working for you.

Delivering Innovation From Concept to Consumer……

Colin Smith

2

Agenda

Brief Introduction

From Concept to Consumer – What does it mean?

Five Innovative Packaging Solutions :-

- Oxygen Barrier Coating

- UV Barrier Coating

- Oxygen Barrier Adhesive

- Laser Marking Technologies

- Brand Protection

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$9.7 billion net sales

190 subsidiaries and affiliates

300 regional locations, 10 world-class R&D centers

21,572 employees in 64 countries

Sun Chemical’s global presence and leadership

Color & Comfort by Chemistry

Strong Parent Company DIC (Japan)

49% Printing Ink

and Supplies

19%Synthetic Resins

18%Chemical Solution

Materials

13%Neo-Graphic

Arts Materials

1%Other

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From Concept To Consumer…..

5

From concept to consumer….delivered!

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-Oxygen Barrier Coating-UV Barrier Coating

-Oxygen Barrier Adhesive-Laser Marking Technologies

-Brand Protection

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Oxygen Barrier Coating

8

Coating Applications - Barrier

PVdC EVOH/PVOH Speciality Oxides Metallized Co-extrusions

Bags Lidding Stand Up Pouches Forming Webs Wraps

Dry Food Chilled Food Liquid Packaging

Market / Applications Package structure Barrier technology

PVdC/FlurocarbonsSiliconesWax basedCo-extrusions/PE

Outer cases Sacks & BagsBoxes & TraysTransient Containers

Fresh foodChilled/Frozen FoodDry FoodFast FoodBakery

Market / Applications Package structure Barrier technology

O2

- Oxygen Barrier- Aroma Barrier- Mineral Oil Barrier

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Technical Data- SunBar O2 barrier

SunBar performances: Untreated polyester film OTR 100-110 cc/m2/24 hrs

PVdC major disadvantage – contains chlorine & higher OTR AlOx / SiOx major disadvantage – brittle & higher OTR EVOH deteriorates over time in humid storage conditions

Oxygen transmission rate measured using a MOCON OX-TRAN® 221 within 24 hours of coating.

OTR varies with PET grade.

SunBar coating replaces PVdC, EVOH, AIOx and SiOx for O2 barrier

0

1

2

3

4

5

6

7

8

9

PVdC-PET Met-PET AlOx -PET SiOx-PET EVOH-PET SunBar-PET

23ºC & 50% RH

PET / 50 PE:EVOH:PE Extrusion

0.3 dry coating weight

Oxy

ge

n T

ran

smis

sio

n R

ate

(cc

/ m

² /

24

hrs

)

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Light weighting

Coating Applications

Commercial 3-Ply Laminate

Removal of barrier film or foil and one layer of adhesive Lighter weight packaging (up to 30% reduction) Improved laminate integrity (post flexing O2 barrier improvement) Lower material and / or operational costs Improved recycling Improved shelf life

Polymer Film

Ink

Adhesive

MET Polymer Film

Adhesive

Polymer Film

Polymer Film

Barrier Coating

Ink

Adhesive

Polymer Film

2-Ply Laminate plus printable barrier coating

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Barrier Coating

Monoweb

No chlorine No adhesive Improved O2 barrier Improved shelf life Increased sales opportunity for converter-monoweb Increased yield

Commercial 2-Ply Laminate 1-Ply plus printable barrier coating

Polymer Film

OPV

Polymer Film

Adhesive

PVdC coated PET

Ink Ink

Coating Applications- SunBar O2 Barrier

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Technical Data – SunBar O2 barrier

Flexibility of barrier coatings

Oxide coated and metallized films have poor flex resistance

0

1

2

3

4

5

6

7

8

9

0 5 10 20 50

AlOx-PET

SiOx-PET

Met-PET

PVdC-PET

EVOH co-ex/PET

SunBar-PET

Number of Gelbo Flexes

OT

R @

23o

C &

50

%R

H

(

cc /

m2 /

24

hrs

)

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SunBar value proposition – general summary

Chlorine-free

Enables light weighting

Improves sustainability

Removes metal

Transparent

Improves ability to recycle

Alternative to expensive

barrier films

Excellent O2 / aroma / odor barrier

Replaces PVdC and EVOH barriers

Improves flex crack resistance of oxide / metallized

films

Extends shelf life

Coating can be applied at conventional film weights

Can be applied on existing equipment

Enables removal of barrier film & adhesive in multi-ply laminates

Allows duplex laminates to compete with triplex

Reduces processing waste

Reduces energy consumption

Saves on inventory working capital

Applied only where needed

Market Barrier

Application

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UV Barrier Coating

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SunBar UV barrier coatings

potential uses

Protects sensitive foodstuffs from degradation accelerated by UV light

Improved visibility of UV sensitive products at point of sale Allows transparent packaging Potential to extend shelf life of UV sensitive foods

