative of the type to be approved shall be submittedto the technical service responsible for conducting the approvaltests.

Vol. 1845, A-8940

1995


220 303 The competent authority shall verify the existence of satisfactoryarrangements for ensuring effective control of the conformity ofproduction before type approval is granted.

220 304-220 399

Section 4: Tvoe-aooroval

220 400 If the vehicle submitted for approval pursuant to this Appendix meetsthe provisions of section 5 below, approval of that vehicle type shallbe granted.

220 401 An approval number shall be assigned to each type approved. Its firsttwo digits (oo for the Appendix in its present form) shall indicatethe series of amendments incorporating the most recent major technicalamendments made to the provisions at the time of issue of theapproval. The same Contracting Party may not assign the same number toanother vehicle type within the meaning of marginal 220 200 (2) above.

220 402 Notice of approval or of extension of approval of a vehicle typepursuant to this Appendix shall be communicated to the ContractingParties by means of a form conforming to the model reproduced inmarginal 221 000.

220 403 There shall be affixed, conspicuously and in a readily accessibleplace specified on the approval form, to every vehicle conforming to avehicle type approved under this Appendix an international approvalmark consisting of:

(1) a circle surrounding the letters "ADR" followed by thedistinguishing number of the country which has grantedapproval /;

!/ I for Germany, 2 for France, 3 for Italy, 4 for the Netherlands, 5for Sweden, 6 for Belgium, 7 for Hungary, 8 for the Czech Republic, 9 forSpain, 10 for Yugoslavia, 11 for the United Kingdom, 12 for Austria, 13 forLuxembourg, 14 for Switzerland, 15 (reserved), 16 for Norway, 17 for Finland,18 for Denmark, 20 for Poland, 21 for Portugal, 22 (reserved), 23 for Greece,24 (reserved), 25 for Croatia, 26 for Slovenia, 27 for Slovakia, 28 forBelarus, 29 and 30 (reserved), 31 for Bosnia Herzegovina. Subsequent numbersshall be assigned by the Secretary General of the United Nations to othercountries which become Contracting Parties to the ADR.

Vol. 1845, A-8940


220 403 (2) the approval number to the right of the circle prescribed in(cont'd) paragraph (I); and

(3) an additional symbol separated from the approval number andconsisting of the symbol identifying the vehicle type approved inaccordance with marginal 220 301(2).

220 404 The approval mark shall be clearly legible and be indelible.

220 405 The approval mark shall be placed close to or on the vehicle dataplate affixed by the manufacturer.

220 406-220 499

Section 5: Technical orovisions

220 500 Motor vehicles and trailers intended for use as transport units fordangerous goods shall, depending on their category and type, complywith the following provisions according to the table below.

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364 United Nations - Treaty Series - Nations Unies - Recueil des Traitis

TABLE

. 185 A84060 CiE

Vol. 1845. A-8940

x x x x

K K

N X X X "I X

W,


220 501-220 509

Electrical eouipment

General provisions

220 510 The electrical installation as a whole shall meet the provisions ofmarginal 220 511 to 220 515 in accordance with the table of marginal220 500.

WirCing

220 511 (1) The size of conductors shall be large enough to avoid overheating.Conductors shall be adequately insulated. All circuits shall beprotected by fuses or automatic circuit breakers, except for thefollowing :

- from the battery to cold start and stopping systems of the engine- from the battery to the alternator- from the alternator to the fuse or circuit breaker box- from the battery to the starter motor- from the battery to the power control housing of the endurance

braking system (see marginal 220 522 below), if this system iselectrical or electromagnetic.

The above unprotected circuits shall be as short as possible.

(2) Cables shall be securely fastened and positioned in such a waythat the conductors are adequately protected against mechanical andthermal stresses.

Battery master switch

220 512 (1) A switch for breaking the electrical circuits shall be placed asclose to the battery as possible.

(2) Direct or indirect control devices shall be installed, one in thedriver's cab and a second on the outside of the vehicle. They shall bereadily accessible and distinctively marked. The control devicelocated in the driver's cab shall be within immediate reach of thedriver seated in the driver's seat. It shall be protected againstinadvertent operation by either adding a protective cover, or by usinga dual movement control device or by other suitable means.

Vol. 1845, A-8940


220 512 (3) It shall be possible to open the switch while the engine is(cont'd) running, without causing any dangerous excess voltage. Operation

of the switch shall not constitute a fire hazard in an explosive

atmosphere ; this can be ensured by using a switch having a casingwith protection degree IP65 in accordance with IEC Standard 529.

(4) The cable connections on the battery master switch shall have a

protection degree IP54. However this does not apply if these connections

are contained in a housing which may be the battery box. In this case itis sufficient to insulate the connections against short circuits, forexample with a rubber cap.

Batteries

220 513 The battery terminals shall be electrically insulated or covered by

the insulating battery box cover. If the batteries are not locatedunder the engine bonnet, they shall be fitted in a vented box.

Tachographs

220 514 The electrical supply to the tachograph shall be provided via a safetybarrier connected directly to the battery. The electrical supply leadsto and from the tachograph, which remain energized when the battery

master-switch is open, shall be intrinsically safe according to therequirements of European Standard EN 50 020. The tachograph and the

safety barrier shall meet the requirements for associated electricalequipment according to European Standard EN 50 020.

Permanently energized installations

220 515 Those parts of the. electrical installation, other than the tachograph,which remain energized when the battery master-switch is open, shall

be suitable for use in a hazardous area and shall meet the appropriaterequirements of European .Atandard EN 50 014 and one of EuropeanStandards EN 50 015 to 50 020 or EN 50 028. The requirements for therelevant gas group according to the product being carried shall bemet.

Vol. 1845, A-8940

366


Provisions concerning that part of the electrical installationsituated to the rear of the driver's cab

220 516 The whole installation shall be so designed, constructed and protectedsuch that it cannot provoke any ignition or short-circuit under normalconditions of use of vehicles and that these risks can be minimized inthe event of an impact or deformation. In particular

(1) Wiring

The wiring located behind the driver's cab shall be protected againstimpact, abrasion and chafing during normal vehicle operation. Examplesof appropriate protection are given in the figures 1, 2, 3 and 4below. However, the sensor cables of anti-lock braking devices do notneed additional protection.

Corugated polyamide conduit

Sinqsulat wires

Fieure N" I

j Corrugated polyarmide conduit

P Insulating sheath

-- --UU -~h~z-F - - arae insulated wiresPigure N'.2

Vol. 1845, A-8940


Polyurethane sheath

--- With ine: sheath

Separate insulated wiresFigure N" 3.

Outer la Metal-threaded protection

Separate insulatedvilres

Figure No. 4

ir layer(2) Lgtn

Lamp bulbs with a screw cap shall not be used.

Electrical lifting mechanits

210 517 The electrical equipment of the mechanism for lifting a bogie axleshall be installed outside the chassis frame in a sealed housing.

220 518-220 519

Brakina eouioment

General orovisions

220 520 In addition to the following technical provisions, to be applied inaccordance with the table of marginal 220 500, motor vehicles andtrailers intended for use as transport units for dangerous goods shallfulfil all relevant technical requirements of the ECE Regulation N" 13or the Directive 71/320/EEC !/ In their latest amended form applicableat the time of vehicle approval.

!/ Originally published in the Official Journal of the EuropeanCommunities No. L 202 of 6.9.1971.

Vol. 1845, A-8940


Anti-lock Braking System

220 521 (1) Motor vehicles having a maximum mass exceeding 16 tonnes, orauthorized to tow a trailer with a maximum mass exceeding 10 tonnes,shall be equipped with an anti-lock braking system of category Iaccording to ECE Regulation N" 13, Annex 13, or to Directive71/320/EEC !/.

(2) Trailers having a maximum mass exceeding 10 tonnes shall beequipped with an anti-lock braking system of category A according toECE Regulation No. 13, Annex 13, or to Directive 71/320/EEC !_/.

(3) Electrical connections between drawing vehicles and the trailersfor the anti-lock system in the trailer shall be made by means of aconnector conforming to ISO 7638:1985.

Endurance braking system

220 522 (1) Endurance braking system means a system intended to stabilizevehicle speed on a long descent, without the use of the service,secondary or parking braking systems.

(2) Motor vehicles having a maximum mass exceeding 16 tonnes or

authorized to tow a trailer with a maximum mass exceeding 10 tonnesshall be fitted with an endurance braking system which complies with

the following requirements:

(a) The endurance braking system may be a single device or a

combination of several devices. Each device may have its owncontrol.

(b) All three endurance braking control options provided for inECE Regulation N' 13, paragraph 2.14 or in Directive71/320/EEC !/ shaTl be permitted, but, in the case of afailure of the anti-lock system, integrated or combinedretarders shall be switched off automatically.

_/ Originally published in the Official Journal of the European

Communities N. L 202 of 6.9.1971.

Vol. 1845. A-8940


220 522 (c) The effectiveness of the endurance braking system shall be(cont'd) controlled by the anti-lock braking system such that the

axle(s) braked by the endurance braking system cannot belocked by the endurance braking system at speeds above15 km/h. However, this provision shall not apply to thatpart of the braking system constituted by natural enginebraking.

(d) The endurance braking system shall comprise several stagesof effectiveness, including a low stage appropriate for theunladen condition. Where the endurance braking system of amotor vehicle is constituted by its engine, the differentgear ratios shall be considered to provide the differentstages of effectiveness.

(e) The performance of the endurance braking system must be suchthat it fulfils the requirements of ECE Regulation N* 13,Annex 5 (Type II A test), or of the corresponding EECDirective .2/, with a laden vehicle mass comprising theladen mass of the motor vehicle and its authorized maximumtowed mass but not exceeding a total of 44 tonnes.

(f) If the motor vehicle does not fulfil the performancerequirements for the endurance braking system as defined inparagraph (2) (e) above, it shall at least fulfil therequirements of ECE Regulation N" 13, Annex 5, or thecorresponding EEC Directive 2*/, and shall be restricted tobe coupled only to a trailer fitted with an endurancebraking system. Such a motor vehicle must be fitted with acontrol device for the endurance braking system on thetrailer.

(3) If a trailer is equipped with an endurance braking system it shallfulfil the requirements of ECE Regulation N' 13, Annex 5, or thecorresponding EEC Directive 2*/, and the provisions of paragraphs (2)(a) to (2) (d) above.

2/ Exact reference to be included.

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United Nations - Treaty Series e Nations Unies - Recuell des Traitis

220 523-220 529

Prevention of fire risks

General Drovisions

220 530 The following technical provisions shall apply in accordance withthe table of marginal 220 500.

Vehicle cab

220 531 (1) Only material not readily flammable shall be used in theconstruction of the driver's cab. This provision will be deemed to bemet if, in accordance with the procedure specified in ISO standard3795:1989, samples of the following cab components have a burn ratenot exceeding 100 mm/min : seat cushions, seat backs, safety belts,head lining, opening roofs, arm rests, all trim panels including door,front, rear, and side panels, compartment shelves, head restraints,floor coverings, sun visors, curtains, shades, wheel housing covers,engine compartment covers, mattress covers and any other interiormaterials, including padding and crash-deployed elements, that aredesigned to absorb energy on contact by occupants in the event of acrash.

(2) Unless the driver's cab is made of not readily flammablematerials, a shield made of metal or other suitable material ofthe same width as the tank shall be fitted at the back of the cab. Anywindows in the back of the cab or in the shield shall be hermeticallyclosed and made of fire resistant safety glass with fire resistantframes. Furthermore, there shall be a clear space of not less than15 cm between the tank-and the cab or the shield.

Fuel tanks

220 532 The fuel tanks for supplying the engine of the vehicle shall meet thefollowing requirements:

(1) The fuel tanks shall be so placed as to be protected as far aspossible against any collision.

(2) In the event of any leakage, the fuel shall drain to the groundwithout coming into contact with hot parts of the vehicle or the load.

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220 532 (3) Fuel tanks containing petrol shall be equipped with an effective(cont'd) flame trap at the filler opening or with a closure with which the

opening can be kept hermetically sealed.

220 533 The engine propelling the vehicle shall be so equipped and situated toavoid any danger to the load through heating or ignition. In the caseof transport of explosive substances or articles (vehicle types EX/IIand EX/III) the engine shall be placed forward of the front wall ofthe body: it may nevertheless be placed under the body, provided thisis done in such a way as to avoid any heating, even localized, of theload.

Exhaust system

220 534 The exhaust system as well as the exhaust pipes shall be so directedor protected to avoid any danger to the load through heating orignition. Parts of the exhaust system situated directly below the fueltank (diesel) shall have a clearance of at least 100 mm or beprotected by a thermal shield. In the case of transport of explosivesubstances or articles (vehicle types EX/II and EX/I11) the exhaustsystem shall be placed forward of the front wall of the body orseparated from the load-carrying part of the vehicle by a fire-resistant and heat-insulating screen. In this case the exhaust pipeoutlet shall be directed outwards from the vehicle.

Vehicle endurance brakino

220 535 Vehicles equipped with endurance braking systems emitting hightemperatures placed behind the rear wall of the driver's cab shall beequipped with a thermal shield securely fixed and located between thissystem and the tank or load so as to avoid any heating, even local, ofthe tank shell or the load.

In addition, the thermal shield shall protect the braking systemagainst any outflow or leakage, even accidental, of the load. Forinstance, a protection including a twin-shell shield shall beconsidered satisfactory.

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Auxiliary heating device

220 536 Auxiliary heating for the cab shall be sufficiently secure from thestandpoint of fire prevention and shall be placed forward of theprotective wall (rear wall of the cab). The heating appliance shall beplaced as far forward and as high as possible (at least 80 cm abovefloor level) and shall be fitted with devices preventing any objectfrom being brought into contact with the hot surfaces of the applianceor its exhaust pipe. Only appliances with a means of rapidlyrestarting the combustion air ventilator (max. 20 s) may be used.

220 537-220 539

Speed limitation device

220 540 Motor vehicles (rigid vehicles and tractors for semi-trailers) with amaximum mass exceeding 12 tonnes, shall be equipped in accordance withmarginal 10 261 with a speed limitation device according to theprovisions of ECE Regulation N" 89 or of Directives 92/6/EEC and92/24/EEC. The set speed V as defined in paragraph 2.1.2 of ECERegulation No. 89 shall not exceed 85 km/h.

220 541-220 599

Section 6: Modification of the vehicle tVe and extension of aooroval

220 600 Every modification of the vehicle type shall be notified to theadministrative department which approved the vehicle type. Thedepartment may then either:

(1) Consider that the modifications made are unlikely to have anappreciable adverse effect and that in any case the vehicle stillcomplies with the requirements, or

(2) Require a further test report from the technical serviceresponsible for conducting the tests.

220 601 Confirmation or refusal of approval, specifying the alteration, shallbe communicated by the procedure specified in marginal 22C. 402 to theContracting Parties.

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220 602 The competent authority issuing an extension of approval shall assign

a series number to each communication form drawn up for such an

extension and inform thereof the other Parties by means of acommunication form conforming to the model in marginal 221 000.

220 603-220 699

Section 7: Conformity of oroduction

Initial assessment

220 700 The approval authority of a Contracting Party shall verify - before

granting type approval - the existence of satisfactory arrangementsand procedures for ensuring effective control so that vehicles when inproduction conform to the approved type.

220 701 The requirement in marginal 220 700 shall be verified to thesatisfaction of the authority granting type approval but may also beverified, on behalf of the authority granting type approval, by the

approval authority of another Contracting Party. In that case, thelatter approval authority prepares a statement of compliance outlining

the areas and production facilities it has covered as relevant to thevehicle(s) to be type approved.

220 702 The approval authority shall also accept the manufacturer'sregistration to harmonized standard ISO 9002 (the scope of

which/covers the vehicle(s) to be approved) or an equivalent

accreditation standard as satisfying the requirements ofmarginal 220 700. The manufacturer shall provide details of theregistration and undertake to inform the approval authority of anyrevisions to its validity or scope.

220 703 On receiving an application from the authority of another ContractingParty the approval authority shall send forthwith the statement of

compliance mentioned in the last sentence of marginal 220 701 or

advise that it is not in a position to provide such a statement.

220 704-

220 709

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Conformity of production

220 710 Every vehicle approved under this Appendix shall be so manufacturedas to conform to the type approved by meeting the provisions set outin section 5 above.

220 711 The approval authority of a Contracting Party granting a typeapproval pursuant to this Appendix shall verify the existence ofadequate arrangements and documented control plans, to be agreed withthe manufacturer for each approval, to carry out at specifiedintervals those tests or associated checks necessary to verify

continued conformity with the approved type including specifically,where applicable, tests specified in this Appendix.

220 712 The holder of the approval shall in particular:

(1) Ensure the existence of procedures for effective control of theconformity of vehicles to the type approval;

(2) Have access to the testing equipment necessary for checking theconformity to each approved type;

(3) Ensure that test results data are recorded and that annexeddocuments remain available for a period to be determined in agreementwith the approval authority. This period shall not exceed 10 years;

(4) Analyse results of each type of test, in order to verify andensure the stability of the vehicle characteristics, making allowancefor variation of an industrial production;

(5) Ensure that for each type of vehicle, at least the checks andtests prescribed in this Appendix are carried out;

(6) Ensure that any set of samples or test pieces giving evidence ofnon-conformity in the type of test in question gives rise to a furthersampling and test. All the necessary steps shall be taken to restoreconformity of the corresponding production.

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376 United Nations - Treaty Series o Nations Unies - Recueil des Traitks

220 713 The authority which has granted type approval may at any time verifythe conformity control methods applied in each production facility.The normal frequency of these verifications shall be consistent withthe arrangements (if any) accepted under marginals 220 701 or 220 702of this Appendix and be such as to ensure that the relevant controlsare reviewed over a period consistent with the climate of trustestablished by the approval authority.

(1) At every inspection, the test records and production recordsshall be available to the visiting inspector.

(2) Where the nature of the test is appropriate, the inspector mayselect samples at random to be tested in the manufacturer's laboratoryor by the Technical Service according to section 9 below. The minimumnumber of samples may be determined according to the results of themanufacturer's own verification.

(3) Where the level of control appears unsatisfactory, or when itseems necessary to verify the validity of the tests carried out inapplication of paragraph (2) above, the inspector shall select samplesto be sent to the Technical Service which conducts the type approvaltests.

(4) The approval authority may carry out any check or test prescribedin this Appendix.

(5) In cases where unsatisfactory results are found during aninspection, the approval authority shall ensure that all necessarysteps are taken to restore conformity of production as rapidly aspossible."

220 714-220 719

Penalties for non-conformity of production

220 720 The approval granted in respect of a vehicle type pursuant to thisAppendix may be withdrawn'if the provisions laid down in section 5above are not complied with.

220 721 If a Contracting Party withdraws an approval it has previouslygranted, it shall forthwith so notify the other Contracting Parties bymeans of a communication form conforming to the model inmarginal 221 000.

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220 722-

220 799

Section 8: Production definitely discontinued

220 800 If the holder of the approval completely ceases to manufacture a typeof vehicle approved in accordance with this Appendix, he shall soinform the authority which granted the approval. Upon receiving therelevant communication, that authority shall inform thereof the otherParties by means of a communication form conforming to the model inmarginal 221 000.

220 801-220 899

Section 9: Names and addresses of technical services resoonsible forconductino anoroval tests and of administrative deoartments

220 900 The Contracting Parties shall communicate to the United Nationssecretariat the names and addresses of the technical servicesresponsible for conducting approval tests and of the administrativedepartments which grant approval and to which forms certifyingapproval or extension, or refusal or withdrawal of approval orproduction definitely discontinued, issued in other countries, are tobe sent.

220 901-220 999

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221 000 COMMUNICATION

(Maximum format : A4 (210 x 297 mm))

Cissued by: Name of Administration

........ ,,.............

CONCERNING: Z/ APPROVAL GRANTEDAPPROVAL EXTENDEDAPPROVAL REFUSEDAPPROVAL WITHDRAWNPRODUCTION DEFINITELY DISCONTINUED OF A VEHICLETYPE WITH REGARD TO SPECIFIC CONSTRUCTIONALFEATURES FOR THE TRANSPORT OF DANGEROUS GOODS

Approval N" ...... ................. ..Extension N° . ........

I. Trade name or mark of vehicle ..........................................

2. Vehicle type : Chassis-cab, tractor for semi-trailer, trailer,semi-trailer, trailer with a self-supporting bodyZ/ ...................

3. Type of vehicle according to marginal 220 301(2) (EX/II, EX/III, FL,

OX, AT) .................................................................

4. Manufacturer's name and address ........................................

5. If applicable, name and address of manufacturer's representative .......

6. Mass of vehicle :

6.1 Technical maximum mass of complete vehicle .............................

.1 Distinguishing number of the country which has granted/extended/refused/withdrawn approval (see footnote J/ to marginal 220 403

()).

Z/ Strike out what does not apply.

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1995


7. Specific equipment of the vehicle:

7.1 The vehicle is/is not equipped with specific electrical devices.

Summary description: ..............................................

7.2 The vehicle is/is not equipped with a brake anti-lock device.

Approval number: ..................................................Category of device: ...............................................

7.3 The vehicle is/is not equipped with an endurance braking system ...

Approval number: ..................................................

Technical maximum mass of the vehicule corresponding to the performance

of the endurance braking system .......................................

Summary description ................................................

7.4 The vehicle is/is not equipped with devices for the prevention of fire

risks.

Summary description: .................................................

7.5 In the case of a motor vehicle .......................................

7.5.1 Type of engine: positive-ignition; compression ignition

7.5.2 The vehicle is/is not equipped with a device to limit the speed byconstruction adjusted to a speed of ... km/h.

Approval number: ....................................................

8. Vehicle submitted for approval on ...................................

9. Technical service responsible for carrying out approval inspections ..

...............................aet se ......... . ......... ...........

10. Date of report issued by that service ...............................

11. Number of report issued by that service .............................

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380 United Nations -Treaty Series * Nations Unies - Recueil des Trait6s 1995

12. Approval granted / refused / extended / withdrawn Z/ .................

13. Position of approval mark on the vehicle ............................

14. Place ...............................................................

15. Date ................................................................

16. Signature ...........................................................

21 Strike out what does not apply.

221 001-229 999"

Appendix 8.5 marginal 250 000 should be replaced by the new marginalbelow:

Vol. 1845, A-8940


"250 000 List of substances and identification numbers

(1) The hazard identification number consists of two or threefigures. In general, the figures indicate the following hazards:

2 Emission of gas due to pressure or to chemical reaction3 Flammability of liquids (vapours) and gases or self-

heating liquid4 Flammability of solids or self-heating solid5 Oxidizing (fire-intensifying) effect6 Toxicity or risk of infection7 Radioactivity8 Corrosivity9 Risk of spontaneous violent reaction

Note: The risk of spontaneous violent reaction within the meaning offigure 9 include the possibility following from the nature of asubstance of a risk of explosion, disintegration andpolymerization reaction following the release of considerableheat or flammable and/or toxic gases.

Doubling of a figure indicates an intensification of thatparticular hazard.

Where the hazard associated with a substance can be adequatelyindicated by a single figure, this is followed by zero.

The following combinations of figures, however, have a specialmeaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539, 606,623, 642, 823, 842 and 90, see (2) below.

If a hazard identification number Is prefixed by the letter "X", thisindicates that the substance will react dangerously with water. Forsuch substances, water may only be used by approval of experts.

(2) The hazard identification numbers listed in paragraph (3) havethe following meanings:

20 inert gas22 refrigerated gas223 refrigerated flammable gas225 refrigerated oxidizing (fire-intensifying) gas

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250 000 23 flammable gas(cont'd) 236 flammable gas, toxic

239 flammable gas, which can spontaneously lead to violentreaction

25 oxidizing (fire-intensifying) gas26 toxic gas265 toxic gas, oxidizing (fire-intensifying)266 highly toxic gas268 toxic gas, corrosive286 corrosive gas, toxic

30 flammable liquid (flash-point between 23 *C and 61 *C,inclusive) or flammable liquid or solid in the moltenstate with a flash-point above 61 *C, heated to atemperature equal to or above its flash-point, or self-heating liquid

323 flammable liquid which reacts with water, emittingflammable gases

X323 flammable liquid which reacts dangerously with water,emitting flammable gases:/

33 highly flammable liquid (flash-point below 23C)333 pyrophoric liquid

X333 pyrophoric liquid which reacts dangerously with water!/336 highly flammable liquid, toxic338 highly flammable liquid, corrosive

X338 highly flammable liquid, corrosive, which reactsdangerously with water:/

339 highly flammable liquid which can spontaneously lead toviolent reaction

36 flammable liquid (flash-point between 23 *C and 61 'Cinclusive), slightly toxic, or self-heating liquid, toxic

362 flammable liquid, toxic, which reacts with water,emitting flammable gases

X362 flammable liquid toxic, which reacts dangerously withwater, emitting flammable gases:/

38 flammable liquid (flash-point between 23 'C and 61 *C,inclusive), corrosive

/ Water not to be used except by approval of experts.

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250 000 382 flammable liquid, corrosive, which reacts with water,(cont'd) emitting flammable gases

X382 flammable liquid, corrosive, which reacts dangerouslywith water, emitting flammable gases:/

39 flammable liquid, which can spontaneously lead to violentreaction

40 flammable or self-heating solid423 solid which reacts with water, emitting flammable gasesX423 flammable solid which reacts dangerously with water,

emitting flammable gases:/44 flammable solid, in the molten state at an elevated

temperature446 flammable solid, toxic, in the molten state, at an

elevated temperature46 flammable or self-heating solid, toxic462 toxic solid which reacts with water, emitting flammable

gases48 flammable or self-heating solid, corrosive

482 corrosive solid which reacts with water, emittingflammable gases

50 oxidizing (fire-intensifying) substance539 flammable organic peroxide55 strongly oxidizing (fire-intensifying) substance

556 strongly oxidizing (fire-intensifying) substance, toxic558 strongly oxidizing (fire-intensifying) substance,

corrosive559 strongly oxidizing (fire-intensifying) substance, which

can spontaneously lead to violent reaction56 oxidizing substance (fire-intensifying), toxic

568 oxidizing substance (fire-intensifying), toxic, corrosive58 oxidizing substance (fire-intensifying), corrosive59 oxidizing substance (fire-intensifying) which can

spontaneously lead to violent reaction

60 toxic or slightly toxic substance606 infectious substance

623 toxic liquid, which reacts with water, emitting flammablegases

63 toxic substance, flammable (flash-point between-23C and61C inclusive)

638 toxic substance, flammable (flash-point between 23"C and61C inclusive), corrosive

./ Water not to be used except by approval of experts.

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250 000 639 toxic substance, flammable (flash-point between 23"C and

(cont'd) 61C inclusive) which can spontaneously lead to violent

reaction64 toxic solid, flammable or self-heating

642 toxic solid, which reacts with water, emitting flammable

gases65 toxic substance, oxidizing (fire-intensifying)66 highly toxic substance663 highly toxic substance, flammable (flash-point not above

61C)664 highly toxic solid, flammable or self-heating

665 highly toxic substance, oxidizing (fire-intensifying)668- highly toxic substance, corrosive669 highly toxic substance which can spontaneously lead to

violent reaction68 toxic substance, corrosive

69 toxic substance, which can spontaneously lead to violent

reaction

70 radioactive material72 radioactive gas723 radioactive gas, flammable

73 radioactive liquid, flammable (flash-point not above

61C)74 radioactive solid, flammable

75 radioactive material, oxidizing (fire-intensifying)76 radioactive material, toxic78 radioactive material, corrosive

80 corrosive or slightly corrosive substanceX80 corrosive or slightly corrosive substance, which reacts

dangerously-with water:/823 corrosive liquid which reacts with water, emitting

flammable gases83 corrosive or slightly corrosive substance, flammable

(flash-point between 23C and 61C inclusive)X83 corrosive or slightly corrosive substance, flammable,

(flash-point between 23"C and 61C inclusive), whichreacts dangerously with water:/

836 corrosive or slightly corrosive substance, flammable

(flash-point between 23C and 61"C), toxic839 corrosive or slightly corrosive substance, flammable

(flash-point between 23"C and 61"C inclusive) which can


_ Water not to be used except by approval of experts

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250 000 X839 corrosive or slightly corrosive substance, flammable(cont'd) (flash-point between 23"C and 61C inclusive), which can

spontaneously lead to violent reaction and which reactsdangerously with water:/

84 corrosive solid, flammable or self-heating842 corrosive solid which reacts with water, emitting

flammable gases85 corrosive or slightly corrosive substance, oxidizing

(fire-intensifying)856 corrosive or slightly corrosive substance, oxidizing

(fire-intensifying) and toxic86 corrosive or slightly corrosive substance, toxic88 highly corrosive substanceX88 highly corrosive substance, which reacts dangerously with

water:/883 highly corrosive substance, flammable (flash-point

between 23C and 61C inclusive)884 highly corrosive solid, flammable or self-heating885 highly corrosive substance, oxidizing (fire-intensifying)886 highly corrosive substance, toxicX886 highly corrosive substance, toxic, which reacts

dangerously with water:/89 corrosive or slightly corrosive substance, which can


90 environmentally hazardous substance; miscellaneousdangerous substances

(3) The identification numbers referred to in marginal 10 500 arelisted in Tables I, II and III below.

Note 1: The identification numbers to be shown on the orangeplates should be looked for first in Table I. If in thecase of substances of classes 3, 4.1, 4.2, 4.3, 5.1, 5.2,6.1, 6.2, 7, i and 9 the name of the substance to becarried or the collective heading which covers it is notlisted in Table I, the identification numbers are to betaken from Table II.

Note 2: Table III contains all the entries in Tables I and II insubstance identification number order.

./ Water not to be used except by approval of experts

Vol. 1845, A-8940


Table I

List of substances described under their chemical names or under collective headings which aregiven a specific "substance identification number" [column (b)]. [For solutions and mixtures ofsubstances (such as preparations and wastes), see also marginal 2002 (8) and (9)].

This table also includes substances not shown in the class lists of substances, but whichnevertheless fall within the classes and item numbers shown in column (e).

NOTE: For substances of Classes 3, 4.1, 4.2, 4.3, 5.1, 6.1, 6.2, 7, 8 and 9 not mentioned in thistable, see Table II. Substances are listed in alphabetical order.

Name of substance Substance HA, rd Label Clas and itemIdentLication Identafication number

No. No.(Louer pa) (Upper patA)

(a) (b) () (d) e)

Acetal 1088 33 3 3, 3°(b)

Acetaldehyde 1089 33 3 3, 1 *(a)

Acetaldehyde oxime 2332 30 3 3, 31 °(c)

Acetic acid, glacial 2789 83 8+3 8, 32'(b)2.

Acetic acid, solution 2789 83 8+3 8, 32°(b)2.

Acetic acid, solution 2790 80 8 8, 32*(b)l.,(c)

Acetic anhydride 1715 83 8+3 8, 32'(b)2.

Acetone 1090 33 3 3, 3°(b)

Acetone cyanohydrin, stabilized 1541 66 6.1 6.1, 12°(a)

Acetone oils 1091 33 3 3, 3°(b)

Acetonitrile (methyl cyanide) 1648 33 3 3. 3°(b)

Acetyl bromide 1716 s0 8 8, 35°(b)l.

Acetyl chloride 1717 X338 3+8 3, 25°(b)

Acetyl iodide 1898 80 8 8. 35°*(b)1.

Acetyl methyl carbinol 2621 30 3 3, 31 °(c)

Acridine 2713 60 6.1 6.1, 12°(c)

Acrolein, dimer, stabilized 2607 39 3 3, 31°(c)

Acrolein, inhibited 1092 663 6.1+3 6.1, 8°(a)

Acrylamide 2074 60 6.1 6.1, 12°(c)

Acrylic acid, inhibited 2218 839 8+3 8, 32°(b)2.

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Name of substmnce Subetarcc Hazad LAbc Ck.i and itemIdentiicalton Idcntiication number

No. No(Lo.wcr part) (Upper pan)

(a) (b) (c) (d) (a)

AcrylonitrUe, inhibited 1093 336 3+6.1 3, 11*(a)

Adhesives 1133 33 3 3, 5(a),(b),(c)

Adhesives 1133 30 3 3, 31 °(c)

Adiponitrile 2205 60 6.1 6.1, 120(c)

Air, compressed 1002 20 2 2, 2°(a)

Air, deeply-refrigerated 1003 225 2+05 2, 8°(a)

Alcoholic beverages 3065 30 3 3, 31 °(c)

Alcoholic beverages 3065 33 3 3, 3(b)

Aldol 2839 60 6.1 6.1, 14*(b)

Alkali metal amalgam 1389 X423 4.3 4.3, 11 *(a)

Alkali metal amides 1390 423 4.3 4.3, 19(b)

Alkali metal dispersion 1391 X423 4.3 4.3, 11 *(a)

Alkaline earth metal amalgam 1392 X423 4.3 4.3, 11*(a)

Alkaline earth metal dispersion 1391 X423 4.3 4.3, 11 '(a)

Alkylsulphonic acids, liquid 2584 80 8 8, 1°'(b)

Alkylsulphonic acids, liquid 2586 80 8 8, 340(c)

Alkylsulphonic acids, solid 2583 80 8 8, 1°'(b)

Alkylsulphonic acids, solid 2585 80 8 8, 34(c)

Alkylsulphuric acids 2571 80 8 8, 34°(b)

AII)l acetate 2333 336 3+6.1 3, 17- (b)

Allyl alcohol 1098. 663 6.1+3 6.1, 8*(a)

Allyl bromide 1099 336 3+6.1 3, 16'(a)

Allyl chloride 1100 336 3+6.1 3, 16'(a)

Allyl chloroformate 1722 638 6.1+8+3 6.1, 28-(a)

Allyl ethyl ether 2335 336 3+6.1 3, 17°(b)

Allyl formate 2336 336 3+6.1 3. 7 *(a)

Allyl glycidyl ether 2219 30 3 3, 31*(c)

Allyl iodide 1723 338 3+8 3, 25°(b)

Allyl isothiocyanate, inhibited 1545 639 6.1+3 6.1, 20°(b)

Allylamine 2334 663 6.1+3 6.1, 70(a)2.

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Name of substance Substance Hazar LAbel Clas and itemIdentificaiion Identification number

No. No.(Lower par) (Upper pt)

(a) (b) (e) (d) (ci

Allyltrichlorosilane, stabilised 1724 X839 8+3 8, 37'(b)

Aluminium alkyl halides 3052 X333 4.2+4.3 4.2, 32-(a)

Aluminium alkyl hydrides 3076 X333 4.2+4.3 4.2. 32°(a)

Aluminium alkyls 3051 X333 4.2+4.3 4.2, 31*(a)

Aluminium borohydride 2870 X333 4.2+4.3 4.2, 17°(a)

Aluminium borohydride in devices 2870 X333 4.2+4.3 4.2, 17°(a)

Aluminium bromide solution 2580 80 8 8, 5*(c)

Aluminium bromide, anhydrous 1725 80 8 8, 11 -(b)

Aluminium carbide 1394 423 4.3 4.3, 17°(b)

Aluminium chloride solution 2581 80 8 8. S"(c)

Aluminium chloride, anhydrous 1726 80 8 8, 11 °(b)

Aluminium dross 3170 423 4.3 4.3, 13°(b),(c)

Aluminium ferrosilicon powder 1395 462 4.3+6.1 4.3, 15°(b)

Aluminium nitrate 1438 50 5.1 5.1, 22°(c)

Aluminium powder, coated 1309 40 4.1 4.1, 13(b),(c)

Aluminium powder, uncoated 1396 423 4.3 4.3, 13'(b)

Aluminium resinate 2715 40 4.1 4.1, 12 (c)

Aluminium silicon powder, uncoated 1398 423 4.3 4.3, 13°(c)

2-Amino-4-chlorophenol 2673 60 6.1 6.1, 12-(b)

2-Amino-5-diethylaminopentane 2946 60 6.1 6.1, 12°(c)

2-(2-Aminoethoxy) ethanol 3055 80 8 8, 53°(c)

N-Aminoethylpiperazine 2815 80 8 8, S3(c)

Aminophenols (o-, mn-, p-) 2512 60 6.1 6.1, 12°(c)

Aminopyridines (o-, m-, p-) 2671 60 6.1 6.1, 12"(b)

Ammonia 1005 268 6.1 2, 3°(at)

Ammonia dissolved in water with 2073 268 6.1 2, 9 -'at)more than 35% but not more than40% ammonia

Ammonia dissolved in water with 2073 268 6.1 2, 9°(at)more than 40% but not more than50% ammonia

Vol 1845, A-8940


Name of oubsanuce Substice HuAzrd Label Class ard itemIdentification Identifcaion number

No No.(Lowcr pLn) (Upp, p .r)

(a) (b) (C) (d) (e)

Ammonia solution containing between 2672 80 8 8, 43°(c)10 and 35% ammonia I

Ammonium arsenate 1546 60 6.1 6.1. 51 "(b)

Ammonium dichromate 1439 50 5.1 5.1. 27-(b)

Ammonium dinitro-o-cresolate 1843 60 6.1 6.1. 12°(b)

Ammonium fluoride 2505 60 6.1 6.1, 63"(c)

Ammonium fluorosilicate 2854 60 6.1 6.1, 64*(c)

Ammonium hydrogendifluoride, solid 1727 80 8 8, 9°(b)

Ammonium hydrogendifluoride 2817 86 8+6.1 8, 7*(b),(c)solution

Ammonium hydrogen sulphate 2506 80 8 8, 13°(b)

Ammonium metavanadate 2859 60 6.1 6.1, 58-(b)

Ammonium nitrate 1942 50 5.1 5.1, 21"(c)

Ammonium nitrate fertilizers, type Al1 2067 50 5.1 5.1, 21°(c)

Ammonium nitrate fertilizers, type A2 2068 50 5.1 5.1, 21*(c)

Ammonium nitrate fertilizers, type A3 2069 50 5.1 5.1, 21 *(c)

Ammonium nitrate fertilizers, type A4 2070 50 5.1 5.1, 21 °(c)

Ammonium nitrate, liquid, (hot 2426 59 5.1 5.1, 20*concentrated solution)

Ammonium persulphate 1444 50 5.1 5.1, 18°(c)

Ammonium polysulphide solution 2818 86 8+6.1 8, 45°(c)

Ammonium polysulphide solution 2818 86 8+6.1 8, 45°(b)1.

Ammonium polyvanadate 2861 60 6.1 6.1, 58'(b)

Ammonium sulphide, solution 2683 86 8+6.1+3 8, 45-(b)2.

Arnyl acetates 1104 30 3 3, 31°(c)

Amyl acid phosphate 2819 80 8 8, 38°(c)

Amyl alcohols 1105 30 3 3, 31 °(c)

Amyl alcohols 1105 33 3 3, 3"(b)

Amyl butyrates 2620 30 3 3. 31 (c)

Amyl chloride 1107 33 3 3, 3°(b)

Amyl formates 1109 30 3 3, 31°(c)

Vol. 1845, A-8940


Nan of wubsa.rce Substance Hazard Label Clas and itemIdentification Identification number

No. No.(Lower Wa) (Upper pa t)

(a) (b) (c) (d) (C)

Amyll mercaptan 1111 33 3 3, 3*(b)

n-Amyl methyl ketone 1110 30 3 3. 31 *(c)

Amyl nitrate 1112 30 3 3, 31 (c)

Amyl nitrite 1113 33 3 3, 3"(b)

Amylamines (n-amylimine, ten- 1106 338 3+8 3, 22"(b)amylamine)

Amylamine (sec-amylamine) 1106 38 3+8 3, 33°(c)

Amyltrichlorosilane 1728 X80 8 8, 36°(b)

Aniline 1547 60 6.1 6.1. 120(b)

Aniline hydrochloride 1548 60 6.1 6.1, 12°(c)

Anisidines 2431 60 6.1 6.1, 12(c)

Anisole (phenyl methyl ether) 2222 30 3 3, 31 "(c)

Anisoyl chloride 1729 80 8 8, 35°(b)1.

Antimony lactate 1550 60 6.1 6.1, 59 ° (c)

Antimony pentachloride solution 1731 80 8 8, 12°(b),(c)

Antimony pentachloride, liquid 1730 80 8 8, 12°(b)

Antimony pentafluoride 1732 86 8+6.1 8, 10°(b)

Antimony potassium tartrate 1551 60 6.1 6.1, 59°(c)

Antimony powder 2871 60 6.1 6.1, 590(c)

Antimony trichloride 1733 80 8 8, 11 °(b)

Argon, compressed 1006 20 2 2. 1'(a)

Argon, deeply-refrigerated 1951 22 2 2, 7*(a)

Arsenic 1558 60 6.1 6.1, 51-(b)

Arsenic acid, liquid 1553 66 6.1 6.1, 51'(a)

Arsenic acid, solid 1554 60 6.1 6.1, 51"(b)

Arsenic bromide 1555 60 6.1 6.1, 51(b)

Arsenic pentoxide 1559 60 6.1 6.1, 51 "(b)

Arsenic trichloride 1560 66 6.1 6.1, 51 *(a)

Arsenic trioxide 1561 60 6.1 6.1, 51"(b)

Arsenical dust 1562 60 6.1 6.1, 51"(b)

Vol. 1845, A-8940


Nae of substajce Subsriaee HZArd LAbW| Class and itemIdcntification ldcntricaion number

No. No.(Lower PIK) (Upper Pan)

(a) (b) (C) (d) (C)

Arylsulphonic acids, liquid 2584 80 8 8. I °(b)

Arylsulphonic acids, liquid 2586 80 8 8, 34°(c)

Arylsulphonic acids, solid 2583 80 8 8, 1 °(b)

Arylsulphonic acids, solid 2585 80 8 8, 34"(c)

Barium 1400 423 4.3 4.3, 11 -(b)

Barium bromate 2719 56 5.1+6.1 5.1, 29(b)

Barium chlorate 1445 56 5.1+6.1 5.1, 29-(b)

Barium hypochlorite 2741 56 5.1+6.1 5.1. 29 0(b)

Barium nitrate 1446 56 5.1+6.1 5.1, 29*(b)

Barium oxide 1884 60 6.1 6.1, 60'(c)

Barium perchlorate 1447 56 5.1+6.1 5.1, 29 0(b)

Barium permanganate 1448 56 5.1+6.1 5.1, 29 0(b)

Barium peroxide 1449 56 5.1+6.1 5.1, 29'(b)

Battery fluid, alkali 2797 80 8 8, 42*(b)

Battery fluid, acid 2796 80 8 8, 1-(b)

Benzene 1114 33 3 3, 3"(b)

Benzenesulphonyl chloride 2225 80 8 8, 35"(c)

Benzidine 1885 60 6.1 6.1, 120b)

Benzonitrile 2224 60 6.1 6.1, 12"(b)

Benzoquinone 2587 60 6.1 6.1, 14'(b)

Benzotrichloride 2226 80 8 8, 66°(b)

Benzotrifluoride 2338 33 3 3, 3"(b)

Benzoyl chloride 1736 80 8 8, 35"(b)1.