0

0.5

1

1.5

2

2.5

3

0 0.5 1 1.5 2 2.5 3 3.5 4

Coating Weight gsm dry

Abs

orba

nce

Wavelength (nm)

% T

rans

mis

sion

300.0 350 400 450 500 550 600 650 700 750 800.0

-10.0

0

10

20

30

40

50

60

70

80

90

100.0

nm

%T

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SunBar UV barrier coatings

transparent packaging for food applications

Improved shelf life when using transparent film

Results after 140 days in typical retail lighting and 20oC

Scoring by trained sensory panellists

Sensory Assessment Grades vs Days

0

1

2

3

4

5

6

7

8

9

0 28 58 84 112 140

Days

Sen

sory

Gra

de

Light exposed Window laminate bags

Light exposed UVAC laminate bags

Dark control laminate bags

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SunBar UV barrier coatings

transparent packaging for food applications

Reduced photo-bleaching of natural food pigments Cooked ham (results after 4 days at D65 and 4ºC) - carotene results after 2 weeks at D65 and RTP

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SunBar UV barrier coatings

The SunBar UV barrier coating acts as a barrier to UV light whilst allowing visible light to penetrate into the package.

Some foods are affected by visible light as well as UV light. The SunBar UV barrier coating is not a barrier to visible light.

Customers need to understand whether blocking the UV light will bring the required benefit.– SunBar UV barrier coating is only available in its pre

commercialisation form and is not fully transparent.

– Volume commitment is needed for scale up to the fully transparent version.

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Oxygen Barrier Adhesive

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What is PASLIM

PASLIM is a new generation of patented solvent based adhesive, approved for food packaging application, offering additional oxygen barrier proprieties to the normal feature provided by conventional solvent based adhesive.

PASLIM product range consist of two systems for following application:

J40-OX+KX43C for non metallized substratesJ40-OX+KX43C for non metallized substrates

J40-OX+HX42M+AD42 for metallized substratesJ40-OX+HX42M+AD42 for metallized substrates

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Range of application

PASLIM adhesives have been developed with aim of:

Light weighting the laminate retaining the oxygen barrier proprieties

Improve the oxygen barrier proprieties of existing laminates

Retain the barrier proprieties of laminate after retort process

Increasing the shelf life of food staff

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Key feature of PASLIM adhesive

PASLIM adhesive provide the following features:Be applied as conventional solvent based adhesive by rotogravure/semi flexo trolley at higher solid content (50-60%)

Same level of performance in term of Bond and Heat seal strength of conventional adhesive (laminate related)

Oxygen barrier proprieties

Flexibility when compare with other barrier coating (eg SiOx, AlOx) avoiding lost of barrier by coating cracking

Oxygen barrier proprieties independent to relative humidity (improve vs EvOH)

Low retort resistance (121°C x 30 min) without loosing oxygen barrier proprieties

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Flexibility feature

OTR ： cc/m2 ・ day ・ atm(23℃) 　Coating weight: J40-OX/HX42M/AD42=about

4g/m2(dry) Conventional adhesive=about

3.5g/m2(dry)

PASLIM

Conventional adhesi

ve

PASLIM protects the barrier layer from flexional stress.

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Retort feature

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Barrier Adhesive

PETConventional Adhesive

CPP

OTR ： cc/m2 ・ day ・ atm(23℃) 　　 MVTR ： g/m2 ・ day(40℃/90%RH)Coating weight: J40-OX/KX43C=about 5g/m2(dry) Conventional adhesive=about 3.5g/m2(dry)

OTR OTR OTR OTR0%RH 90%RH 0%RH 90%RH

Ny15/PE60 47 53 5.5 Ny15/PE60 14 9 4.7

PET12/PE60 105 80 5.2 PET12/PE60 17 11 4.5

PET12/CPP70 116 92 5.9 PET12/CPP70 17 11 5.0

Ny15/CPP70 47 58 5.9 Ny15/CPP70 10 8 3.7

Barrier Adhesive(J 40-OX/KX43C)Conventional adhesiveFilms organization : Conventional Films

MVTRMVTR

Comparison data of barrier performance

PASLIM gives barrier performance to conventional laminated films

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Barrier Adhesive

PETConventional Adhesive

VM-CPP

(AL Vacuumed

Layer)　