Benzyl bromide 1737 68 6.1+8 6.1, 27°(b)

Benzyl chloride 1738 68 6.1+8 6.1, 27°(b)

Benzyl chloroformate 1739 88 8 8, 64"(a)

Benzyl iodide 2653 60 6.1 6.1, 15(b)

Benzyldimethylamine 2619 83 8+3 8, 54*(b)

Benzylidene chloride 1886 60 6.1 6.1, 15(b)

Beryllium nitrate 2464 56 5.1 +6.1 5.1, 29°(b)

Vol. 1845, A-8940

1995 391


Name of substaicc Subsawe Hazard LAbel Clu ad itemIdeniifica ion Identirication number

No. No.(Lower paW) (Upper Part)

(a) (b) (c) (d) (e)

Beryllium powder 1567 64 6:1+4.1 6.1. 54"(b)1.

Bisulpbates, aqueous solution 2837 80 8 8, 1 "(b).(c)

Blue asbestos (Crocidolite) 2212 90 9 9, 1(b)

Borneol 1312 40 4.1 4.1, 6(c)

Boron tribromide (boron bromide) 2692 X88 8 8, 12'(a)

Boron trifluoride 1008 26 6.1 2, 1 (at)

Boron trifluoride acetic acid complex 1742 80 8 8, 33"(b)

Boron trifluoride diethyl etherate 2604 883 8+3 8, 33*(a)

Boron trifluoride dihydrate 2851 80 8 8, 10*(b)

Boron trifluoride dimithyl etherate 2965 382 4.3+3+8 4.3, 2*(a)

Boron trifluoride propionic acid 1743 80 8 8, 33°(b)complex

Bromine or bromine solution 1744 886 8+6.1 8, 14°

Bromine pentafluoride 1745 568 5.1+6.1+8 5.1, 5°

Bromine trifluoride 1746 568 5.1+6.1+8 5.1. 5

2-Bromo-2-nitropropane-1,3-diol 3241 60 6.1 6.1, 17°(c)

I-Bromo-3-chloropropane 2688 60 6.1 6.1, 15'(c)

I-Bromo-3-methylbutane 2341 30 3 3, 31 °(c)

Bromoacetic acid 1938 80 8 8, 31 -(b)

Bromoacetone 1569 63 6.1+3 6.1, 16°(b)

Bromoacetyl bromide 2513 X80 8 8, 35"(b)1.

Bromobenzene 2514 30 3 3, 31'(c)

Bromobenzyl cyanides 1694 66 6.1 6.1, 17"(a)

l-Bromobutane 1126 33 3 3, 3°(bY

2-Bromobutane 2339 33 3 3, 30(b)

Bromochlorodifluoromethane (R 12BI) 1974 20 2 2. 3*(a)

Bromochloromethane 1887 60 6.1 6.1, 15°(c)

2-Bromoethyl ethyl ether 2340 33 3 3, 3*(b)

Bromoform 2515 60 6.1 6.1, 150(c)

Bromomethylpropanes 2342 33 3 3, 3"(b)

Vol. 1845, A-8940


Name of substance Subsace HUArd LAWeI Cl-sa and itemIdentification Identifica ion number

No. No.(Lower pt) (Upper pst)

(a) (b) (€) (d) (e)

2-Bromopentane 2343 33 3 3, 30(b)

Bromopropanes 2344 33 3 3. 3(b)

3-Bromopropyne 2345 33 3 3, 30(b)

Bromotrifluoromethane (R 13 BI) 1009 20 2 2, 5°(a)

Brown asbestos (Amosite or Mysorite) 2212 90 9 9. 1°(b)

Brucine 1570 66 6.1 6.1, 90°(a)

1,3-Butadiene 1010 239 3 2, 3°(c)

1,2-Butadiene 1010 239 3 2, 3°(c)

Butane, technically-pure 1011 23 3 2, 3°(b)

Butanedione (diacetyl) 2346 33 3 3, 3°(b)

Butanols 1120 33 3 3, 30(b)

Butanols 1120 30 3 3, 31 °(c)

Butoxyl 2708 30 3 3, 31 °(c)

Butyl acetates 1123 30 3 3, 31 °(c)

Butyl acetates 1123 33 3 3, 3°(b)

Butyl acid phosphate 1718 80 8 8, 38°(c)

Butyl acrylate, inhibited 2348 39 3 3, 31 °(c)

n-Butyl bromide 1126 33 3 3, 3°(b)

n-Butyl chloroformate 2743 638 6.1+3+8 6.1, 28°(b)

n-Butyl formate 1128 33 3 3, 3°(b)

tert-Butyl isocyanate 24.4. 663 6.1 + 3 6.1, 6°(a)

n-Butyl isocyanate 2485 663 6.1+3 6.1, 6°(a)

Butyl mercaptan 2347 33 3 3, 3'(b)

n-Butyl methacrylate, inhibited 2227 39 3 3, 31°(c)

Butyl methyl ether 2350 33 3 3. 3°(b)

Butyl nitrites 2351 33 3 3; 3*(b)

Butyl nitrites 2351 30 3 3, 31°(c)

Butyl propionate 1914 30 3 3, 31 °(c)

Butyl vinyl ether, inhibited 2352 339 3 3, 3°(b)

n-Butylamine 1125 338 3+8 3, 22°(b)

Vol. 1845, A-8940

394 United Nations - Treaty Series - Nations Unies - Recueil des Trait6s 1995

Name of subsumce Subtamce Hazard Label Class and itemIdentfication identdfcation number

No. No.(Lower pLt) (Upper put)

(a) (b) (e) (d) (a)

N-Butylaniline 2738 60 6.1 6.1, 12-(b)

Butylbemzenes 2709 30 3 3. 31 ° (c)

tert-Butylcyclohexyl chloroformate 2747 60 6.1 6.1, 17'(c)

1-Butylene (1-Butene) 1012 23 3 2, 3°03)

cis-2-Butylene (cis-2-Butene) 1012 23 3 2. 3°(b)

trans-2:Butylene (trans-2-Butene) 1012 23 3 2, 3°(b)

1,2-Butylene oxide, stabilized 3022 339 3 3, 3(b)

N,n-Butylimidazole 2690 60 6.1 6.1, 120b)

Butyltoluenes 2667 60 6.1 6.1, 25*(c)

Butyltrichlorosilane 1747 X83 8+3 8, 37-(b)

1,4-Butynediol 2716 60 6.1 6.1, 14*(c)

Butyraldehyde 1129 33 3 3, 3(b)

Butyraldoxime 2840 30 3 3, 31 °(c)

Butyric acid 2820 80 8 8, 32°(c)

Butyric anhydride 2739 80 8 8, 32°(c)

Butyronitrile 2411 336 3+6.1 3, 11'(b)

Butyryl chloride 2353 338 3+8 3, 25- b)

Cacodylic acid 1572 60 6.1 6.1, 510(b)

Cadmium compound 2570 66 6.1 6.1, 61 *(a)

Cadmium compound 2570 60 6.1 6.1, 61 (b),(c)

Caesium 1407 X423 4.3 4.3, 11 -(a)

Caesium hydroxide 2682 80 8 8, 41-(b)

Caesium hydroxide, solution 2681 80 8 8, 420(b),(c)

Caesium nitrate 1451 50 5.1 5.1, 22'(c)

Calcium 1401 423 4.3 4.3, 11-(b)

Calcium arsenate 1573 60 6.1 6.1..51(b)

Calcium arsenate and calcium arsenite 1574 60 6.1 6.1, 51-(b)mixture, solid

Calcium carbide 1402 423 4.3 4.3. 17'(b)

Calcium chlorate 1452 50 5.1 5.1, 11(b)

Vol. 1845, A-8940


Name of rubsunce Subsume HAzAM Label Cass and itemIdentiiction identificaion number

No. No.(Lower paLr) (Upper pa)

(a) (b) (c) (d) (e)

Calcium chlorate, aqueous solution 2429 50 5.1 5.1, 11°b)

Calcium chlorite 1453 50 5.1 5.1, 14°(b)

Calcium cyanamide 1403 423 4.3 4.3, 19-(c)

Calcium dithionite 1923 40 4.2 4.2, 13'(b)

Calcium hypochlorite mixture, dry 2208 50 5.1 5.1, 15N(c)

Calcium hypochlorite, dry 1748 50 5.1 5.1, 15(b)

Calcium hypochlorite, hydrated 2880 50 5.1 5.1, 15(b)

Calcium hypochlorite, hydrated 2880 50 5.1 5.1, 150(b)mixture

Calcium hypochlorite, mixture, dry 1748 50 5.1 5.1, 15°(b)

Calcium manganese silicon 2844 423 4.3 4.3, 12°(c)

Calcium nitrate 1454 50 5.1 5.1, 22°(c)

Calcium perchlorate 1455 50 5.1 5.1, 13 0(b)

Calcium permanganate 1456 50 5.1 5.1, 17'(b)

Calcium peroxide 1457 50 5.1 5.1, 25'(b)

Calcium resinate 1313 40 4.1 4.1, 12°(c)

Calcium resinate, fused 1314 40 4.1 4.1, 12°(c)

Calcium silicide 1405 423 4.3 4.3, 12*(b).(c)

Camphor oil 1130 30 3 3, 31°(c)

Camphor, synthetic 2717 40 4.1 4.1, 6°(c)

Caproic acid 2829 80 8 8, 32°(c)

Carbon 1"361 40 4.2 4.2, 1(b),(c)

Carbon black 1361 40 4.2 4.2, 1(b),(c)

Carbon dioxide 1013 20 2 2, 5-(a)

Carbon dioxide containing not more 1041 239 3 2, 6°(c)than 35% ethylene oxide by mass

Carbon dioxide containing not less 1014 20 2 2, 6-(a)than 1% and not more than 10%oxygen by mass

Carbon dioxide containing not more 1952 239 3 2, 6°(c)than 35% ethylene oxide by mass I _ _

Carbon dioxide, deeply-refrigerated '.187 122 12 12, 7(a)

Vol. 1845, A-8940


Name of substuce Substance H.a&Z Label Clu and itemIdentification dentificaion number

No. No.(Lower pai) (Upper pu)

(a) (b) We) (d) (e)

Carbon disulphide 1131 336 3+6.1 3, 18*(a)

Carbon monoxide 1016 236 6.1+3 2, 1 bt)

Carbon tetrabromide 2516 60 6.1 6.1, 15-(c)

Carbon tetrachloride 1846 60 6.1 6.1, 15-(b)

Carbon sulphide 1131 336 3+6.1 3. 18°(a)

Carbon, activated 1362 40 4.2 4.2, 1°(c)

Cerium 3078 423 4.3 4.3, 13-(b)

Chloral, anhydrous, inhibited 2075 60 6.1 6.1. 17 0(b)

Chlorate lnd borate mixture 1458 50 5.1 5.1, 11 -(b)

Chlorate and magnesium chloride 1459 50 5.1 5.1, 110 (b)mixture

Chloric acid, aqueous solution 2626 50 5.1 5.1, 4 0(b)

Chlorine 1017 266 6.1+8 2, 30(at)

Chlorite solution with not less than 1908 80 8 8, 61 (b),(c)16% available chlorine

1-Chloro-1,1-difluoroethane (R 142b) 2517 23 3 2, 3-(b)

l-Chloro-1,2,2,2-tetrafluoroethane 1021 20 2 2, 3°(a)(R 124)

1-Chloro-2,2,2-trifluoroethane 1983 20 2 2, 3(a)(R 133a)

3-Chloro-4-methylphenyl isocyanate 2236 60 6.1 6.1, 19'(b)

4-Chloro-o-toluidine hydrochloride 1579 60 6.1 6.1, 17-(c)

Chloroacetaldehyde 2232 66 6.1 6.1, 17°(a)

Chloroacetic acid solution 1750 68 6.1+8 6.1,,27°(b)

Chloroacetic acid, molten 3250 68 6.1+8 6.1, 24-(b)

Chloroacetic acid, solid 1751 68 6.1+8 6.1, 27'(b)

Chloroacetone, stabilized 1695 60 6.1 6.1, 17°(b)

Chloroacetonitrile 2668 63 6.1+3 6.1, 11-(b)

Chloroacetophenone 1697 60 6.1 6.1, 17'(b)

Chloroacetyl chloride 1752 668 6.1+8 6.1, 27°(a)

Chloroanilines, liquid 2019 60 6.1 6.1, 12(b)

Vol. 1845, A-8940

1995


Name of substance Substance Hazard Label Class and itemIdenification Idcetuication nmmber

No. No.(Lower piM) (Upper pau)

(a)() (c) (d) (e)

Chloroanilines, solid 2018 60 6.1 6.1, 12*(b)

Chloroanisidines 2233 60 6.1 6.1, 17-(c)

Chlorobenzene 1134 30 3 3. 31 °(c)

Chlorobenzotrifluorides (o-, m-, p-) 2234 30 3 3, 31°(c)

Chlorobenzyl chlorides 2235 60 6.1 6.1, 17*(c)

Chlorobutanes 1127 33 3 3, 3*(b)

Chlorocresols 2669 60 6.1 6.1, 14(b)

Chlorodifluoromethane (R 22) 1018 20 2 2, 3*(a)

Chlorodinitrobenzenes 1577 60 6.1 6.1, 12-(b)

Chloroform 1888 60 6.1 6.1, 15°(c)

Chloromethyl chloroformate 2745 68 6.1+8 6.1, 27'(b)

Chloromethyl ethyl ether 2354 336 3+6.1 3, 16*(b)

Chloronitroanilines 2237 60 6.1 6.1, 17°(c)

Chloronitrobenzenes 1578 60 6.1 6.1, 12*(b)

Chloronitrotoluenes 2433 60 6.1 6.1, 17°(c)

Chloropentafluoroethane (R 115) 1020 20 2 2, 3°(a)

Chlorophenolates. liquid 2904 80 8 8, 62°(c)

Chlorophenolates, solid 2905 80 8 8, 62°(c)

Chlorophenols, liquid 2021 60 6.1 6.1, 17°(c)

Chlorophenols, solid 2020 60 6.1 6.1, 17*(c)

Chlorophenyltrichlorosilane 1753 XS0 8 8, 36°(b)

Chloropicrin 1580 66 6.1 6.1, 17-(a)

Chloroplatinic acid, solid 2507 80 8 8, 16'(c)

Chloroprene, inhibited 1991 336 3+6.1 3, 16°(a)

2-Chloropropane 2356 33 3 3, 2°(a)

I-Chloropropane (Propyl chloride) 1278 33 3 3, 20(b)

3-Chloropropanol-I 2849 60 6.1 6.1, 17°(c)

2-Chloropropene 2456 33 3 3, 1 *(a)

2-Chloropropionic acid 2511 80 8 8, 32°(c)

2-Chloropyridine 2822 60 6.1 6.1, 12-(b)

Vol. 1845, A-8940


Name of subutance Substanc HUAzM LAl ClSS and itemldcntiicasion Identificaion number

No. No.(Lower p) (Upper Pt)

(a) (b) (c) (d) (c)

Chlorosulphonic acid 1754 88 8 8. 12°(a)

Chlorotoluenes (o-, m-, p-) 2238 30 3 3, 31"(c)

Cblorotoluidines 2239 60 6.1 6.1, 17°(c)

Chiorotrifluoromethane (R 13) 1022 20 2 2. 50(a)

Chromic acid, solution 1755 80 8 8, 17*(b),(c)

Chromic fluoride, solid 1756 80 8 8, 9"(b)

Chromic fluoride, solution 1757 80 8 8, 8°(b).(c)

Chromijim nitrate 2720 50 5.1 5.1. 22 °(c)

Chromium oxychloride 1758 88 8 8, 12*(a)

Chromium trioxide, anhydrous 1463 58 5.1+8 5.1, 31°(b)

Chromosulphuric acid 2240 88 8 8. 1 (a)

Coal tar distillates 1136 33 3 3. 3°(b)

Coal tar distillates 1136 30 3 3, 31°(c)

Coating solution 1139 33 3 3. 5°(a).(b),(c)

Coating solution 1139 30 3 3, 310(c)

Cobalt naphthenates, powder 2001 40 4.1 4.1, 12"(c)

Cobalt resinate, precipitated 1318 40 4.1 4.1, 12°(c)

Copper acetoarsenite 1585 60 6.1 6.1, 51 °b)

Copper arsenite 1586 60 6.1 6.1, 51°(b)

Copper chlorate 2721 50 5.1 5.1, 11(b)

Copper chloride 2802 80 8 8, I 1 (c)

Copper cyanide 1587 60 6.1 6.1. 41°(b)

Copra 1363 40 4.2 4 .2, 2"(c)

Cotton waste, oily 1364 40 4.2 4.2, 3"(c)

Cotton, wet 1365 40 4.2 4.2, 3*(c)

Cresols (o-,m-,p-) 2076 68 6.1+8 6.1, 27 -(b)

Cresylic acid 2022 68 6.1+8 6.1, 279(b)

Crotonaldehyde, stabilized 1143 663 6.1+3 6.1. 8°(a)

Crotonic acid 2823 80 8 8. 31(c)

Vol. 1845, A-8940


Name of substance Substance Hazard Label Class arn itemldentification Identification number

No. No.(Lower pan) (Upper pan)

(a) (b) (C) (d) (C)

Crotonylene (2-Butyne) 1144 339 3 3, 1 '(a)

Cupriethylenediaxnine, solution 1761 86 8+6.1 8,53°(b)(c)

Cyanogen bromide 1889 668 6.1+8 6.1, 27°(a)

Cyanuric chloride 2670 80 8 8,39°(b)

Cyclobutyl chloroformate 2744 638 6.1+3+8 6.1, 28°(b)

1,5.9-Cyclododecatriene 2518 60 6.1 6.1, 25°(c)

Cycloheptane 2241 33 3 3, 3°b)

Cycloheptatriene 2603 336 3+6.1 3, 19 0(b)

Cycloheptene 2242 33 3 3, 3°(b)

Cyclohexane 1145 33 3 3, 3b)

Cycloheptene 2242 33 3 3, 3°(b)

Cyclohexanone 1915 30 3 3, 31 °(c)

Cyclohexene 2256 33 3 3, 3 0(b)

Cyclohexenyltrichlorosilane 1762 X80 8 8, 36*(b)

Cyclohexyl acetate 2243 30 3 3, 31 °(c)

Cyclohexyl isocyanate 2488 63 6.1+3 6.1, 18°(b)

Cyclohexyl mercaptan 3054 30 3 3. 31 °(c)

Cyclohexylamine 2357 83 8+3 8, 54°(b)

Cyclohexyltrichlorosilane 1763 X80 8 8, 36°(b)

Cyclooctadienes 2520 30 3 3, 31 °(c)

Cyclooctatetraene 2358 33 3 3, 3'(b)

Cyclopentane 1146 33 3 3, 3°(b)

Cyclopentanol 2244 30 3 3, 31-(c)

Cyclopentanone 2245 30 3 3, 31-(c)

Cyclopentene 2246 33 3 3, 2'(b)

Cyclopropane 1027 23 3 2. 3(b)

Cymenes (o-, m-. p-) (Methyl 2046 30 3 3, 31°(c)isopropyl benzenes)

Decaborane 1868 46 4.1+6.1 4.1, 16°(b)

Decahydronaphthalene 1147 30 3 3, 31 (c)

Vol. 1845, A-8940


Name of substance Subm Haz LAbel Clm and itemIdentiicaion Idcntifiwation number

No. No.(Lowr p&A) (Upper p )

(a) (b) (C) (d) (e)

n-Decane 2247 30 3 3, 31 °(c)

Deuterium 1957 23 3 2, 1 °(b)

1,2-Di-(dimethylamino) ethane 2372 33 3 3. 3°(b)

Di-n-amylamine 2841 36 3+6.1 3, 32°(c)

Di-n-butylamine 2248 83 8+3 8, 54*(b)

Di-n-propyl ether 2384 33 3 3. 3°(b)

Diacetone alcohol, chemically pure 1148 30 3 3, 31 °(c)

Diacetone alcohol, technically-pure 1148 33 3 3, 3°(b)

Diallyl ether 2360 336 3+6.1 3, 17-(b)

Diallylamine 2359 338 3+8+6.1 3, 27°(b)

4,4'-Diaminodiphenylmethane 2651 60 6.1 6.1, 12°(c)

Dibenzyldichlorosilane 2434 X80 8 8, 36-(b)

Dibromobenzene 2711 30 3 3, 31 °(c)

1,2-Dibromobutan-3-one 2648 60 6.1 6.1, 17'(b)

Dibromochloropropanes 2872 60 6.1 6.1, 150(c)

Dibromomethane 2664 60 6.1 6.1, 15°(c)

Dibutyl ethers 1149 30 3 3, 31 °(c)

Dibutylaminoethanol 2873 60 6.1 6.1, 12°(c)

1,2-Dichloro-1,1,2,2-tetrafluoroethane 1958 20 2 2, 3°(a)(R 114)

1,1-Dichloro-l-nitroethane 2650 60 6.1 6.1, 17°(b)

Dichloroacetic acid 1764 80 8 8, 32-(b)1.

1,3-Dichloroacetone 2649 60 6.1 6.1,17-(b)

Dichloroacetyl chloride 1765 X80 8 8, 35-(b)1.

Dichloroanilines 1590 60 6.1 6.1, 12'(b)

o-Dichlorobenzene 1591 60 6.1 6.1, 15°(c)

2,2'-Dichlorodiethyl ether 1916 63 6.1+3 6.1, 16-(b)

Dichlorodifluoromethane (R 12) 1028 20 2 2, 3°(a)

Dichlorodifluoromethane and ethylene 3070 26 6.1 2, 4°(at)oxide mixture with not more than12% ethylene oxide by mass

Vol. 1845, A-8940


Name of substance Substance Huard Label Class and itemldentLfication ldentification number

No. No(Loer pan) (Upper part)

(M) (b) (() (d) Ce)

1,2-Dichloroethane (Ethylene 1184 336 3+6.1 3, 16°(b)dichloride)

1,1-Dichloroethane (Ethylidene 2362 33 3 3, 3°(b)chloride)

1,2-Dichloroethylene 1150 33 3 3, 3(b)

Dichlorofluoromethane (R 21) 1029 20 2 2, 3(a)

Dichloroisocyanuric acid salts 2465 50 5.1 5.1. 26°(b)

Dichloroisocyanuric acid, dry 2465 50 5.1 5.1, 260(b)

Dichloroisopropyl ether 2490 60 6.1 6.1, 17"b)

Dichloromethane 1593 60 6.1 6.1, 15'(c)

Dichloropentanes 1152 30 3 3, 31 (c)

Dichlorophenyl isocyanates 2250 60 6.1 6.1, 19°(b)

Dichlorophenyltrichlorosilane 1766 X80 8 8, 36(b)

1,2-Dichloropropane 1279 33 3 3, 3*(b)

1,3-Dichloropropanol-2 2750 60 6.1 6.1, 170 (b)

Dichloropropenes 2047 30 3 3, 31 (c)

Dichloropropenes 2047 33 3 3, 3°(b)

Dicyclohexylamine 2565 80 8 8, 53°(c)

Dicyclohexylammonium nitrite 2687 40 4.1 4.1, 11°(c)

Dicyclopentadiene 2048 30 3 3, 31 °(c)

Didymium nitrate 1465 50 5.1 5.1, 22*(c)

Diesel fuel 1202 30 3 3, 31 °(c)

Diethoxymethane 2373 33 3 3, 3-(b)

3,3-Diethoxypropene 2374 33 3 3, 3(b)

Diethyl carbonate (Ethyl carbonate) 2366 30 3 3, 31 -(c)

Diethyl ether (ethyl ether) 1155 33 3 3, 2°(a)

Diethyl ketone 1156 33 3 3, 3°(b)

Diethyl sulphate 1594 60 6.1 6.1, 14(b)

Diethyl sulphide 2375 33 3 3, 3*(b)

Diethylanine 1154 338 3+8 3, 22"0()

Diethylaminoethanol 2686 30 3 3, 31 °(c)

Vol 1845, A-8940


Name of substance Substance Hazard Label Clts and itemIdentificafion Identification number

No. No,

(Lower paft) (Upper pas)

(a) (b) (C) (d) Ce)

Diethylaminopropylamine 2684 38 3+8 3, 33°(c)

N,N-Diethylaniline 2432 60 6.1 6.1, 12°(c)

Diethylbenzenes (o-, rn-, p-) 2049 30 3 3, 31°(c)

Diethyldichlorosilane 1767 X83 8+3 8,37°(b)

Diethylenetriamine 2079 80 8 8, 53(b)

N,N-Diethylethylenediamine 2685 83 8+3 8, 54°(b)

Diethylthiophosphoryl chloride 2751 80 8 8, 35°(b)1.

Diethylzinc 1366 X333 4.2+4.3 4.2, 31 *(a)

i,1-Diflueroethane (R 152a) 1030 23 3 2, 3°(b)

,1-Difluoroethylene (Vinylidene 1959 239 3 2, 50(c)fluoride)

Difluorophosphoric acid, anhydrous 1768 80 8 8, 8°(b)

2,3-Dihydropyran 2376 33 3 3, 3°(b)

Diisobutyl ketone 1157 30 3 3, 31 °(c)

Diisobutylaznine 2361 38 3+8 3, 33*(c)

Diisobutylene, isomeric compounds 2050 33 3 3, 3°(b)

Diisooctyl acid phosphate 1902 80 8 8, 380(c)

Diisopropyl ether 1159 33 3 3, 3°(b)

Diisopropylamine 1158 338 3+8 3, 22 °(b)

Diketene, inhibited 2521 663 6.1+3 6.1, 13°(a)

1.2-Dimethoxyethane 2252 33 3 3, 3°(b)

1,1-Dimethoxyethane 2377 33 3 3. 30(b)

Dimethyl carbonate 1161 33 3 3, 3(b)

Dimethyl disulphide 2381 33 3 3, 3°(b)

Dimethyl ether 1033 23 3 2, 3'(b)

Dimethyl sulphate 1595 668 6.1+8 6.1, 270(a)

Dimethyl sulphide 1164 33 3 3, 2°(b)

Dimethyl thiophosphoryl chloride 2267 68 6.1+8 6.1, 270(b)

Dimethylamine, anhydrous 1032 236 3+6.1 2, 3(t)

Dimethylamine aqueous solution 1 160 338 3+8 3, 220(b)

Vol. 1845, A-8940


Name of ubtance Substance HAMM LAbcl Cluas and itemIdcnzi1ficaion Identification nmber

No. No.(Lower pan) (Upper p-t)

(a) (b) (€) (d) (e)

2-Dimethylaminoacetonitrile 2378 336 3+6.1 3, 11 ON)

2-Dimethylaminoethanol 2051 83 8+3 8, 54°(b)

Dimethylaminoethyl methacrylate 2522 69 6.1 6.1, 12-(b)

N,N-Dimethylaniline 2253 60 6.1 6.1, 12N(b)

2,3-Dimethylbutane 2457 33 3 3, 3°(b)

1,3-Dimethylbutylamine 2379 338 3+8 3, 22°(b)

Dimethylcarbamoyl chloride 2262 80 8 8, 35(b)1.

Dimethylcyclohexanes 2263 33 3 3, 3*(b)

Dimethylcyclohexylamine 2264 83 8+3 8, 54°(b)

Dimethyldichlorosilane 1162 X338 3+8 3, 21 °(b)

Dimethyldiethoxysilane 2380 33 3 3, 3°(b)

Dimethyldioxanes 2707 33 3 3, 3°(b)

Dimethyidioxanes 2707 30 3 3, 31 °(c)

N,N-Dimethylformamide 2265 30 3 3, 3 ! (c)

Dimethylhydrazine, symmetrical 2382 663 6.1+3 6.1, 7°(a)2.

Dimethylhydrazine, unsymmetrical 1163 663 6.1+3+8 6.1, 7°(a)l.

Dimethyl-N-propylamine 2266 338 3+8 3, 22°(b)

Dimethylzinc 1370 X333 4.2+4.3 4.2, 31 *(a)

Dinitro-o-cresol 1598 60 6.1 6.1, 12-(b)

Dinitroanilines 1596 60 6.1 6.1, 12'(b)

Dinitrobenzenes 1597 60 6.1 6.1, 12°(b)

Dinitrophenol solutions 1599 60 6.1 6.1, 120(b),(c)

Dinitrotoluenes 2038 60 6.1 6.1. 12-(b)

Dinitrotoluenes, molten 1600 60 6.1 6.1, 24(Nb)1.

Dioxane 1165 33 3 3, 3°(b)

Dioxolane 1166 33 3 3, 3°(b)

Dipentene 2052 30 3 3, 31 (c)

Diphenylamnine chloroarsine 1698 66 6.1 6.1. 34°(a)

Diphenylchloroarsine 1699 66 6.1 6.1, 34°(a)

Diphenyldichlorosilane 1769 X80 8 8, 36-(b)

Vol 1845. A-8940


Name of aubsacnce Subsace Hawd Label Clas and itemIdentification ldcntification number

No. No.(Lower part) (Upper pan)

(a) (b) (C) (d) (e)

Diphenylmethane-4,4'-diisocyanate 2489 60 6.1 6.1, 19'(c)

Diphenylmethyl bromide 1770 80 8 8, 65(b)

Dipropyl ketone 2710 30 3 3, 31 °(c)

Dipropylamine 2383 338 3+8 3, 22-(b)

Disodium trioxosilicate pentahydrate 3253 80 8 8, 41 °(c)

Divinyl ether inhibited 1167 339 3 3, 2°(a)

Dodecyltrichlorosilane 1771 X80 8 8, 36-(b)

Epibromohydrin 2558 663 6.1+3 6.1, 16°(a)

Epichlorohydrin 2023 63 6.1+3 6.1, 16°(b)

1,2-Epoxy-3-ethoxypropane 2752 30 3 3, 31 °(c)

Ethane 1035 23 3 2, 5'(b)

Ethane, deeply-refrigerated 1961 223 3 2, 7-(b)

Ethanol (Ethyl alcohol) or ethanol 1170 33 3 3, 3 0(b)(Ethyl alcohol) solutioncontaining more than 70 vol.-%alcohol

Ethanolamine or ethanolamine solution 2491 80 8 8, 53°(c)

Ethanol solution (Ethyl alcohol 1170 30 3 3, 31 °(c)solution) containing more than24 vol.-% and not more than 70vol.-% alcohol

Ethyl acetate 1173 33 3 3, 3*(b)

Ethyl acrylate, inhibited 1917 339 3 3, 3 (b)

Ethyl amyl ketones 2271 30 3 3, 31°(c)

Ethyl borate 1176 33 3 3, 3'(b)

Ethyl bromide 1891 60 6.1 6.1, 15-(b)

Ethyl bromoacetate 1603 63 6.1+3 6.1, 16°(b)

Ethyl butyl ether 1179 33 3 3, 30(b)

Ethyl butyrate 1180 30 3 3, 31 °(c)

Ethyl chloride 1037 236 3+6.1 2, 3°(bt)

Ethyl chloroacetate 1181 63 6.1+3 6.1, 16-(b)

Ethyl chloroformate 1182 663 6.1+3+8 6.1, 10°(a)

Vol. 1845, A-8940

1995 United Nations - Treaty Series * Nations Unies - Recueil des Trait&s 405

Namen of gubstance Subsance Hazard Label Clas and itemIdentification lde*ificaion number

No. No.(Lower p n) (Upper part)

(a) (b) (C) (d) te)

Ethyl chlorothiofornate 2826 80 8 8, 64 (b)

Ethyl crotonate 1862 33 3 3. 3°b)

Ethyl cyanoacetate 2666 60 6.1 6.1, 12°(c)

Ethyl formate 1190 33 3 3, 3°0b)

Ethyl isobutyrate 2385 33 3 3, 3*b)

Ethyl lactate 1192 30 3 3, 31°(c)

Ethyl mercaptan 2363 33 3+6.1 3, 2°(a)

Ethyl methacrylate 2277 339 3 3, 3*Nb)

Ethyl methyl ketone (methyl ethyl 1193 33 3 3, 3*(')ketone)

Ethyl nitrite solution 1194 336 3+6.1 3, 15*(a)

Ethyl orthoformate 2524 30 3 3, 31 °(c)

Ethyl oxalate 2525 60 6.1 6.1, 14°(c)

Ethyl propionate 1195 33 3 3, 3°b)

Ethyl propyl ether 2615 33 3 3, 3* b)

Ethyl 2-chloropropionate 2935 30 3 3, 31 °(c)

N-Ethyl-N-benzylaniline 2274 60 6.1 6.1, 12°(c)

Ethylamine. anhydrous 1036 236 3+6.1 2, 3°(bt)

Ethylamine, aqueous solution 2270 338 3+8 3, 22Nb)

N-Ethylaniline 2272 60 6.1 6.1, 120(c)

2-Ethylaniline 2273 60 6.1 6.1, 12°(c)

Ethylbenzene 1175 33 3 3, 3°b)

N-Ethylbenzyltoluidines 2753 60 6.1 6.1, 12°(c)

2-Ethylbutanol 2275 30 3 3, 31 (c)

Ethylbutyl acetate 1177 30 3 3, 31 (c)

2-Ethylbutyraldehyde 1178 33 3 3, 3.'(b)

Ethyldichloroarsine 1892 66 6.1 6.1, 34°(a)

Ethyldichlorosilane 1183 X338 4.3+3+8 4.3, 1 *(a)

Ethylene 1962 23 3 2, 5°b)

Ethylene chlorohydrin 1135 663 6.1+3 6.1, 16°(a)

Vol. 1845, A-8940


Naje of subst-.cc SubtaeAc Hazrd LAbel Class and itemIdentificaLion Idenification number

No. No.(Lowe, pan) (Upper p,)

(a) (b) (C) (d) (C)

Ethylene dibromide 1605 66 6.1 6.1, 15-(a)

Ethylene glycol diethyl ether 1153 30 3 3, 31 °(c)

Ethylene glycol monobutyl ether 2369 60 6.1 6.1, 140 (c)

Ethylene glycol monoethyl ether 1171 30 3 3, 31 -(c)

Ethylene glycol monoethyl ether 1172 30 3 3, 31 *(c)acetate

Ethylene glycol monomethyl ether 1188 30 3 3, 310(c)

Ethylene glycol monomethyl ether 1189 30 3 3, 31 (c)acetate

Ethylene oxide and propylene oxide 2983 336 3+6.1 3, 17°(a)mixture

Ethylene oxide containing more than 1041 236 3+6.1 2, 6°(ct)10% but not more than 50% carbondioxide

Ethylene oxide containing not more 1041 236 3+6.1 2, 4°(ct)

than 10% carbon dioxide by mass

Ethylene oxide with nitrogen 1040 236 3+6.1 2, 4"(ct)

Ethylene, acetylene and propylene in 3138 223 3 2, 8°(b)mixture, refrigerated liquid

Ethylene, deeply-refrigerated 1038 223 3 2, 7'(b)

Ethylenediamine 1604 83 8+3 8, 54'(b)

Ethyleneimine, inhibited 1185 663 6.1+3 6.1. 4°

2-Ethylhexyl chloroformate 2748 68 6.1+8 6.1, 270(b)

2-Ethylhexylamine 2276 38 3+8 3, 33°(c)

Ethylphenyldichlorosilane 2435 X80 8 8, 36°(b)

1-Ethylpiperidine 2386 338 3+8 3, 23°(b)

N-Ethyltoluidines 2754 60 6.1 6.1, 12-(b)

Ethyltrichlorosilane 1196 X338 3+8 3, 21 -(b)

Extracts, aromatic, liquid 1169 30 3 3, 31 °(c)

Extracts, aromatic, liquid 1169 33 3 3, 5"(a),(b),(c)

Extracts, flavouring, liquid 1197 33 3 3, 5*(a),(b),(c)

Extracts, flavouring, liquid 1197 30 3 3, 31 *(c)

Vol. 1845. A-8940


Name of substance Subce Hu~azd LAbWl Clas ad item

Idenfiicaion IdcnLfc.aion numberNo. No.

(Lower par) (Upper pal)

(a) (b) (C) (d) (')

Ferric arsenate 1606 60 6.1 6.1, 51°(b)

Ferric arsenite 1607 60 6.1 6.1, 51-(b)

Ferric chloride, anhydrous 1773 80 8 8, 11 "(c)

Ferric chloride solution 2582 80 8 8, 5 -(c)

Ferric nitrate 1466 50 5.1 5.1. 22°(c)

Ferrocerium 1323 40 4.1 4.1, 13'(b)

Ferrosilicon 1408 462 4.3+6.1 4.3, 15*(c)

Ferrous arsenate 1608 60 6.1 6.1, 51 °(b)

Ferrous metal borings, shavings, 2793 40 4.2 4.2, 12°(c)turnings or cuttings

Fluoroboric acid 1775 80 8 8, 8*(b)

Fluoroacetic acid 2642 66 6.1 6.1, 17°(a)

Fluoroanilines 2941 60 6.1 6.1, 12°(c)

Fluorobenzene 2387 33 3 3, 3(b)

Fluorophosphoric acid, anhydrous 1776 80 8 8, 8°(b)

Fluorosilicic acid 1778 80 8 8, 8'(b)

Fluorosulphonic acid 1777 88 8 8, 8'(a)

Fluorotoluenes 2388 33 3 3, 3°(b)

Formaldehyde solution 2209 80 8 8, 63*(c)

Formaldehyde solution, flammable 1198 38 3+8 3, 33-(c)

Formic acid 1779 80 8 8, 32°(b)l.

Fuel, aviation, turbine engine 1863 33 3 3, 1 *(a),2"(a),(b), 3*(b)

Fuel, aviation, turbine engine 1863 30 3 3, 31 °(c)

Fumaryl chloride 1780 80 8 8, 35-(b)1.

Furan 2389 33 3 3, 1 *a)

Furfural (furfuraldehyde) 1199 30 3 3, 31-(c)

Furfuryl alcohol 2874 60 6.1 6.1, 14°c)

Furfurylarine 2526 38 3+8 3, 330(c)

Fusel oil 1201 33 3 3, 30(b)

Fusel oil 1201 30 3 3, 31(c)

Vol 1845. A-8940

1995


Nam of gubstance Substance HazArd Label CluS WWd itcmIdentification Idenlification number

No. No.(Lower pLu) (Upper pC")

(a) (b) (C) (d) (Ce)

Gallium 2803 80 8 8, 65 -(c)

Gas mixture R 500 2602 20 2 2, 4°(a)

Gas mixture R 502 1973 20 2 2, 40(a)

Gas mixture R 503 2599 20 2 2, 6°(a)

Gas oil 1202 30 3 3, 31°(c)

Glycerol alpha-monochlorohydrin 2689 60 6.1 6.1, 17°(c)

Glycidaldehyde 2622 336 3+6.1 3, 17-(b)

Guanidine nitrate 1467 50 5.1 5.1, 22°(c)

Hafnium powder, dry 2545 40 4.2 4.2, 12°(b),(c)

Hafnium powder, wetted 1326 40 4.1 4.1, 13'(b)

Heating oil (ight) 1202 30 3 3, 31 °(c)

Helium, compressed 1046 20 2 2, 1(a)

Helium, deeply-refrigerated 1963 22 2 2, 7"(a)

n-Heptaldehyde 3056 30 3 3, 31 -(c)

Heptanes 1206 33 3 3, 3(b)

n-Heptene 2278 33 3 3, 3°(b)

Hexachloroacetone 2661 60 6.1 6.1, 170(c)

Hexachlorobenzene 2729 60 6.1 6.1, 15°(c)

Hexachlorobutadiene 2279 60 6.1 6.1, 15°(c)

Hex achlorocyclopentadiene 2646 66 6.1 6.1, 15°(a)

Hexachlorophene 2875 60 6.1 6.1, 170 (c)

Hexadecyltrichlorosilane i781 X80 8 8, 36°(b)

Hexadiene 2458 33 3 3, 3°(b)

Hexaethyl tetraphosphate 1611 60 6.1 6.1, 230(b)

Hexafluoroacetone hydrate 2552 60 6.1 6.1, 17-(b)

Hexafluoroethane (R 116) 2193 20 2 2, 5.(a)

Hexafluorophosphoric acid 1782 80 8 8, 8°(b)

Hexafluoropropylene (R 1216) 1858 26 6.1 2, 3'(at)

Hexaldhyde 1207 30 3 3, 31 °(c)

Hexamethylene diisocyanate 2281 60 6.1 6.1, 19*(b)

Vol 1845. A-8940

United Nations - Treaty Series a Nations Unies - Recueil des Traitks

Name of subsunce Substance Hazard Iabel Clus and itemIdentification Identificauon numtber

No. No(Lower part) (Upper pWu)

(a) (b) (C) (d) Ce)

Hexamethylenediamine, solid 2280 80 8 8, 52°(c)

Hexamethylenediamine, solution 1783 80 8 8, 53°(b), (c)

Hexamethyleneimine 2493 338 3+8 3, 23'(b)

Hexamethylenetetramine 1328 40 4.1 4.1, 6"(c)

Hexanes 1208 33 3 3, 3*(b)

Hexanols 2282 30 3 3, 31 °(c)

l-Hexene 2370 33 3 3, 3*(b)

Hexyltrichlorosilane 1784 X80 8 8, 36*(b)

Hydrazine, *aqueous solution 2030 86 8+6.1 8, 44°(b)

Hydrazine hydrate 2030 86 8+6.1 8, 44°(b)

Hydrazine. aqueous solution 3293 60 6.1 6.1, 65°(c)

Hydriodic acid, solution 1787 80 8 8, 5°(b),(c)

Hydrobromic acid, solution 1788 80 8 8, 5*(b),(c)

Hydrochloric acid, solution 1789 80 8 8. 5°(b),(c)

Hydrofluoric acid and sulphuric acid 1786 886 8+6.1 8, 7°(a)mixture

Hydrofluoric acid solution containing 1790 886 8+6.1 8, 7°(a)between 60 and 85% hydrogenfluoride

Hydrofluoric acid solution containing 1790 86 8+6.1 8, 70(b)less than 60% hydrogen fluoride I

Hydrofluoric acid solution containing 1790 886 8+6.1 8, 60more than 85% hydrogen fluoride

Hydrogen bromide 1048 286 8+6.1 2, 3°(at)

Hydrogen chloride 1050 286 8+6.1 2, 5"(at)

Hydrogen cyanide, aqueous solution 1613 663 6.1+3 6.1, 2(Hydrocyanic acid)

Hydrogen cyanide, solution in alcohol 3294 663 6.1+3 6.1, 2

Hydrogen fluoide, anhydrous 1052 886 8+6.1 8, 6

Hydrogen peroxide and peroxyacetic 3149 58 5.1+8 5.1, l(b)acid mixture, stabilized

Hydrogen peroxide, aqueous solution 2014 58 5.1+8 5.1, 1 (b)

Vol. 1845, A-8940

United Nations - Treaty Series 9 Nations Unies - Recueil des Traitis

Name of substance Substance HAzard Label Class and itemIdentification Idcntification number

No. No.(Lower p#A) (Upper pmA)

(a) (b) (e) (d) (C)

Hydeogen peroxide. aqueous solution 2984 50 5.1 5.1, 1-(c)

Hydrogen peroxide, aqueous solution, 2015 559 5.1+8 5.1, 1°(a)stabilized

Hydrogen peroxide, stabilized 2015 559 5.1+8 .5.1, 1°(a)

Hydrogen sulphide 1053 236 3+6.1 2, 3"(bt)

Hydrogen, compressed 1049 23 3 2, 1 o(b)

Hydrogen, deeply-refrigerated 1966 223 3 2, 7'(b)

Hydroquinone 2662 60 6. 1 6.1, 14*(c)

Hydroxylamnine sulphate 2865 80 8 8, 16°(c)

Hypochlorite solution with between 1791 80 8 8, 61°(b),(c)5 and 16% active chlbrine

3,3'-Iminodipropylamine 2269 80 8 8, 53°(c)

Iodine monochloride 1792 80 8 8, 12°(b)

Iodine pentafluoride 2495 568 5.1+6.1+8 5.1, 50

2-1odobutane 2390 33 3 3, 35 (b)

Iodomethylpropanes 2391 33 3 3, 3*(b)

Iodopropanes 2392 30 3 3, 31 °(c)

Iron oxide, spent 1376 40 4.2 4.2, 16°(c)

Iron pentacarbonyl 1994 663 6.1+3 6.1, 3

Iron sponge, spent 1376 40 4.2 4.2, 16°(c)

Isobutane 1969 23 3 2, 3*(b)

Isobutanol 1212 30 3 3, 31 "(c)

Isobutyl acetate 1213 33 3 3, 3'(b)

Isobutyl acrylate, inhibited 2527 39 3 3, 31 °(c)

Isobutyl formate 2393 33 3 3, 3'(b)

Isobutyl isobutyrate 2528 30 3 3, 31 °(c)

Isobutyl isocyanate 2486 336 3+6.1 3, 14°(b)

Isobutyl methacrylate, inhibited 2283 39 3 3, 31 (c)

Isobutyl propionate 2394 33 3 3, 3°(b)

Isobutylamine 1214 338 3+8 3, 22'(b)

Isobutylene 1055 23 3 2, 3(b)

Vol 1845, A-8940

410


Name of substnce Subswace Haad Label Class and trmIdentification Identsication number

No. No.(Lower p&) (Upper pan)

(a) (b) (C) (d)e)

Isobutyraldehyde 2045 33 3 3, 3(b)

Isobutyric acid 2529 38 3+8 3, 33-(c)

Isobutyric anhydride 2530 38 3+8 3, 33*(c)

Isobutyronitrile 2284 336 3+6.1 3, 11 °(b)

Isobutyryl chloride 2395 338 3+8 3. 250(b)

Isocyanatobenzotrifluorides 2285 63 6.1+3 6.1, 18"(b)

Isoheptene 2287 33 3 3, 3-(b)

Isohexene 2288 33 3 3. 3*(b)

Isooctenes 1216 33 3 3, 3*(b)

Isopentenes 2371 33 3 3, 1 *(a)

Isophorone diisocyanate 2290 60 6.1 6.1, 19°(c)

Isophoronediarnine 2289 80 8 8, 53°(c)

Isoprene, inhibited 1218 339 3 3, 2°(a)

Isopropanol (Isopropyl alcohol) 1219 33 3 3, 3°(b)

Isopropenyl acetate 2403 33 3 3, 3*(b)

Isopropenylbenzene 2303 30 3 3. 31 °(c)

Isopropyl 2-chloropropionate 2934 30 3 3, 31 °(c)

Isopropyl acetate 1220 33 3 3, 30(b)

Isopropyl acid phosphate 1793 80 8 8, 38*(c)

Isopropyl butyrate 2405 30 3 3, 31 *(c)

Isopropyl chloroacetate 2947 30 3 3, 31 '(c)

Isopropyl isobutyrate 2406 33 3 3, 3-(b)

Isopropyl isocyanate 2483 336 3+6.1 3, 14°(a)

Isopropyl propionate 2409 33 3 3, 3"(b)

Isopropylamine 1221 338 3+8 3, 22'(a)

Isopropylbenzene (Cumene) 1918 30 3 3, .3i°(c)

Kerosene 1223 30 3 3, 31 (c)

Krypton, compressed 1056 20 2 2. l'(a)

Krypton, deeply-refrigerated 1970 22 2 2, 7*(a)

Lead acetate 1616 60 6.1 6.1. 62"(c)

Vol. 1845. A-8940


Name of substajcc Substuce HAd Labl Clss and itemIdetifiaion Ide ificalion number

No. No.

(Lowr pL, ) (Upper pW)(a) (b) (C) (d) (e)

Lead arsenates 1617 60 6.1 6.1, 51(b)

Lead arsenites 1618 60 6.1 6.1, 51 (b)

Lead cyanide 1620 60 6.1 6.1, 41(b)

Lead dioxide 1872 56 5.1+6.1 5.1, 29°(c)

Lead nitrate 1469 56 5.1+6.1 5.1. 29°(c)

Lead perchlorate 1470 56 5.1+6.1 5.1, 29(b)

Lead phosphite, dibasic 2989 40 4.1 4.1, 110(b),(c)

Lead sulphate 1794 80 8 8, 1 b)

Lithium 1415 X423 4.3 4.3, 11 *(a)

Lithium alkyls 2445 X333 4.2+4.3 4.2, 31*(a)

Lithium ferrosilicon 2830 423 4.3 4.3, 12-(b)

Lithium hydride, fused solid 2805 423 4.3 4.3, 16-(b)

Lithium hydroxide, monohydrate 2680 80 8 8, 41°(b)

Lithium hydroxide, solution 2679 80 8 8, 42°(b),(c)

Lithium hypochlorite, mixture or dry 1471 50 5.1 5.1, 15°(b)

Lithium nitrate 2722 50 5.1 5.1, 22°(c)

Lithium peroxide 1472 50 5.1 5.1, 25-(b)

Lithium silicon 1417 423 4.3 4.3, 12'(b)

London purple 1621 60 6.1 6.1, 51 -b)

Magnesium 1869 40 4.1 4.1, 13°(c)

Magnesium alkyls 3053 X333 4.2+4.3 4.2, 31'(a)

Magnesium alloys 1869 40 4.1 4.1, 13°(c)

Magnesium arsenate 1622 60 6.1 6.1, 51-(b)

Magnesium bromate 1473 50 5.1 5.1, 16-(b)

Magnesium chlorate 2723 50 5.1 5.1, 11-(b)

Magnesium diamide 2004 40 4.2 4.2, 16-(b)

Magnesium diphenyl 2005 X333 4.2+4.3 4.2, 31 *(a)

Magnesium fluorosilicate 2853 60 6.1 6.1, 64-(c)

Magnesium granules, coated 2950 423 4.3 4.3, 11 °(c)

Magnesium nitrate 1474 50 5.1 5.1, 22*(c)

Vol. 1845, A-8940


Name of substance Subtance Hazard Label Clus and itemIdentification Identification number

No. No.(Lower par) (Upper pWr)

(a) (b) (C) cd) (€)

Magnesium perchlorate 1475 50 5.1 5.1, 13-()

Magnesium peroxide 1476 50 5.1 5.1, 25-(b)

Magnesium powder 1418 423 4.3+4.2 4.3, 14°(b)

Magnesium silicide 2624 423 4.3 4.3, 12°(b)

Maleic anhydride 2215 80 8 8, 31°(c)

Malononitrile 2647 60 6.1 6.1, 12"(b)

Maneb 2210 40 4.2+4.3 4.2, 160(c)

Maneb preparation 2210 40 4.2+4.3 4.2, 160(c)

Maneb preparation, stabilized 2968 423 4.3 4.3, 200(c)

Maneb, stabilized 2968 423 4.3 4.3, 20°(c)

Manganese nitrate 2724 50 5.1 5.1, 22°(c)

Manganese resinate 1330 40 4.1 4.1, 12°(c)

Mercuric arsenate 1623 60 6.1 6.1, 51°(b)

Mercuric chloride 1624 60 6.1 6.1, 52*(b)

Mercuric nitrate 1625 60 6.1 6.1, 52*(b)

Mercurous nitrate 1627 60 6.1 6.1, 52*(b)

Mercury 2809 80 8 8, 660(c)

Mercury acetate 1629 60 6.1 6.1, 52°(b)

Mercury ammonium chloride 1630 60 6.1 6.1, 52-(b)

Mercury benzoate 1631 60 6.1 6.1, 520(b)

Mercury bromides 1634 60 6.1 6.1, 52°(b)

Mercury cyanide 1636 60 6.1 6.1, 41°(b)

Mercury gluconate 1637 60 6.1 6.1, 52-(b)

Mercury iodide 1638 60 6.1 6.1, 52°(b)

Mercury nucleate 1639 60 6.1 6., 52"(b)

Mercury oleate 1640 60 6.1 6.1, 52°(b)

Mercury oxide 1641 60 6.1 6.1. 52*(b)

Mercury oxycyanide, desensitized 1642 60 6.1 6.1, 41 °(b)

Mercury potassium iodide 1643 60 6.1 6.1, 52°(b)

Mercury salicylate 1644 60 6.1 6.1, 52°(b)

Vol. 1845, A-8940

413


Name of xubstanece Substance Hazard LAbel CLus and itemIdentiication Identirication number

No. No.

(Lower pail) (Upper part)

(a) (b) (c) (d) ()

Mercury sulphate 1645 60 6.1 6.1, 52*(b)

Mercury thiocyanate 1646 60 6.1 6.1, 52 0(b)

Mesityl oxide 1229 30 3 3, 31°(c)

Metal catalyst, dry 2881 40 4.2 4.2, 1200b),(c)

Metal catalyst, wetted 1378 40 4.2 4.2, 12"b)

Metaldehyde 1332 40 4.1 4.1, 6°(c)

Methacrylaldehyde, inhibited 2396 336 3+6.1 3, 17°(b)

Methacrylic acid, inhibited 2531 89 8 8, 32°(c)

Methacrylonitrile, inhibited 3079 336 3+6.1 3, 11°(a)

Methallyl alcohol 2614 30 3 3, 31 °(c)

Methane, compressed 1971 23 3 2, 1°(b)

Methane, deeply-refrigerated 1972 223 3 2, 7°(b)

Methanesulphonyl chloride 3246 668 6.1+ 8 6.1, 27°(a)

Methanol 1230 336 3+6.1 3, 17-(b)

1-Methoxy-2-propanol 3092 30 3 3, 31 °(c)

4-Mehoxy-4-methylpentan-2-one 2293 30 3 3, 31 °(c)

Methoxymethyl isocyanate 2605 336 3+6.1 3, 14°(a)

Methyl acetate 1231 33 3 3, 3-b)

Methyl acrylate, inhibited 1919 339 3 3, 3°(b)

Methyl benzoate 2938 60 6.1 6.1, 14°(c)

Methyl bromide 1062 26 6.1 2, 30(at)

Methyl bromide and ethylene 1647 66 6.1 6.1, 15°(a)dibromide mixture, liquid

Methyl bromoacetate 2643 60 6.1 6.1, 17"b)

Methyl butyrate 1237 33 3 3, 3°(b)

Methyl chloride 1063 236 3+6.1 2, 3°(bt)

Methyl chloroacetate 2295 63 6.1+3 6.1, 16*0b)

Methyl chloroformate 1238 663 6.1+3+8 6.1, lO°(a)

Methyl chloromethyl ether 1239 663 6.1+3 6.1, 9°(a)

Methyl dichloroacetate 2299 60 6.1 6.1, 170(c)

Vol. 1845, A-8940


Name of substance Substncc HaZld LAbel Cliss and itemIdentification Identificution number

No. No.(Lower ptt) (Upper pan)

(a) (b) (C) (d) (C)

Methyl formate 1243 33 3 3, 1 *(a)

Methyl iodide 2644 60 6.1 6.1, 15*(b)

Methyl isobutyl carbinol 2053 30 3 3, 31 °(c)

Methyl isobutyl ketone 1245 33 3 3, 3'(b)

Methyl isopropenyl ketone, inhibited 1246 339 3 3, 3*(b)

Methyl isothiocyanate 2477 63 6.1+3 6.1, 20-(b)

Methyl isovalerate 2400 33 3 3, 30(b)

Methyl magnesium bromide in ethyl 1928 X323 4.3+3 4.3, 30(a)ether,

Methyl mercaptan 1064 236 3+6.1 2, 3(bt)

Methyl methacrylate monomer, 1247 339 3 3, 3-(b)inhibited

Methyl orthosilicate 2606 663 6.1+3 6.1, 8°(a)

(Tetramethoxysilane)

Methyl propionate 1248 33 3 3, 3*(b)

Methyl propyl ether 2612 33 3 3, 2-(b)

Methyl propyl ketone 1249 33 3 3, 3 (b)

Methyl ten-butyl ether 2398 33 3 3, 3-(b)

Methyl trichloroacetate 2533 60 6.1 6.1, 17*(c)

Methyl vinyl ether 1087 236 3+6.1 2, 3°(ct)

Methyl vinyl ketone 1251 339 3 3, 3°(b)

2-Methyl-l-butene 2459 33 3 3, 1*(a)

3-Methyl-l-butene (Isopropylethylene) 2561 33 3 3, 1*(a)

2-Methyl-2-butene 2460 33 3 3. 2'(b)

Methyl 2-chloropropionate 2933 30 3 3, 31 (c)

2-Methyl-5-ethylpyridine 2300 60 6.1 6.1, 12°(c)

Methylal 1234 33 3 3, 2-(b)

Methylallyl chloride 2554 33 3 3, 3°(b)

Methylamine. anhydrous 1061 236 3+6.1 2, 3(bt)

Methylamine, aqueous solution 1235 338 3+8 3, 22°(b)

Methylamyl acetate 1233 30 3 3, 31°(c)

Vol 1845, A-8940


Name of substance Substance HZAd Label CLas and itemIdcrnificazion Idcritrwaion number

No. No.(Lower pu,) (Upper WaL )

(a) (b) (c) (d) (e)

N-Methylaniline 2294 60 6.1 6.1, 12°(c)

alpha-Methylbeozyl alcohol 2937 60 6.1 6.1, 14*(c)

3-Methylbutan-2-one 2397 33 3 3. 30(b)

N-Methylbutylamine 2945 338 3+8 3, 22(b)

Methylcyclohexane 2296 33 3 3, 30(b)

Methylcyclohexanols 2617 30 3 3. 31 °(c)

Methylcyclohexanones 2297 30 3 3, 31 °(c)

Methylcyclopentane 2298 33 3 3, 30(b)

Methyldichlorosilane 1242 X338 4.3+3+8 4.3, 1*(a)

2-Methylfuran 2301 33 3 3, 3°(b)

5-Methylhexan-2-one 2302 30 3 3. 31 (c)

Methylhydrazine 1244 663 6.1+3+8 6.1, 7°(a)l.

Methylmorpholine 2535 338 3+8 3, 23°(b)

Methylpentadiene 2461 33 3 3. 3°(o)

2-Methylpentan-2-ol 2560 30 3 3, 31 °(c)

Methylphenyldichlorosilane 2437 X80 8 8, 36-(b)

1-Methylpiperidine 2399 338 3+8 3, 23-(b)

Methyltetrahydrofuran 2536 33 3 3, 3'(b)

Methyltrichlorosilane 1250 X338 3+8 3, 21 *(a)

alpha-Methylvaleraldehyde 2367 33 3 3, 3*(b)

Mixtures Fl, F2 and F3 1078 20 2 2, 40(a)

Mixtures of 1,3-butadiene and 1010 239 3 2, 4"(c)hydrocarbons

Mixtures of hydrocarbons (liquefied 1965 23 3 2, 4-(b)gases)(Mixtures A, AO, Al, B andC)

Mixtures of methyl bromide and 1581 26 6.1 2, 4"(ai)chloropicrin (liquefied gas)

Mixtures of methyl bromide and 1647 236 3+6.1 2.4°(bt)ethylene bromide

Mixtures of methyl chloride and 1582 236 3+6.1 2.4°(bt)chloropicrin (liquefied gas)

Vol. 1845. A-8940

1995


Name of substance Substance Hazard Label Clas and itemIdentification Identification number

No. No.(Lower pWA) (Upper put)

(a) (b) (C) (d) (e)

Mixtures of methyl chloride and 1912 236 3+6.1 2, 4(bt)methylene chloride (liquefied gas) I

Mixtures of methylacetylene and 1060 239 3 2, 4°(c)propadiene with hydrocarbons '1

Molybdenum pentachloride 2508 80 8 8, 11 °(c)

Morpholine 2054 30 3 3, 31 -(c)

Motor fuel anti-knock mixture 1649 66 6.1 6.1, 31 *(a)

Motor spirit 1203 33 3 3, 3°(b)

Naphthalene, crude or refined 1334 40 4.1 4.1, 6°(c)

Naphthalene, molten 2304 44 4.1 4.1, 5O

beta-Naphthylamine 1650 60 6.1 6.1, 12°(b)

alpha-Naphthylamine 2077 60 6.1 6.1, 120(c)

Naphthylthiourea 1651 60 6.1 6.1, 21-(b)

Naphhylurea 1652 60 6.1 6.1, 12°(b)

Natural gas, compressed 1971 23 3 2, 2°(b)

Natural gas, deeply-refrigerated 1972 223 3 2, 8*(b)

Neon, compressed 1065 20 2 2, 1 *(a)

Neon, deeply-refrigerated 1913 22 2 2, 7°(a)

Nickel carbonyl 1259 663 6.1+3 6.1, 3*

Nickel cyanide 1653 60 6.1 6.1, 41-(b)

Nickel nitrate 2725 50 5.1 5.1, 22°(c)

Nickel nitrite 2726 50 5.1 5.1, 23o(c)

Nicotine 1654 60 6.1 6.1, 90°(b)

Nicotine hydrochloride or nicotine 1656 60 6.1 6.1, 90(b)hydrochloride solution I

Nicotine salicylate 1657 60 6.1 6.1, 90°(b)

Nicotine sulphate, solid 1658 60 6.1 6.1: 900b)

Nicotine sulphate, solution 1658 60 6.1 6.1, 90°(b)

Nicotine tartrate 1659 60 6.1 6.1, 90 0(b)

Nitrating acid mixture, spent, 1826 80 8 8, 3(b)containing less than 50% nitric acid I I

Vol. 1845, A-8940

418 United Nations - Treaty Series o Nations Unies - Recueil des Trait~s

Name of substance Substance HazArd Label Cus and itemIdentficafion Identificstion number

No. No.(Lower part) (Upper part)

(a) (b) (€) (d) (c)

Nitrating acid mixture, spent, 1826 885 8+05 8, 3°(a)containing more than 50% nitric acid

Nitrating acid, mixture containing less 1796 80 8 8, 3°(b)than 50% nitric acid

Nitrating acid, mixture containing 1796 885 8+05 8, 3(a)more than 50% nitric acid

Nitric acid containing less than 70% 2031 80 8 8, 2°(b)pure acid

Nitric acid containing more than 70% 2031 885 8 8, 2°(a)l.pure acid

Nitric acia, red fuming 2032 856 8+05+6.1 8, 2°(a)2.

3-Nitro-4-chlorobenzotrifluoride 2307 60 6.1 6.1, 12°(b)

Nitroanilines (o-, m-, p-) 1661 60 6.1 6.1, 12°(b)

Nitroanisole 2730 60 6.1 6.1, 12°(c)

Nitrobenzene 1662 60 6.1 6.1, 12°(b)

Nitrobenzenesulphonic acid 2305 80 8 8, 34°(b)

Nitrobenzotrifluorides 2306 60 6.1 6.1, 12°(b)

Nitrobromobenzene 2732 60 6.1 6.1, 12°(c)

Nitrocellulose solution, flammable 2059 33 3 3, 4(a),(b)

Nitrocellulose solution, flammable 2059 30 3 3, 34°(c)

Nitrocresols (o-, m-, p-) 2446 60 6.1 6.1, 12°(c)

Nitroethane 2842 30 3 3, 31 °(c)

Nitrogen dioxide (NO 2) 1067 265 6.1+05 2, 3°(at)

Nitrogen, compressed 1066 20 2 2, 1 *(a)

Nitrogen, deeply-refrigerated 1977 22 2 2, 7°(a)

Nitronaphthalene 2538 40 4.1 4.1, 6°(c)

Nitrophenols 1663 60 6.1 6.1, 12°(c)

Nitropropanes 2608 30 3 3, 31 "(c)

p-Nitrosodimethylaniline 1369 40 4.2 4.2, 50(b)

Nitrosylsulphuric acid 2308 80 8 8, 1 °(b)

Nitrotoluenes (o-, m-, p-) 1664 60 6.1 6.1, 12°(b)

Nitrotoluidines (rn.ono) 2660 60 6.1 6.1, 12°(c)

Vol. 1845, A-8940

1995


NLme of substance Subsunce HWArd Label Class and stemldcntificaion Identificaion number

No. No.

(Lower paen) (Upper paLe)

(a) (b) (C) (d) (e)

Nitrous oxide (N20) 1070 25 2+05 2, 5*(a)

Nitrous oxide, deeply-refrigerated 2201 225 2+05 2, 7*(a)

Nitroxylenes (o-, m-, p-) 1665 60 6.1 6.1, 12"(b)

Nonanes 1920 30 3 3, 31 *(c)

Nonyltrichlorosilane 1799 X80 8 8, 36*(b)

2,5-Norbornadiene 2251 339 3 3, 3(b)(Dicycloheptadiene), inhibited

Octadecyltrichlorosilane 1800 X80 8 8, 36*(b)

Octadiene. 2309 33 3 3, 3°(b)

Octafluorocyclobutane (RC 318) 1976 20 2 2, 3*(a)

Octanes 1262 33 3 3, 30(b)

Octyl aldehydes (ethyl hexaldehydes) 1191 30 3 3, 31°(c)

tert-Octyl mercaptan 3023 63 6.1+3 6.1, 200(b)

Octyltrichlorosilane 1801 X80 8 8, 36'(b)

Oxygen, compressed 1072 20 2+05 2, 1 *(a)

Oxygen, deeply-refrigerated 1073 225 2+05 2, 7*(a)

Paint 1263 30 3 3, 31"(c)

Paint 1263 33 3 3, 5"(a),(b),(c)

Paint or paint related material 3066 80 8 8, 66(b),(c)

Paint related material 1263 30 3 3, 31"(c)

Paint related material 1263 33 3 3, 5"(a),(b),(c)

Paper, unsaturated oil treated 1379 40 4.2 4.2, 3"(c)

Paraformaldehyde 2213 40 4.1 4.1, 6"(c)

Paraldehyde 1264 30 3 3, 31*(c)

Pentaborane 1380 333 4.2+6.1 4.2, 19*(a)

Pentachloroethane 1669 60 6.1 6.1, 15"(b)

Pentachlorophenol 3155 60 6.1 6.1, 17"(b)

Pentafluoroethane (R 125) 3220 20 2 2, 5*(a)

Pentamethylheptane (Isododecane) 2286 30 3 3, 31"(c)

Pentan-2,4-dione 2310 30 3 3, 31"(c)

Vol 1845, A-8940

419


Name of substace Substance Hazard LAbe Class and itemIdentification IdentifLcaion number

No. No.(Lower pLil) (Upper Part)

(a) (b) (c) (d) (e)

Pentanes, liquid 1265 33 3 3, 1*(a)

Pentanes, liquid 1265 33 3 3, 2-(b)

l-Pentene (n-Amylene) 1108 33 3 3, 1 *(a)

I-Pentol 2705 80 8 8, 66°(b)

Perchloric acid 1802 85 8 8, 4-(b)

Perchloric acid, with more than 1873 558 5.1+8 5.1, 3°(a)50% but not more than 72% acid,by mass

Perchloromethyl mercaptan 1670 66 6.1 6.1, 17'(a)

Perfumery products 1266 33 3 3, 5°(a),(b),(c)

Perfumery products 1266 30 3 3, 31 °(c)

Petroleum crude oil 1267 33 3 3, 1 *(a),2 * (a),(b), 3°(b)

Petroleum crude oil 1267 30 3 3, 31 °(c)

Phenacyl bromide 2645 60 6.1 6.1, 17'(b)

Phenetidines 2311 60 6.1 6.1, 12°(c)

Phenol solution 2821 60 6.1 6.1, 14(b),(c)

Phenol, molten 2312 60 6.1 6.1, 24°(b)

Phenol, solid 1671 60 6.1 6.1, 14(b)

Phenolates, liquid 2904 80 8 8. 620(c)

Phenolates, solid 2905 80 8 8, 620(c)

Phenolsulphonic acid, liquid 1803 80 8 8, 34°(b)

Phenyl chloroformate 2746 68 6.1+8 6.1, 27-(b)

Phenyl isocyanate 2487 63 6.1+3 6.1, 18°(b)

Phenyl mercaptan 2337 663 6.1+3 6.1, 200(a)

Phenylacetonitrile, liquid 2470 60 6.1 6.1, 12°(c)

Phenylacetyl chloride 2577 80 8 8, 35°(b)1.

Phenylcarbylamine chloride 1672 66 6.1 6.1, 17°(a)

Phenylenediamines (o-, m-, p-) 1673 60 6.1 6.1, 12°(c)

Phenylhydrazine 2572 60 6.1 6.1, 12-(b)

Phenylmercuric acetate 1674 60 6.1 6.1, 33-(b)

Vol. 1845. A-8940

United Nations - Treaty Series * Nations Unies - Recuel des Trait6s

Name of substance Substance HId LAbe Claus an itemIdnwfication Idenification number

No. No.(Lower pan) (Upper PWn)

(a) (b) (c) (d) (e)

Phenylmercuric hydroxide 1894 60 6.1 6.1, 33 '(b)

Phenylmercuric nitrate 1895 60 6.1 6.1, 33°(b)

Phenylphosphorus dichloride 2798 80 8 8, 35°0b)1.

Phenylphosphorus thiodichloride 2799 80 8 8, 35"(b)1.

Phenyltrichlorosilane 1804 X80 8 8, 360(N)

Phosgene 1076 266 6.1+8 2, 3*(at)

9-Phosphabicyclononanes 2940 40 4.2 4.2, 5"(b)(cyclooctadiene phosphines)

Phosphbric acid 1805 80 8 8, 17"(c)

Phosphorous acid 2834 80 8 8, 16°(c)

Phosphorus oxychloride 1810 80 8 8, 12*(b)

Phosphorus, white or yellow, dry 1381 46 4.2+6.1 4.2, 11*(a)

Phosphorus heptasulphide 1339 40 4.1 4.1, I1 -b)

Phosphorus oxybromide 1939 80 8 8, 11 °(b)

Phosphorus oxybromide, molten 2576 80 8 8, 15-

Phosphorus pentabromide 2691 80 8 8, 11 °b)

Phosphorus pentachloride 1806 80 8 8, 11 °b)

Phosphorus pentasulphide 1340 423 4.3 4.3, 20(b)

Phosphorus pentoxide 1807 80 8 8, 16N(b)

Phosphorus sesquisulphide 1341 40 4.1 4.1, 11b)

Phosphorus tribromide 1808 80 8 8, 12-(b)

Phosphorus trichloride 1809 886 8+6.1 8, 12*(a)

Phosphorus trioxide 2578 80 8 8, 16@(c)

Phosphorus trisulphide 1343 40 4.1 4.1, 11-(b)

Phosphorus, amorphous 1338 40 4.1 4.1, ll(c)

Phosphorus, white or yellow, molten 2447 446 4.2+6.1 4.2, 22*

Phthalic anhydride 2214 80 S 8, 31°(c)

Picolines 2313 30 3 3, 31"(c)

Pine oil 1272 30 3 3, 31 *(c)

alpha-Pinene 2368 30 3 3, 31 *(c)

Vol. 1845, A-8940


Name of substance Substance Hazard Label Clas and item

ldenxification IdeAitfrwation numberNo. No

('Lowrpan) (upper pan)

(a) (b) (C) (d) (e)

Piperazine 2579 80 8 8, 52°(c)

Piperidine 2401 338 3+8 3, 23*(b)

Polycdorinated biphenyls 2315 90 9 9. 2*(b)

Polyhalogenated biphenyls, liquid 3151 90 9 9. 2°(b)

Polyhalogenated biphenyls, solid 3152 90 9 9. 2'(b)

Polyhalogenated terphenyls, liquid 3151 90 9 9, 20(b)

Polyhalogenated terphenyls, solid 3152 90 9 9, 20(b)

Polymeric beads, expandable 2211 90 9 9, 4°(c)

Potassium 2257 X423 4.3 4.3, 11 *(a)

Potassium arsenate 1677 60 6.1 6.1, 51 e(b)

Potassium arsenite 1678 60 6.1 6.1, 510(b)

Potassium bromate 1484 50 5.1 5.1, 16*(b)

Potassium chlorate 1485 50 5.1 5.1, 110(b)

Potassium chlorate aqueous solution 2427 50 5.1 5.1, 11-(b)

Potassium cuprocyanide 1679 60 6.1 6.1, 41-(b)

Potassium dithionite 1929 40 4.2 4.2, 13-(b)

Potassium fluoride 1812 60 6.1 6.1. 630(c)

Potassium fluoroacetate 2628 66 6.1 6.1, 17°(a)

Potassium fluorosilicate 2655 60 6.1 6.1, 64(c)

Potassium hydrogen sulphate 2509 80 8 8, 13'(b)

Potassium hydrogendifluoride 1811 86 8+6.1 8, 9"(b)

Potassium hydroxide solution 1814 80 8 8, 42e(b),(c)

Potassium hydroxide, solid 1813 80 8 8, 41 '(b)

Potassium metal alloys 1420 X423 4.3 4.3, 11-(a)

Potassium metavanadate 2864 60 6.1 6.1, 58*(b)

Potassium monoxide 2033 80 8 8, 41'(b)

Potassium nitrate 1486 50 5.1 5.1, 22°(c)

Potassium nitrate and sodium nitrite 1487 50 5.1 5.1, 24°(b)mixtures

Potassium nitrite 1488 50 5.1 5.1, 23°(b)

Vol. 1845, A-8940


Name of substAnce Substance Hazard Label Chls and item

Identificaion ldentification numberNo. No.

(Lower par,) (Upper pa)

(a) (b) () (d) ()

Potassium perchlorate 1489 50 5.1 5.1, 13°b)

Potassium permanganate 1490 50 5.1 5.1, 17°b)

Potassium persulphate 1492 50 5.1 5.1, 18-(c)

Potassium sodium alloys 1422 X423 4.3 4.3, 1l°(a)

Potassium sulphide, anhydrous 1382 40 4.2 4.2, 13'(b)

Potassium sulphide, hydrated 1847 80 8 8, 45(b)1.

Potassium sulphide, with tess than 1382 40 4.2 4.2, 13-(b)30% water of crystallisation

Printing ink 1210 33 3 3,5°(a),(b),(c)

Printing ink 1210 30 3 3,31 °(c)

Propane, technically-pure 1978 23 3 2, 3(b)

Propanethiols (propyl mercaptans) 2402 33 3 3, 3°(b)

n-Propanol 1274 33 3 3. 3(b)

n-Propanol 1274 30 3 3, 31 °(c)

Propionadehyde 1275 33 3 3, 3°b)

Propionic acid 1848 80 8 8, 32°(c)

Propionic anhydride 2496 BC 8 8, 32°(c)

Propionitrile 2404 336 3+6.1 3, 11(b)

Propionyl chloride 1815 338 3+8 3, 25'(b)

n-Propyl acetate 1276 33 3 3, 3*(b)

n-Propyl chloroformate 2740 668 6.1+8+3 6.1, 28°(a)

Propyl formates 1281 33 3 3, 3(b)

n-Propyl isocyanate 2482 663 6.1+3 6.1, 6°(a)

Propylamine 1277 338 3+8 3, 22'(b)

n-Propylbenzene 2364 30 3 3, 31 °(c)

Propylene 1077 23 3 2, 3°b)

Propylene chlorohydrin 2611 63 6.1+3 6.1, 16'(b)

Propylene oxide, inhibited 1280 339 3 3, 2°(a)

Propylene tetramer 2850 30 3 3, 31 °(c)

1,2-Propylenediamine 2258 83 8+3 8, 54*(b)

Vol. 1845. A-8940

424 United Nations - Treaty Series e Nations Unies - Recueil des Trait~s 1995

Name of aubswce Substance Ha.rd LAbWl Cluas and stem

Identifie aion Idenhs'scion numberNo. No.

(Lower Wan) (Upper paW)(a) (b) (e) (d) (C)

Propyleneimine, inhibited 1921 336 3+6.1 3, 12*

Propyhtrichlorosilane 1816 X83 8+3 8, 37"(b)

Pyridine 1282 33 3 3, 3"(b)

Pyrosulphuryl chloride 1817 80 8 8. 120(b)

Pyrrolidine 1922 338 3+8 3, 23"(b)

Quinoline 2656 60 6.1 6.1, 12*(c)

Resin solution, flammable. 1866 33 3 3, 5(a),(b),(c)

Resin solution, flammable 1866 30 3 3, 31*(c)

Resorcinol 2876 60 6.1 6.1, 14°(c)

Rosin oil 1286 30 3 3, 310(c)

Rosin oil 1286 33 3 3, 5"(a),(0),(c)

Rubber scrap or shoddy 1345 40 4.1 4.1, 1(b)

Rubber solution 1287 33 3 3, 5"(a),(b),(c)

Rubber solution 1287 30 3 3, 31°(c)

Rubidium 1423 X423 4.3 4.3, 11 *(a)

Rubidium hydroxide 2678 80 8 8, 41 '(b)

Rubidium hydroxide solution 2677 80 8 8, 42(b),(c)

Seed cake 1386 40 4.2 4.2, 2°(c)

Seed cake 2217 40 4.2 4.2, 2°(c)

Selenium disulphide 2657 60 6.1 6.1, 550(b)

Selenium oxychloride 2879 886 3+6.1 8, 12"(a)

Selenium powder 2658 60 6.1 6.1, 55°(c)

Shale oil 1288 30 3 3, 31"(c)

Shale oil 1288 33 3 3, 3-03)

Silicon powder, amorphous 1346 40 4.1 4.1, 13"(c)

Silicon tetrachloride 1818 80 8 8, -12!(b)

Silver arsenite 1683 60 6.1 6.1, 51(b)

Silver cyanide 1684 60 6.1 6.1, 41-(b)

Silver nitrate 1493 50 5.1 5.1, 22'(b)

Sludge acid 1906 80 8 8, 1(b)

Vol. 1845, A-8940


Name of subsance Substance Hazard Label Class and ItemIdentification Identification number

No No

(LowCr Part) (Upper PLr)

(*) b) (C) (d) (C)

Soda lime 1907 80 8 8, 41 °(c)

Sodium 1428 X423 4.3 4.3, 11 *(a)

Sodium aluminate, solution 1819 80 8 8, 42°0),(c)

Sodium aluminium hydride 2835 423 4.3 4.3. 160(b)

Sodium ammonium vanadate 2863 60 6.1 6.1, 58°(b)

Sodium arsanilate 2473 60 6.1 6.1, 34°(c)

Sodium arsenate 1685 60 6.1 6.1, 51 °(b)

Sodium arsenite, aqueous solution 1686 60 6.1 6.1. 51 *(b),(c)

Sodium.arsenite, solid 2027 60 6.1 6.1, 51°(b)

Sodium bromate 1494 50 5.1 5.1, 16 (b)

Sodium cacodylate 1688 60 6.1 6.1, 51 (b)

Sodium chlorate 1495 50 5.1 5.1, 11 °(b)

Sodium chlorate, aqueous solution 2428 50 5.1 5.1, 115 (b)

Sodium chlorite 1496 50 5.1 5.1, 14°(b)

Sodium chloroacetate 2659 60 6.1 6.1, 17*(c)

Sodium cuprocyanide solution 2317 66 6.1 6.1, 41*(a)

Sodium dithionite (Sodium 1384 40 4.2 4.2, 130(bhydrosulphite)

Sodium fluoride 1690 60 6.1 6.1, 63°(c)

Sodium fluoroacetate 2629 66 6.1 6.1, 17°(a)

Sodium fluorosilicate 2674 60 6.1 6.1, 64*(c)

Sodium hydrogendifluoride 2439 80 8 8, 9-(b)

Sodium hydrosulphide hydrated 2318 40 4.2 4.2, 13°(b)

Sodium hydrosulphide 2949 80 8 8, 45°(b)l.

Sodium hydroxide solution 1824 80 8 8, 42°(b),(c)

Sodium hydroxide, solid 1823 80 8 8, 410(b)

Sodium methylate 1431 48 4.2+8 4.2, 15-(b)

Sodium methylate solution 1289 338 3+8 3, 24°(b)

Sodium methylate solution 1289 38 3+8 3, 33°(c)

Sodium monoxide 1825 80 8 8, 41 °(b)

Vol. 1845, A-8940


Name of substance Substance Hazed lAbel Clas and itemIdentification Identification mumber

No. No.(Lower pat) (Upper paLr)

(a) (b) (C) (d) (C)

Sodium nitrate 1498 50 5.1 5.1, 22°(c)

Sodium nitrate and potassium nitrate 1499 50 5.1 5.1, 22°(c)mixture

Sodium nitrite 1500 50 5.1 5.1, 23°(c)

Sodium pentachlorophenate 2567 60 6.1 6.1, 170b)

Sodium percarbonates 2467 50 5.1 5.1, 19*(c)

Sodium perchlorate 1502 50 5.1 5.1, 13(b)

Sodium permanganate 1503 50 5.1 5.1, 17°b)

Sodium plroxoborate, anhydrous 3247 50 5.1 5.1, 27(b)

Sodium persulphate 1505 50 5.1 5.1, 18°(c)

Sodium sulphide, anhydrous 1385 40 4.2 4.2, 13°(b)

Sodium sulphide, hydrated 1849 80 8 8, 45 0(b)1.

Sodium sulphide, with less than 1385 40 4.2 4.2, 13'(b)30% water of crystallisation

Stannic chloride pentahydrate 2440 80 8 8, 11 -(C)

Stannic chloride, anhydrous 1827 80 8 8, 12'(b)

Strontium arsenite 1691 60 6.1 6.1, 51(b)

Strontium chlorate 1506 50 5.1 5.1, 11'(b)

Strontium nitrate 1507 50 5.1 5.1, 22°(c)

Strontium perchlorate 1508 50 5.1 5.1, 13°(b)

Strontium peroxide 1509 50 5.1 5.1, 25°b)

Strychnine or strychnine, salts 1692 66 6.1 6.1, 90°(a)

Styrene monomer, inhibited 2055 39 3 3, 31 °(c)(Vinylbenzene)

Sulphamic acid 2967 80 8 8, 16-(c)

Sulphur 1350 40 4.1 4.1, 11(c)

Sulphur chlorides 1828 X88 8 8, 12-(a)

Sulphur dioxide 1079 26 6.1 2, 3*(at)

Sulphur hexafluoride 1080 20 2 2, 5 -(a)

Sulphur trioxide, inhibited 1829 X88 8 8, 1 *(a)

Sulphur, molten 2448 44 4.1 4.1, 15-

Vol. 1845, A-8940


Name of substncc Substance Hazard label Clus and item

Identirseaion Identification numberNo. No.

(Lower pan) (Upper Part)

(a) (b) (C) (d) (C)

Sulphuric acid, containing more than 1830 80 8 8, 1 °(b)51% acid

Sulphuric acid, fuming 1831 X886 8+6.1 8, 1*(a)

Sulphuric acid, spent 1832 80 8 8. 1 '(b)

Sulphuric acid. with more than 2796 80 8 8, 1 '(b)51% acid

Sulphurous acid 1833 80 8 8, 1 °(b)

Sulphuryl chloride 1834 X88 8 8, 12°(a)

Synthesis gas 2600 236 3+6.1 2, 2°(bt)

Tars, liquid 1999 30 3 3, 31°(c)

Tars, liquid 1999 33 3 3. 5(b),(c)

Terpinolene 2541 30 3 3, 31°(c)

Tetrabromoethane 2504 60 6.1 6.1, 15° (c)

1, 1,2,2-Tetrachloroethane 1702 60 6.1 6.1, 15°(b)

Tetrachloroethylene 1897 60 6.1 6.1, 15°(c)

Tetraethyl dithiopyrophosphate 1704 60 6.1 6.1, 23*(b)

Tetraethyl silicate 1292 30 3 3, 31 °(c)

Tetraethylenepentamine 2320 80 8 8, 530(c)

1,1,1,2-Tetrafluorethane 3159 20 2 2, 3°(a)(R 134a)

Tetrafluoromethane (R 14) 1982 20 2 2, 1 (a)

1,2,3,6-Tetrahydrobenzaldehyde 2498 30 3 3, 31 °(c)

Tetrahydrofuran 2056 33 3 3, 3°(b)

Tetrahydrofurfurylamine 2943 30 3 3, 31 *(c)

Tetrahydrophthalic anhydrides 2698 80 8 8, 31°(c)

1,2,3,6-Tetrahydropyridine 2410 33 3 3, 3°0)

Tetrahydrothiophene (thiolanne) 2412 33 3 3, 3°(b)

Tetramethylammonium hydroxide 1835 80 8 8, 51°(Nb)

Tetramethylsilane 2749 33 3 3, 1 *(a)

Tetranitromethane 1510 559 5.1+6.1 5.1, 2°(a)

Tetrapropyl orthotitanate 2413 30 3 3. 31 (c)

Vol. 1845, A-8940


Name of substance Substance Hazard LAbel Cla" and itemIdentification ldentification number

No. No.(Lower Pan) (upper Pl")

(a) (b) (c) (d) (e)

Thallium chlorate 2573 56 5.1+6.1 5.1, 29(b)

Thallium nitrate 2727 65 6.1+05 6.1, 68°(b)

Thioacetic acid 2436 33 3 3, 3*(b)

Thioglycol 2966 60 6.1 6.1. 21*(b)

Thioglycolic acid 1940 80 8 8, 32*(b)l.

Thiolactic acid 2936 60 6.1 6.1, 21°(b)

Thionyl chloride 1836 X88 8 8, 120(a)

4-Thiapentanal 2785 60 6.1 6.1, 21 °(c)

Thiophene 2414 33 3 3, 3°(b)

Thiophosgene 2474 60 6.1 6.1, 21 ° (b)

Thiophosphoryl chloride 1837 80 8 8, 12°(b)

Tinctures, medicinal 1293 30 3 3, 31°(c)

Tinctures, medicinal 1293 33 3 3, 3*()

Titanium disulphide 3174 40 4.2 4.2, 13°(c)

Titanium hydride 1871 40 4.1 4.1, 140(b)

Titanium powder, dry 2546 40 4.2 4.2, 120(b),(c)

Titanium powder, wetted 1352 40 4.1 4.1, 13-(b)

Titanium sponge, powder or granules 2878 40 4.1 4.1, 13-(c)

Titanium tetrachloride 1838 80 8 8, 12°(b)

Titanium trichlorde mixture 2869 80 8 8, 11 (b),(c)

Toluene 1294 33 3 3, 30(b)

Toluene diisocyanate 2078 60 6.1 6.1, 19'(b)

Toluidines 1708 60 6.1 6.1, 12'(b)

2,4-Toluylenediamine 1709 60 6.1 6.1, 12°(c)

Town gas 2600 236 3+6.1 2, 2(bt)

Triallyl borate 2609 60 6.1 6.1, "14-(c)

Triallylamine 2610 38 3+8 3, 33°(c).

Tributylamine 2542 80 8 8, 530(c)

Trichloroacetic acid 1839 80 8 8, 310(b)

Trichloroacetic acid solution 2564 80 8 8, 32-(c)

Vol. 1845, A-8940

United Nations - Treaty Series * Nations Unies - Recueil des Traits

Naime of aubsncc Subuajce HzArd Label Clus am itemIdentificaion IdfnmicaZuon numlbr

No. No.(Lowcr pas) (Uppcr p )

(a) (b) (C) (d) ()

Trichloroacetic acid solution 2564 80 8 8, 32°(b)l.

Trichloroacetyl chloride 2442 X80 8 8, 35°(b)!.

Trichaorobenzents, liquid 2321 60 6.1 6.1, 15"(c)

Trichlorobutene 2322 60 6.1 6.1, 15"(b)

1,1,1-Trichloroethane 2831 60 6.1 6.1, 15"(c)

Trichloroethylene 1710 60 6.1 6.1, 15"(c)

Trichloroisocyanuric acid, dry 2468 50 5.1 5.1, 26*(b)

Trichlorosilane 1295 X338 4.3+3+8 4.3, 1*(a)

Tricresyl phosphate 2574 60 6.1 6.1, 23"(b)

Triethyl phosphite 2323 30 3 3, 31 *(c)

Triethylamine 1296 338 3+8 3, 22*(b)

Triethylenetetramine 2259 80 8 8, 53"(b)

Trifluoroacetic acid 2699 88 8 8, 32"(a)

Trifluorochloroethylene (R 1113) 1082 236 3+6.1 2, 3*(ct)

1,1,1-Trifluoroethane 2035 23 3 2, 30 (b)

Trifluoromethane (R 23) 1984 20 2 2, 5a(a)

2-Trifluoromethylaniline 2942 60 6.1 6.1, 12"(c)

3-Trifluoromethylaniline 2948 60 6.1 6.1, 17'(b)

Tris-(1-aziridinyl) phosphine oxide 2501 60 6.1 6.1, 23"(b),(c)solution

Triisobutylene (Isobutylene trimer) 2324 30 3 3, 31 *(c)

Triisocyanatoisocyanurate of 2906 30 3 3, 31 (c)isophoronediisocyanate, solution

Triisopropyl borate 2616 30 3 3, 31 °(c)

Triisopropyl borate 2616 33 3 3, 3-(b)

Trimethyl borate 2416 33 3 3, 3-(b)

Trimethyl phosphite 2329 30 3 3, 31 (c)

Trimethylacetyl chloride 2438 663 6.1+3+8 6.1, 10*(a)

Trimethylamine, anhydrous 1083 236 3+6.1 2, 30(bt)

Trimethylamine, aqueous solution 1297 338 3+8 3, 220(a),(b)

Trimethylamine. aqueous solution 12'7 38 3+8 3, 33"(c)

Vol 1845. A-8940

429


Name of substance Substance Haard Label Clus and itemIdentifieaion Identiflation number

No. No.(Lower part) (Upper pat)

(a) (b) (C) (d) (e)

1,3,5-Trimethylbenzene 2325 30 3 3, 31 °(c)

Trimethylchlorosilane 1298 X338 3+8 3, 21(b)

Trimethylcyclohexylamine 2326 80 8 8, 53°(c)

Trimethylhexamethylene diisocyanate 2328 60 6.1 6.1, 19°(c)

Trimethylhexamethylenediamine 2327 80 8 8, 53°(c)

Tripropyamine 2260 38 3+8 3, 330(c)

Tripropylene 2057 33 3 3, 30(b)

Tripropylene 2057 30 3 3, 31 °(c)

Turpentine 1299 30 3 3, 31 °(c)

Turpentine substitute 1300 33 3 3, 3"b)

Turpentine substitute 1300 30 3 3, 31 *(c)

Undecane 2330 30 3 3, 31 *(c)

Uranyl nitrate hexahydrate solution 2980 78 7A,7B or 7, Sch 5,6 or 137C+8

Urea hydrogen peroxide 1511 58 5.1+8 5.1, 31 °(c)

Valeraldehyde 2058 33 3 3, 3(b)

Valeryl chloride 2502 83 8+3 8, 35°(b)2.

Vanadium oxytrichloride 2443 80 8 8, 12'(b)

Vanadium pentoxide 2862 60 6.1 6.1, 58°(b)

Vanadium tetrachloride 2444 88 8 8, 12°(a)

Vanadium trichloride 2475 80 8 8, 11 °(c)

Vanadyl sulphate 2931 60 6.1 6.1, 58-(b)

Vinyl acetate, inhibited 1301 339 3 3, 3(b)

Vinyl bromide 1085 236 3+6.1 2, 3°(ct)

Vinyl butyrate, inhibited 2838 339 3 3, 30(b)

Vinyl chloride 1086 239 3 2, 3*..:)

Vinyl chloroacetate 2589 63 6.1+3 6.1, 16-(b)

Vinyl ethyl ether, inhibited 1302 339 3 3, 2°(a)

Vinyl fluoride 1860 239 3 2, 5°(c)

Vinyl isobutyl ether, inhibited 1304 339 3 3, 3(b)

Vol. 1845, A-8940


Name of substante SubstLnce Hazard Label Class and itemIdentif/eation Identiracion number

No. No.(L.r pa) (Upper pa)

(a) (b) (e) (d) (Ce)

Vinylidene chloride, inhibited 1303 339 3 3, 1 *(a)

Vinyltoluene, inhibited (o-,m-,p-) 2618 39 3 3, 31°(c)

Vinylpyridines, inhibited 3073 639 6.1+3 6.1, 11 0(b)

Vinyltrichlorosilane, inhibited 1305 X338 3+8 3, 21 *(a)

Water gas 2600 236 3+6.1 2, 2°(bt)

White asbestos (Actinolite,. 2590 90 9 9, 1 °(c)Anthophyllite, Chrysotile orTremolite)

Wood preservatives, liquid 1306 33 3 3, 5*(b),(c)

Wood preservatives, liquid 1306 30 3 3, 31 5 (c)

Xenon 2036 20 2 2, 5°(a)

Xenon, deeply-refrigerated 2591 22 2 2, 7°(a)

Xylenes 1307 30 3 3, 31 O(c)

Xylenes 1307 33 3 3, 3°(b)

Xylenols 2261 60 6.1 6.1, 14(b)

Xylidines 1711 60 6.1 6.1, 12°(b)

Xylyl bromide 1701 60 6.1 6.1, 15°(b)

Zinc ammonium nitrite 1512 50 5.1 5.1, 23(b)

Zinc arsenate 1712 60 6.1 6.1, 51(b)

Zinc arsenate and zinc arsenite 1712 60 6.1 6.1, 51(b)mixture

Zinc arsenite 1712 60 6.1 6.1, 51°(b)

Zinc ashes 1435 423 4.3 4.3, 13°(c)

Zinc bromate 2469 50 5.1 5.1, 16°(c)

Zinc chlorate 1513 50 5.1 5.1, 11(b)

Zinc chloride solution 1840 so 8 8, 5(c)

Zinc chloride, anhydrous 2331 80 8 8, 11 (c)

Zinc cyanide 1713 66 6.1 6.1, 41°(a)

Zinc dust 1436 423 4.3+4.2 4.3, 14°(b),(c)

Zinc fluorosilicate 2855 60 6.1 6.1, 64°(c)

Zinc nitrate 1514 50 5.1 5.1, 22*Nb)

Vol. 1845, A-8940


Name of ubsance Subaamce HAZAM LAbel ClaS and itemIdenti€fiaion Idecific*ion number

No. No.(L*. A) (Upper p-)

(a) (b) (C) (d) (e)

Zinc permanganate 1515 50 5.1 5.1, 17°(b)

Zinc peroxide 1516 50 5.1 5.1, 250(b)

Zinc powder 1436 423 4.3+4.2 4.3, 14°(b),(c)

Zinc resinate 2714 40 4.1 4.1, 12*(c)

Zirconium bydride 1437 40 4.1 4.1, 14°(b)

Zirconium nitrate 2728 50 5.1 5.1, 22*(c)

Zirconium powder, dry 2008 40 4.2 4.2, 12°(b),(c)

Zirconium powder, wetted 1358 40 4.1 4.1, 13°(b)

Zirconium scrap 1932 40 4.2 4.2, 120(c)

Zirconium suspended in a flammable 1308 33 3 3, 1 *(a),liquid 2°(a),(b), 30(b)

Zirconium suspended in a flammable 1308 30 3 3, 31-(c)liquid

Zirconium tetrachloride 2503 80 8 8, 11 °(c)

Zirconium, dry 2858 40 4.1 4.1, 13"(c)

Vol. 1845. A-8940


Table 2

List of collective headings or n.o.s. entries which are not listed by name, or which do not fallunder a collective heading in Table 1.

This table includes two types of collective headings or n.o.s. entries:

- specific collective headings or n.o.s. entries applicable to groups of chemical compounds ofthe same type;

- general collective headings or n.o.s. entries applicable to groups of substances which presentsimilar primary and secondary hazards.

Substances may only be classified under a general collective heading or n.o.s. entry if theycannot be classified under a specific collective heading or n.o.s. entry.

NOTE: This table applies only to substances not included in Table 1.

Group of substances Substance Hazard Label Class and itemIdentlfication Identificaton number

No No.(Lower par) (Upper part)

(a) (b) (c) (d) (e)

Class 3: Flammable liquids

Specific n.o.s. entries orspecific collective headings

Petroleum distillates, n.o.s. 1268 33 3 3, 1 *(a)1268 33 3 3, 2°(a)1268 33 3 3, 2-(b)1268 33 3 3, 30(b)1268 30 3 3, 31 *(c)

Petroleum products, n.o.s. 1268 33 3 3, 1 *(a)1268 33 3 3, 2°(a)1268 33 3 3, 2-(b)1268 33 3 3, 3-(b)1268 30 3 3, 31 *(c)

Hydrocarbons, liquid, n.o.s. 3295 33 3 3, 1 '(a)3295 33 3 3, 2-(a)3295 33 3 3, 2-(b)3295 33 3 3, 3'(b)3295 30 3 3, 31 *(c)

Aldehydes, flammable, n.o.s. 1989 33 3 3, 2'kb)1989 33 3 3, 3°(b)

1 1989 30 3 3, 31°(c)

Alcohols, flammable, n.o.s. 1987 33 3 3, 2*(b)1987 33 3 3. 3°(b)1987 30 3 3, 31 *(c)

Vol. 1845, A-8940

433


Group of substances Substance HaZMd Label Class and itemIdentification Identification number

No. No.(LOWer Pa) (Upper p-)

(a) (b) (c) (d) Ce)

Ketones, n.o.s. 1224 33 3 3, 2°b)1224 33 3 3, 30(b)1224 30 3 3, 31 -(c)

Ethers, n.o.s. 3271 33 3 3, 3°(b)3271 30 3 3, 31 °(c)

Esters, n.o.s. 3272 33 3 3, 3-(b)3272 30 3 3, 31°(c)

Nitriles, flammable, toxic, n.o.s. 3273 336 3+6.1 3, 11 *(a),(b)

Isocyanates or isocyanate solution, 2478 336 3+6.1 3, 14-(b)flammable, toxic, n.o.s. 2478 36 3+6.1 3, 32°(c)

Alcohols, flammable, toxic, n.o.s. 1986 336 3+6.1 3, 17°(a),(b)1986 36 3+6.1 3, 32°(c)

Aldehydes, flammable, toxic, n.o.s. 1988 336 3+6.1 3, 17°(a),(b)1988 36 3+6.1 3, 32°(c)

Mercaptans or mercaptan mixture, 1228 336 3+6.1 3, 18°(b)liquid, flammable, toxic, n.o.s. 1228 36 3+6.1 3, 32°(c)

Medicine, liquid, flammable, toxic, 3248 336 3+6.1 3, 19-(b)n.o.s. 3248 36 3+6.1 3, 32°(c)

Chlorosilanes, flammable, corrosive, 2985 338 3+8 3, 21°(b)n.o.s.

Amines or polyamines, flammable, 2733 338 3+8 3, 22°(a),(b)

corrosive, n.o.s. 2733 38 3+8 3, 330(c)

Alcoholates solution, n.o.s. 3274 338 3+8 3, 24'(b)

Terpene hydrocarbons, n.o.s. 2319 30 3 3, 31 °(c)

Pesticides

Organophosphorous pesticide, liquid, 2784 336 3+6.1 3, 41 *(a),(b)flammable, toxic

Organochlorine pesticide, liquid, 2762 336 3+6.1 3, 420(a),(b)flammable, toxic

Phenoxy pesticide, liquid, flammable, 2766 336 3+6.1 3, 43°(a),(b)toxic

Carbamate pesticide, liquid, flammable, 2758 336 3+6.1 3, 44(a),(b)toxic

Mercury based pesticide, liquid, 2778 336 3+6.1 3, 45°(a).(b)flammable, toxic

Vol. 1845, A-8940

1995 United Nations - Treaty Series i Nations Unies - Recueil des Traitks 435

Group of substances Substance Hazard Label Class sd stemIdentdkcaion Identification number

No. No.(Lower pal) (Upper pan)

(a) (b) (c) (d) (e)

Organotin pesticide, liquid, flammable, 2787 336 3+6.1 3, 46°(a),(b)toxic

Coumarin derivative pesticide, liquid, 3024 336 3+6.1 3, 47°(a),(b)flammable, toxic

Bipyridilium pesticide, liquid, 2782 336 3+6.1 3, 48°(a),(b)flammable, toxic

Arsenical pesticide, liquid, flammable, 2760 336 3+6.1 3, 49°(a),(b)toxic

Copper based pesticide, liquid, 2776 336 3+6.1 3, 50°(a),(b)flammable, toxic

Substituted nitrophenol pesticide, 2780 336 3+6.1 3, 51 *(a),(b)liquid, flammable, toxic

Triazine pesticide, liquid, flammable, 2764 336 3+6.1 3, 52°(a),(b)toxic

Benzoic derivative pesticide, liquid, 2770 336 3+6.1 3, 53°(a),(b)flammable, toxic

Phthalimide derivative pesticide, 2774 336 3+6.1 3, 54°(a),(b)liquid, flammable, toxic

Phenyl urea pesticide, liquid, 2768 336 3+6.1 3, 550(a),(b)flammable, toxic

Dithiocarbamate pesticide, liquid, 2772 336 3+6.1 3, 56°(a),(b)flammable, toxic

Pesticide, liquid, flammable, toxic, 3021 336 3+6.1 3, 570(a),(b)n.o.s.

General n.o.s. entries

Flammable liquid, n.o.s. 1993 33 3 3, 1 *(a)1993 33 3 3, 2°(a)1993 33 3 3, 2 0 (b)1993 33 3 3, 3°(b)1993 33 3 3, 50(c)1993 30 3 3, 31P(c)

Flammable liquid, toxic, n.o.s. 1992 336 3+6.1 3, 19'(a),(b)1992 36 3+6.1 3, 32°(c)

Flammable liquid, corrosive, n.o.s. 2924 338 3+8 3, 26°(a),(b)2924 38 3+8 3, 33°(c)

Flammable liquid, toxic, corrosive, 3286 368 3+6.1+8 3, 27°(a),(b)n.o.s.

Vol. 1845. A-8940

Vol. 1845, A-8940

Recueil des Trait~s 1995436 United Nations - Treaty Series * Nations Unies -

Group of aubtanccs substancc HL"aml Label Class and itemIdentificasion Idntifdtaion number

No. No.(Lower pain) (Upper pLs)

(a) (b) (C) (d) Ce)

Elevated temperature liquid, 3256 30 3 3, 61 °(c)flammable, n.o.s.

Class 4.1: Flammable solids

Speciic n.o.s, entries

Metal hydrides, flammable, n.o.s. 3182 40 4.1 4.1, 14°(b),(c)

General no.s, entries

Solids containing flammable liquid, 3175 40 4.1 4.1, 4-(c)n.o.s.

Flammable solid, organic, molten, 3176 44 4.1 4.1, 5i..s. 1325 40 4.1_41, ________

Flammable solid, organic , n.o.s. 1325 40 4.1 4.1, 6°(b),(c)

Flammable solid, toxic, organic, nos. 2926 46 4.1+6.1 4.1, 7°(),(c)

Flammable solid, corrosive, organic, 2925 48 4.1+8 4.1, 8(b),(c)n.o.s.

Flammable solid, inorganic, n.o.s. 3178 40 4.1 4.1, 11 °(b),(c)

Metal salts of organic compounds, 3181 40 4.1 4.1, 12°(b),(c)flammable, n.o.s.

Metal powder, flammable, n.o.s. 3089 40 4.1 4.1, 130(b),(c)

Flammable solid, toxic, inorganic, 3179 46 4.1+6.1 4.1, 16°(b),(c)

Flammable solid, corrosive, inorganic, 3180 48 4.1+8 4.1, 17*(b),(c)n.o.s.

Class 4.2: Substances liable to

spontaneous combustion

Specific n.o.s. entries

Fibres, animal, vegetable or synthetic 1373 40 4.2 4.2, 3°(c)n.o.s.

Alkaline earth metal alcoholates, n.o.s. 3205 40 4.2 4.2, 14°(b),(c)

Alkali metal alcoholates, n.o.s. 3206 48 4.2+8 4.2, 15°(b),(c)


Group of subsumces Subsnce Hazard lAbel Class sod item

Identificaion Identiication number

No. No.(Lower pat) (Upper p-t)

(a) (b) (C) (d) (e)

Metal alkyls, n.o.s. or metal aryls, 2003 X333 4.2+4.3 4.2, 31*(a)D.O.S.

Metal alkyl halides, n.o.s. or metal 3049 X333 4.2+4.3 4.2, 32°(a)aryl halides, n.o.s.

Metal alkyl hydrides, n.o.s. or metal 3050 X333 4.2+4.3 4.2, 32°(a)aryl hydrides, n.o.s.


Self-heating solid, organic, n.o.s. 3088 40 4.2 4.2, 5°(b),(c)

Pyrophoric liquid, organic, n.o.s. 2845 333 4.2 4.2, 6°(a)

Self-hiating liquid, organic, n.o.s. 3183 30 4.2 4.2, 6 0 (b),(c)

Self-heating solid, toxic, organic, 3128 46 4.2+6.1 4.2, 7°(b),(c)n.o.s.

Self-heating liquid, toxic, organic, 3184 36 4.2+6.1 4.2, 8°(b),(c)n.o.s.

Self-heating solid, corrosive, organic, 3126 48 4.2+8 4.2, 9°(b),(c)n.o.s.

Self-heating liquid, corrosive, organic, 3185 38 4.2+8 4.2, 10*(b),(c)n.o.s.

Self-heating metal powder, n.o.s. 3189 40 4.2 4.2, 12*(b),(c)

Self-heating solid, inorganic, n.o.s. 3190 40 4.2 4.2, 16°(b),(c)

Pyrophoric liquid, inorganic, n.o.s. 3194 333 4.2 4.2, 17T(a)

Self-heating liquid, inorganic, n.o.s. 3186 30 4.2 4.2, 17°(b),(c)

Self-heating solid, toxic, inorganic, 3191 46 4.2+6.1 4.2, 18°(b),(c)n.o.s.

Self-heating liquid, toxic, inorganic. 3187 36 4.2+6.1 4.2, 19°(b),(c)D.O.S.

Self-heating solid, corrosive, inorganic, 3192 48 4.2+8 4.2, 20*(b),(c)D.O.S.

Self-heating liquid, corrosive, 3188 38 4.2+8 4.2, 21"(b),(c)inorganic, n.o.s.

Pyrophoric organometallic compound, 3203 X333 4.2+4.3 4.2, 33°(a)n.o.s.

Vol. 1845. A-8940


Group of substunces Substane Hazard Label Cias and itemIdentificsaton Identification number

No No.(Lower pit) (Upper pa)

(a) (b) (C) (d) (e)

Class 4.3: Substances, which, incontact with water, emit flammablegases


Cborosilanes, water-reactive, 2988 X338 4.3+3+8 4.3, 1 '(a)flammable, corrosive, n.o.s.

Alkali metal alloy, liquid, i:o.s. 1421 X423 4.3 4.3, 11 *(a)

Alkaline earth metal alloy, n.o.s. 1393 423 4.3 4.3, 11 °(b)

Metal hydrides, water-reactive, n.o.s. 1409 423 4.3 4.3, 16°(b)


Organometalic compound or solution 3207 X323 4.3+3 4.3, 3°(a)or dispersion, water-reactive, 3207 323 4.3+3 4.3, 3°(b),(c)flammable, n.o.s.

Metallic substance, water-reactive, 3208 423 4.3 4.3, 13*(b),(c)n.o.s.

Metallic substance, water-reactive, 3209 423 4.3+4.2 4.3, 14°(b),(c)

self-heating, n.o.s.

Water-reactive solid, n.o.s. 2813 423 4.3 4.3, 20°(b),(c)

Water reactive liquid, n.o.s. 3148 X323 4.3 4.3, 21°(a)3148 323 4.3 4.3, 21°(b),(c)

Water-reactive solid, toxic, n.o.s. 3134 462 4.3+6.1 4.3, 22*(b),(c)

Water-reactive liquid, toxic, n.o.s. 3130 X362 4.3+6.1 4.3, 23°(a)3130 362 4.3+6.1 4.3, 23°(b),(c)

Water-reactive solid, corrosive, n.o.s. 3131 482 4.3+8 4.3, 24°(b),(c)

Water-reactive liquid, corrosive, n.o.s. 3129 X382 4.3+8 4.3, 25°(a)3129 382 4.3+8 4.3, 25°(b),(c)

Class 5.1: Oxidizing substances


Chlorates, inorganic, n.o.s. 1461 50 5.1 5.1, lie(b)

Chlorates, inorganic, aqueous solution 3210 50 5.1 5.1, 11 '(b)n.o.s.

Perchlorates, inorganic, n.o.s. 1481 50 5.1 5.1, 13°(b)

Vol 1845, A-8940


Oroup of substances SubstLncc HzuAd LAbel Clas and itemIdcntificuion Identification numbet

No. No.(Lower p a) (Upper p-)

(a) (b) (C) (d) (e)

Perchlorates, inorganic, aqueous 3211 50 5.1 5.1, 13(b)

solution, n.o.s. _

Chlorites, inorganic, n.o.s. 1462 50 5.1 5.1, 14*(b)

Hypochlorites, inorganic, n.o.s. 3212 50 5.1 5.1, 15°(b)

Bromates, inorganic, n.o.s. 1450 50 5.1 5.1, 160(b)

Bromates, inorganic, aqueous solution 3213 50 5.1 5.1, 16°(b).(c)D.O.S.

Permanganates, inorganic, n.o.s. 1482 50 5.1 5.1, 17-(b)

Permanganates, inorganic, aqueous 3214 50 5.1 5.1, 17°(b)solution, n.o.s.

Persulphates, inorganic, n.o.s. 3215 50 5.1 5.1, 18°(c)

Persulphates, inorganic, aqueous 3216 50 5.1 5.1, 18'(c)solution, n.o.s.

Percarbonates, inorganic, n.o.s. 3217 50 5.1 5.1, 19°(c)

Nitrates, inorganic, n.o.s. 1477 50 5.1 5.1, 22*(b),(c)

Nitrates, inorganic, aqueous solution, 3218 50 5.1 5.1, 22°(b),(c)11.0.5. 1

Nitrites, inorganic, o.o.s. 2627 50 5.1 5.1, 23-(b)

Nitrites, inorganic, aqueous solution, 3219 50 5.1 5.1, 23°(b),(c)n.o.s.

Peroxides, inorganic, n.o.s. 1483 50 5.1 5.1, 25-(b)


Oxidizing solid, n.o.s. 1479 50 5.1 5.1, 27*(b),(c)

Oxidizing solid, toxic, n.o.s. 3087 56 5.1+6.1 5.1, 29*(b),(c)

Oxidizing solid, corrosive, n.o.s. 3085 58 5.1+8 5.1, 31°(b),(c)

Class 5.2: Organic peroxides

Specific collective headings

Organic peroxide, type F, liquid 3109 539 5.2+(8) 5.2, 9'(b)

Organic peroxide, type F, liquid, 3119 539 5.2 5.2, 19°(b)temperature controlled

Vol. 1845, A-8940


Goup of subsunce Subsmnce Hazrd Label CL-a. and item

Idcrnitirieion Identi calion numberNo. No.

(Lower pWi) (Upper pa"l)(a) (b) (C) (d) (e)

Organic peroxide, type F, solid 3110 539 5.2 5.2, 10°(b)

Organic peroxide, type F, solid, 3120 539 5.2 5.2, 20°(b)

temperature controlled

Class 6.1: Toxic substances

Specific n.o.s. entries orSpecific collective headings

Organic substances

Nitriles, toxic, flammable, n.o.s. 3275 663 6.1+3 6.1, 1l=(a)3275 63 6.1+3 6.1, 11 °(b)

Nitriles, toxic, n.o.s. 3276 66 6.1 6.1, 12*(a)3276 60 6.1 6.1, 12°(b),(c)

Chloropicrin mixture, n.o.s. 1583 66 6.1 6.1, 17(a)1583 60 6.1 6.1, 17=(b),(c)

Halogenated irritating liquid, n.o.s. 1610 66 6.1 6.1, 170 (a)1610 60 6.1 6.1, 17*(b),(c)

Chloroformates, toxic, corrosive, 3277 68 6.1+8 6.1, 27°(b)n.o.s.

Chloroformates, toxic, corrosive, 2742 638 6.1+3+8 6.1, 28°(b)

flammable, n.o.s.

Isocyanates, toxic, flammable, n.o.s. 3080 63 6.1+3 6.1, 18*(b)

Isocyanate solution, toxic, flammable, 3080 63 6.1+3 6.1, 18°(b)n.o.s.

Isocyanates. toxic, n.o.s. 2206 60 6.1 6.1, 19"(b),(c)

Isocyanate solution, toxic, n.o.s. 2206 60 6.1 6.1, 19*(b),(c)

Mercaptans, liquid, toxic, 3071 63 6.1+3 6.1, 20°(o)flammable, n.o.s.

Mercaptans mixture, liquid, toxic, 3071 63 6.1+3 6.1, 20-(b)flammable, n.o.s.

Organophosphorus compound, toxic, 3279 663 6.1+3 6.1. 22 *(a)flammable, n.o.s. 3279 663 6.1+3 6.1, 22-(b)

Organophosphorus compound, toxic, 3278 66 6.1 6.1, 23°(a)

n.o.s. 3278 60 6.1 6.1, 23°(b),(c)

Disinfectant, liquid, toxic, n.o.s. 3142 66 6.1 6.1, 25°(a)

3142 60 6.1 6.1, 25°(b),(c)

Vol. 1845, A-8940


Goup of substances Substance HAzad Label Clas an itemIdentification |denticahion number

No. No.(Lower pajr) (Upper part)

(a) (b) (e) (d) (c)

Disinfectant, solid, toxic, n.o.s. 1601 66 6.1 6.1, 25*(a)1601 60 6.1 6.1, 25*b),(c)

Dye, liquid, toxic, n.o.s. 1602 66 6.1 6.1, 25°(a)1602 60 6.1 6.1, 25"(b),(c)

Dye, intermediate, liquid, toxic, n.o.s. 1602 66 6.1 6.1, 250(a)1602 60 6.1 6.1, 25 0(b),(c)

Dye, solid, toxic, n.o.s. 3143 66 6.1 6.1, 25"(a)3143 60 6.1 6.1, 250(b),(c)

Dye intermediate, solid, toxic, n.o.s. 3143 66 6.1 6.1, 25°(a)3143 60 6.1 6.1, 25°(b),(c)

Tear gas substance, liquid or solid, 1693 66 6.1 6.1, 25°(a)n.o.s. 1693 60 6.1 6.1, 25°(b)

Organometallic substances

Organotin compound, liquid, n.o.s. 2788 66 6.1 6.1, 320(a)2788 60 6.1 6.1, 32°(b),(c)

Organotin compound, solid, n.o.s. 3146 66 6.1 6.1, 32°(a)3146 60 6.1 6.1, 32°(b),(c)

Phenylmercuric compound, n.o.s. 2026 66 6.1 6.1, 33°(a)2026 60 6.1 6.1, 33°(b),(c)

Organoarsenic compound, n.o.s. 3280 66 6.1 6.1, 340(a)3280 60 6.1 6.1, 340(b),(c)

Metal carbonyls, n.o.s. 3281 66 6.1 6.1, 36(a)

3281 60 6.1 6.1, 360(b),(c)


Cyanides, inorganic, solid, n.o.s. L.583 66 6.1 6.1, 41°(a)1588 60 6.1 6.1, 41 "(b),(c)

Cyanide solution, n.o.s. 1935 66 6.1 6.1, 41 *(a)1935 60 6.1 6.1, 41 -(b),(c)

Arsenic compound, liquid, n.o.s. 1556 66 6.1 6.1, 51*(a)(arsenates, arsenites and arsenic 1556 60 6.1 6.1, 51 (b),(c)sulphides)

Arsenic compound, solid, n.o.s. 1557 66 6.1 6.1, 51°(a)(arsenates, arsenites and arsenic 1557 60 6.1 6.1, 51'(b),(c)sulphides) I II

Mercury compound, liquid, n.o.s. 2024 66 6.1 6.1, 52*(a)2024 60 6.1 6.1, 52°(b),(c)

Vol. 1845, A-8940


Group of uibstances Substance Hazrd Label Clas and itemIdenlifiewaion Identiication number

No. No.

(Lo-er part) (Upper parW)(a) (b) (c) (d) (e)

Mercury compound, solid, n.o.s. 2025 66 6.1 6.1, 52°(a)1 2025 60 6.1 6.1, 52"(b),(c)

Thallium compound, n.o.s. 1707 60 6.1 6.1, 53°(b)2.

Beryllium compound, n.o.s. 1566 60 6.1 6.1, 54°(b)2.,(c)

Selenium compound, n.o.s. 3283 66 6.1 6.1, 55°(a)3283 60 6.1 6.1, 55°(b),(c)

Tellurium compound, n.o.s. 3284 60 6.1 6.1, 57°(b),(c)

Vanadium compound, n.o.s. 3285 60 6.1 6.1, 58°(b),(c)

Antimony compound, inorganic, liquid, 3141 60 6.1 6.1, 59°(c)n.o.s.

Antimony compound, inorganic, solid, 1549 60 6.1 6.1, 59°(c)n.o.s.

Barium compound, n.o.s. 1564 60 6.1 6.1, 60°(b),(c)

Lead compound, soluble, n.o.s. 2291 60 6.1 6.1, 62*(c)

Fluorosilicates, n.o.s. 2856 60 6.1 6.1, 640(c)

Cadmium compound 2570 66 6.1 6.1, 61 *(a)2570 60 6. j 6.1, 61 °(b),(c)

Pesticides

Organophosphorus pesticide, solid, 2783 66 6.1 6.1, 71 *(a)toxic 2783 60 6.1 6.1, 71 *(b),(c)

Organophosphorus pesticide, liquid, 3017 663 6.1+3 6.1, 71(a)toxic, flammable 3017 63 6.1+3 6.1, 71 *(b),(c)

Organophosphorus pesticide, liquid, 3018 66 6.1 6.1, 71*(a)toxic 3019 60 6.1 6.1, 71 °(b),(c)

Organochlorine pesticide, solid, toxic 2761 66 6.1 6.1, 720(a)2761 60 6.1 6.1, 72°(b),(c)

Organochlorine pesticide, liquid, toxic, 2995 663 6.1+3 6.1, 720(a)flammable 2995 63 6.1+3 6.1, 72°(b),(c)

Organochlorine pesticide, liquid, toxic 2996 66 6.1 6.1. 720(a)2996 60 6.1 6.1, 72°(b),(c)

Phenoxy pesticide, solid, toxic 2765 66 6.1 6.1, 730(a)2765 60 6.1 6.1, 73"(b),(c)

Phenoxy pesticide, liquid, toxic, 2999 63 6.1+3 6.1. 73°(a)flammable 2999 63 6.1+3 6.1, 730(b),(c)

Vol 1845, A-8940


Group of substances Substance HwArd LAbel Clai and itemIdentification Identification number

No. No.(Lowcr pan) (Upper pa)

(a) (b) (c) (d) (c)

Phenoxy pesticide, liquid, toxic 3000 66 6.1 6.1, 73°(a)3000 60 6.1 6.1, 73°(b).(c)

Carbamate pesticide, solid, toxic 2757 66 6.1 6.1, 74°(a)2757 60 6.1 6.1, 74"(b),(c)

Carbamate pesticide, liquid, toxic 2991 663 6.1+3 6.1, 74°(a)flammable 2991 63 6.1+3 6.1, 74 0 (b),(c)

Carbamate pesticide, liquid, toxic 2992 66 6.1 6.1, 74°(a)2992 60 6.1 6.1, 74°(b),(c)

Mercury based pesticide, solid, toxic 2777 66 6.1 6.1, 75°(a)2777 60 6.1 6.1, 75°(b),(c)

Mercury based pesticide, liquid, toxic, 3011 663 6.1+3 6.1, 75°(a)flammable 3011 63 6.1+3 6.1, 75°(b),(c)

Mercury based pesticide, liquid, toxic 3012 66 6.1 6.1, 75°(a)3012 60 6.1 6.1, 75°(b),(c)

Organotin pesticide, solid, toxic 2786 66 6.1 6.1, 76°(a)2786 60 6.1 6.1, 76°(b),(c)

Organotin pesticide, liquid, toxic, 3019 663 6.1+3 6.1, 76°(a)flammable 3019 63 6.1+3 6.1, 76°(b),(c)

Organotin pesticide, liquid, toxic 3020 66 6.1 6.1, 76°(a)3020 60 6.1 6.1, 76°(b),(c)

Coumarin derivative pesticide, liquid, 3025 663 6.1+3 6.1, 77°(a)toxic, flammable 3025 63 6.1+3 6.1, 77°(b),(c)

Coumarin derivative pesticide, liquid, 3026 66 6.1 6.1, 77°(a)toxic 3026 60 6.1 6.1, 77°(b),(c)

Coumarin derivative pesticide, solid, 3027 66 6.1 6.1, 77*(a)toxic 3027 60 6.1 6.1, 77°(b),(c)

Bipyridilium pesticide, solid, toxic 2781 66 6.1 6.1, 78(a)2781 60 6.1 6.1, 78°(b),(c)

Bipyridilium pesticide, liquid, toxic, 3015 663 6.1+3 6.1, 78°(a)flammable 3015 63 6.1+3 6.1, 78°(b),(c)

Bipyridilium pesticide, liquid, toxic 3016 66 6.1 6.1, 78°(a)3016 60 6.1 6.1, 78*(b),(c)

Arsenical pesticide, solid, toxic 2759 66 6.1 6.1, 79°(a)2759 60 6.1 6.1, 79°(b),(c)

Arsenical pesticide, liquid, toxic, 2993 663 6.1+3 6.1, 79°(a)flammable 2993 63 6.1+3 6.1, 79°(b),(c)

Vol. 1845, A-8940

United Nations - Treaty Series a Nations Unies - Recueil des Trait~s

Group of substances Substance Hazard Label Class and itemIdentification ldentifcaion number

No. No.(Lower pas) (Upper Past)

(a) (b) (c) (d) (e)

Arsenical pesticide, liquid, toxic 2994 66 6.1 6.1, 79°(a)2994 60 6.1 6.1, 79°(b),(c)

Copper based pesticide, solid, toxic 2775 66 6.1 6.1, 80*(a)2775 60 6.1 6.1, 80°(b),(c)

Copper based pesticide, liquid, toxic, 3009 663 6.1+3 6.1, 80°(a)flammable 3009 63 6.1+3 6.1, 80°(b),(c)

Copper based pesticide, liquid, toxic 3010 66 6.1 6.1, 800(a)3010 60 6.1 6.1, 80+(b),(c)

Substituted nitrophenol pesticide. 2779 66 6.1 6.1, 81 *(a)solid, tdxic 2779 60 6.1 6.1, 81 °(b),(c)

Substituted nitrophenol pesticide, 3013 663 6.1+3 6.1, 81"(a)liquid, toxic, flammable 3013 63 6.1+3 6.1, 81"(b),(c)

Substituted nitrophenol pesticide, 3014 66 6.1 6.1, 81 °(a)liquid, toxic 3014 60 6.1 6.1, 81°(b),(c)

Triazine pesticide, solid, toxic 2763 66 6.1 6.1, 82°(a)2763 60 6.1 6.1, 82=(b),(c)

Triazine pesticide, liquid, toxic, 2997 663 6.1+3 6.1, 82°(a)flammable 2997 63 6.1+3 6.1, 82N(b),(c)

Triazine pesticide, liquid, toxic 2998 66 6.1 6.1, 82°(a)2998 60 6.1 6.1, 82°(b),(c)

Benzoic derivative pesticide, solid, 2769 66 6.1 6.1, 83°(a)toxic 2769 60 6.1 6.1, 83°(b).(c)

Benzoic derivative pesticide, 3003 663 6.1+3 6.1, 83°(a)liquid, toxic, flammable 3003 63 6.1+3 6.1,83°(b),(c)

Benzoic derivative pesticide, liquid 3004 66 6.1 6.1,83°(a)toxic 3004 60 6.1 6.1, 83°(b),(c)

Phthalimide derivative pesticide, liquid, 2773 66 6.1 6.1. 84°(a)toxic 2773 60 6.1 6.1, 84°(b),(c)

Phthalimide derivative pesticide, 3007 663 6.1+3 6.1, 84-(a)liquid, toxic, flammable 3007 63 6.1+3 6.1, 84(b),(c)

Phthalimide derivative pesticide, 3008 66 6.1 6.1. 84°(a)liquid, toxic 3008 60 6.1 6.1, 84°(b),(c)

Phenyl urea pesticide, solid, toxic 2767 66 6.1 6.1, 85°(a)2767 60 6.1 6.1, 85*(b),(c)

Phenyl urea pesticide, liquid, toxic, 3001 663 6.1+3 6.1, 85-(a)flammable 3001 63 6.1+3 6.1, 85°(b),(c)

Vol. 1845, A-8940

444


oroup of substances Subslance Hazd LAbel Clais and iemIdentificazion Identification number

No. No.(Lower pa-) (Upper pil)

(a) (b) (c) (d) (c)

Phenyl urea pesticide, liquid, toxic 3002 66 6.1 6.1, 85°(a)

3002 60 6.1 6.1, 85°(b),(c)

Dithiocarbamate pesticide, solid, toxic 2771 66 6.1 6.1, 86*(a)2771 60 6.1 6.1, 86(b),(c)

Dithiocarbamate pesticide, liquid, 3005 663 6.1+3 6.1, 86°(a)toxic, flammable 3005 63 6.1+3 6.1, S6°(b),(c)

Dithiocarbamate pesticide,'liquid, toxic 3006 66 6.1 6.1, 86*(a)3006 60 6.1 6.1, 86°(b),(c)

Pesticide solid, toxic, n.o.s. 2588 66 6.1 6.1, 87°(a)2588 60 6.1 6.1, 87°(b),(c)

Pesticide liquid, toxic, n.o.s. 2902 66 6.1 6.1, 87°(a)2902 60 6.1 6.1, 87°(b),(c)

Pesticide liquid, toxic, flammable, 2903 663 6.1+3 6.1, 87°(a)n.o.s. 2903 63 6.1+3 6.1, 87°(b),(c)

Actives substances

Alkaloids or Alkaloid salts, liquid, 3140 66 6.1 6.1, 90°(a)n.o.s. 3140 60 6.1 6.1, 90°(b),(c)

Alkaloids or Alkaloid salts, solid, 1544 66 6.1 6.1, 90°(a)n.o.s. 1544 60 6.1 6.1, 90*(b),(c)

Nicotine compound or nicotine 3144 66 6.1 6.1, 90°(a)preparation, liquid, n.o.s. 3144 60 6.1 6.1, 90°(b),(c)

Nicotine compound or nicotine 1655 66 6.1 6.1, 90°(b),(c)preparation, solid, n.o.s. 1655 60 6.1 6.1,90'(b),(c)

Toxins, extracted from living sources, 3172 66 6.1 6.1, 90"(a)

n.o.s. 3172 60 6.1 6.1, 90*(b),(c)

Medicine, liquid, toxic, n.o.s. 1851 60 6.1 6.1, 90*(b),(c)

Medicine, solid, toxic, n.o.s. 3249 60 6.1 6.1, 90"(b),(c)


Organic substances

Toxic liquid, organic, n.o.s. 2810 66 6.1 6.1, 25°(a)2810 60 6.1 6.1, 25°(b),(c)

Toxic solid, organic, n.o.s. 2811 66 6.1 6.1, 25S(a)2811 60 6.1 6.1, 25°(b),(c)

Toxic liquid, flammable, organic, 2929 663 6.1+3 6.1, 26*(a)1.n.o.s. 2929 63 6.1+3 6.1, 260(b).

Vol 1845. A-8940


Group of substanccs Subtance Hazard Label Clas and item

ldcriific ion ldutiicatLion numberNo. No.

(Lower part) (Upper pw)(a) (b) (C) (d) (e)

Toxic solid, flammable, organic, 2930 664 6.1+4.1 6.1, 26°(a)2.n.o.s. 2930 64 6.1+4.1 6.1, 26"(b)2.

Toxic liquid, corrosive, organic, n.o.s. 2927 668 6.1+8 6.1, 27°(a)2927 68 6.1+8 6.1, 27'(b)

Toxic solid, corrosive, organic, n.o.s. 2928 668 6.1+8 6.1, 27°(a)2928 68 6.1+8 6.1, 27'(b)

Organometallic substances I

Organometallic compound toxic, n.o.s. 3282 66 6.1 6.1, 35°(a)3282 60 6.1 6.1. 35°(b),(c)


Toxic liquid, water-reaetiy°, n.o.s. 3123 623 6.1 +4.3 6.1, 44"(),(c)Toxic solid, water-reactive, n.o.s. 3125 642 6.1+4.3 6.1, 44°(b),(c)

Solids containing toxic liquid, n.o.s. 3243 60 6.1 6.1, 65°(b)

Toxic liquid, inorganic, n.o.s. 3287 66 6.1 6.1, 650(a)3287 60 6.1 6.1. 650(b),(c)

Toxic solid, inorganic, n.o.s. 3288 66 6.1 6.1, 65°(a)3288 60 6.1 16.1, 65 °(),(c)

Toxic solid, self-heating, n.o.s. 3124 664 6.1+4.2 6.1, 660(a)3124 64 6.1+4.2 6.1, 66'(b)

Toxic liquid, corrosive, inorganic, 3289 668 6.1+8 6.1, 67°(a)n.o.s. 3289 68 6.1+8 6.1, 67°()

Toxic solid, corrosive, inorganic. 3290 668 6.1+8 6.1, 67°(a)n.o.s. 3290 68 6.1+8 6.1, 67°(b)

Toxic liquid, oxidizing, n.o.s. 3122 665 6.1+05 6.1, 68°(a)3122 65 6.1+05 6.1, 68'(1b)

Toxic solid, oxidizing, n.o.s. 3086 665 6.1+05 6.1, 68°(a)

3086 65 6.1+05 6.1. 68'(b)

Class 6.2: Infectious substances

Specific collective headings

Infectious substance, affecting humans 2814 606 6.2 6.2, 3(0)

Infectious substance, affecting animals 2900 606 6.2 6.2, 3(b)

only


Clinical wzste, unspecified, n.o.s. 3291 606 6.2 6.2, 4"(b)

Vol. 1845. A-8940


Group of substances Substance Haza Label Class and itemIdentification Identification number

No. No(Lower part) (Upper part)

(a) (b) (C) (d) (e)

Class 7: Radioactive materialSpecific n.o.s. entries

Radioactive material, low specific 2912 70 7A,7B or 7, Sch 5,6 or 13activity (ISA), n.o.s. 7C

gas 72 7A,7B or7C

gas, flammable 723 7A,7B, or7C+3

liquid, flammable with flash-point 73 7A,7B ornot above 61 °C 7C+3

solid, flammable 74 7A,7B or7C+4.1

oxidizing 75 7A,7B or7C+05

toxic 76 7A,7B or7C+6.1

corrosive 78 7A,7B or7C+8


Radioactive material, n.o.s. 2982 70 7A,7B or 7, Sch 9,10,117C or 13

gas 72 7A,7B or7C

gas, flammable 723 7A,7B or7C+3

liquid, flammable with flash-point 73 7A,7B ornot above 61 °C 7C+3

solid, flammable 74 7A,7B or7C+4.1

oxidizing 75 7A,7B or7C+05

toxic 76 7A,7B or7C+6.1

corrosive 78 7A,7B or7C+8

Class 8: Corrosive substances



Hydrogendifluorides, n.o.s. 1740 80 8 8, 9°(b),(c)

Vol. 1845, A-8940


Group of subsunces Sub tame HazAid Label Cluj and itemIdentification Identiriction number

No. No.(Lower put) (Upper put)

(a) (b) (c) (d) (C)

Bisulphites, aqueous solution, n.o.s. 2693 80 8 8, 17*(c)

Organic substances

Chlorosilanes, corrosive, n.o.s. 2987 80 8 8, 36*(b)

Chlorosilanes, corrosive, flammable, 2986 X83 8+3 8, 37°(b).O.S.

Alkylphenols, solid, n.o.s. 2430 88 8 8, 39°(a)2430 80 8 8, 39°(b),(c)

Alkylphenols, liquid, n.o.s. 3145 88 8 8, 40'(a)3145 80 8 8, 40°(b),(c)

Amines or polyamines, solid, 3259 88 8 8, 52*(a)corrosive, n.o.s. 3259 80 8 8, 52°(b),(c)

Amines or polyamines, liquid, 2735 88 8 8, 53°(a)corrosive, n.o.s. 2735 80 8 8, 53-(b),(c)

Amines or polyamines, liquid, 2734 883 8+3 8, 54°(a)corrosive, flammable, n.o.s. 2734 83 8+3 8, 54°(b)

Dye or dye intermediate, solid, 3147 80 8 8, 65*(b),(c)corrosive, n.o.s.

Dye or dye intermediate, liquid, 2801 80 8 8, 660 (b),(c)corrosive, n.o.s.

Disinfectant, liquid, corrosive,.n.o.s. 1903 88 8 8, 66°(a)1903 80 8 8, 66°(b),(c)


Acid substances

Corrosive solid, acidic, inorganic, 3260 88 8 8, 16°(a)n.o.s. 3260 80 8 8,16°(b),(c)

Corrosive liquid, acidic, inorganic, 3264 88 8 8, 17°(a)

n.o.s. 3264 80 8 8, 17°(b),(c)

Organic substances

Corrosive solid, acidic, organic, n.o.s. 3261 88 8 8, 39°(a)3261 80 8 8, 39°(b),(c)

Corrosive liquid, acidic, organic, n.o.s. 3265 88 8 8, 40°(a)3265 80 8 8, 40*(b),(c)

Vol 1845, A-8940


Group of substances Substace Hazard Label Class and itemIdenification idenccrtiraion number

No. No.

(Lower pa-) (Upper par)(a) (b) (c) (d) (€)

Basic substances


Caustic alkali liquid, n.o.s. 1719 80 8 8, 42°(b),(c)

Corrosive solid, basic, inorganic, 3262 88 8 8, 46°(a)n.o.s. 3262 80 8 8, 46°(b),(c)

Corrosive liquid, basic, inorganic, 3266 88 8 8, 47°(a)n.o.s. 3266 80 8 8, 47°(b),(c)

Organic substances

Corro~iv solid, basic, organic, n.o.s. 3263 88 8 8, 55°(a)3263 80 8 8, 55a(b),(c)

Corrosive liquid, basic, organic, n.o.s. 3267 88 8 8, 56°(a)3267 80 8 8, 560(b),(c)

Other corrosive substances

Solids containing corrosive liquid, 3244 80 8 8, 65°(b)n.o.s.

Corrosive solid, n.o.s. 1759 88 8 8, 65°(a)1759 80 8 8, 65°(b),(c)

Corrosive liquid, n.o.s. 1760 88 8 8, 66°(a)1760 80 8 8, 66°(b),(c)

Corrosive solid, flammable, n.o.s. 2921 884 8+4.1 8, 67°(a)2921 84 8+4.1 8, 670(b)

Corrosive liquid, flammable, n.o.s. 2920 883 8+3 8, 68°(a)2920 83 8+3 8, 68-(b)

Corrosive solid, self-heating, n.o.s. 3095 84 8+4.2 8, 69°(b)

Corrosive liquid, self-heating. n.o.s. 3301 884 8+4.2 8, 70°(a)3301 84 8+4.2 8, 70-(b)

Corrosive solid, water-reactive, n.o.s. 3096 842 8+4.3 8, 71 -(b)

Corrosive liquid, water-reactive, n.o.s. 3094 823 8+4.3 8, 72°(a),(b)

Corrosive solid, oxidizing, n.o.s. 3084 885 8+05 8, 73a(a)3084 85 8405 8, 73°(b)

Corrosive liquid, oxidizing, n.o.s. 3093 885 8+05 8, 74°(a)3093 85 8+05 8, 74°(b)

Corrosive solid, toxic, n.o.s. 2923 886 8+6.1 8, 75°(a)2923 86 8+6.1 8, 75°(b),(c)

Vol 1845, A-8940


Group of subsLtances Substnce Haurd Label Clas and itemIdentification Idenification number

No. No.(Lower pat) (Upper part)

(a) (b) () (d) (W)

Corrosive liquid, toxic, n.o.s. 2922 886 8+6.1 8, 76°(a)2922 86 8+6.1 8, 76°(b),(c)

Class 9: Miscellaneous dangeroussubstances and articles

Enviromentally hazardoussubstances

Environmentally hazardous -substance, 3082 90 9 9, 11 °(c)liquid, n.o.s.

Environmentally hazardous substance, 3077 90 9 9, 12'(c)solid, n.o.s.

Vol. 1845. A-8940


Table 3

Numerical list - this table contains all the entries of tables I and 2 in substance identification number order

Substance Name of substance HaZARd Label Class and itemIdentification Identification number

No No.(Lower part) (Upper pail)

(a) (b) (e) (d) (c)

1002 Air, compressed 20 2 2, 2°(a)

1003 Air, deeply-refrigerated 225 2+05 2, 8°(a)

1005 Ammonia 268 6.1 2, 3°(at)

1006 Argon, compressed 20 2 2, 1°(a)

1008 Boron trifluoride 26 6.1 2, 1 *(at)

1009 Bromotrifluoromethane (R 13 BI) 20 2 2, 5°(a)

1010 1,3-Butadiene 239 3 2, 3°(c)

1010 Mixtures of 1,3-butadiene and 239 3 2, 4°(c)hydrocarbons

1010 1,2-Butadiene 239 3 2, 3°(c)

1011 Butane, technically-pure 23 3 2, 3 0(b)

1012 1-Butylene (1-Butene) 23 3 2, 3-(b)

1012 cis-2-Butylene (cis-2-Butene) 23 3 2, 3-(b)

1012 trans-2-Butylene (trans-2-Butene) 23 3 2, 3 0(b)

1013 Carbon dioxide 20 2 2, 5°(a)

1014 Carbon dioxide containing not less 20 2 2, 6°(a)than 1% and not more than 10%oxygen by mass

1016 Carbon monoxide 236 6.1+3 2, 10(bt)

1017 Chlorine 266 6.1+8 2, 3°(at)

1018 Chlorodifluoromethane (R 22) 20 2 2, 3°(a)

1020 Chloropentafluoroethane (R 115) 20 2 2, 3°(a)

1021 1-Chloro-1,2,2,2-tetrafluoroethane 20 2 2, 3°(a)(R 124)

1022 Chlorotrifluoromethane (R 13) 20 2 2, 5°(a)

1027 Cyclopropane 23 3 2, 3-(b)

1028 Dichlorodifluoromethane (R 12) 20 2 2, 3°(a)

1029 Dichlorofluoromethane (R 21) 20 2 2, 3°(a)

Vol. 1845, A-8940

Substme Name of aubstance Hazard Label Clas and item

Identification Identificaion numbertNo. No.

(Lower part) (Upper pan)(a) (b) (() d) (e)

1030 1,1-Difluoroethane (R 152a) 23 3 2, 3*(b)

1032 Dimethylamine, anhydrous 236 3+6.1 2, 3°(bt)

1033 Dimethyl ether 23 3 2, 3"(b)

1035 Ethane 23 3 2, 5*(b)

1036 Ethylamine, anhydrous 236 3+6.1 2, 3°(bt)

1037 Ethyl chloride 236 3+6.1 2, 3°(bt)

1038 Ethylene, deeply-refrigerated 223 3 2, 7°(b)

1040 Ethylene oxide with nitrogen 236 3+6.1 2, 4"(ct)

1041 Ethylene oxide containing not more 236 3+6.1 2, 4°(ct)than 10% carbon dioxide by mass

1041 Ethylene oxide containing more 236 3+6.1 2, 6 0 (ct)than 10% but not more than 50%carbon dioxide

1041 Carbon dioxide containing not more 239 3 2, 6 0 (c)

than 35% ethylene oxide by mass

1046 Helium, compressed 20 2 2, 1 °(a)

1048 Hydrogen bromide 286 8+6.1 2, 3°(at)

1049 Hydrogen, compressed 23 3 2, I (b)

1050 Hydrogen chloride 286 8+6.1 2, 5°(at)

1052 Hydrogen fluoride, anhydrous 886 8+6.1 8, 6

1053 Hydrogen sulphide 236 3+6.1 2, 3°(bt)

1055 Isobutylene 23 3 2, 3'(b)

1056 Krypton, compressed 20 2 2, 1 *(a)

1060 Mixtures of methylacetylene and 239 3 2, 4°(c)propadiene with hydrocarbons

1061 Methylamine, anhydrous 236 3+6.1 2, 3°(bt)

1062 Methyl bromide 26 6.1 2, 3°(at)

1063 Methyl chloride 236 3+6.1 2, 3°bt)

1064 Methyl mercaptan 236 3+6.1 2, 3-(bt)

1065 Neon, compressed 20 2 2, 1 '(a)

1066 Nitrogen, compressed 20 2 2, 1°(a)

Vol. 1845. A-8940

452 United Nations - Treaty Series 0 Nations Unies - Recueil des Trait~s

Substance Name of subatAnce HAZArd LAbel Chas and item

Identifiaition Identification numberNo. No.

(Lower pan) (Upper pl)(a) (b) (C) (d) (C)

1067 Nitrogen dioxide (NO) 265 6.1 +05 2, 30(at)

1070 Nitrous oxide (N20) 25 2+05 2, 5(a)

1072 Oxygen, compressed 20 2+05 2, I (a)

1073 Oxygen, deeply-refrigerated 225 2+05 2, 7(a)

1076 Phosgene 266 6.1+8 2, 3*(at)

1077 Propylene 23 3 2, 30(b)

1078 Mixtures F I, F2 and F3 20 2 2, 4(a)

1079 Sulphur dioxide 26 6.1 2, 3*(at)

1080 Sulphur hexafluoride 20 2 2, 5(a)

1082 Trifluorochloroethylene (R 1113) 236 3+6.1 2, 3(ct)

1083 Trimethylamine, anhydrous 236 3+6.1 2, 3(bt)

1085 Vinyl bromide 236 3+6.1 2, 3(ct)

1086 Vinyl chloride 239 3 2, 3*(c)

1087 Methyl vinyl ether 236 3+6.1 2, 3°(ct)

1088 Acetal 33 3 3, 3(b)

1089 Acetaldehyde 33 3 3, 1 *(a)

1090 Acetone 33 3 3, 3(b)

1091 Acetone oils 33 3 3, 3(b)

1092 Acrolein, inhibited 663 6.1+3 6.1, 8(a)

1093 Acrylonitrile, inhibited 336 3+6.1 3, 11*(a)

1098 Allyl alcohol 663 6.1+3 6.1, 8(a)

1099 Allyl bromide 336 3+6.1 3, 16(a)

1100 Allyl chloride 336 3+6.1 3, 16(a)

1104 Amyl acetates 30 3 3, 31(c)

1105 Amyl alcohols 30 3 3. 3!(c)

1105 Amyl alcohols 33 3 3, 3-(b)

1106 Amylarnine (n-amylamine, 338 3+8 3, 22(b)tei-amylamine)

1106 Amylarnine (sec-amylamnine) 38 3+8 3. 33(c)

1107 Amyl chloride 33 3 1 3(b)

Vol 1845. A-8940

1995 United Nations - Treaty Series e, Nations Unies - Recueil des "Irait~s

454 United Nations - Treaty Series , Nations Unies - Recueil des Traitks 1995

Substance Name of subs=ac HazAud Label Class Mnd itemIdestiicaiion Identification number

No. No.(Lower panl) (Upper pat)

(a) (b) (c) (d) (e)

1108 -Pentene (n-Amylene) 33 3 3, 1 '(a)

1109 Amyl formates 30 3 3, 31°(c)

1110 n-Arnyl methyl ketone 30 3 3, 31(c)

1111 Amyl mercaptan 33 3 3, 3°(b)

1112 Amy] nitrate 30 3 3, 31 °(c)

1113 Amyl nitrite 33 3 3. 3°(b)

1114 Benzene 33 3 3, 3°(b)

1120 Butanols 33 3 3, 3°b)

1120 Butanols 30 3 3, 31 °(c)

1123 Butyl aceetates 30 3 3, 31 °(c)

1123 Butyl acetates 33 3 3, 3°(b)

1125 n-Butylamine 338 3+8 3, 22°(b)

1126 I-Bromobutane (n-Butyl bromide) 33 3 3, 3*Nb)

1127 Chlorobutaies 33 3 3, 3°b)

1128 n-Butyl formate 33 3 3, 3°b)

1129 Butyraldehyde 33 3 3, 3(b)

1130 Camphor oil 30 3 3, 31°(c)

1131 Carbon disulphide (Carbon sulphide) 336 3+6.1 3, 18°(a)

1133 Adhesives 33 3 3, 5°(a),(b),(c)

1133 Adhesives 30 3 3, 31°(c)

1134 Chlorobenzene 30 3 3, 31 *(c)

1135 Ethylene chlorohydrin 663 6.1+3 6.1, 16°(a)

1136 Coal tar distillates 33 3 3, 3-(b)

1136 Coal tar distillates 30 3 3, 31°(c)

1139 Coating solution 33 3 3, 5°(a),(b),(c)

1139 Coating solution 30 3 3, 31°(c)

2143 Crotonaldehyde, stabilized 663 6.1+3 6.1, 8°(a)

1144 Crotonylene (2-Butyne) 339 3 3, 1 *(a)

1145 Cyclohexane 33 3 3, 3°(b)

Vol. 1845, A-8940


Substance Name of substance Hazatd label Class and itemIdentiication Identification number

No No.(Lower pitt) (Upper part)

(a) (b) (c) (d) (c)

1146 Cyclopentane 33 3 3, 3(b)

1147 Decahydronaphthalene 30 3 3, 31 *(c)

1148 Diacetone alcohol, technical 33 3 3, 3°(b)

1148 Diacetone alcohol, chemically pure 30 3 3, 31 °(c)

1149 Dibutyl ethers 30 3 3, 31 °(c)

1150 1,2-Dichloroethylene 33 3 3, 3°(b)

1152 Dichloropentanes 30 3 3, 31 °(c)

1153 Ethylene glycol diethyl ether 30 3 3, 31 °(c)

1154 Diethylamine 338 3+8 3, 22(b)

1155 Diethyl ether (ethyl ether) 33 3 3, 2°(a)

1156 Diethyl ketone 33 3 3. 3 0(b)

1157 Diisobutyl ketone 30 3 3, 31 °(c)

1158 Diisopropylamine 338 3+8 3, 22°(b)

1159 Diisopropyl ether 33 3 3, 3°b)

1160 Dimethylamine aqueous solution 338 3+8 3, 22°(b)

1161 Dimethyl carbonate 33 3 3, 3 0(b)

1162 Dimethyldichlorosilane X338 3+8 3, 21 0(b)

1163 Dimethylhydrazine, unsymmetrical 663 6.1+3+8 k. 1, 7°(a)1.

1164 Dimethyl sulphide 33 3 3, 2'(b)

1165 Dioxane 33 3 3, 3 0(b)

1166 Dioxolane 33 3 3, 3'(b)

1167 Divinyl ether inhibited 339 3 3, 2°(a)

1169 Extracts, aromatic, liquid 33 3 3. 50 (a) (b), (c)

1169 Extracts, aromatic, liquid 30 3 3, 31 °(c)

1170 Ethanol or ethanol solution 33 3 3, 3(b)containing more than70 vol.-% alcohol

1170 Ethanol solution containing more than 30 3 3, 31 °(c)24 vol.-% and not more 70 vol.-%alcohol

1171 Ethylene glycol monomethyl ether 30 3 3, 31°(c)

Vol. 1845, A-8940

455


Substance Name of iubstuncc Hazard LAbel CILa and item

ldcntification Identification numberNo No.

(Lower past) (Upper past)(a) (b) (C) (d) (a)

1172 Ethylene glycol monomethyl ether 30 3 3, 31 °(c)

acetate

1173 Ethyl acetate 33 3 3, 3°(b)

1175 Ethylbenzene 33 3 3, 3(b)

1176 Ethyl borate 33 3 3, 3°(b)

1177 Ethylbutyl acetate 30 3 3. 31 -(c)

1178 2-Ethylbutyraldehyde 33 3 3, 30(b)

1179 Ethyl butyl ether 33 3 3. 3°(b)

1180 Ethyl butyrate 30 3 3, 31°(c)

1181 Ethyl chloroacetate 63 6.1+3 6.1, 16°(b)

1182 Ethyl chloroformate 663 6.1+3+8 6.1, 10°(a)

1183 Ethyldichlorosilane X338 4.3+3+8 4.3, °(a)

1184 1,2-Dichloroethane (Ethylene 336 3+6.1 3, 16°(b)dichloride)

1185 Ethyleneimine, inhibited 663 6.1+3 6.1, 4

1188 Ethylene glycol monomethyl ether 30 3 3, 31 *(c)

1189 Ethylene glycol monomethyl ether 30 3 3, 31°(c)acetate

1190 Ethyl formate 33 3 3, 3°(b)

1191 Octyl aldehydes (Ethyl hexaldehydes) 30 3 3, 31 ° (c)

1192 Ethyl lactate 30 3 3, 31 °(c)

1193 Ethyl methyl ketone (methyl 33 3 3, 3°(b)ethyl ketone)

1194 Ethyl nitrite solution 336 3+6.1 3, 15'(a)

1195 Ethyl propionate 33 3 3, 3-(b)

1196 Ethyltrichlorosilane X338 3+8 3, 21°(b)

1197 Extracts, flavouring, liquid 33 3 3, 5°(a),(b),(c)

1197 Extracts, flavouring, liquid 30 3 3, 31(c)

1198 Formaldehyde solution, flammable 38 3+8 3, 33*(c)

1199 Furfura] (furfuraldehyde) 30 3 3, 31 °(c)

120' Fusel oil 33 3 3, 3°(b)

Vol. 1845, A-8940

Subtance Name of substance Hazard Label Class and itemIdentification Idcntification number

No No.(Lower Wa" ) (Upper part)

(a) (b) (e) (d) (e)

1201 Fusel oil 30 3 3, 31 '(c)

1202 Gasoil 30 3 3, 31 °(c)

1202 Diesel fuel 30 3 3, 31 -(c)

1202 Heating oil (light) 30 3 3, 31 °(c)

1203 Motor spirit 33 3 3, 3°(b)

1206 Heptanes 33 3 3, 3(b)

1207 Hexaldehyde 30 3 3, 31 °(c)

1208 Hexanes 33 3 3, 30(b)

1210 Printing ink 33 3 3, 50(a),(b),(c)

1210 Printing ink 30 3 3, 31 °(c)

1212 Isobutanol 30 3 3, 31 °(c)

1213 Isobutyl acetate 33 3 3, 3*(b)

1214 Isobutylamine 338 3+8 3, 22'(b)

1216 Isoctenes 33 3 3, 3°(b)

1218 Isoprene, inhibited 339 3 3, 2*(a)

1219 Isopropanol (Isopropyl alcohol) 33 3 3, 3*(b)

1220 Isopropyl acetate 33 3 3, 3°(b)

1221 Isopropylamine 338 3+8 3, 22°(a)

1223 Kerosene 30 3 3, 31 *(c)

1224 Ketones, n.o.s. 33 3 3, 2*(b), 3°(b)

1224 Ketones, n.o.s. 30 3 3, 31 °(c)

1228 Mercaptans or mercaptan mixture, 336 3+6.1 3, 18-(b)liquid, flammable, toxic n.o.s.

1228 Mercaptans or mercaptans mixture, 36 3+6.1 3, 32*(c)liquid, flammable, toxic, n.o.s.

1229 Mesityl oxide 30 3 3, 31°(c)

1230 Methanol 336 3+6.1 3, 17'(b)

1231 Methyl acetate 33 3 3, 3(b)

1233 Methylamyl acetate 30 3 3, 31°(c)

1234 Methylal 33 3 3, 2°(b)

Vol. 1845, A-8940


458 United Nations - Treaty Series 9 Nations Unies - Recueil des Traitis 199!

Subst ce Name of gubstance Hazud Label ClUS and itemIdentification Identiiction number

No. No.(Lower pt) (Upper pt)

(a) (b) (c) (d) (e)

1235 Methylamine, aqueous solution 338 3+8 3, 22*(b)

1237 Methyl butyrate 33 3 3, 3°(b)

1238 Methyl chloroformate 663 6.1+3+8 6.1, 10°(a)

1239 Methyl chloromethyl ether 663 6.1+3 6.1, 9°(a)

1242 Methyldichlorosilane X338 4.3+3+8 4.3, 1*(a)

1243 Methyl formate 33 3 3, 1*(a)

1244 Methylhydrazine t 6.1+3+8 6.1, 7°(a)l.

1245 Methyl isobutyl ketone 33 3 3, 3-(b)

1246 Methyl isopropenyl ketone, inhibited 339 3 3, 3-(b)

1247 Methyl methacrylate monomer, 339 3 3, 3(b)inhibited

1248 Methyl propionate 33 3 3, 3(b)

1249 Methyl propyl ketone 33 3 3, 3(b)

1250 Methyltrichlorosilane X338 3+8 3, 21 *(a)

1251 Methyl vinyl ketone 339 3 3, 3*(b)

1259 Nickel carbonyl 663 6.1+3 6.1, 3o

1262 Octanes 33 3 3, 3°(b)

1263 Paint 33 3 3, 5°(a)(b),(c)

1263 Paint 30 3 13, 31 °(c)

1263 Paint related material 33 3 3, 5°(a),(b),(c)

1263 Paint related material 30 3 3, 31'(c)

1264 Paraldehyde 30 3 3, 31 °(c)

1265 Pentanes, liquid 33 3 3, 1*(a), 2"(b)

1266 Perfumery products 33 3 3, 5°(a),(b),(c)

1266 Perfumery products 30 3 3,31*(c)

1267 Petroleum crude oil 33 3 3, 1 '(a),2°(a),(b), 3(c)

1267 Petroleum crude oil 30 3 3, 31°(c)

1268 Petroleum distillates, n.o.s. 33 3 3, 1 *(a),1___ _2*(a),(b), 3°(c)

Vol. 1845. A-8940

substance Name of substance Hazard Label Class and item

Identification Identification numberNo No.

(Lower part) (Upper pai)(a) (b) (C) (d) (C)

1268 Petroleum distillates, n.o.s. 30 13 3, 31°(c)

1268 Petroleum products, n.o.s. 33 3 3, 1 *(a),2 (a),(b), 3 (c)

1268 Petroleum products, n.o.s. 30 3 3, 310(c)

1272 Pine oil 30 3 3, 31 °(c)

1274 n-Propanol 33 3 3, 3*(b)

1274 n-Propanol 30 3 3, 31 °(c)

1275 Propionaldehyde 33 3 3, 3°(b)

1276 n-Propyl acetate 33 3 3, 3°(b)

1277 Propylamine 338 3+8 3, 22*(b)

1278 -Chloropropane (Propyl chloride) 33 3 3, 2°(b)

1279 1,2-Dichloropropane 33 3 3, 3°(b)

1280 Propylene oxide, inhibited 339 3 3, 2°(a)

1281 Propyl formates 33 3 3, 3(b)

1282 Pyridine 33 3 3, 3°(b)

1286 Rosin oil 33 3 3, 5°(a),(b),(c)

1286 Rosin oil 30 3 3, 31°(c)

1287 Rubber solution 33 3 3, 5°(a),(b).(c)

1287 Rubber solution 30 3 3, 31 °(c)

1288 Shale oil 33 3 3, 3°(b)

1288 Shale oil 30 3 3, 31°(c)

1289 Sodium methylate solution 338 3+8 3, 24°(b)

1289 Sodium methylate solution 38 3+8 3, 33°(c)

1292 Tetraethyl silicate 30 3 3, 31°(c)

1293 Tinctures, medicinal 33 3 3, 3°(b)

1293 Tinctures, medicinal 30 3 ^.- - °(c)

1294 Toluene 33 3 3, 3'(b)

1295 Trichlorosilane X338 4.3+3+8 4.3, 1*(a)

1296 Triethylamine 338 3+8 3, 22-(b)

1297 Trimethylamine. aqueols solution 338 3+8 3, 22°(a),(b)

Vol. 1845. A-8940

1995 United Nations -Treaty Series Nations Unies - Recueil des Traitks


Subance NTme of substancc Hazard Label Clus and itemIdentification Idenaiicatlion number

No No.(Lower pai) (Upper pan)

(a) (b) (c) (d) (c)

1297 Trimethylamine, aqueous solution 38 3+8 3. 33(c)

1298 Trimethylchlorosilane X338 3+8 3, 21 (b)

1299 Turpentine 30 3 3, 31 °(c)

1300 Turpentine substitute 33 3 3, 3°(b)

1300 Turpentine substitute 30 3 3, 31 *(c)

1301 Vinyl acetate, inhibited 339 3 3, 3°(b)

1302 Vinyl ethyl ether inhibited 339 3 3, 2°(a)

1303 Vinylidene chloride, inhibited 339 3 3, 1 *(a)

1304 Vinyl isobutyl ether, inhibited 339 3 3, 3°(b)

1305 Vinyltrichlorosilane, inhibited X338 3+8 3, 21 '(a)

1306 Wood preservatives, liquid 33 3 3, 5°(b),(c)

1306 Wood preservatives, liquid 30 3 3, 31 °(c)

1307 Xylenes 33 3 3, 30(b)

1307 Xylenes 30 3 3, 31 °(c)

1308 Zirconium suspended in a flammable 33 3 3, 1 *(a),liquid 2 * (a),(b), 3°(b)

1308 Zirconium suspended in a flammable 30 3 3, 310(c)liquid

1309 Aluminium powder, coated 40 4.1 4.1, 13°(b),(c)

1312 Borneol 40 4.1 4.1, 6°(c)

1313 Calcium resinate 40 4.1 4.1, 120(c)

1314 Calcium resinate, fused 40 4.1 4.1, 120(c)

1318 Cobalt resinate, precipitated 40 4.1 4.1, 12°(c)

1323 Ferrocerium 40 4.1 4.1, 13"(b)

1325 Flammable solid, organic, n.o.s. 40 4.1 4.1, 6°(b),(c)

1326 Hafnium powder, wetted 40 4.1 4.1, 13°(b)

1328 Hexamethylenetetramine 40 4.1 4.1, 60 (c)

1330 Manganese resinate 40 4.1 4.1, 12"(c)

1332 Metaldehyde 40 4.1 4.1, 6°(c)

1334 Naphthalene, crude or refined 40 4.1 4.1, 60(c)

Vol. 1845, A-8940


Substance Narnc of substance Hazad LAbel Clu and Vtemdentiication Identiication number

No. No(Lower pan) (Upper par)

(a) (b) () (d) ()

1338 Phosphorus, amorphous 40 4.1 4.1, 1 l1(c)

1339 Phosphorus heptasulphide 40 4.1 4.1, 11 °(b)

1340 Phosphorus pentasulphide 423 4.3 4.3, 20°(b)

1341 Phosphorus sesquisulphide 40 4.1 4.1, 11-(b)

1343 Phosphorus trisulphide 40 4.1 4.1, 11 -(b)

1345 Rubber scrap or shoddy 40 4.1 4.1, 1 -(b)

1346 Silicon powder, amorphous 40 4.1 4.1, 13°(c)

1350 Sulphur 40 4.1 4.1, 11 °(c)

1352 Titanium powder, wetted 40 4.1 4.1, 13°(b)

1358 Zirconium powder, wetted 40 4.1 4.1, 13°(b)

1361 Carbon 40 4.2 4.2, 1 *(b),(c)

1361 Carbon black 40 4.2 4.2, 1 °(b),(c)

1362 Carbon, activated 40 4.2 4.2, 1 °(c)

1363 Copra 40 4.2 4.2, 20 (c)

1364 Cotton waste, oily 40 4.2 4.2, 3°(c)

1365 Cotton, wet 40 4.2 4.2, 3°(c)

1366 Diethylzinc X333 4.2+4.3 4.2, 31 *(a)

1369 p-Nitrosodimethylaniline 40 4.2 4.2, 5°(b)

1370 Dimethylzinc X333 4.2+4.3 4.2, 31 °(a)

1373 Fibres, animal, vegetable or 40 4.2 4.2, 3°(c)synthetic, n.o.s.

1373 Fabrics, animal, vegetable or 40 4.2 4.2, 3°(c)synthetic, n.os.

1376 Iron oxide, spent 40 4.2 4.2, 16°(c)

1376 Iron sponge, spent 40 4.2 4.2, 16°(c)

1378 Metal catalyst, wetted 40 4.2 4.2, 12°(b)

1379 Paper, unsaturated oil treated 40 4.2 4.2, 3°(c)

1380 Pentaborane 333 4.2+6.1 4.2, 19*(a)

1381 Phosphorus, white or yellow, dry 46 4.2+6.1 4.2, 11 °(a)

1382 Potassium sulphide, anhydrous 40 4.2 14.2, 13*(b)

Vol 1845, A-8940

462 United Nations - Treaty Series • Nations Unies - Recueil des Trait~s 1995

Suboanc Name of substance Hazard Label Clams and itemldenircwazion ldcnraiicalion number

No. No.(Lower pat) (Upper p )

(a) (b) (C) (d) (e)

1382 Potassium sulphide, with less 40 4.2 4.2, 13'(b)than 30% water of crystallisation

1384 Sodium dithionite (Sodium 40 4.2 4.2, 13"(b)hydrosulphite)

1385 Sodium sulphide, anhydrous 40 4.2 4.2, 13°(b)

1385 Sodium sulphide, with less than 40 4.2 4.2, 13"(b)30% water of crystallisation

1386 Seed cake 40 4.2 4.2, 2°(c)

1389 Alkali metal amalgam X423 4.3 4.3, 11 *(a)

1390 Alkali metal amides 423 4.3 4.3, 19-(b)

1391 Alkali metal dispersion X423 4.3 4.3, 11 *(a)

1391 Alkaline-earth metal dispersion X423 4.3 4.3, 11 *(a)

1392 Alkaline-earth metal amalgam X423 4.3 4.3, 11 *(a)

1393 Alkaline-earth metal alloy, n.o.s. 423 4.3 4.3, 11°(b)

1394 Aluminium carbide 423 4.3 4.3,17-(b)

1395 Aluminium ferrosilicon powder 462 4.3+6.1 4.3, 15(b)

1396 Aluminium powder, uncoated 423 4.3 4.3, 13"(b)

1398 Aluminium silicon powder, uncoated 423 4.3 4.3, 13"(c)

1400 Barium 423 4.3 4.3, 11 (b)

1401 Calcium 423 4.3 4.3, 11 *(b)

1402 Calcium carbide 423 4.3 4.3, 17'(b)

1403 Calcium cyanamide 423 4.3 4.3, 190(c)

1405 Calcium silicide 423 4.3 4.3, 12"(b),(c)

1407 Caesium X423 4.3 4.3, 11 *(a)

1408 Ferrosilicon 462 4.3+6.1 4.3, 15*(c)

1409 Metal hydrides, water-reactive, n.o.s. 423 4.3 4.3, 16"(b)

1415 Lithium X423 4.3 4.3, 11 *(a)

1417 Lithium silicon 423 4.3 4.3, 12"(b)

1418 Magnesium powder 423 4.3+4.2 4.3, 14"(b)

1418 Magnesium alloy powder 423 4.3+4.2 4.3, 4"(b)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Class and itemIdentification Identification number

No. No.(Lower paW) (Upper pa-)

(a) (b) (e) (d) (c)

1420 Potassium metal alloys X423 4.3 4.3, 11 *(a)

1421 Alkali metal alloy, liquid, n.o.s. X423 4.3 4.3, ll(a)

1422 Potassium sodium alloys X423 4.3 4.3, 11 *(a)

1423 Rubidium X423 4.3 4.3, 11 *(a)

1428 Sodium X423 4.3 4.3, 11 *(a)

1431 Sodium methylate 48 4.2+8 4.2, 15-b)

1435 Zinc ashes 423 4.3 4.3, 13°(c)

1436 Zinc powder 423 4.3+4.2 4.3, 14°(b),(c)

1436 Zinc dust 423 4.3+4.2 4.3, 14°(b),(c)

1437 Zirconium hydride 40 4.1 4.1, 14'b)

1438 Aluminium nitrate 50 5.1 5.1, 22 5 (c)

1439 Ammonium dichromate 50 5.1 5.1, 27-(b)

1444 Ammonium persulphate 50 5.1 5.1, 18(c)

1445 Barium chlorate 56 5.1+6.1 5.1, 29'(b)

1446 Barium nitrate 56 5.1+6.1 5.1, 29°(b)

1447 Barium perchlorate 56 5.1+6.1 5.1, 29°(b)

1448 Barium permanganate 56 5.1+6.1 5.1, 290(b)

1449 Barium peroxide 56 5.1+6.1 5.1, 29°(b)

1450 Bromates, inorganic, n.o.s. so 5.1 5.1, 16-(b)

1451 Caesium nitrate 50 5.1 5.1, 22°(c)

1452 Calcium chlorate 50 5.1 5.1, 11'(b)

1453 Calcium chlorite 50 5.1 5.1, 14 0(b)

1454 Calcium nitrate 50 5.1 5.1, 22°(c)

1455 Calcium perchlorate 50 5.1 5.1, 13-(b)

1456 Calcium permanganate 50 5.1 5.1, 17-(b)

1457 Calcium peroxide 50 5.1 5.1, 25°(b)

1458 Chlorate and borate mixture 50 5.1 5.1, 110(b)

1459 Chlorate and magnesium chloride 50 5.1 5.1, 11'(b)mixture

1461 Chlorates, inorganic, n.o.s. 50 5.1 5.1, 113) I

Vol. 1845, A-8940


Substance Name of substanc HaZd Label Claas and itcmideicrzon Idectii€alion number

No. No(Lower pant) (tUpper pas)

(a) (b) (c) (d) (e)

1462 Chlorites, inorganic, n.o.s. 50 5.1 15.1. 14'(b)

1463 Chromium trioxide, anhydrous 58 5.1+8 5.1, 31 (b)

1465 Didymium nitrate 50 5.1 5.1, 22°(c)

1466 Ferric nitrate 50 5.1 5.1, 22'(c)

1467 Guanidine nitrate 50 5.1 5.1, 22*(c)

1469 Lead nitrate 56 5.1+6.1 5.1, 29'(b)

1470 Lead perchlorate 56 5.1+6.1 5.1, 29'(b)

1471 Lithium hypochlorite, mixture or dry 50 5.1 5.1, 15-(b)

1472 Lithium peroxide 50 5.1 5.1, 25°(b)

1473 Magnesium bromate 50 5.1 5.1, 16-(b)

1474 Magnesium-nitrate 50 5.1 5.1, 22"(c)

1475 Magnesium perchlorate 50 5.1 5.1, 13(b)

1476 Magnesium peroxide 50 5.1 5.1, 25-(b)

1477 Nitrates, inorganic, n.o.s. 50 5.1 5.1, 22°(b),(c)

1479 Oxidizing solid, n.o.s. 50 5.1 5.1, 27°(b),(c)

1481 Perchlorates, inorganic, n.o.s. 50 5.1 5.1, 13°b)

1482 Permanganates, inorganic, n.o.s. 50 5.1 5.1, 17-(b)

1483 Peroxides, inorganic, n.o.s. 50 5.1 5.1, 25-(b)

1484 Potassium bromate 50 5.1 5.1, 16-(b)

1485 Potassium chlorate 50 5.1 5.1, 110(b)

1486 Potassium nitrate 50 5.1 5.1. 22-(c)

1487 Potassium nitrate and sodium 50 5.1 5.1, 24-(b)nitrite mixture

1488 Potassium nitrite 50 5.1 5.1, 23°(b)

1489 Potassium perchlorate 50 5.1 5.1, 13'(b)

1490 Potassium permanganate 50 5.1 5.1, 17-(b)

1492 Potassium persulphate 50 5.1 5.1, 19"(c)

1493 Silver nitrate 50 5.1 5.1, 22-(b)

1494 Sodium bromate 50 5.1 5.1, 16°(b)

1495 Sodium chlorate 150 5.1 5.1, 11nt)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Clas and itemIdentification IdentiJeation number

No. No.(Lower part) (Upper par)

(a) (b) te) (d) (e)

1496 Sodium chlorite 50 5.1 5.1, 14°b)

1498 Sodium nitrate 50 5.1 5.1, 22°(c)

1499 Sodium nitrate and potassium nitrate 50 5.1 5.1, 22*(c)mixture

1500 Sodium nitrite 50 5.1 5.1, 23°(c)

1502 Sodium perchlorate 50 5.1 5.1, 13°(b)

1503 Sodium permanganate 50 5.1 5.1, 17-(b)

1505 Sodium persulphate 50 5.1 5.1, 18°(c)

1506 Strontium chlorate 50 5.1 5.1, 11 °(b)

1507 Strontium nitrate 50 5.1 5.1, 22°(c)

1508 Strontium perchlorate 50 5.1 5.1, 13° (b)

1509 Strontium peroxide 50 5.1 5.1, 25°(b)

1510 Tetranitromethane 559 5.1+6.1 5.1, 2°(a)

1511 Urea hydrogen peroxide 58 5.1+8 5.1, 31 °(c)

1512 Zinc ammonium nitrite 50 5.1 5.1, 23 0(b)

1513 Zinc chlorate 50 5.1 5.1, 11-(b)

1514 Zinc nitrate 50 5.1 5.1, 22(b)

1515 Zinc permanganate 50 5.1 5.1, 17oNb)

1516 Zinc peroxide 50 5.1 5.1, 25(b)

1541 Acetone cyanohydrin, stablized 66 6.1 6.1, 12*(a)

1544 Alkaloids or acaloid salts, solid, 66 6.1 6.1, 90°(a)n.o.s.

1544 Alkaloids or alcaloid salts, solid, 60 6.1 6.1, 90°(b),(c)n.o.s.

1545 Allyl isothiocyanate, inhibited 639 6.1+3 6.1, 20'(b)

1546 Ammonium arsenate 60 6.1 6.1. 51-(b)

1547 Aniline 60 6.1 6.'1, 12*(b)

1548 Aniline hydrochloride 60 6.1 6.1, 12°(c)

1549 Antimony compound, inorganic, 60 6.1 6.1, 59°(c)solid, n.o.s. _

1550 Antimony lactate 60 6.1 6.1, 59°(c)

Vol. 1845, A-8940


Subatasice Namc of gubstmce Hazard Label CaSs and itemIdentifiwion idensifiction number

No. No.(Loer pas) (Upper pea)

(a) (b) c) (d) (e)

1551 Antimony potassium tartrate 60 6.1 6.1, 59'(c)

1553 Arsenic acid, liquid 66 6.1 16.1, 51 *(a)

1554 Arsenic acid, solid 60 6.1 6.1, 51°(b)

1555 Arsenic bromide 60 6.1 6.1, 51-(b)

1556 Arsenic compound, liquid, n.o.s. 66 6.1 6.1, 51*(a)

1556 Arsenic compound, liquid, n.o.s. 60 6.1 6.1, 51(b),(c)

1557 Arsenic compound, solid, n.o.s. 66 6.1 6.1, 51°(a)

1557 Arsenic compound, solid, n.o.s. 60 6.1 6.1, 510 (b),(c)

1558 Arsenic 60 6.1 6.1, 51(0)

1559 Arsenic pentoxide 60 6.1 6.1, 51-(b)

1560 Arsenic trichloride 66 6.1 6.1, 51*(a)

1561 Arsenic trioxide 60 6.1 6.1, 51 -(b)

1562 Arsenical dust 60 6.1 6.1, 51-(b)

1564 Barium compound, n.o.s. 60 6.1 6.1, 60°(b),(c)

1566 Beryllium compound, no.s. 60 6.1 6.1,540(b)2.,(c)

1567 Beryllium powder 64 6.1+4.1 6.1, 54°(b)1.

1569 Bromoacetone 63 6.1+3 6.1, 16-(b)

1570 Brucine 66 6.1 6.1, 90"(a)

1572 Cacodylic acid 60 6.1 6.1, 51°(b)

1573 Calcium arsenate 60 6.1 6.1, 51-(b)

1574 Calcium arsenate and calcium 60 6.1 6.1, 51°(b)arsenite mixture, solid

1577 Chlorodinitrobenzenes 60 6.1 6.1, 12°(b)

1578 Chloronitrobenzenes 60 6.1 6.1, 12°(b)

1579 4-Chloro-o-toluidine hydrochloride 60 6.1 6.1, 17°(c)

1580 Chloropicrin 66 6.1 6.1, 17'(a)

1581 Mixtures of methyl bromide and 26 6.1 2, 4°(at)chloropicrin (liquefied gas)

1582 Mixtures of methyl chloride and 236 3+6.1 2, 4°(bt)L ___ chloropicrin (liquefied gas) I I

Vol. 1845. A-8940


Subsatnce Name of subsLance Hazard Label Class and itemIdentification Identification number

No. No.(Lower part) (Upper pai)

(a) (b) () (d) (e)

1583 Chloropicrin mixture, n.o.s. 66 6.1 6.1, 17"(a)

1583 Chloropicrin mixure, n.o.s. 60 6.1 6.1, 170(b),(c)

1585 Copper acetoarsenite 60 6.1 6.1, 51 -(b)

1586 Copper arsenite 60 6.1 6.1, 51 -(b)

1587 Copper cyanide 60 6.1 6.1, 41-(b)

1588 Cyanides, inorganic, solid, n.o.s. 66 6.1 6.1, 41*(a)

1588 Cyanides, inorganic, solid, n.o.s. 60 6.1 6.1, 41(b),(c)

1590 Dichloroanilines 60 16.1 6.1, 12 0(b)

1591 o-Dichlorobenzene 60 6.1 6.1, 15"(c)

1593 Dichloromethane 60 6.1 6.1, 15°(c)

1594 Diethyl sulphate 60 6.1 6.1, 14-(b)

1595 Dimethyl sulphate 668 6.1+8 6.1, 27°(a)

1596 Dinitroanilines 60 6.1 6.1, 12 0(b)

1597 Dinitrobenzenes 60 6.1 6.1, 12 0(b)

1598 Dinitro-o-cresol 60 6.1 6.1, 12°(b)

1599 Dinitrophenol solution 60 6.1 6.1, 12°(b),(c)

1600 Dinitrotoluenes, molten 60 6.1 6.1, 24 0(b)].

1601 Disinfectant, solid, toxic, n.o.s. 66 6.1 6.1, 250(a)

1601 Disinfectant, solid, toxic, n.o.s. 60 6.1 6.1, 25°0b),(c)

1602 Dye, liquid, toxic, n.o.s. 66 6.1 6.1, 25-(a)

1602 Dye, liquid, toxic, n.o.s. 60 6.1 6.1, 25°(b),(c)

1602 Dye intermediate, liquid, toxic, n.o.s. 66 6.1 6.1, 25°(a)

1602 Dye intermediate, liquid, toxic, n.o.s. 60 6.1 6.1, 25°(b),(c)

1603 Ethyl bromoacetate 63 6.1+3 6.1, 16-(b)

1604 Ethylenediamine 83 8+3 8, 54 0(b)

1605 Ethylene dibromide 66 6.1 6.1, 15°(a)

1606 Ferric arsenate 60 6.1 6.1, 510(b)

1607 Ferric arsenite 60 6.1 6.1, 51°(b)

1608 Ferrous arsenate 60 6.1 6.1, 51(b)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Clas and itemIdentiication Identification number

No. No(Lower put) (Upper pt)

(a) (b) (c) (d) (e)

1610 Halogenated irritating liquid, n.o.s. 66 6.1 6.1, 17"(a)

1610 Halogenated irritating liquid, n.o.s. 60 6.1 6.1, 17(b),(c)

1611 Hexaethyl tetraphosphate 60 6.1 6.1, 23°(b)

1613 Hydrogen cyanide, aqueous solution 663 6.1+3 6.1, 2 °

(Hydrocyanic acid)

1616 Lead acetate 60 6.1 6.1, 62°(c)

1617 Lead arsenates 60 6.1 6.1, 51(b)

1618 Lead arsenites 60 6.1 6.1, 51(b)

1620 Lead cyanide 60 6.1 6.1, 41°(b)

1621 London purple 60 6.1 6.1, 51°(b)

1622 Magnesium arsenate 60 6.1 6.1, 51 (b)

1623 Mercuric arsenate 60 6.1 6.1, 510(b)

1624 Mercuric chloride 60 6.1 6.1. 52°(b)

1625 Mercuric nitrate 60 6.1 6.1, 52°(b)

1627 Mercurous nitrate 60 6.1 6.1, 52-(b)

1629 Mercury acetate 60 6.1 6.1, 52°(b)

1630 Mercury ammonium chloride 60 6.1 6.1, 52*(b)

1631 Mercury benzoate 60 6.1 6.1. 52°b)

1634 Mercury bromides 60 6.1 6.1, 52°b)

1636 Mercuy cyanide 60 6.1 6.1, 41 -(b)

1637 Mercury gluconate 60 6.1 6.1, 52"b)

1638 Mercury iodide 60 6.1 6.1, 52-(b)

1639 Mercury nucleate 60 6.1 6.1, 52 0(b)

1640 Mercury oleate 60 6.1 6.1, 52-(b)

1641 Mercury oxide 60 6.1 6.1, 52°(b)

1642 Mercury oxycyanide, desensitized 60 6.1 6.1, 41 -(b)

1643 Mercury potassium iodide 60 6.1 6.1, 52'(b)

1644 Mercury salicylate 60 6.1 6.1. 52 (b)

1645 Mercury sulphate 60 6.1 6.1, 52°(b)

1646 Mercury thiocyanate 60 6.1 6.1, 52-(b)

Vol. 1845, A-8940


Substance Nane of subst=ee Hazard Label Cluss and itemIdentification Identlication number

No. No(Lower pea) (Upper part)

(a) (b) (C) (d) (e)

1647 Mixtures of methyl bromide and 236 3+6.1 2, 4(bt)ethylene bromide

1647 Methyl bromide and ethylene 66 6.1 6.1, 15°(a)dibromide mixture, liquid

1648 Acetonitrile (methyl cyanide) 33 3 3. 3*(b)

1649 Motor fuel anti-knock mixture 66 6.1 6.1, 31*(a)

1650 beta-Naphthylamine 60 6.1 6.1, 12°(b)

1651 Naphthylthiourea 60 6.1 6.1, 21°(b)

1652 Naphthylurea 60 6.1 6.1, 12(b)

1653 Nickel cyanide 60 6.1 6.1, 41°(b)

1654 Nicotine 60 6.1 6.1, 90°(b)

1655 Nicotine compound or nicotine 66 6.1 6.1, 90°(a)preparation, solid, n.o.s.

1655 Nicotine compound or nicotine 60 6.1 6.1, 90°(b),(c)preparation, solid, n.o.s.

1656 Nicotine hydrochloride or nicotine 60 6.1 6.1, 90°(b)hydrochloride solution

1657 Nicotine sajicylate 60 6.1 6.1, 90'(b)

1658 Nicotine sulphate, solid 60 6.1 6.1, 90*(b)

1658 Nicotine sulphate, solution 60 6.1 6.1, 90-(b)

1659 Nicotine tartrate 60 6.1 6.1, 90°(b)

1661 Nitroanilines (o-,m-,p-) 60 6.1 6.1, 12°(b)

1662 Nitrobenzene 60 6.1 6.1, 12°(b)

1663 Nitrophenols (o-,m-,p-) 60 6.1 6.1, 12°(c)

1664 Nitrotoluenes (o-,m-,p-) 60 6.1 6.1, 12°(b)

1665 Nitroxylenes (o-,m-,p-) 60 6.1 6.1, 12°(Nb)

1669 Pentachloroethane 60 6.1 6.1, 15-(b)

1670 Perchloromethyl mercaptan 66 6.1 6.1, 17°(a)

1671 Phenol, solid 60 6.1 6.1, 14(b)

1672 Phenylcarbylamine chloride 66 6.1 6.1, 17'(a)

1673 Phenylenediamines (o-,m-,p-) 60 6.1 6.1. 12°(c)

Vol. 1845, A-8940

470 United Nations - Treaty Series a Nations Unies - Recueil des Trait~s

Substance Name or tubstance Hazard Label Class and itemIdentificaion Identificaion number

No. No.(Lower pan) (Upper Pas)

(a) (b) (C) (d) (e)

1674 Phenylmercuric acetate 60 6.1 6.1, 33°(b)

1677 Potassium arsenate 60 6.1 6.1, 51 *(b)

1678 Potassium arsenite 60 6.1 6.1, 51 (b)

1679 Potassium cuprocyanide 60 6.1 6.1, 41-(b)

1683 Silver arsenite 60 6.1 6.1, 51 °(b)

1684 Silver cyanide 60 6.1 6.1, 41(b)

1685 Sodium arsenate 60 6.1 6.1, 51"(b)

1686 Sodium arsenite, aqueous solution 60 6.1 6.1, 51 °(b),(c)

1688 Sodium-.cacodylate 60 6.1 6.1, 51*(b)

1690 Sodium fluoride 60 6.1 6.1, 63°(c)

1691 Strontium arsenite 60 6.1 6.1, 51 °(b)

1692 Strychnine or strychnine salts 66 6.1 6.1, 90*(a)

1693 Tear gas substance, liquid or 66 6.1 6.1, 25°(a)solid, n.o.s.

1693 Tear gas substance, liquid or 60 6.1 6.1, 25*(b)solid, n.o.s.

1694 Bromobenzyl cyanides 66 6.1 6.1, 17°(a)

1695 Chloroacetone, stabilized 60 6.1 6.1. 17*(b)

1697 Chloroacetophenone 60 6.1 6.1, 17 0(b)

1698 Diphenylamine chloroarsine 66 6.1 6.1, 340(a)

1699 Diphenylchloroarsine 66 6.1 6.1, 34°(a)

1701 Xylyl bromide 60 6.1 6.1. 15°b)

1702 1, 1,2,2-Tetrachloroethane 60 6.1 6.1, 15-(b)

1704 Tetraethyl dithiopyrophosphate 60 6.1 6.1, 230(b)

1707 Thallium compound, n.o.s. 60 6.1 6.1, 53°(b)

1708 Toluidines 60 6.1 6.1, 12°(b)

1709 2,4-Toluylenediamine 60 6.1 6.1, 12°(c)

1710 Trichloroethylene 60 6.1 6.1, 150(c)

1711 Xylidines 60 6.1 6.1, 12-(b)

1712 Zinc arsenate 60 6.1 6.1, 51°(b)

Vol. 1845, A-8940

1995


Substance Name of substance Hazard Label Clan and item

Identification Identification numberNo. No.

(Lower part) (Upper par).(a) (b) (e) (d) (e)

1712 Zinc arsenate and zinc arsenite 60 6.1 6.1, 51 0(b)mixture

1712 Zinc arsenite 60 6.1 6.1, 51(b)

1713 Zinc cyanide 66 6.1 6.1, 41 *(a)

1715 Acetic anhydride 83 8+3 8, 32°b)2.

1716 Acetyl bromide 80 8 8, 35°(b)l.

1717 Acetyl chloride X338 3+8 3, 25°(b)

1718 Butyl acid phosphate 80 8 8, 38*(c)

1719 Caustic alkali liquid, n.o.s. 80 8 8, 42 0(b),(c)

1722 Allyl chloroformate 668 6.1+8+3 6.1, 28°(a)

1723 Allyl iodide 338 3+8 3, 25(b)

1724 Allyltrichlorosilane, stabilized X839 8+3 8, 37-(b)

1725 Aluminium bromide, anhydrous 80 8 8, 11 0(b)

1726 Aluminium chloride, anhydrous 80 8 8, 11 0(b)

1727 Ammonium hydrogendifluoride, solid 80 8 8, 9°(b)

1728 Amyltrichlorosilane X80 8 8, 36°(b)

1729 Anisoyl chloride 80 8 8, 35°(b)1.

1730 Antimony pentachloride, liquid 80 8 8, 12-(b)

1731 Antimony pentachloride solution 80 8 8, 12°(b),(c)

1732 Antimony pentafluoride 86 8+6.1 8, 10-(b)

1733 Antimony trichloride 80 8 8, 11 0(b)

1736 Benzoyl chloride 80 8 8, 35-(b)1.

1737 Benzyl bromide 68 6.1+8 6.1, 27°(b)

1738 Benzyl chloride 68 6.1+8 6.1, 27 0(b)

1739 Benzyl chloroformate 88 8 8, 64°(a)

1740 Hydrogendifluorides, n.o.s. 80 8 8, 9(b),(c)

1742 Boron trifluoride acetic acid complex 80 8 8, 33-(b)

1743 Boron trifluoride propionic acid 80 8 8, 33°(b)c o m p l e x I_1__ _

1744 Bromine or bromine solution 886 8+6.1 8, 14'

Vol. 1845, A-8940


Sujbstance Name of substance HzAud Labe Class and itemldentifieation ldenhification number

No. No.(Lower pan) (Upper Past)

(a) (b) (c) (d) (e)

1745 Bromine pentafluoride 568 5.1+6.1+8 5.1, 5*

1746 Bromine trifluoride 568 5.1+6.1+8 5.1, 5

1747 Butyltrichlorosilane X83 8+3 8, 37'(b)

1748 Calcium hypochlorite, dry 50 5.1 5.1, 15"(b)

1748 Calcium hypochlorite mixture, dry 50 5.1 5.1, 15(b)

1750 Chloroacetic acid solution 68 6.1+8 6.1, 27'(b)

1751 Chloroacetic acid, solid 68 6.1+8 6.1, 27'(b)

1752 Chloroacetyl chloride 668 6.1+8 6.1, 27'(a)

1753 Chlorophenyltrichlorosilane X80 8 8, 36-(b)

1754 Chlorosulphonic acid 88 8 8, 12*(a)

1755 Chromic acid solution 80 8 8, 17"(b),(c)

1756 Chromic fluoride, solid 80 8 8, 9'(b)

1757 Chromic fluoride solution 80 8 8, 80(b),(c)

1758 Chromium oxychloride 88 8 8, 12°(a)

1759 Corrosive solid, n.o.s. 88 8 8, 65*(a)

1759 Corrosive solid, n.o.s. 80 8 8, 650(b),(c)

1760 Corrosive liquid, n,o.s. 88 8 8, 66"(a)

1760 Corrosive liquid, n.o.s. 80 8 8, 66"(b),(c)

1761 Cupriethylenediamine solution 86 8+6.1 8, 53"(b),(c)

1762 Cyclohexenyltrichlorosilane X80 8 8, 36-(b)

1763 Cyclohexyltrichlorosilane X80 8 8, 36"(b)

1764 Dichloroacetic acid 80 8 8, 32"(b)l.

1765 Dichloroacetyl chloride X80 8 8, 35"(b)1.

1766 Dichlorophenyltrichlorosilane X80 8 8, 36'(b)

1767 Diethyldichlorosilane X83 8+3 8, 37*(b)

1768 Difluorophosphoric acid, anhydrous 80 8 8, 8*(b)

1769 Diphenyldichlorosilane X80 8 8, 36°(b)

1770 Diphenylmethyl bromide 80 8 8, 65'(b)

1771 Dodecyltrichlorosilane X80 8 8, 36°(b)

Vol. 1945, A-8940

United Nations - Treaty Series 9 Nations Unies - Recueil des Trait~s

Substance Name of substance Hazard Label Class and itemIdentification denti iicion number

No. No.(Lo.wcr pat) (Upper pat)

(a) (b) (e) (d) (e)

1773 Ferric chloride, anhydrous 80 8 8, 11 °(c)

1775 Fluoroboric acid 80 8 8, 80)

1776 Fluorophosphoric acid, anhydrous 80 8 8, 8-(b)

1777 Fluorosulphonic acid 88 8 8, 80(a)

1778 Fluorosilicic acid 80 8 8, 8 0(b)

1779 Formic acid 80 8 8, 32°(b)1.

1780 Fumaryl chloride 80 8 8, 35°(b)1.

1781 Hexadecyltrichlorosilane X80 8 8, 36'(b)

1782 Hexafluorophosphoric acid 80 8 8, 8'(b)

1783 Hexamethylenediamine solution 80 8 8, 53°(b),(c)

1784 Hexyltrichlorosilane X80 8 8, 36'(b)

1786 Hydrofluoric acid and sulphuric acid 886 8+6.1 8, 7°(a)mixture

1787 Hydriodic acid 80 8 8, 5°(b),(c)

1788 Hydrobromic acid 80 8 8, 5°(b),(c)

1789 Hydrochloric acid 80 8 8, 5°(b),(c)

1790 Hydrofluoric acid with more than 85% 886 8+6.1 8, 6'hydrogen fluoride

1790 Hydrofluoric acid with more than 60% 886 8+6.1 8, 7°(a)but not more than 85% hydrogenfluoride

1790 Hydrofluoric acid with not more than 86 8+6.1 8, 7°(b)60% hydrogen fluoride

1791 Hypochlorite solution with between 80 8 8, 61 -(b)5 and 16% active chlorine

1791 Hypochlorite solution with more than 80 8 8, 61 (c)5% but less than 16% availablechlorine

1792 Iodine monochloride 80 8 8, 12'(b)

1793 Isopropyl acid phosphate 80 8 8, 38°(c)

1794 Lead sulphate 80 8 8, 1°(b)

Nitrating acid mixture with more than50% nitric acid

8+05 8, 3(a)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Class and itemIdentifcation Idctiricafion number

No No.(Lower pIA) (Upper pat)

(a) (b) (c) (d) (c)

1796 Nitrating acid mixture with not more 80 8 8, 3-(b)

than 50% nitric acid

1799 Nonyltrichlorosilane X80 8 8, 36*(b)

1800 Octadecyltrichlorosilane X80 8 8, 36*(b)

1801 Octyltrichlorosilane X80 8 8, 36°(b)

1802 Perchloric acid 85 8+05 8, 4-(b)

1803 Phenolsulphonic acid, liquid 80 8 8, 34°(b)

1804 Phenyltrichlorosilane X80 8 8, 36*(b)

1805 Phosphoric acid 80 8 8, 17*(c)

1806 Phosphorus pentachloride 80 8 8, 11 °(b)

1807 Phosphorus pentoxide 80 8 8, 16°(b)

1808 Phosphorus tribromide 80 8 8, 12'(b)

1809 Phosphorus trichloride 886 8+6.1 8, 12°(a)

1810 Phosphorus oxychloride 80 8 8, 12°(b)

1811 Potassium hydrogendifluoride 86 8+6.1 8, 9°(b)

1812 Potassium fluoride 60 6.1 6.1, 63°(c)

1813 Potassium hydroxide, solid 80 8 8, 41 °(b)

1814 Potassium hydroxide solution 80 8 8, 42°(b),(c)

1815 Propionyl chloride 338 3+8 3, 25'(b)

1816 Propyltrichlorosilane X83 8+3 8, 37-(b)

1817 Pyrosulphuryl chloride 80 8 8, 12'(b)

1818 Silicon tetrachloride 80 8 8, 12°(b)

1819 Sodium aluminate solution 80 8 8, 42°(b),(c)

1823 Sodium hydroxide, solid 80 8 8, 41-(b)

1824 Sodium hydroxide solution 80 8 8, 420(b),(c)

1825 Sodium monoxide 80 8 8, 41 -(b)

1826 Nitrating acid mixture, spent with not 80 8 8, 3-(b)more than 50% nitric acid 1

1826 Nitrating acid mixture, spent with 885 8+05 8, 3°(a)more than 50% nitric acid I

Vol. 1845, A-8940

1995 United Nations - Treaty Series a Nations Unies - Recueil des Trait6s 475

Subsace Name of subsancc Hazard Label Cram tem

Identication Idenzification number

No. No.(Lower pa.n) (Upper pal)

(a) (b) (C) (d) ()

1827 Stannic chloride, anhydrous 80 8 8, 120(b)

1828 Sulphur chlorides X88 8 8, 12-(a)

1829 Sulphur trioxide, inhibited X88 8 8, 1 (a)

1830 Sulphuric acid, with more than 51% 80 8 8, 10()acid

1831 Sulphuric acid, fuming X886 8+6.1 8, 1-(a)

1832 Sulphuric acid, spent 80 8 8, 1°(b)

1833 Sulphurous acid 80 8 8. 1 "(b)

1834 Sulphuryl chloride X88 8 8, 120(a)

1835 Tetramethylammonium hydroxide 80 8 8, 51 -(b)

1836 Thionyl chloride X88 8 8, 12°(a)

1837 Thiophosphoryl chloride 80 8 8, 12°(b)

1838 Titanium tetrachloride 80 8 8, 12-(b)

1839 Trichloroacetic acid 80 8 8, 31 0 (b)

1840 Zinc chloride solution 80 8 8, 5°(c)

1843 Ammonium dinitro-o-cresolate 60 6.1 6.1, 12 0(b)

1846 Carbon tetrachloride 60 6.1 6.1, 15'(b)

1847 Potassium sulphide, hydrated 80 8 8, 45°(b)1.

1848 Propionic acid 80 8 8, 32°(c)

1849 Sodium sulphide, hydrated 80 8 8, 45-(b)1.

1851 Medicine, liquid, toxic, n.o.s. 60 6.1 6.1, 90°(b),(c)

1858 Hexafluoropropylene (R 1216) 26 6.1 2, 3*(at)

1860 Vinyl fluoride 239 3 2, 50(c)

1862 Ethyl crotonate 33 3 3, 3-(b)

1863 Fuel, aviation, turbine engine 33 3 3, 1 *(a),2°(a),(b), 3*(b)

1863 Fuel, aviation, turbine engine 30 3 3, 31°(c)

1866 Resin solution 33 3 3, 5°(a),(b),(c)

1866 Resin solution 30 3 3, 31 °(c)

1868 Decaborane 46 4.1+6.1 4.1. 16'(b)

Vol. 1845, A-8940


Subtanc Name of ublstance Hazard Label Clus and itemIdentificazion Identification number

No. No.(Lower part) (upper PAR)

(a) (b) () (d) (e)

1869 Magnesium 40 4.1 4.1, 13°(c)

1869 Magnesium alloys 40 4.1 4.1, 13°(c)

1871 Titanium hydride 40 4.1 4.1, 14(b)

1872 Lead dioxide 56 5.1+6.1 5.1, 29°(c)

1873 Perchloric acid, with more than 50% 558 5.1+8 5.1, 3°(a)but not more than 72% acid, bymass

1884 Barium oxide 60 6.1 6.1, 60'(c)

1885 Benzidine 60 6.1 6.1, 12-(b)

1886 Benzylidene chloride 60 6.1 6.1, 15'(b)

1887 Bromochloromethane 60 6.1 6.1, 15'(c)

1888 Chloroform 60 6.1 6.1, 15°(c)

1889 Cyanogen bromide 668 6.1+8 6.1, 27°(a)

1891 Ethyl bromide 60 6.1 6.1, 150 (b)

1892 Ethyldichloroarsine 66 6.1 6.1, 34"(a)

1894 Phenylmercuric hydroxide 60 6.1 6.1, 33°(b)

1895 Phenylmercuric nitrate 60 6.1 6.1, 33°b)

1897 Tetrachloroethylene 60 6.1 6.1, 15°(c)

1898 Acetyl iodide 80 8 8, 35*(b)1.

1902 Diisooctyl acid phosphate 80 8 8, 38°(c)

1903 Disinfectant, liquid, corrosive, 88 8 8, 66°(a)n,o.s.

1903 Disinfectant, liquid, corrosive, 80 8 8, 66°(b),(c)n.o.s.

1906 Sludge acid so 8 8, 1°(b)

1907 Soda lime 80 8 8, 41°(c)

1908 Chlorite solution with not less than s0 8 8, 61"(b),(c)16% available chlorine

1912 Mixtures of methyl chloride and 236 3+6.1 2, 4°(bt)methylene chloride (liquefied gas) I 1 _

1913 Neon, deeply-refrigerated 22 22, 7(a)

Vol 1845, A-8940


Subslance Name of substance Hazard Label Class an item

Identification Identificafion numberNo. No.

(Lower pat) (Upper pai)(a) (b) (c) (d) (e)

1914 Butyl propionate 30 3 3, 31°(c)

1915 Cyclohexanone 30 3 3, 31 °(c)

1916 2,2'-Dichlorodiethyl ether 63 6.1+3 6.1, 160(b)

1917 Ethyl acrylate, inhibited 339 3 3, 3(b)

1918 Isopropylbenzene (Cumene) 30 3 3, 31°(c)

1919 Methyl acrylate, inhibited 339 3 3. 3-(b)

1920 Nonanes 30 3 3, 31 °(c)

1921 Propyleneimine, inhibited 336 3+6.1 3, 120

1922 Pyrrolidine 338 3+8 3, 23°(b)

1923 Calcium dithionite 40 4.2 4.2, 13'(b)

1928 Methyl magnesium bromide in ethyl X323 4.3+3 4.3, 3°(a)ether

1929 Potassium dithionite 40 4.2 4.2, 13'(b)

1932 Zirconium scrap 40 4.2 4.2, 12°(c)

1935 Cyanide solution, n.o.s. 66 6.1 6.1, 41 *(a)

1935 Cyanide solution, n.o.s. 60 6.1 6.1, 41 °(b),(c)

1938 Bromoacetic acid 80 8 8, 31(b)

1939 Phosphorus oxybromide 80 8 8, 11 (b)

1940 Thioglycolic acid 80 8 8, 32°(b)1.

1942 Ammonium nitrate 50 5.1 5.1, 21 ° (c)

1951 Argon, deeply-refrigerated 22 2 2, 7O(a)

1952 Carbon dioxide containing not more 239 3 2, 6°(c)than 35% ethylene oxide by mass

1957 Deuterium 23 3 2, 1(b)

1958 1,2-Dichloro-1,1,2,2-tetra- 20 2 2, 3°(a)fluoroethane (RI 14)

1959 1, 1-Difluoroethylene (Vinylidene 239 3 2, 5-(c)fluoride)

1961 Ethane, deeply-refrigerated 223 3 2, 7-(b)

1962 Ethylene 23 3 2, 5°(b)

1963 Helium, deeply-refrigerated 22 2 2,7 0 (a)

Vol. 1845, A-8940


SubvAncc Name of subvAncc Hazad Label Clu and itemIdentt*,iion lderificZion number

No. No.(Lower put) (Upper pa)

(a) (b) () (d) ()

1965 Mixtures of hydrocarbons (liquefied 23 3 2, 4(b)gases) (Mixtures A. AO, A l, Band C)

1966 Hydrogen, deeply-refrigerated 223 3 2, 7°(b)

1969 Isobutane 23 3 2, 3°(b)

1970 Krypton, deeply-refrigerated 22 2 2, 7(a)

1971 Methane, compressed 23 3 2, 1(b)

1971 Natural gas, compressed 23 3 2, 2°(b)

1972 Natural gas, deeply-refrigerated 223 3 2, 8'(b)

1972 Methane, deeply-refrigerated 223 3 2, 7'(b)

1973 Gas mixture R 502 20 2 2, 4°(a)

1974 Bromochlorodifluoromethane 20 2 2, 3°(a)(R 12B1)

1976 Octafluorocyclobutane (RC 318) 20 2 2, 3°(a)

1977 Nitrogen, deeply-refrigerated 22 2 2, 7°(a)

1978 Propane, technically-pure 23 3 12, 3'(b)

1982 Tetrafluoromethane (R 14) 20 2 2, 1'(a)

1983 1-Chloro-2,2,2-trifluoroethane 20 2 2, 3°(a)(R 133a)

1984 Trifluoromethane (R 23) 20 2 2, S°(a)

1986 Alcohols, flammable, toxic, n.o.s. 336 3+6.1 3, 17°(a),(b)

1986 Alcohols, flammable, toxic, n.o.s. 36 3+6.1 3, 32°(c)

1987 Alcohols, flammable, n.o.s. 33 3 3. 2°(b), 3°(b)

1987 Alcohols, flammable, n.o.s. 30 3 3, 31°(c)

1988 Aldehydes, flammable, toxic, n.o.s. 336 3+6.1 3, 17°(a),(b)

1988 Aldehydes, flammable, toxic, n.o.s. 36 3+6.1 3, 320(c)

1989 Aldehydes, flammable, n.o.s. 33 3 3, 2*(b), 3°(b)

1989 Aldehydes, flammable, n.o.s. 30 3 3, 31 °(c)

1991 Chloroprene. inhibited 336 3+6.1 3, 160 (a)

1992 Flammable liquid, toxic, n.o.s. 336 3+6.1 3. 19°(a),(b)

1992 Flammable liquid, toxic, n.o.s. 36 3+6.1 3, 32°(c)

Vol. 1945, A-8940

1995

1995 United Nations - Treaty Series * Nations Unies - Recueii des Traitks 479

Substnce Namc of aubstance Hazard Label Clas and itemIdentificafion Ideecrticatjon number

No. No.(Lowcr ptn) (Upper p-t)

(a) (b) (€) (d) (C)

1993 Flammable liquid, n.o.s. 33 3 3, 1 (a),20(a),(b), 30 (b),50(c)

1993 Flammable liquid. n.o.s. 30 3 3, 31 °(c)

1994 Iron pentacarbonyl 663 6.1+3 6.1, 3°

1999 Tars, liquid 33 3 3, 5°(b),(c)

1999 Tars, liquid 30 3 3, 31°(c)

2001 Cobalt naphthenates, powder 40 4.1 4.1, 12'(c)

2003 Metal alkyls, n.o.s. or metal X333 4.2+4.3 4.2, 31°(a)aryls, n.o.s.

2004 Magnesium diamide 40 4.2 4.2, 16(b)

2005 Magnesium diphenyl X333 4.2+4.3 4.2, 31 *(a)

2008 Zirconium powder, dry 40 4.2 4.2, 12°(b),(c)

2014 Hydrogen peroxide, aqueous solution 58 5.1+8 5.1, 1*(b)

2015 Hydrogen peroxide, stabilized 559 5.1+8 5.1, 1 '(a)

2015 Hydrogen peroxide, aqueous 559 5.1+8 5.1, 1°(a)solution, stabilized

2018 Chloroanilines, solid 60 6.1 6.1, 12-(b)

2019 Chloroanilines, liquid 60 6.1 6.1, 120(b)

2020 Chlorophenols, solid 60 6.1 6.1, 17°(c)

2021 Chlorophenols, liquid 60 6.1 6.1, 17°(c)

2022 Cresylic acid 68 6.1+8 6.1, 27-(b)

2023 Epichlorohydrin 63 6.1+3 6.1, 16-(b)

2024 Mercury compound, liquid, n.o.s. 66 6.1 6.1, 52°(a)

2024 Mercury compound, liquid, n.o.s. 60 6.1 6.1, 52°(b),(c)

2025 Mercury compound, solid, n.o.s. 66 6.1 6.1, 520(a)

2025 Mercury compound, solid, n.o.s. 60 6.1 6.1, 52°(b),(c)

2026 Phenylmercuric compound, n.o.s. 66 6.1 6.1, 33°(a)

2026 Phenylmercuric compound, n.o.s. 60 6.1 6.1, 33 0(b),(c)

2027 Sodium arsenite, solid 60 6.1 6.1, 51°(b)

2030 Hydrazine hydrat,- 86 8+6.1 8, 44°(b)

Vol. 1845, A-8940


Subtamce Name of aubuance Haznl Label Clais and itemIdentification Idwnzificalion number

No. No.(Lower pan) (Upper pat)

(a) (b) (c) (d) (e)

2030 Hydrazine, aqueous solution 86 8+6.1 8, 44(b)

2031 Nitric acid containing less than 80 8 8, 2-(b)70% pure acid

2031 Nitric acid containing more than 88 8 8, 2*(a)l.

70% pure acid

2032 Nitric acid, red fuming 856 8+05+6.1 8, 2°(a)2.

2033 Potassium monoxide 80 8 8. 41 °(b)

2035 1,1,1-Trifluoroethane 23 3 2, 3°(b)

2036 Xenon 20 2 2, 5°(a)

2038 Dinitrotoluenes 60 6.1 6.1, 12°(b)

2045 Isobutyraldehyde 33 3 3, 3-(b)

2046 Cymenes (o-,m-,p-) (Methyl 30 3 3, 31°(c)isopropyl benzenes)

2047 Dichloropropenes 33 3 3, 3°(b)

2047 Dichloropropenes 30 3 3. 31 (c)

2048 Dicyclopentadiene 30 3 3, 31 °(c)

2049 Diethylbenzenes (o-,m-,p-) 30 3 3, 31 a(c)

2050 Diisobutylene, isomeric compounds 33 3 3, 3(b)

2051 2-Dimethylaminoethanol 83 8+3 8, 54-(b)

2052 Dipentene 30 3 3.31 °(c)

2053 Methyl isobutyl carbinol 30 3 3, 31 °(c)

2054 Morpholine 30 3 3, 31 °(c)

2055 Styrene monomer, inhibited 39 3 3. 31°(c)(Vinylbenzene)

2056 Tetrahydrofuran 33 3 3. 3°(b)

2057 Tripropylene 33 3 3, 3°(b)

2057 Tripropylene 30 3 3, 31°(c)

2058 Valeraldehyde 33 3 3, 3°(b)

2059 Nitrocellulose solution, flammable 33 3 3, 4°(a),(by

2059 Nitrocellulose solution, flammable 30 3 3, 34°(c)

Vol. 1845, A-8940


Subtancc Name of substance Hzard Label Clas and itemIdentif ction Identification number

No. No.(Lowcr pa) (Upper par)

(a) (b) () (d) We)

2067 Ammonium nitrate fertilizers, 50 5.1 5.1, 21 (c)type Al

2068 Ammonium nitrate fertilizers, 50 5.1 5.1, 21 °(c)type A2

2069 Ammonium nitrate fertilizers, 50 5.1 5.1, 21 (c)type A3

2070 Ammoniurfi nitrate fertilizers, 50 5.1 5.1, 21 *(c)type A4

2073 Ammonia dissolved in water with 268 6.1 2, 9°(at)more than 35% but not more than40% ammonia

2073 Ammonia dissolved in water with 268 6.1 2, 90(at)more than 40% but not more than50% ammonia

2074 Acrylarnide 60 6.1 6.1, 12°(c)

2075 Chloral, anhydrous, inhibited 60 6.1 6.1, 17-(b)

2076 Cresols (o-,m-,p-) 68 6.1+8 6.1, 27*(b)

2077 alpha-Naphthylamine 60 6.1 6.1, 12°(c)

2078 Toluene diisocyanate 60 6.1 6.1, 190(b)

2079 Diethylenetriamine 80 8 8, 53'(b)

2187 Carbon dioxide, deeply-refrigerated 22 2 2, 7°(a)

2193 Hexafluoroethane (R 116) 20 2 2, 5°(a)

2201 Nitrous oxide, deeply-refrigerated 225 2+05 2, 7-(a)

2205 Adiponitrile 60 6.1 6.1, 12*(c)

2206 Isocyanates, toxic, n.o.s. 60 6.1 6.1, 19(b),(c)

2206 Isocyanate solution, toxic, n.o.s. 60 6.1 6.1, 19°(b),(c)

2208 Calcium hypochlorite mixture, dry 50 5.1 5.1, 15°(c)

2209 Formaldehyde solution 80 8 8, 63°(c)

2210 Maneb 40 4.2+4.3 4.2, 16'(c)

2210 Maneb preparation 40 4.2+4.3 4.2, 16°(c)

2211 Polymeric beads, expandable 90 9 9, 4°(c)

2212 Blue asbestos (Crocidolite) 90 9 9, 1 (b)

Vol 1845, A-8940


Subsance Name of substance Hazard Label Clas and itemIdentification Identification number

No. No.(Lower Par) (Upper par)

(a) (b) (c) (d) (Ce)

2212 Brown asbestos (Amosite or Mysorite) 90 9 9, 1 *(b)

2213 Paraformaldehyde 40 4.1 4.1, 6°(c)

2214 Phthalic anhydride 80 8 8, 31 '(c)

2215 Maleic anhydride 80 8 8, 31°(c)

2217 Seed cake 40 4.2 4.2, 2°(c)

2218 Acrylic acid, inhibited 839 8+3 8, 32°(b)2.

2219 Allyl glycidyl ether 30 3 3, 31°(c)

2222 Anisole (phenyl methyl ether) 30 3 3, 31*(c)

2224 Benzonitrile 60 6.1 6.1, 12°(b)

2225 Benzenesulphonyl chloride 80 8 8, 350(c)

2226 Benzotrichloride 80 8 8, 66°(b)

2227 n-Butyl methacrylate, inhibited 39 3 3, 31 °(c)

2232 Chloroacetaldehyde 66 6.1 6.1, 17 *(a)

2233 Chloroanisidines 60 6.1 6.1, 17°(c)

2234 Chlorobenzotrifluorides (o-,m-,p-) 30 3 3, 31 °(c)

2235 Chlorobenzyl chlorides 60 6.1 6.1, 17°(c)

2236 3-Chloro-4-methylphenyl isocyanate 60 6.1 6.1, 190(b)

2237 Chloronitroanilines 60 6.1 6.1, 17°(c)

2238 Chlorotoluenes (o-,m-,p-) 30 3 3, 31 °(c)

2239 Chlorotoluidines 60 6.1 6.1. 170(c)

2240 Chromosulphuric acid 88 8 8, 1 *(a)

2241 Cycloheptane 33 3 3. 30(b)

2242 Cycloheptene 33 3 3, 3°(b)

2243 Cyclohexyl acetate 30 3 3, 31 °(c)

2244 Cyclopentanol 30 3 3, 3 * (c)

2245 Cyclopentanone 30 3 3, 31°(c)

2246 Cyclopentene 33 13 3, 2-(b)

2247 n-Decane 30 3 3, 31 °(c)

2248 Di-n-butylamine 83 8+3 8, 54-(b)

Vol. 1845, A-8940


Substtnce Name of substance H&2ard Label Class am item

Identiica ion Identificaion numberNo. No.

(Lower pWc) (Upper pa-t)(a) (b) (c) (d) (e)

2250 Dichlorophenyl isocyanates 60 6.1 6.1, 19°(b)

2251 2,5-Norbornadiene, inhibited 339 3 3, 3°(b)(Dicycloheptadiene)

2252 1,2-Dimethoxyethane 33 3 3, 3°(b)

2253 N,N-Dimethylaniline 60 6.1 16.1, 12-(b)

2256 Cyclohexene 33 3 3. 3* b)

2257 Potassium X423 4.3 4.3, 11 *(a)

2258 1,2-Propylenediamine 83 8+3 8, 54°(b)

2259 Triethylenetetramine 80 8 8, 53*(b)

2260 Tripropylamine 38 3+8 3, 33°(c)

2261 Xylenols 60 6.1 6.1, 14 0(b)

2262 Dimethylcarbamoyl chloride 80 8 8, 35-(b)1.

2263 Dimethylcyclohexanes 33 3 3, 3°b)

2264 Dimethylcyclohexylamine 83 8+3 8, 54°(b)

2265 N,N-Dimethylformamide 30 3 3, 31°(c)

2266 Dimethyl-N-propylamine 338 3+8 3, 22-b)

2267 Dimethyl thiophosphoryl chloride 68 6.1+8 6.1, 27 0(b)

2269 3,3'-Iminodipropylamine 80 8 8, 53°(c)

2270 Ethylamine, aqueous solution 338 3+8 3, 22 0(b)

2271 Ethyl amyl ketones 30 3 3, 31 °(c)

2272 N-Ethylaniline 60 6.1 6.1, 12'(c)

2273 2-Ethylaniline 60 6.1 6.1, 12°(c)

2274 N-Ethyl-N-benzylaniline 60 6.1 6.1, 12°(c)

2275 2-Ethylbutanol 30 3 3, 31 °(c)

2276 2-Ethylhexylamine 38 3+8 3, 33°(c)

2277 Ethyl methacrylate 339 3 3," 3- k(b)

2278 n-Heptene 33 3 3, 3°(b)

2279 Hexachlorobutadiene 60 6.1 6.1, 15°(c)

2280 Hexamethylenedianine, solid 80 8 8, 52°(c)

2281 Hexamethylene diisocvanate 60 6.1 6.1, 19°(b)

Vol. 1845. A-8940


Substarce Name of substance Hzard Label Clus a item

Identification ldentification numberNo. No.

(Lower p-) (Upper pan)(a) (b) () (d) (e)

2282 Hexanols 30 3 3, 31 °(c)

2283 Isobutyl methacrylate, inhibited 39 3 3, 31°(c)

2284 Isobutyronitrile 336 3+6.1 3, 11 ()

2285 Isocyanatobenzotrifluorides 63 6.1+3 6.1, 18(0)

2286 Pentamethylheptane (sododecane) 30 3 3, 31 °(c)

2287 Isoheptene 33 3 3, 3°(b)

2288 Isohexene 33 3 3, 3°(b)

2289 Isophoronediamine 80 8 8, 53"()

2290 Isophorone diisocyanate 60 6.1 6.1, 19°(c)

2291 Lead compound, soluble, n.o.s. 60 6.1 6.1, 62 °(c)

2293 4-Methoxy-4-methylpentan-2-one 30 3 3, 31 °(c)

2294 N-Methylaniline 60 6.1 6.1, 12°(c)

2295 Methyl chloroacetate 63 6.1+3 6.1, 16°(b)

2296 Methylcyclohexane 33 3 3, 3°(b)

2297 Methylcyclohexanones 30 3 3, 31 *(c)

2298 Methylcyclopentane 33 3 3, 3*(b)

2299 Methyl dichloroacetate 60 6.1 6.1, 17'(c)

2300 2-Methyl-5-ethylpyridine 60 6.1 6.1, 12'(c)

2301 2-Methylfuran 33 3 3, 3-(b)

2302 5-Methylhexan-2-one 30 3 3, 31 °(c)

2303 Isopropenylbenzene 30 3 3, 31-(c)

2304 Naphthalene, molten 44 4.1 4.1, 5@

2305 Nitrobenzenesulphonic acid 80 8 8, 34°(b)

2306 Nitrobenzotrifluorides 60 6.1 6.1, 12°(b)

2307 3-Nitro-4-chlorobenzotrifluoride 60 6.1 6.1, 12°(b)

2308 Nitrosylsulphuric acid 80 8 8, 10(b)

2309 Octadiene 33 3 3, 30 (b)

2310 Pentan-2,4-dione 30 3 3, 31 *(c)

2311 Phenetidines 60 6.1 6.1, 12"(c)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Class and itemIdentification Identiieation number

No. No.(Lower pan) (Upper pn)

(a) (b) (c) (d) (e)

2312 Phenol, molten 60 6.1 6.1, 24 0(b)

2313 Picolines 30 3 3, 31 *)

2315 Polychlorinated biphenyls 90 9 9, 20(b)

2317 Sodium cuprocyanide solution 66 6.1 6.1, 41°(a)

2318 Sodium hydrosulphide 40 4.2 4.2, 13-(b)

2319 Terpene hydrocarbons, n.o.s. 30 3 3, 31°(c)

2320 Tetraethylenepenramine 80 8 8, 53°(c)

2321 Trichlorobenzenes. liquid 60 6.1 6.1, 15°(c)

2322 Trichlorobutene 60 6.1 6.1, 15*(b)

2323 Triethyl phosphite 30 3 3, 31°(c)

2324 Triisobutylene (Isobutylene trimer) 30 3 3, 31°(c)

2325 1,3,5-Trimethylbenzene 30 3 3, 31 °(c)

2326 Trimethylcyclohexylamine 80 8 8, 530(c)

2327 Trimethylhexamethylenediamines 80 8 8, 530(c)

2328 Trimethylhexamethylene diisocyanate 60 6.1 6.1, 19'()

2329 Trimethyl phosphite 30 3 3, 31 *(c)

2330 Undecane 30 3 3, 31 °(c)

2331 Zinc chloride, anhydrous 80 8 8, 11 °(c)

2332 Acetaldehyde oxime 30 3 3, 31°(c)

2333 Allyl acetate 336 3+6.1 3, 17(b)

2334 Allylamine 663 6.1+3 6.1, 7°(a)2.

2335 Allyl ehtyl ether 336 3+6.1 3, 17-(b)

2336 Allylformate 336 3+6.1 3, 170(a)

2337 Phenyl mercaptan 663 6.1+3 6.1, 200(a)

2338 Benzotrifluoride 33 3 3, 305Q, )

2339 2-Bromobutane 33 3 3, 3°(b)

2340 2-Bromoethyl ethyl ether 33 3 3, 3(b)

2341 1-Bromo-3-methylbutane 30 3 3, 31 °(c)

2342 Bromomethylpropanes 33 3 3, 3*(b)

Vol 1845, A-8940


Substance Name of substance Hazy.d Label Class and itemIdentifcat"ion Identification number

No. No.(Lower part) (Upper pail)

(a) (b) (c) (d) Wo)

2343 2-Bromopentane 33 3 3, 3°(b)

2344 Brornopropanes 33 3 3, 3-(b)

2345 3-Bromopropyne 33 3 3. 3(b)

2346 Butanedione (diacetyl) 33 3 3, 3°(b)

2347 Butyl mercaptan 33 3 3, 3°(b)

2348 Butyl acrylate, inhibited 39 3 3, 31 (c)

2350 Butyl methyl ether 33 3 3, 3°(b)

2351 Butyl nitrites 33 3 3, 3 0(b)

2351 Butyl nitrites 30 3 3, 31°(c)

2352 Butyl vinyl ether, inhibited 339 3 3, 3°(b)

2353 Butyryl chloride 338 3+8 3, 25'(b)

2354 Chloromethyl ethyl ether 336 3+6.1 3, 16°(b)

2356 2-chloropropane 33 3 3, 2-(a)

2357 Cyclohexylamine 83 8+3 8, 54-(b)

2358 Cyclooctatetraene 33 3 3, 3°(b)

2359 Diallylamine 338 3+8+6.1 3, 27-(b)

2360 Diallyl ether 336 3+6.1 3, 17'(b)

2361 Diisobutylamine 38 3+8 3, 33°(c)

2362 1,1-Dichloroethane (Ethylidene 33 3 3, 3*(b)chloride)

2363 Ethyl mercaptan 33 3 3, 2°(a)

2364 n-Propylbenzene 30 3 3, 31 °(c)

2366 Diethyl carbonate (Ethyl carbonate) 30 3 3, 31 °(c)

2367 alpha-Methylvaleraldehyde 33 3 3, 3°(b)

2368 alpha-Pinene 30 3 3, 31 °(c)

2369 Ethylene glycol monobutyl ether 60 6.1 6.1, 140(c)

2370 I-Hexene 33 3 3, 3(b)

2371 Isopentenes 33 3 3, 1 *(a)

2372 1,2-Di-(dimethylamino) ethane 33 3 3, 30 (b)

2373 Diethoxymethane 33 3 3, 3°(b)

Vol. 1845, A-8940


Substcc Name of substance Hazajd Label Clus and itemIdenification Identificltion number

No. No(Lower pai) (Upper pais)

(a) (b) (c) (d) (a)

2374 3,3-Diethoxypropene 33 3 3, 3(b)

2375 Diethyl sulphide 33 3 3, 3°()

2376 2,3-Dihydropyran 33 3 3, 3°(b)

2377 1,i-Dimethoxyethane 33 3 3, 3°b)

2378 2-Dimethylaminoacetonitrile 336 3+6.1 3, 11 -(b)

2379 1,3-Dimethylbutylamine 338 3+8 3. 22-(b)

2380 Dimethyldiethoxysilane 33 3 3, 3*(b)

2381 Dimethyl disulphide 33 3 3, 3°(b)

2382 Dimethylhydrazine, symmetrical 663 6.1+3 6.1, 7°(a)2.

2383 Dipropylarnine 338 3+8 3, 22'(b)

2384 di-n-propyl ether 33 3 3, 3(b)

2385 Ethyl isobutyrate 33 3 3, 3*(b)

2386 I-Ethylpiperidine 338 3+8 3, 23°(b)

2387 Fluorobenzene 33 3 3, 3 °0b)

2388 Fluorotoluenes 33 3 3, 3°(b)

2389 Furan 33 3 3, 1 *(a)

2390 2-lodobutane 33 3 3, 3°Nb)

2391 lodomethylpropanes 33 3 3, 3°(b)

2392 lodopropanes 30 3 3, 31 °(c)

2393 Isobutyl formate 33 3 3, 3°(b)

2394 Isobutyl propionate 33 3 3, 3(b)

2395 Isobuyryl chloride 338 3+8 3, 25°(b)

2396 Methacrylaidehyde, inhibited 336 3+6.1 3, 17-(b)

2397 3-Methylbutan-2-one 33 3 3, 3-(b)

2398 Methyl ten-butyl ether 33 3 3, 3°(b)

2399 i-Methylpiperidine 338 3+8 3, 23-(b)

2400 Methyl isovaerate 33 3 3, 3'(b)

2401 Piperidine 338 3+8 3, 23(b)

2402 Propanethiols (propyl mercaptans) 33 3 3, 3'(b)

Vol. 1845. A-8940


Substatwe Nare of substance Hazard l~bel ClU and itemIdentification ldentification number

No. No.(Lower pat) (Upper par)

(a) (b) () (d) (e)

2403 Isopropenyl acetate 33 3 3, 3°(b)

2404 Propionitrile 336 3+6.1 3, 11°0)

2405 Isopropyl butyrate 30 3 . 3, 31 °(c)

2406 Isopropyl isobutyrate 33 3 3, 3°(b)

2409 Isopropyl propionate 33 3 3, 3°b)

2410 1,2,3,6-Tetrahydropyridine 33 3 3, 3°(b)

2411 Butyronitrile 336 3+6.1 3, 11(b)

2412 Tetrahydrothiophene (tliolanne) 33 3 3, 30(b)

2413 Tetrapropyl orthotitanate 30 3 3, 31-(c)

2414 Thiophene 33 3 3, 3*(b)

2416 Trimethyl borate 33 3 3, 3*0()

2426 Ammonium nitrate, liquid, (hot 59 5.1 5.1, 20 °

concentrated solution)

2427 Potassium chlorate aqueous solution 50 5.1 5.1, 11-(b)

2428 Sodium chlorate, aqueous solution 50 5.1 5.1, 11 0(b)

2429 Calcium chlorate, aqueous solution 50 5.1 5.1, 110(b)

2430 Alkylphenols, solid, n.o.s. 88 8 8, 39°(a)

2430 Alkylphenols, solid, n.o.s. 80 8 8, 39°(b),(c)

2431 Anisidines 60 6.1 6.1, 120(c)

2432 NN-Diethylaniline 60 6.1 6.1, 12°(c)

2433 Chloronitrotoluenes 60 6.1 6.1, 17°(c)

2434 Dibenzyldichlorosilane XS0 8 8, 36-(b)

2435 Ethylphenyldichlorosilane X80 8 8, 36°(b)

2436 Thioacetic acid 33 3 3, 3°00)

2437 Methylphenyldichlorosilane X80 8 8, 36°(b)

2438 Trimethylacetyl chloride 663 6.1+3+8 6.1, 10°(a)

2439 Sodium hydrogendifluoride 80 8 8. 9'(b)

2440 Stannic chloride pentahydrate 80 8 8, 11 -(c)

2442 Trichloroacetyl chloride X80 8 8, 350(b) 1.

2443 1 Vanadium oxytrichloride 80 8 8, 12°(b)

Vol. 1845, A-8940


Substamce Name of substance Hazard Label Clus and itemIdentification Identic-tion number

No. No.(LOwer Pai) (upper pai)

(a) (b) (e) (d) (e)

2444 Vanadium tetrachloride 88 18 8, 12°(a)

2445 Lithium alkyls X333 4.2+4.3 4.2, 31 *(a)

2446 Nitrocresols 60 6.1 6.1, 12°(c)

2447 Phosphorus, white, molten 446 4.2+6.1 4.2, 22-

2448 Sulphur, molten 44 4.1 4.1, 15-

2456 2-Chloropropene 33 3 3, 1 *(a)

2457 2,3-Dimethylbutane 33 3 3, 3"(b)

2458 Hexadiene 33 3 3, 3°(b)

2459 2-Methyl-l-butene 33 3 3, 1 *(a)

2460 2-Methyl-2-butene 33 3 3, 2*(b)

2461 Methylpentadiene 33 3 3, 3 0(b)

2464 Beryllium nitrate 56 5.1+6.1 5.1, 29°(b)

2465 Dichloroisocyanuric acid, dry 50 5.1 5.1, 26*(b)

2465 Dichloroisocyanuric acid salts 50 5.1 5.1. 26°(b)

2467 Sodium percarbonates 50 5.1 5.1, 19°(c)

2468 Trichloroisocyanuric acid, dry 50 5.1 5.1, 26-(b)

2469 Zinc bromate 50 5.1 5.1, 16°(c)

2470 Phenylacetonitrile, liquid 60 6.1 6.1, 120(c)

2473 Sodium arsanilate 60 6.1 6.1, 34°(c)

2474 Thiophosgene 60 6.1 6.1, 21(b)

2475 Vanadium trichloride 80 8 8, 11 (c)

2477 Methyl isothiocyanate 63 6.1+3 6.1, 20°(b)

2478 Isocyanates or isocyanate solution, 336 3+6.1 3, 14(b)flammable, toxic, n.o.s.

2478 Isocyanates or isocyanate solution, 36 3+6.1 3, 32°(c)flammable, toxic, n.o.s.

2482 n-Propyl isocyanate 663 6.1+3 6.1, 6°(a)

2483 Isopropyl isocyanate 336 3+6.1 3, 14°(a)

2484 tert-Butyl isocyanate 663 6.1+3 6.1, 6°(a)

2485 n-Butyl isocyanate 663 6.1+3 6.1, 6°(a)

Vol. 1845, A-8940


Substance Name of substance Hazasd Label Class and itmIdentification Identification nwmber

No. No.(Lower pall) (Upper pa )

(a) (b) (c) (d) (c)

2486 Isobutyl isocyanate 336 3+6.1 3, 14(b)

2487 Phenyl isocyanate 63 6.1+3 6.1, IS(b)

2488 Cyclohexyl isocyanate 63 6.1+3 6.1. 18'(b)

2489 Diphenylmethane-4.4'-diisocyanate 60 6.1 6.1. 19°(c)

2490 Dichloroisopropyl ether 60 6.1 6.1. 17°(b)

2491 Ethanolanine or ethanolamine 80 8 8, 53-(c)solution

2493 Hexamethyleneimine 338 3+8 3, 23-(b)

2495 Iodine pentafluoride 568 5.1+6.1+8 5.1, 5 °

2496 Propionic anhydride 80 8 8, 32-(c)

2498 1,2,3,6-Tetrahydrobenzaldehyde 30 3 3, 31 °(c)

2501 Tris-(1-aziridinyl) phosphine oxide 60 6.1 6.1, 23*(b),(c)solution

2502 Valeryl chloride 83 8+3 8, 35"(b)2.

2503 Zirconium tetrachloride 80 8 8, 11 °(c)

2504 Tetrabromoethane 60 6.1 6.1, 15°(c)

2505 Ammonium fluoride 60 6.1 6.1, 63°(c)

2506 Ammonium hydrogen sulphate 80 8 8, 13°(b)

2507 Chloroplatinic acid, solid 80 8 8, 16°(c)

2508 Molybdenum pentachloride 80 8 8, 11 -(c)

2509 Potassium hydrogen sulphate 80 8 8, 13-(b)

2511 2-Chloropropionic acid 80 8 8, 32-(c)

2512 Aminophenols (o-,m-,p-) 60 6.1 6.1, 12-(c)

2513 Bromoacetyl bromide X80 8 8, 35-(b)1.

2514 Bromobenzene 30 3 3, 31 °(c)

2515 Bromoform 60 6.1 6.1, 15°(c)

2516 Carbon tetrabromide 60 6.1 6.1, 15e(c)

2517 i-Chloro-l,]-difluoroethane (R 142b) 23 3 2, 3°(b)

2518 1,5,9-Cyclododecatriene 60 6.1 6.1, 25-(c)

2520 Cyclooctadienes 30 3 3. 31 °(c)

Vol. 1845, A-8940


Sub tance Nane of substance Haard Label Class and itemIdntfication Identification number

No. No.(Lower pWi) (Upper pail)

(a) (b) (c) (d) (ce)

2521 Diketene, inhibited 663 6.1+3 6.1, 13°(a)

2522 Dimethylaminoethyl methacrylate 69 6.1 6.1, 12°(b)

2524 Ethyl orthoformate 30 3 3, 31 °(c)

2525 Ethyl oxalate 60 6.1 6.1, 14°(c)

2526 Furfurylamine 38 3+8 3, 33°(c)

2527 Isobutyl acrylate, inhibited 39 3 3, 31 o(c)

2528 Isobutyl isobutyrate 30 3 3, 31 "(c)

2529 Isobutyric acid 38 3+8 3, 33°(c)

2530 Isobutyric anhydride 38 3+8 3, 33°(c)

2531 Methacrylic acid, inhibited 89 8 8, 32°(c)

2533 Methyl trichloroacetate 60 6.1 6.1, 17°(c)

2535 Methylmorpholine 338 3+8 3, 23°(b)

2536 Methyltetrahydrofuran 33 3 3, 3°(b)

2538 Nitronaphthalene 40 4.1 4.1, 6"(c)

2541 Terpinolene 30 3 3, 31 '(c)

2542 Tributylamine 80 8 8, 53°(c)

2545 Hafnium powder, dry 40 4.2 4.2, 12°(b),(c)

2546 Titanium powder, dry 40 4.2 4.2, 12°(b),(c)

2552 Hexafluoroacetone hydrate,. 60 6.1 6.1, 17'(b)

2554 Methylallyl chloride 33 3 3, 3°(b)

2558 Epibromohydrin 663 6.1+3 6.1, 16'(a)

2560 2-Methylpentan-2-ol 30 3 3. 31 °(c)

2561 3-Methyl-l-butene 33 3 3. 1 *(a)(Isopropylethylene)

2564 Trichloroacetic acid solution 80 8 8, 32°(b)I.,(c)

2565 Dicyclohexylamine 80 8 8, 53e(c)

2567 Sodium pentachlorophenate 60 6.1 6.1, 17-(b)

2570 Cadmium compound 66 6.1 6.1, 61 *(a)

2570 Cadmium compound 60 6.1 6.1, 61 °(b),(c)

2571 Alkylsulphuric acids 80 8 8, 34°(b)

Vol. 1845, A-8940

492 United Nations - Treaty Series a Nations Unies - Recueil des Trait6s 1995

Subscane Name of substawc Hazard Label Class and itemIdeztifiaeion Identification number

No. No.(Lower pat) (Upper put)

(a) (b) (c) (d) (e)

2572 Phenylhydrazine 60 6.1 6.1, 120(b)

2573 Thallium chlorate 56 5.1+6.1 5.1, 29°(b)

2574 Tricresyl phosphate 60 6.1 6.1, 23-b)

2576 Phosphorus oxybromide, molten 80 8 8, 15-

2577 Phenylacetyl chloride 80 8 8, 35a(b)l.

2578 Phosphorus trioxide 80 8 8, 16*(c)

2579 Piperazine 80 8 8, 52-(c)

2580 Aluminium bromide solution 80 8 8, 5°(c)

2581 Aluminium chloride solution 80 8 8, 5 0 (c)

2582 Ferric chloride solution 80 8 8, 50(c)

2583 Alkylsulphonic acids, solid 80 8 8, 1 0(b)

2583 Arylsulphonic acids, solid 80 8 8, 1 (b)

2584 Alkylsulphonic acids, liquid 80 8 8, 1-(b)

2584 Arylsulphonic acids, liquid 80 8 8, 1 0(b)

2585 Alkylsulphonic acids, solid 80 8 8, 340(c)

2585 Arylsulphonic acids, solid 80 8 8, 34*(c)

2586 Alkylsulphonic acids, liquid 80 8 8, 34°(c)

2586 Arylsulphonic acids, liquid 80 8 8, 34°(c)

2587 Benzoquinone 60 6.1 6.1, 14°(b)

2588 Pesticide, solid, toxic, n.o.s. 66 6.1 6.1, 87 0 (a)

2588 Pesticide, solid, toxic, n.o.s. 60 6.1 6.1, 870(b),(c)

2589 Vinyl chloroacetate 63 6.1+3 6.1, 16-(b)

2590 White asbestos (Actinolite, 90 9 9, 1 °(c)Anthophyllite, Chrysotile orTremol ite)

2591 Xenon, deeply-refrigerated 22 2 2, 7*(a)

2599 Gas mixture R 503 20 2 2, 6°(a)

2600 Town gas 236 3+6.1 2, 2a(bt)

2600 Water gas 236 3+6.1 2, 2°(b)

2600 Synthesis gas 236 3+6.1 2, 2(bt)

Vol. 1845, A-8940


SubeLtnce Name of substance Hazard Label Clau and oam

lderaircaseion Idntifr. ion numberNo. No.

(Lower pan) (Upper p-)(a) (b) () (d) (€)

2602 Gas mixture R 500 20 2 2, 4*(a)

2603 Cycloheptatriene 336 3+6.1 3, 190(b)

2604 Boron trifluoride diethyl etherate 883 8+3 8, 330(a)

2605 Methoxymethyl isocyanate 336 3+6.1 3, 14°(a)

2606 Methyl orthosilicate 663 6.1+3 6.1, 8*(a)(Tetrarnethoxysilane)

2607 Acrolein dimer, stabilized 39 3 3, 31 0(c)

2608 Nitropropanes 30 3 3, 31 °(c)

2609 Triallyl borate 60 6.1 6.1, 14°(c)

2610 Triallylamine 38 3+8 3, 33=(c)

2611 Propylene chlorohydrin 63 6.1+3 6.1, 16°(b)

2612 Methyl propyl ether 33 3 3, 2°(b)

2614 Methailyl alcohol 30 3 3, 31 "(c)

2615 Ethyl propyl ether 33 3 3, 3*(b)

2616 Triisopropyl borate 33 3 3, 3*(b)

2616 Triisopropyl borate 30 3 3. 31 °(c)

2617 Methylcyclohexanols 30 3 3. 31'(c)

2618 Vinyltoluene, inhibited (o-,m-,p-) 39 3 3, 31"(c)

2619 Benzyldimethylamine 83 8+3 8, 54°(b)

2620 Amyl butyrates 30 3 3, 31 *(c)

2621 Acetyl methyl carbinol 30 3 3, 31°(c)

2622 Glycidaldehyde 336 3+6.1 3, 17'(b)

2624 Magnesium silicide 423 4.3 4.3, 12'(b)

2626 Chloric acid, aqueous solution 50 5.1 5.1, 40(b)

2627 Nitrites, inorganic, n.o.s. 50 5.1 5.1, 23'(b)

2628 Potassium fluoroacetate 66 6.1 6.1, 17°(a)

2629 Sodium fluoroacetate 66 6.1 6.1, 17°(a)

2642 Fluoroacetic acid 66 6.1 6.1, 170(a)

2643 Methyl bromoacetate 60 6.1 6.1, 17-(b)

264.4 Methyl iodide 60 6.1 6.1, 15°(b)

Vol 1845, A-8940

493


Subnajnce Name of substance Hazard LAbcl Class and itemldentifcation Idcntification number


(a) (b) (€) (d) (e)

2645 Phenacyl bromide 60 6.1 6.1, 170(b)

2646 Hexachlorocyclopentadiene 66 6.1 6.1, 15*(a)

2647 Malononitrile 60 6.1 6.1, 12"(b)

2648 1,2-Dibromobutan-3-one 60 6.1 6.1, 17a(b)

2649 1,3-Dichloroacetone 60 6.1 6.1. 17*(b)

2650 1, I-Dichloro- I-nitroethane 60 6.1 6.1, 17*(b)

2651 4,4'-Dianinodiphenyl methane 60 6.1 6.1, 12°(c)

2653 Benzyl iodide 60 6.1 6.1. I15(b)

2655 Potassium fluorosilicate 60 6.1 6.1, 640(c)

2656 Quinoline 60 6.1 6.1, 120(c)

2657 Selenium disulphide 60 6.1 6.1, 55"(b)

2658 Selenium powder 60 6.1 6.1, 550(c)

2659 Sodium chloroacetate 60 6.1 6.1, 17°(c)

2660 Nitrotoluidines (mono) 60 6.1 6.1, 120(c)

2661 Hexachloroacetone 60 6.1 6.1, 17"(c)

2662 Hydroquinone 60 6.1 6.1, 14e(c)

2664 Dibromomethane 60 6.1 6.1, 15e(c)

2666 Ethyl cyanoacetate 60 6.1 6.1, 12°(c)

2667 Butyltoluenes 60 6.1 6.1, 25"(c)

2668 Chloroacetonitrile 63 6.1+3 6.1, 11 *(b)

2669 Chlorocresols 60 6.1 6.1, 14(b)

2670 Cyanuric chloride 80 8 8, 39-(b)

2671 Aminopyridines (o-,m-,p-) 60 6.1 6.1, 12*(b)

2672 Ammonia solution containing between 80 8 8, 43-(c)10 and 35% ammonia 1

2673 2-Amino-4-chlorophenol 60 6.1 6.1, 12-(b)

2674 Sodium fluorosilicate 160 6.1. 6.1, 640(c)

2677 Rubidium hydroxide solution 80 8 8, 420(b),(c)

2678 Rubidium hydroxide 80 8 8, 41 °(b)

2679 Lithium hydroxide solution 80 8 8, 42"(b),(c)

Vol. 1845, A-8940


Substance Name of substance Hazd Label Class and aem

IdenificaZon Identiricaion numberNo. No.

(Lower WaA) (Upper p-n)(a) (b) (c) (d) (e)

2680 Lithium hydroxide monohydrate 80 8 8, 41°(b)

2681 Caesium hydroxide solution 80 8 8, 42°(b),(c)

2682 Caesium hydroxide 80 8 8, 41°(b)

2683 Ammonium sulphide solution 86 8+6.1+3 8, 45'(b)2.

2684 Diethylaminopropylamine 38 3+8 3, 33°(c)

2685 N,N-Diethylethylened iamine 83 8+3 8, 54°(b)

2686 Diethylaminoethanol 30 3 3, 31*(c)

2687 Dicyclohexylammonium nitrite 40 4.1 4.1, 11 (c)

2688 1 -Bromo-3-chloropropane 60 6.1 6.1, 15°(c)

2689 Glycerol aipha-monochlorohydrin 60 6.1 6.1, 17°(c)

2690 N,n-Butylimidazole 60 6.1 6.1, 12°(b)

2691 Phosphorus pentabromide 80 8 8, 11 o(b)

2692 Boron tribromide (boron bromide) X88 8 8, 12°(a)

2693 Bisulphites, aqueous solution, n.o.s. 80 8 8, 17°(c)

2698 Tetrahydrophthalic anhydrides- 80 8 8, 31 °(c)

2699 Trifluoroacetic acid 88 8 8, 32*(a)

2705 l-Pentol 80 8 8, 66°(b)

2707 Dimethyldioxanes 33 3 3, 3*(b)

2707 Dimethyldioxanes 30 3 3, 31 °(c)

2708 Butoxyl 30 3 3, 31 '(c)

2709 Butylbenzenes 30 3 3, 31 °(c)

2710 Dipropyl ketone 30 3 3, 31 (c)

2711 Dibromobenzene 30 3 3, 31 '(c)

2713 Acridine 60 6.1 6.1, 12°(c)

2714 Zinc resinate 40 4.1 4.1. 12*(c)

2715 Aluminium resinate 40 4.1 4.1, 12*(c)

2716 1,4-Butynediol 60 6.1 6.1, 14(c)

2717 Camphor, synthetic 40 4.1 4.1, 6°(c)

2719 Barium bromate 56 5.1+6.1 5.1, 29-(b)

Vol. 1845, A-8940

Substance Name of substance Hazard Label Class and itemIdcnifiation Identification number

No. No.(Lower pat) (Upper part)

(a) (b) () (d) ()

2720 Chromium nitrate 50 5.1 5. 1, 22 *(c)

2721 Copper chlorate 50 5.1 5.1, 11 °(b)

2722 Lithium nitrate 50 5.1 5.1, 22°(c)

2723 Magnesium chlorate 50 5.1 5.1, 1l °(b)

2724 Manganese nitrate 50 5.1 .5.1, 22°(c)

2725 Nickel nitrate 50 5.1 15.1. 22°(c)

2726 Nickel nitrite 50 5.1 5.1, 23°(c)

2727 Thallium nitrate 65 6.1+05 6.1, 68°(b)

2728 Zirconium nitrate 50 5.1 5.1, 22°(c)

2729 Hexachlorobenzene 60 6.1 6.1, 15°(c)

2730 Nitroanisole 60 6.1 16.1, 12°(c)

2732 Nitrobromobenzene 60 6.1 6.1, 12°(c)

2733 Amines or polyamines, flammable, 338 3+8 3, 22°(a),(b)corrosive, n.o.s.

2733 Amines or polyamines, flammable, 38 3+8 3, 33°(c)corrosive, n.o.s.

2734 Amines or polyamines, liquid, 883 8+3 8, 54°(a)corrosive, flammable, n.o.s.

2734 Amines or polyamines, liquid, 83 8+3 8. 54°(b)corrosive, flammable, n.o.s.

2735 Amines or polyamines, liquid, 88 8 8. 53(a)corrosive, n.o.s.

2735 Amines or polyamines, liquid, 80 8 8, 53°(b),(c)corrosive, n.o.s.

2738 N-Butylaniline 60 6.1 6.1, 12°(b)

2739 Butyric anhydride 80 8 8, 32°(c)

2740 n-Propyl chloroformate 668 6.1+8+3 6.1, 28°(a)

2741 Barium hypochlorite 56 5.1+6.1 5.1, 29-(b)

2742 Chloroformates, toxic, corrosive, 638 6.1+3+8 6.1, 28°(b)flammable, n.o.s. _

2743 n-Butyl chloroformate 638 6.1+3+8 6.1, 28-(b)

2744 Cyclobutyl chloroformate 638 6.1+3+8 6.1, 28-(b)

Vol 1845, A-8940



Subtance Name of gubstance Hzad Label Class and itemIdentification Idenification number

No. No.(Lower pan) (upper pil)

(a) (b) (€) (d) (e)

2745 Chloromethyl chloroformate 68 6.1+8 6.1, 27-(b)

2746 Phenyl chloroformate 68 6.1+8 6.1, 27°(b)

2747 tert-Butylcyclohexyl chloroformate 60 6.1 6.1, 17°(c)

2748 2-Ethylhexyl chloroformate 68 6.1+8 6.1, 27°(b)

2749 Tetramethylsilane 33 3 3, 1 '(a)

2750 1,3-Dichloropropanol-2 60 6.1 6.1, 17 -(b)

2751 Diethylthiophosphoryl chloride 80 8 8, 35(b)1.

2752 1,2-Epoxy-3-ethoxypropane 30 3 3, 31 °(c)

2753 N-Ethylbenzyltoluidines 60 6.1 6.1, 12°(c)

2754 N-Ethyltoluidines 60 6.1 6.1, 12 °(b)

2757 Carbamate pesticide, solid, toxic 66 6.1 6.1, 74°(a)

2757 Carbamate pesticide, solid, toxic 60 6. 1 6.1, 740(b).(c)

2758 Carbamate pesticide, liquid, 336 3+6.1 3, 44(a),(b)flammable, toxic

2759 Arsenical pesticide, solid, toxic 66 6.1 6.1, 790(a)

2759 Arsenical pesticide, solid, toxic 60 6.1 6.1, 79°(b),(c)

2760 Arsenical pesticide, liquid, 336 3+6.1 3, 490(a),(b)flammable, toxic

2761 Organochlorine pesticide, solid, toxic 66 6.1 6.1, 72°(a)

2761 Organochlorine pesticide,-solid, toxic 60 6.1 6.1, 72*(b),(c)

2762 Organochlorine pesticide, liquid, 336 3+6.1 3, 42°(a),(b)flammable, toxic

2763 Triazine pesticide, solid, toxic 66 6.1 6.1, 82°(a)

2763 Triazine pesticide, solid, toxic 60 6.1 6.1, 82(b),(c)

2764 Triazine pesticide, liquid, flammable, 336 3+6.1 3, 520(a),(b)toxic

2765 Phenoxy pesticide, solid, toxic 66 6.1 6.1, 73'(a)

2765 Phenoxy pesticide, solid, toxic 60 6.1 6.1. 73°(b),(c)

2766 Phenoxy pesticide, liquid, 336 3+6.1 3, 43*(a),(b)flammable, toxic

2767 Phenyl urea pesticide, solid, toxic 66 6.1 6.1, 85°(a)

Vol. 1845, A-8940

498 United Nations - Treaty Series a Nations Unies - Recueil des Traitis

SubsLaoe Name of subxacc Hazwrd Label Cass and itemIdenUrlkation Identiflcaion number

No. No.(Lower pan) (Upper pa-)

(a) (b) (C) (d) (C)

2767 Phenyl urea pesticide, solid, toxic 60 6.1 6.1, 85°(b),(c)

2768 Phenyl urea pesticide, liquid, 336 3+6.1 3, 55°(a),(b)flammable, toxic

2769 Benzoic derivative pesticide, solid, 66 6.1 6.1, 83-(a)toxic

2769 Benzoic derivative pesticide, solid, 60 6.1 6.1, 83°(b),(c)toxic

2770 Benzoic derivative pesticide, liquid, 336 3+6.1 3, 53°(a),(b)flammable, toxic

2771 Dithiocarbamate pesticide, solid, 66 6.1 6.1, 86°(a)toxic

2771 Dithiocarbamate pesticide, solid, 60 6.1 6.1, 860(b),(c)toxic

2772 Dithiocarbamate pesticide, liquid, 336 3+6.1 3, 56°(a),(b)flammable, toxic

2773 Phthalimide derivative pesticide, 66 6.1 6.1, 84°(a)solid, toxic

2773 Phthaiimide derivative pesticide, 60 6.1 6.1, 84°(b),(c)solid, toxic

2774 Phthalimide derivative pesticide, 336 3+6.1 3, 54°(a),(b)liquid, flammable, toxic

2775 Copper based pesticide, solid, toxic 66 6.1 6.1, 800(a)

2775 Copper based pesticide, solid, toxic 60 6.1 6.1, 80*(b),(c)

2776 Copper based pesticide, liquid, 336 3+6.1 3, 50°(a),(b)flammable, toxic

2777 Mercury based pesticide, solid, toxic 66 6.1 6.1, 75*(a)

2777 Mercury based pesticide, solid, toxic 60 6.1 6.1, 75*(b),(c)

2778 Mercury based pesticide, liquid, 336 3+6.1 3, 450(a),(b)flammable, toxic

2779 Substituted nitrophenol pesticide, 66 6.1 6.1: 81*(a)solid, toxic

2779 Substituted nitrophenol pesticide, 60 6.1 6.1, 81 (b),(c)solid, toxic I

2780 Substituted nitrophenol pesticide, 336 3+6.1 3, 51 (a),(b)______ liquid, flammable, toxic I _

Vol. 1845, A-8940

1995


Substaswc Name of substance Hazard Label Class and itemIdentification Identifieation ewober

No. No.(Lower pait) (Upper part)

(a) (b) (c) (d) (e)

2781 Bipyridilium pesticide. solid, toxic 66 6.1 6.1, 78°(a)

2781 Bipyridilium pesticide, solid, toxic 60 6.1 6.1, 780 (b),(c)

2782 Bipyridilium pesticide, liquid, 336 3+6.1 3, 48°(a),(b)flammable, toxic

2783 Organophosphorus pesticide, solid, 66 6.1 6.1, 71 '(a)toxic

2783 Organophosphorus pesticide, solid, 60 6.1 6.1, 71*(b).(c)toxic

2784 Organophosphorous pesticide, liquid, 336 3+6.1 3, 41 °(a),(b)flammable, toxic

2785 4-Thiapentanal 60 6.1 6.1, 21 *(c)

2786 Organotin pesticide, solid, toxic 66 6.1 6.1, 76°(a)

2786 Organotin pesticide, solid, toxic 60 6. ! 6.1, 76*(b),(c)

2787 Organotin pesticide, liquid, 336 3+6.1 3, 46°(a),(b)flammable, toxic

2788 Organotin compound, liquid, n.o.s. 66 6.1 6.1, 32°(a)

2788 Organotin compound, liquid, n.o.s. 60 6.1 6.1, 32°(b),(c)

2789 Acetic acid, glacial 83 8+3 8, 32°(b)2.

2789 Acetic acid, solution 83 8+3 8, 32-(b)2.

2790 Acetic acid, solution 80 8 8, 32°(c)

2793 Ferrous metal borings, shavings, 40 4.2 4.2, 12°(c)turnings or cuttings

2796 Sulphuric acid, with more than 80 8 8, 1 °(b)51% acid

2796 Battery fluid, acid 80 8 8, 1-(b)

2797 Battery fluid, alkali 80 8 8, 42'(b)

2798 Phenylphosphorus dichloride 80 8 8, 35°(b)l.

2799 Phenylphosphorus thiodichloride 80 8 8. 35°(b).

2801 Dye or dye intermediate, liquid, 80 8 8, 66°(b),(c)corrosive, n.o.s.

2802 Copper chloride 80 8 8, 11 °(c)

2803 Gallium 80 8 8, 650(c)

Vol. 1845. A-8940


Substance Name of substance Hazad Label Clue aCd item

Identificution Identification numberNo. No.

(Lower pa t) (Upper Parl)(a) (b) (C) (d) (a)

2805 Lithium hydride, fused solid 423 4.3 14.3, 16°(b)

2809 Mercury 80 8 8, 66"(c)

2810 Toxic liquid, organic, n.o.s. 66 6.1 6.1, 25°(a)

2810 Toxic liquid, organic, n.o.s. 60 6.1 6.1, 25°(b),(c)

2811 Toxic solid, organic, n.o.s. 66 6.1 6.1, 25°(a)

2811 Toxic solid, organic, n.o.s. 60 6.1 6.1, 25"(b),(c)

2813 Water-reactive solid, no.s. 423 4.3 4.3, 20°(b),(c)

2814 Infectious substance, affecting 606 6.2 6.2, 3°(b)humans

2815 N-Aminoethylpiperazine 80 8 8, 530(c)

2817 Ammonium hydrogendifluoride 86 8+6.1 8, 7°(b),(c)solution

2818 Ammonium polysulphide solution 86 8+6.1 8, 45°(c)

2818 Ammonium polysulphide solution 86 8+6.1 8, 45°(b)1.

2819 Amyl acid phosphate 80 8 8, 38°(c)

2820 Butyric acid 80 8 8, 32°(c)

2821 Phenol solution 60 6.1 6.1, 14°(b),(c)

2822 2-Chloropyridine 60 6.1 6.1, 12°(b)

2823 Crotonic acid 80 8 8, 31 °(c)

2826 Ethyl chlorothioformate 80 8 8, 64*(b)

2829 Caproic acid 80 8 8, 32°(c)

2830 Lithium ferrosilicon 423 4.3 4.3, 12-(b)

2831 1, 1, 1 -Trichloroethane 60 6.1 6.1, 15°(c)

2834 Phosphorous acid 80 8 8, 16-(c)

2835 Sodium aluminium hydride 423 4.3 4.3, 16°(b)

2837 Bisulphates, aqueous solution 80 8 8, 1 °(b),(c)

2838 Vinyl butyrate, inhibited 339 3 3, 3°(b)

2839 Aldol 60 6.1 6.1, 14°(b)

2840 Butyraldoxime 30 3 3, 31 (c)

2841 Di-n-amylanine 36 3+6.1 3, 32°(c)

Vol. 1845, A-8940


substance Name of substance Hauzrd Label Cl-ss aMd itemldcrti icaion Identification number

No. No.(Lower part) (Upper pas)

(a) (b) () (d) Wc)

2842 Nitroethane 30 3 3, 31 °(c)

2844 Calcium manganese silicon 423 4.3 4.3, 12°(c)

2845 Pyrophoric liquid, organic, n.o.s. 333 4.2 4.2, 6*(a)

2849 3-Chloropropanol-1 60 6.1 6.1, 17*(c)

2850 Propylene tetramer 30 3 3, 31 *(c)

2851 Boron trifluoride dihydrate 80 8 8, 10*(b)

2853 Magnesium fluorosilicate 60 6.1 6.1, 64°(c)

2854 Ammonium fluorosilicate 60 6.1 6.1, 64°(c)

2855 Zinc fluorosilicate 60 6.1 6.1, 640(c)

2856 Fluorosilicates, n.o.s. 60 6.1 6.1, 64*(c)

2858 Zirconium, dry 40 4.1 4.1, 13°(c)

2859 Ammonium metavanadate 60 6.1 6.1, 58°(b)

2861 Ammonium polyvanadate 60 6.1 6.1, 58'(b)

2862 Vanadium pentoxide 60 6.1 6.1, 58'(b)

2863 Sodium ammonium vanadate 60 6.1 6.1. 58-(b)

2864 Potassium metavanadate 60 6.1 6.1, 58 0(b)

2865 Hydroxylamine sulphate 80 8 8, 16°(c)

2869 Titanium trichloride mixture 80 8 8, 11 (b),(c)

2870 Aluminium borohydride X333 4.2+4.3 4.2, 17°(a)

2870 Aluminium borohydride in devices X333 4.2+4.3 4.2, 17 (a)

2871 Antimony powder 60 6.1 6.1. 59°(c)

2872 Dibromochloropropanes 60 6.1 6.1, 15 °(c)

2873 Dibutylaminoethanol 60 6.1 6.1, 12°(c)

2874 Furfuryl alcohol 60 6.1 6.1, 14(c)

2875 Hexachlorophene 60 6.1 6.1. 17°(c)

2876 Resorcinol 60 6.1 6.1, 140(c)

2878 Titanium sponge, powder or granules 40 4.1 4.1, 130 (c)

2879 Selenium oxychloride 886 8+6.1 8, 12-(a)

2880 Calcium hypochlorite, hydrated 50 5.1 5.1, 15"0b)mixture

Vol 1845. A-8940

1995 501


Substmce Name of substance Hazard LAbel Class and item

Ideruificution Identification numberNo. No.

(Lower pai) (Upper part)(a) (b) (c) (d) (e)

2880 Calcium hypochlorite, hydrated 50 15.1 5.1, 15 °(b)

2881 Metal catalyst, dry 40 4.2 4.2, 12"(b),(c)

2900 Infectious substance, affecting 606 6.2 6.2, 3'(b)animals only

2902 Pesticide, liquid, toxic, n.o.s. 66 6.1 6.1, 87°(a)

2902 Pesticide, liquid, toxic, n.o.s. 60 6.1 6.1, 870(b),(c)

2903 Pesticide, Jiquid, toxic, 663 6.1+3 6.1, 87*(a)flammable, n.o.s.

2903 Pesticide, liquid, toxic, 63 6.1+3 6.1, 87*(b),(c)flammable, n.o.s.

2904 Chlorophenolates, liquid 80 8 8, 62°(c)

2904 Phenolates, liquid 80 8 8, 62°(c)

2905 Chlorophenolates, solid 80 8 8, 62*(c)

2905 Phenolates, solid 80 8 8, 62°(c)

2906 Triisocyanatoisocyanurate of 30 3 3, 31 °(c)isophoronediisocyanate, solution

2912 Radioactive material, low specific 70 7A, 7B or 7, Sch 5,6activity (LSA), not otherwise 7C or 13specified in this appendix

gas 72 7A, 7B or7C

gas, flammable 723 7A, 7B or7C + 3

liquid, flammable, with a 73 7A, 7B orflash-point not above 61 "C 7C + 3

solid, flammable 74 7A, 7B or7C + 4.1

oxidizing 75 7A, 7B or7C + 05

toxic 76 7A, 7B or7C + 6.1

corrosive 78 7A, 7B or7C + 8

2920 Corrosive liquid, flammable, n.o.s. 883 8+3 8, 68°(a)

2920 Corrosive liquid, flammable, n.o.s. 83 8+3 8, 680(b)

2921 Corrosive solid, flammable, n.o.s. 884 8+4.1 8, 67°(a)

Vol. 1845, A-8940


Substance Name of substance HAzard Label Claas and itemIdentification Identification number

No. No.(Lower pan) (Upper part)

(a) (b) (c) (d) (e)

2921 Corrosive solid, flammable, n.o.s. 84 8+4.1 8, 67°(b)

2922 Corrosive liquid, toxic, n.o.s. 886 8+6.1 8, 76°(a)

2922 Corrosive liquid, toxic, n.o.s. 86 8+6.1 8, 760(b),(c)

2923 Corrosive solid, toxic, n.o.s. 886 8+6.1 8, 75°(a)

2923 Corrosive solid, toxic, n.o.s. 86 8+6.1 8, 75*(b),(c)

2924 Flammable liquid, corrosive, n.o.s. 338 3+8 3, 26*(a),(b)

2924 Flammable liquid, corrosive, n.o.s. 38 3+8 3, 33°(c)

2925 Flammable solid, corrosive, organic, 48 4.1+8 4.1, 8°(b),(c)n.o.s.

2926 Flammable solid, toxic, organic, 46 4.1+6.1 4.1, 7°(b),(c)n.o.s.

2927 Toxic liquid, corrosive, organic, 668 6.1+8 6.1, 27°(a)n.o.s.

2927 Toxic liquid, corrosive, organic, 68 6.1+8 6.1, 27'(b)n.o.s.

2928 Toxic solid, corrosive, organic, 668 6.1+8 6.1, 27°(a)n.o.s.

2928 Toxic solid, corrosive, organic, 68 6.1+8 6.1, 27'(b)n.o.s.

2929 Toxic liquid, flammable, organic, 663 6.1+3 6.1, 26°(a)l.n.o.s.

2929 Toxic liquid, flammable, organic, 63 6.1+3 6.1, 26 5 (b)1.n.o.s.

2930 Toxic solid, flammable, organic, 664 6.1+4.1 6.1, 26°(a)2.n.o.s.

2930 Toxic solid, flammable, organic, 64 6.1+4.1 6.1, 26-(b)2.n.o.s.

2931 Vanadyl sulphate 60 6.1 6.1, 58'(b)

2933 Methyl 2-chloropropionate 30 3 3, 31°(c)

2934 Isopropyl 2-chloropropionate 30 3 3, 31 °(c)

2935 Ethyl 2-chloropropionate 30 3 3, 31 °(c)

2936 Thiolactic acid 60 6.1 6.1, 21 '(b)

2937 apha-Methylbenzyl alcohol 60 6.1 6.1, 14°(c)

Vol. 1845, A-8940


Substance Name of substance Hazard Label Class and iLemIdentification Idcntification number


(a) (b) (c) (d) (e)

2938 Methyl benzoate 60 6.1 6.1, 14*(c)

2940 9-Phosphabicyclononanes 40 4.2 4.2, 5(b)(cyclooctadiene phosphines)

2941 Fluoroanilines 60 6.1 6.1, 12°(c)

2942 2-Trifluoromethylaniline 60 6.1 6.1, 12°(c)

2943 Tetrahydrofurfurylamine 30 3 3, 31 °(c)

2945 N-Methylbutylamine 3i8 3+8 3, 22°b)

2946 2-Amino-5-diethylaminopentane 6U 6.1 6.1, 12'(c)

2947 Isopropyl chloroacetate 30 3 3, 31 (c)

2948 3-Trifluoromethylaniline 60 6.1 6.1. 17°(b)

2949 Sodium hydrosulphide hydrated 80 8 8, 45°0b)1.

2950 Magnesium granules, coated 423 4.3 4.3, 11 (c)

2965 Boron trifluoride dimethyl etherate 382 4.3+3+8 4.3, 2-(a)

2966 Thioglycol 60 6.1 6.1, 21-(b)

2967 Sulphamic acid 80 8 8, 16°(c)

2968 Maneb, stabilized 423 4.3 4.3, 200(c)

2968 Maneb preparation, stabilized 423 4.3 4.3, 20°(c)

2980 Uranyl nitrate hexahydrate solution 78 7A, 7B or 7, Sch 5,67C +8 or 13

Vol. 1845. A-8940


Substnce Name of substance Hazard Label Clus and itemIdentification Identifitcion number

No. No.(Lower pt) (Upper put)

(a) (b) (C) (d) (e)

2982 Radioactive material, not otherwise 70 7A, 7B or 7, Sch 9,10,11specified in this appendix 7C or 13

gas 72 7A, 7B or7C

gas, flammable 723 7A, 7B or7C + 3

liquid, flammable, with a 73 7A, 7B orflash-point not above 61 *C 7C + 3

solid, flammable 74 7A, 7B or7C + 4.1

oxidizing 75 7A, 7B or7C + 05

toxic 76 7A, 7B or7C + 6.1

corrosive 78 7A, 7B or17C + 8

2983 Ethylene oxide and propylene 336 3+6.1 3, 17°(a)oxide mixture

2984 Hydrogen peroxide, aqueous solution 50 5.1 5.1, 1°(c)

2985 Chlorosilanes, flammable, 338 3 + 8 3, 21'(b)corrosive, n.o.s.

2986 Chlorosilanes, corrosive, flammable, X83 8+3 8, 37°(b)n.o.s.

2987 Chlorosilanes, corrosive, n.o.s. 80 8 8, 36°(b)

2988 Chlorosilanes, water-reactive, X338 4.3+3+8 4.3, 1'(a)flammable, corrosive, n.o.s.

2989 Lead phosphite, dibasic 40 4.1 4.1, 11(b),(c)

2991 Carbamate pesticide, liquid, toxic, 663 6.1+3 6.1, 74°(a)flammable

2991 Carbamate pesticide, liquid, toxic, 63 6.1+3 6.1, 74°(b),(c)flammable

2992 Carbamate pesticide, liquid, toxic 66 6.1 6.1, 74°(a)

2992 Carbamate pesticide, liquid, toxic 60 6.1 6.1, 74°(b),(c)

2993 Arsenical pesticide, liquid, toxic, 663 6.1+3 6.1, 79°(a)flammable

2993 Arsenical pesticide, liquid, toxic, 63 6.1+3 6.1, 79°(b),(c)flammable

Vol. 1845, A-8940


Substanc Narne of subsicc Hamd Label Class and itemIdertificaton ldentificafion number

No. No.(Lower pan) (upper p)

(a) (b) (C) (d) (e)

2994 Arsenical pesticide, liquid, toxic 66 6.1 6.1, 79*(a)

2994 Arsenical pesticide, liquid, toxic 60 6.1 6.1, 790(b),(c)

2995 Organochlorine pesticide, liquid, 663 6.1+3 6.1, 72 *(a)toxic, flammable

2995 Organochlorine pesticide, liquid, 63 6.1+3 6.1, 72*(b),(c)toxic, flammable

2996 Organochlorine pesticide, liquid, 66 6.1 6.1, 72°(a)toxic

2996 Organochlorine pesticide, liquid, 60 6.1 6.1, 72°(b),(c)toxic

2997 Triazine pesticide, liquid, toxic, 663 6.1+3 6.1, 82*(a)flammable

2997 Triazine pesticide, liquid, toxic, 63 6.1+3 6.1, 820(b),(c)flammable

2998 Triazine pesticide, liquid, toxic 66 6.1 6.1, 82'(a)

2998 Triazine pesticide, liquid, toxic 60 6.1 6.1, 82°(b),(c)

2999 Phenoxy pesticide, liquid, toxic, 663 6.1+3 6.1, 73*(a)flammable

2999 Phenoxy pesticide, liquid, toxic, 63 6.1+3 6.1, 73 0(b),(c)flammable

3000 Phenoxy pesticide, liquid, toxic 66 6.1 6.1, 73°(a)

3000 Phenoxy pesticide, liquid, toxic 60 6.1 6.1, 73°(b),(c)

3001 Phenyl urea pesticide, liquid, toxic, 663 6.1+3 6.1, 85°(a)flammable

3001 Phenyl urea pesticide, liquid, toxic, 63 6.1+3 6.1, 85°(b),(c)flammable

3002 Phenyl urea pesticide, liquid, toxic 66 6.1 6.1, 85-(a)

3002 Phenyl urea pesticide, liquid, toxic 60 6.1 6.1, 85°(b),(c)

3003 Benzoic derivative pesticide, liquid, 663 6.1+3 6.1, 83°(a)toxic, flammable

3003 Bezoic derivative pesticide, liquid, 63 6.1+3 6.1, 83°(b),(c)toxic, flammable

3004 Benzoic derivative pesticide, liquid, 66 6.1 6.1, 83°(a)toxic

Vol. 1845, A-8940


Subsgane Name of substance HazAgd LAWel Class and stemIdentificafion Ident icat number

No. No.(Lower p-A) (Upper par)

(a) (b) () (d) (e)

3004 Benzoic derivative pesticide, liquid, 60 6.1 6.1, 83*(b),(c)toxic

3005 Dithiocarbamate pesticide, liquid, 663 6.1+ 3 6.1, 86°(a)toxic, flammable

3005 Dithiocarbamate pesticide, liquid, 63 6.1+3 6.1, 86*(b),(c)toxic, flammable

3006 Dithiocarbamate pesticide, liquid, 66 6.1 6.1, 86°(a)toxic

3006 Dithiocarbamate pesticide, liquid, 60 6.1 6.1, 86°(b),(c)toxic

3007 Phtha]4mide derivative pesticide, 663 6.1+3 6.1, 84'(a)liquid, toxic, flammable

3007 Phthalimide derivative pesticide, 63 6.1+3 6.1, 84°(b),(c)liquid, toxic, flammable

3008 Phthalimide derivative pesticide, 66 6.1 6.1, 84°(a)liquid, toxic

3008 Phthalimide derivative pesticide, 60 6.1 6.1, 840(b),(c)liquid, toxic

3009 Copper based pesticide, liquid, toxic, 663 6.1+3 6.1, 80°(a)flammable

3009 Copper based pesticide, liquid, toxic, 63 6.1+3 6.1, 80°(b),(c)flammable

3010 Copper based pesticide, liquid, toxic 66 6.1 6.1, 80°(a)

3010 Copper based pesticide, liquid, toxic 60 6.1 6.1, 80°(b),(c)

3011 Mercury based pesticide, liquid, 663 6.1+3 6.1, 75°(a)toxic, flammable

3011 Mercury based pesticide, liquid, 63 6.1+3 6.1, 75°(b),(c)toxic, flammable

3012 Mercury based pesticide, liquid, toxic 66 6.1 6.1, 75°(a)

3012 Mercury based pesticide, liquid, toxic 60 6.1 6.1. 75°(b),(c)

3013 Substituted nitrophenol pesticide, 663 6.1+3 6.1, 81 *(a)liquid, toxic, flammable

3013 Substituted nitrophenol pesticide, 63 6.1+3 6.1, 81°(b),(c)liquid, toxic, flammable I

Vol. 1845, A-8940


Substance Name of substance Hazard Label Class and itemldent'irion ldent ficafion nmber

No. No.(Lowcr pan) (Upper pa)

(a) (b) () (d) (e)

3014 Substituted nitrophenol pesticide, 66 6.1 6.1, 81*(a)liquid, toxic

3014 Substituted nitrophenol pesticide, 60 6.1 6.1, 81°(b),(c)liquid, toxic

3015 Bipyridilium pesticide, liquid, 663 6.1+3 6.1, 78°(a)toxic, flammable

3015 Bipyridilium pesticide, liquid, 63 6.1+3 6.1, 78°(b),(c)toxic, flammable

3016 Bipyridilium pesticide, liquid, toxic 66 6.1 6.1, 78*(a)

3016 Bipyridilium pesticide, liquid, toxic 60 6.1 6.1, 78°(b),(c)

3017 Organophosphorus pesticide, liquid, 663 6.1+3 6.1, 71 *(a)toxic, flammable

3017 Organophosphorus pesticide, liquid, 63 6.1+3 6.1, 71 °(b),(c)toxic, flammable

3018 Organophosphorus pesticide, liquid, 66 6.1 6.1, 71°(a)toxic

3018 Organophosphorus pesticide, liquid, 60 6.1 6.1, 71 °(b),(c)toxic

3019 Organotin pesticide, liquid, toxic, 663 6.1+3 6.1, 76°(a)flammable

3019 Organotin pesticide, liquid, toxic, 63 6.1+3 6.1, 76°(b),(c)flammable

3020 Organotin pesticide, liquid, toxic 66 6.1 6.1, 76°(a)

3020 Organotin pesticide, liquid, toxic 60 6.1 6.1, 76*(b),(c)

3021 Pesticide, liquid, flammable, toxic, 336 3+6.1 3, 57°(a),(b)n.o.s.

3022 1,2-Butylene oxide, stabilized 339 3 3, 3°(b)

3023 tert-Octyl mercaptan 63 6.1 + 3 6.1, 20-(b)

3024 Coumarin derivative pesticide, liquid, 336 3+6.1 3, 47°(a),(b)flammable, toxic

3025 Coumarin derivative pesticide, liquid, 663 6.1+3 6.1, 77*(a)toxic, flammable

3025 Coumarin derivative pesticide, liquid, 63 6.1+3 6.1, 770(b),(c)toxic, flammable III_ I

Vol. 1845. A-8940


Substance Name of substance Ha.ard Label Class and item

Idernifiealion Identification numberNo. No.

(Lower part) (Upper pan)(a) (b) () (d) (W)

3026 Coumarin derivative pesticide, liquid, 66 6.1 6.1, 77°(a)toxic

3026 Coumarin derivative pesticide, liquid, 60 6.1 6.1, 77(b),(c)toxic

3027 Coumarin derivative pesticide, solid, 66 6.1 6.1, 77 *(a)toxic

3027 Coumarin derivative pesticide, solid, 60 6.1 6.1, 77°(b),(c)toxic

3049 Metal alkyl halides, n.o.s. or X333 4.2+4.3 4.2, 32°(a)metal aryl halides, n.o.s.

3050 Metal alkyl hydrides, n.o.s. or X333 4.2+4.3 4.2, 32=(a)metal aryl hydrides, n.o.s.

3051 Aluminium alkyls X333 4.2+4.3 4.2, 31°(a)

3052 Aluminium alkyl halides X333 4.2+4.3 4.2, 32*(a)

3053 Magnesium alkyls X333 4.2+4.3 4.2, 31*(a)

3054 Cyclohexyl mercaptan 30 3 3, 31 °(c)

3055 2-(2-Aminoethoxy) ethanol 80 8 8, 53*(c)

3056 n-Heptaldehyde 30 3 3, 31 °(c)

3065 Alcoholic beverages 30 3 3. 31 *(c)

3065 Alcoholic beverages 33 3 3, 3°(b)

3066 Paint or paint related material 80 8 8, 66°(b),(c)

3070 Dichlorodifluoromethane and 26 6.1 2, 4°(at)ethylene oxide mixtures with notmore than 12% ethylene oxide bymass

3071 Mercaptan mixture, liquid, toxic, 63 6.1+3 6.1, 20°(b)flammable, n.o.s.

3071 Mercaptans. liquid, toxic, 63 6.1+3 6.1, 20°(b)flammable, n.o.s.

3073 Vinylpyridines, inhibited 639 6.1+3 6.1, 11 -(b)

3076 Aluminium alkyl hydrides X333 4.2+4.3 4.2, 32=(a)

3077 Environmentally hazardous substance, 90 9 9, 12°(c)solid, n.o.s.

3078 Cerium 423 4.3 4.3, 13'(b)

Vol 1845, A-8940


Substance Name of sumbce HUAzad Label Clau and itemIdcntifition Idantification number

No. No.(Lower pan) (Upper palr)

(a) (b) () (d) ()

3079 Methacrylonitrile, inhibited 336 3+6.1 13,11 '(a)

3080 Isocyanates, toxic, flammable, n.o.s. 63 6.1+3 6.1, 18°(b)

3080 Isocyanate solution, toxic, flammable, 63 6.1+3 6.1, 18°(b)n.O.S.

3084 Corrosive solid, oxidizing, n.o.s. 885 8+05 8, 73°(a)

3084 Corrosive solid, oxidizing, n.o.s. 85 8+05 8, 73-(b)

3085 Oxidizing solid, corrosive, n.o.s. 58 5.1+8 5.1, 31°(b),(c)

3086 Toxic solid, oxidizing, n.o.s. 665 6.1+05 6.1, 68°(a)

3086 Toxic solid, oxidizing, n.o.s. 65 6.1+05 6.1, 68-(b)

3087 Oxidizing solid, toxic, n.o.s. 56 5.1+6.1 5.1, 29 0(b),(c)

3088 Self-heating solid, organic, n.o.s. 40 4.2 4.2, 5°(b),(c)

3089 Metal powder, flammable, n.o.s. 40 4.1 4.1, 13°0b),(c)

3092 l-Methoxy-2-propanol 30 3 3, 31 °(c)

3093 Corrosive liquid, oxidizing, n.o.s. 885 8+05 8, 74°(a)

3093 Corrosive liquid, oxidizing, n.o.s. 85 8+05 8, 74-(b)

3094 Corrosive liquid, water-reactive 823 8+4.3 8, 72*(a),(b).o.s.

3095 Corrosive solid, self-heating, n.o.s. 84 8+4.2 8, 69-(b)

3096 Corrosive solid, water-reactive, 842 8+4.3 8, 71-(b)n.o.s.

3109 Organic peroxide, type F, liquid 539 5.2+(8) 5.2, 9-(b)

3110 Organic peroxide, type F, solid 539 5.2 5.2. 10-(b)

3119 Organic peroxide, type F, liquid, 539 5.2 5.2, 19-(b)temperature controlled

3120 Organic peroxide, type F, solid, 539 5.2 5.2, 20°(b)temperature controlled

3122 Toxic liquid, oxidizing, n.o.s. 665 6.1+05 6.1, 68-(a)

3122 Toxic liquid, oxidizing, n.o.s. 65 6.1+05 6.1, 68 0(b)

3123 Toxic liquid, water-reactive, n.o.s. 623 6.1+4.3 6.1, 44°(a),(b)

3124 Toxic solid, self-heating, n.o.s. 664 6.1+4.2 6.1, 66*(a)

3124 Toxic solid, self-heating, n.o.s. 64 6.1 +4.2 6.1, 66'(b)

Vol. 1845, A-8940


Substance Name or rubstance Hazard Label Clas and itemIdentification Identification number

No. No.,(Lower pan) (Upper pan)

(a) (b) (C) (d) (€)

3125 Toxic solid, water-reactive, n.o.s. 642 6.1+4.3 6.1, 44°(b),(c)

3126 Self-heating solid, corrosive, organic, 48 4.2+8 4.2, 9*(b),(c)n.o.s.

3128 Self-heating solid, toxic, organic, 46 4.2+6.1 4.2, 7°(b),(c)n.o.s.

3129 Water-reactive liquid, corrosive, X382 4.3+8 4.3, 25*(a)n.o.s,

3129 Water-reactive liquid, corrosive, 382 4.3+8 4.3, 25°(b),(c)n.o.s.

3130 Water-reactive liquid, toxic, n.o.s. X362 4.3+6.1 4.3, 23°(a)

3130 Water-reactive liquid, toxic, n.o.s. 362 4.3+6.1 4.3, 23°(b),(c)

3131 Water-reactive solid, corrosive, n.o.s. 482 4.3+8 4.3, 24°(b),(c)

3134 Water-reactive solid, toxic, n.o.s. 462 4.3+6.1 4.3, 22'(b),(c)

3138 Ethylene, acetylene and propylene 223 3 2, 8 0(b)in mixture, refrigerated liquid

3140 Alkaloids or alcaloid salts, liquid, 66 6.1 6.1, 90°(a)n.o.s.

3140 Alkaloids or alcaloid salts, liquid, 60 6.1 6.1, 90°(b),(c)n.o.s.

3141 Antimony compound, inorganic, 60 6.1 6.1, 59°(c)liquid, n.o.s.

3142 Disinfectant, liquid, toxic, n.o.s. 66 6.1 6.1, 25°(a)

3142 Disinfectant, liquid, toxic, n.o.s. 60 6.1 6.1, 25°(b),(c)

3143 Dye, solid, toxic, n.o.s. 66 6.1 6.1, 25-(a)

3143 Dye, solid, toxic, n.o.s. 60 6.1 6.1, 25°(b),(c)

3143 Dye intermediate, solid, toxic, n.o.s. 66 6.1 6.1, 25°(a)

3143 Dye intermediate, solid, toxic, n.o.s. 60 6.1 6.1, 25°(b),(c)

3144 Nicotine compound or nicotine 66 6.1 6.1, 90°(a)preparation, liquid, n.o.s.

3144 Nicotine compound or nicotine 60 6.1 6.1, 90°(b),(c)preparation, liquid, n.o.s.

3145 Alkylphenols, liquid, n.o.s. 88 8 8, 40°(a)

3145 Alkylphenols, liquid, n.o.s. 80 8 8, 40(b),(c)

Vol. 1845, A-8940

512 United Nations - Treaty Series a Nations Unies - Recueil des Traits 1995

Substance Name of substance HAzuRd Label Clas and itemIdentification Identification number

No. No.(LOwer part) (Upper Parl)

(A) (b) (C) (d) (e)

3146 Organotin compound, solid, n.o.s. 66 6.1 6.1, 32°(a)

3146 Organotin compound, solid, n.o.s. 60 6.1 6.1, 32°(b),(c)

3147 Dye or dye intermediate, solid, 80 8 8, 650(b),(c)corrosive, n.o.s.

3148 Water-reactive liquid, n.o.s. X323 4.3 4.3, 21 *(a)

3148 Water-reactive liquid, n.o.s. 323 4.3 4.3, 21 °(b),(c)

3149 Hydrogen peroxide and peroxyacetic 58 5.1+8 5.1, 1°(b)acid mixture, stabilized

3151 Polyhalogenated biphenyls, liquid 90 9 9, 2°(b)

3151 Polyhalogenated terphenyls, liquid 90 9 9, 2°(b)

3152 Polyhalogenated biphenyls, solid 90 9 9, 2°(b)

3152 Polyhaogenated terphenyls, solid 90 9 9, 2-(b)

3155 Pentachlorophenol 60 6.1 6.1, 17°(b)

3159 1,1,1,2-Tetrafluorethane (R 134a) 20 2 2, 3*(a)

3170 Aluminium dross 423 4.3 4.3, 13°(b),(c)

3172 Toxins, extracted from living- 66 6.1 6.1, 90°(a)sources, n.o.s.

3172 Toxins, extracted from living 60 6.1 6.1, 90°(b),(c)sources, n.o.s.

3174 Titanium disulphide 40 4.2 4.2, 13°(c)

3175 Solids containing flammable liquid, 40 4.1 4.1, 40(c)n.o.s.

3176 Flammable solid, organic, molten, 44 4.1 4.1, 5 °

n.o.s.

3178 Flammable solid, inorganic, n.o.s. 40 4.1 4.1, 1ll(b),(c)

3179 Flammable solid, toxic, inorganic, 46 4.1+6.1 4.1, 16°(b),(c)n.o.s.

3180 Flammable solid, corrosive, 48 4.1+8 4.1, 17°(b),(c)inorganic, n.o.s.

3181 Metal salts of organic compounds, 40 4.1 4.1, 12°(b),(c)flammable, n.o.s.

3182 Metal hydrides, flammable, n.o.s. 40 4.1 4.1, 140 (b),(c)

Self-heating liquid, organic, n.o.s. 4.2, 6°(b),(c)

Vol. 1845, A-8940

I


Sbsuance Name of substance Hazard Label Clas and itemIdentifcation Identication number

No. No.(Lowcr Part) (Upper pal)

(a) (b) ) (d) (a)

3184 Self-heating liquid, toxic, organic. 36 4.2+6.1 4.2, 8°(b),(c)n~o.s.

3185 Self-heating liquid, corrosive, 38 4.2+8 4.2, 10°(b),(c)

organic, n.o.s.

3186 Self-heating liquid, inorganic, n.o.s. 30 4.2 4.2. 17°(b),(c)

3187 Self-beating liquid, toxic, inorganic, 36 4.2+6.1 4.2, 190 (b),(c)n.o.s.

3188 Self-heating liquid, corrosive, 38 4.2+8 4.2. 21 °(b),(c)inorganic, n.o.s.

3189 Metal powder, self-heating, n.o.s. 40 4.2 4.2, 12°(b),(c)

3190 Self-heating solid, inorganic, n.o.s. 40 4.2 4.2, 16°(b),(c)

3191 Self-heating solid, toxic, inorganic, 46 4.2+6.1 4.2, I8°(b),(c)n.o.s.

3192 Self-heating solid, corrosive, 48 4.2+8 4.2, 20°(b),(c)inorganic, n.o.s.

3194 Pyrophoric liquid, inorganic, n.o.s. 333 4.2 4.2, 17°(a)

3203 Pyrophoric organometallic X333 4.2+4.3 4.2, 33°(a)compound, n.o.s.

3205 Alkaline-earth metal alcoholates, 40 4.2 4.2, 14°(b),(c)n.o.s.

3206 Alkali metal alcoholates, n.o.s. 48 4.2+8 4.2, 15°(b),(c)

3207 Organometallic compound, or X323 4.3+3 4.3, 3°(a)solution, or dispersion,water-reactive, flammable, n.o.s.

3207 Organometallic compound, or 323 4.3+3 4.3, 3°(b),(c)solution, or dispersion,water-reactive, flammable, n.o.s.

3208 Metallic substance, water-reactive, 423 4.3 4.3, 13°(b),(c)D.O.S.

3209 Metallic substance, water-reactive, 423 4.3+4.2 4.3. 14°(b),(c)self-heating, n.o.s.

3210 Chlorates, inorganic, aqueous 50 5.1 5.1, 11°(b)solution, n.o.s.

3211 Perchlorates, inorganic, aqueous 50 5.1 5.1, 13°(b)solution, n.o.s. _ _ _

Vol. 1845, A-8940

513


Substance Name of substance Hazard Label Class and itemIdentiication Identification number

No. No.(Lo wr pat) (Upper pat)

(a) (b) (e) (d) (e)

3212 Hypochlorites, inorganic, n.o.s. 50 5.1 5.1, 15-(b)

3213 Bromates, inorganic, aqueous solution 50 5.1 5.1, 16°(b),(c)n.o.s.

3214 Permanganates, inorganic, aqueous 50 5.1 5.1, 17-(b)

solution, n.o.s.

3215 Persulphates, inorganic, n.o.s. 50 5.1 5.1, 18°(c)

3216 Persulfates, inorganic, aqueous 50 5.1 5.1, 18-(c)solution, n.o.s.

3217 Percarbonates, inorganic, n.o.s. 50 5.1 5.1, 19°(c)

3218 Nitrates, inorganic, aqueous 50 5.1 5.1, 22*(b),(c)solution, n.o.s.

3219 Nitrites, inorganic, aqueous 50 5.1 5.1, 23°(b),(c)

solution, n.o.s.

3220 Pentafluoroethane (R 125) 20 2 2, 5°(a)

3241 2-Bromo-2-nitropropane-1,3-diol 60 6.1 6.1, 170(c)

3243 Solids containing toxic liquid, n.o.s. 60 6.1 6.1, 65°(b)

3244 Solids containing corrosive liquid, 80 8 8, 65-(b)n.o.s.

3246 Methanesulphonyl chloride 668 6.1+8 6.1, 27 *(a)

3247 Sodium peroxoborate, anhydrous 50 5.1 5.1, 27-(b)

3248 Medicine, liquid, flammable, toxic, 336 3+6.1 3, 19°(b)n.o.s.

3248 Medicine, liquid, flammable, toxic, 36 3+6.1 3, 32°(c)n.o.s.

3249 Medicine, solid, toxic, n.o.s. 60 6.1 6.1, 90°(b),(c)

3250 Chloroacetic acid, molten 68 6.1+8 6.1, 24°(b)2.

3253 Disodium trioxosilicate pentahydrate 80 8 8, 41 *(c)

3256 Elevated temperature liquid, 30 3 3, 61 °(c)flammable, n.o.s.

3259 Amines or polyamines, solid, 88 8 8, 52-(a)corrosive, n.o.s.

3259 Amines or polyamines, solid, 80 8 8, 52°(b),(c)corrosive, n.o.s.

Vol. 1845, A-8940


Sub.ncec Name of Bubstncc Huard Labe Chs and itemIdeetlICA i.on ldcniifcallon number

No. No.

(Lower put) (Upper Part)(a) (b) (c) (d) (C)

3260 Corrosive solid, acidic, inorganic, 88 8 8,160(a)n.o.s.

3260 Corrosive solid, acidic, inorganic, 80 8 8, 16°(b),(c)n.o.s.

3261 Corrosive solid, acidic, organic, 88 8 8, 390(a)n.o.s.

3261 Corrosive solid, acidic, organic, 80 8 8, 39°(b),(c)n.o.s.

3262 Corrosive solid, basic, inorganic, 88 8 8, 460(a)n.o.s.

3262 Corrosive solid, basic, inorganic, 80 8 8, 46°(b),(c)n.o.s.

3263 Corrosive solid, basic, organic, n.o.s. 88 8 8, 55°(a)

3263 Corrosive solid, basic, organic, n.o.s. 80 8 8, 55°(b),(c)

3264 Corrosive liquid, acidic, inorganic, 88 8 8, 170(a)n.o.s.

3264 Corrosive liquid, acidic, inorganic, 80 8 8, 17°(b),(c)n.o.s.

3265 Corrosive liquid, acidic, organic, 88 8 8, 400(a)n.o.s.

3265 Corrosive liquid, acidic, organic, 80 8 8, 40°(b),(c)n.o..

3266 Corrosive liquid, basic, inorganic, 88 8 8. 470(a)n.O.S.

3266 Corrosive liquid, basic, inorganic, 80 8 8, 470(b).(c)n.o.s.

3267 Corrosive liquid, basic, organic, 88 8 8, 56°(a)n.O.S.

3267 Corrosive liquid, basic, organic, 80 8 8, 56°(b),(c)D.O.S.

3271 Ethers, n.o.s. 33 3 3, 3 ' Cf.)

3271 Ethers, n.o.s. 30 3 3, 310(c)

3272 Esters, n.o.s. 33 3 3. 3*(b)

3272 Esters, n.o.s. 30 3 3, 31 °(c)

3273 Nitriles, flammable, toxic, n.o.s. 336 3+6.1 3, 11(a).(b)

Vol. 1845. A-8940

516 United Nations - Treaty Series e Nations Unies - Recueil des Traitis

Subsuance Name of gubsance Haza Label Class a itemIdentim wation Idergiflieaion number

No. No.(Lo er psA) (Upper pa)

(a) (b) (C) (d) (9)

3274 Alcoholates solution, n.o.s. 338 3+8 3, 24'(b)

3275 Nitriles, toxic, flammable, n.o.s. 663 6.1+3 6.1, 11*(a)

3275 Nitriles, toxic, flammable, n.o.s. 63 6.1+3 6.1, 1l°(b)

3276 Nitriles, toxic, n.o.s. 66 6.1 6.1. 12°(a)

3276 Nitriles, toxic, n.o.s. 60 6.1 6.1, 12°(b),(c)

3277 Chloroformates, toxic, corrosive, 68 6.1+8 6.1, 27°(b)n.o.s.

3278 Organophosphorus compound, toxic, 66 6.1 6.1, 23°(a)n.o.s.

3278 Organophosphorus compound, toxic, 60 6.1 6.1, 23*(b),(c)n.o.s.

3279 Organophosphorus compound, toxic, 663 6.1+3 6.1, 22°(a)flammable, n.o.s.

3279 Organophosphorus compound, toxic, 63 6.1+3 6.1, 22'(b)flammable, n.o.s.

3280 Organoarsenic compound, n.o.s. 66 6.1 6.1, 34o(a)

3280 Organoarsenic compound, n.o.s. 60 6.1 6.1, 340(b),(c)

3281 Metal carbonyls, n.o.s. 66 6.1 6.1, 36°(a)

3281 Metal carbonyls, n.o.s. 60 6.1 6.1, 36°(b),(c)

3282 Organometallic compound, toxic, 66 6.1 6.1, 35°(a)n.o.s.

3282 Organometallic compound, toxic, 60 6.1 6.1, 35°(b),(c)n.o.s.

3283 Selenium compound, n.o.s. 66 6.1 6.1, 55°(a)

3283 Selenium compound, n.o.s. 60 6.1 6.1, 55°(b),(c)

3284 Tellurium compound, n.o.s. 60 6.1 6.1, 57°(b),(c)

3285 Vanadium compound, n.o.s. 60 6.1 6.1, 58°(b),(c)

3286 Flammable liquid, toxic, corrosive, 368 3+6.1+8 3, 27*(a),(b)n.o.s.

3287 Toxic liquid, inorganic, n.o.s. 66 6.1 6.1, 65"(a)

3287 Toxic liquid, inorganic, n.o.s. 60 6.1 6.1, 65*(b),(c)

3288 Toxic solid, inorganic, n.o.s. 66 6.1 6.1, 65°(a)

Vol. 1845, A-8940

1995


Substance Name of substance Hazard label CIA" and itemIdentific&tion Identificaion number

No. No.(Lower p t) (Upper pat)

(a) (b) () (d) ()

3288 Toxic solid, inorganic, n.o.s. 60 6.1 6.1, 65°(b),(c)

3289 Toxic liquid, corrosive, inorganic, 668 6.1+8 6.1, 67°(a)n.o.s.

3289 Toxic liquid, corrosive, inorganic, 68 6.1 + 8 6.1, 67°(b)n.o.s.

3290 Toxic solid, corrosive, inorganic, 668 6.1+8 6.1, 67'(a)n.o.s.

3290 Toxic solid, corrosive, inorganic, 68 6.1+8 6.1, 67-(b)n.o.s.

3291 Clinical waste, unspecified, n.o.s. 606 6.2 6.2, 4-(b)

3293 Hydrazine, aqueous solution 60 6.1 6.1, 65°(c)

3294 Hydrogen cyanide, solution in alcohol 663 6.1+3 6.1, 2-

3295 Hydrocarbons, liquid, n.o.s. 33 3 3, 1 *(a),2°(a),(b), 30(b)

3295 Hydrocarbons, liquid, n.o.s. 30 3 3, 31 °(c)

3301 Corrosive liquid, self-heating, 884 8+4.2 8, 70°(a)n.o.s.

3301 Corrosive liquid, self-heating, 84 8+4.2 8, 70°(b)n.o.s.

Vol 1845, A-8940


CORRIGENDUM concerning the English text of the amendments proposed by the Govern-ment of France to annexes A and B, as amended, to the European Agreement of 30 Sep-tember 1957 concerning the International Carriage of Dangerous Goods by Road(ADR)'

The text of the corrigendum reads as follows:

g 5 to be replaced by the replacement page at the end of thiscorrigendum (No change, but more legible copy).

page : item 14", in the NOTE, replace "above 23" C by "of not less than23" C".

page72 : marginal 2308 (4): the substance identification number and namesshould not be underlined

oaoes 86. 87, 89:

Under items 33" (b), 34" (b), 43o (b) and 44" (b), -indesignations for samples, only the word "smple should beunderlined.

page 99: Marginal 2431: add the following amendment:

"Under items 15" (b) and 15" (c), the name for number 3206 shouldread "Alcali metal alcoholates. self-heatina. corrosive. n.o.s."

page.J 10 Add the following amendment at the bottom of the page: "At theend of the NOTE under I* (b), replace '3104(2)(g)' by'3106(2)(g)'".

pag.._103: Marginal 2553(4), replace "7"(h)" by "7"(b)".

page160: Marginal 2654 (4) (b); in the eleventh line, replace "wouldpenetrate" by "could penetrate".

page L5: In the second paragraph of the page, at the first line only,replace "[see marginal 2002(8)]" by "(see marginal 2000(5)]".

page 174 : Marginal 2800(3) (b) (first sentence) and 2800 (3) (c) (firstsentence):Replace "(a), (b) or (c)" by "(a), (b) and (c)".

pa.geL2 : Marginal 2800(4) (b), at the end, replace "3537" by "3532".

pbg._ ge : Under "class 6.2" replace "1"-4"" by "3" and 4o".

SUnited Nations, Treaty Series, vol. 619, p. 77; for subsequent actions, see references in Cumulative Indexes Nos. 9and 11 to 21, as well as annex A in volumes 1259, 1279, 1283, 1297, 1344, 1394, 1395, 1430, 1489, 1505, 1553, 1580, 1663,1679, 1696,1701, 1719, 1723, 1724,1732, 1775,1777 and 1843.

Vol. 1845, A-8940


oage 259 :Add the following amendment (english only):

"Marginal 3659 (1): For 'For all types of IBCs' read 'For alltypes of flexible IBCs'."

page 261: In the table, add another line for class 4.1 to read: "Other

substances", with a cross in the 50 kg column.

Add a new amendment to read as follows:

In NOTE 1 to marginal 10 011, in the table "Examples of thesecalculations", replace "31"" by "33"(c)" for the class 3 line.

page271: Marginal 10 221 (2), add the following sentence:

"When the transport unit comprises a motor vehicle and a trailer,the requirement applies when the motor vehicle is registeredafter 30 June 1993."

page-273: Delete the amendment concerning marginal 10 381.

page 277: In the note below the table, replace "UN No." by "Identificationnumber".

pa.ge278: Add the following amendment: "Marginal 11 500(5):replace '10 500(8)' by '10 500(9)'".

page285: Add the following amendment:

"41 509: replace 'substances of 34"' by 'substances of 31", 32",41" and 42"', and add at the end "The same rule shall apply if atransport unit is loaded with more than 2 000 kg of substances of33, 34', 43" and 44*".

page 287: Marginal 51 220(2): instead of "unchanged" read: "In the existingtext, replace "prescribed in paragraph (1) above" by "prescribedin marginal 220531(2)".

page 288: Marginal 52500: delete "as well as vehicles and containers forthe carriage of solid dangerous substances in bulk".

page 289: In the left margin, at the bottom of the page, replace "62 200"by "61 200".

page 298: marginal 62 412, third line: replace "loading" by "carrying".

page 302: Under Section 2, insert "(Only the general provisions of Part Iapply)".

page 308: Add the following amendment:

"Marginal 21X 434: Instead of 'refered to in 21X 410(b) and (f)'read 'refered to in 21X 410 (f)'".

page 312: Marginal 21X910, replace "4"(c)" by "4".

Vol. 1845, A-8940


page 313: Add the following amendments:

"Marginal 213 010(c), replace "32" (c)" by "31" (c)".

Appendix B.ld

Marginal 214 250(2): replace "-hydrofluoric acids of marginal2801, 6"" by "-substances of marginal 2801, 6"".

page 316: Marginal 220 403 andfootnote

page 331: Marginal 220 900 Replace "country" by "State".

page 332: Marginal 221 000, Jfootnote *J/

page 338: In the description of the combination "69", insert "or slightlytoxic" after "toxic".

Vol. 1845, A-8940


REPLACEMENT PAGE(-5 -1

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Vol. 1845, A-8940