OTR ： cc/m2 ・ day ・ atm(23℃) 　　 MVTR ： g/m2 ・ day(40℃/90%RH)Coating weight: J40-OX/HX42M/AD42=about 4g/m2(dry) Conventional adhesive=about 3.5g/m2(dry)

OTR OTR OTR OTR0%RH 90%RH 0%RH 90%RH

PET12/VMPET12-PE60 2.2 2.1 0.3 PET12/VMPET12-PE60 0.2 0.1 0.1

PET12/VMOPP15-PE80 8.5 11.1 0.4 PET12/VMOPP15-PE80 1.8 1.7 0.3

PET12/VMCPP25 5.0 5.4 0.4 PET12/VMCPP25 0.4 0.2 0.3

PET12/SiOxPET12-CPP70 0.5 0.2 0.7 PET12/SiOxPET12-CPP70 0.1 0.1 0.7

Barrier Adhesive(J 40-OX/HX42M/AD42)Conventional adhesiveFilms organization : Metal vaporized films

MVTRMVTR

Comparison data of barrier performance

PASLIM enhances the barrier performance of metalized films.

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Comparison data of barrier performance

Conventional Adhesive 　 Barrier Adhesive

ＰＥＴ

ＥＶＯＨ、ＰＶＤＣ　

PE

OTR OTR OTR OTR0%RH 90%RH 0%RH 90%RH

Ny15/EVOH15/PE60 0.1 9 2.9 Ny15/PE60 14 9 4.7

PET-K12*1)/PE60 2 2 1.7 PET12/PE60 17 11 4.5

Ny-K12*2)/PE60 8 9 3.7 Ny15/PE60 14 9 4.7

Ny15/ink/PVDC20*2)/CPP70 13 15 4.1 Ny15/ink*3)/CPP70 12 10 3.7

*1) Made in J apan *2) Made in China： ： *3) Two component ink：

Barrier Adhesive(J 40-OX/KX43C)Conventional adhesiveFilms organization : Conventional FilmsFilms organization : Organic Barrier Films

MVTRMVTR

OTR ： cc/m2 ・ day ・ atm(23℃) 　　 MVTR ： g/m2 ・ day(40℃/90%RH)Coating weight: J40-OX/KX43C=about 5g/m2(dry) Conventional adhesive=about 3.5g/m2(dry)

PASLIM replaces organic barrier films to conventional films.

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Project Simulation – Excel Spreadsheet

To predict the comparative cost/m2, Yield and Barrier performance of alternative barrier structures

Developed to quickly assess alternative barrier laminate structures based on SunBar, Paslim, or a combination of both

© Chris Robinson October 2014

Creating alternative Barrier laminate structures with SunBar Coatings and Paslim Adhesives

This calculator produces a quick assessment of Project viabilityin terms of Yield, Cost/m2, OTR and WVTRusing Paslim Barrier Adhesives to replace traditional lamination films and adhesives within High Performance barrier laminates

The savings estimated are only as good as the data it uses……..!They do not represent guaranteed savings.

Using SunChemical products to replace Triplex laminate structures with Duplex alternatives

Using SunChemical products to replace speciality barrier films in Duplex Structures

Using SunChemical products to create Barrier Laminates from standard low-cost films

Using SunBar coatings to replace Duplex laminate structures with Monoweb alternatives

Note: for very thin films and very light coating weights, the prediction of barrier performance becomes less accurate. Pinholing and surface roughness effects can reduce the effective barrier to both Water and Oxygen.

If barrier performance is critical to the end use of the final laminate, measure it.

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Example 1 – Retort Sausage Packs (China)

SunBar is not chosen for this application because of the Retort requirement

Lam Adh Price Paslim Price SunBar Price

4.00 Eur/kg 12.00 Eur/kg 7.00 Eur/kg

Original Structure

TRIPLEX LAMINATE REPLACEMENT

15u PA – polyamide Weight Yield Cost OTR 0%RH OTR 85% RH WVTRLamination Adhesive 3.50 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/day25u EVOH CoEx 93.75 10.67 0.24 0.10 No data 1.91Lamination Adhesive 3.50 gsm50u PE – polyethylene

Alternative Structure 1 - Using Barrier adhesive to replace the Barrier Layer

15u PA – polyamide Weight Yield Cost OTR 0%RH OTR 85% RH WVTRBarrier Adhesive 5.00 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/day50u PE – polyethylene 69.3 14.43 0.21 11.93 No data 2.94

35% -11%Yield improved by 35.3% producing 3763 additional m2 per Tonne, Laminate Cost reduced by 0.03 Eur/m2

Alternative Structure 2 - Using Barrier Coating and conventional adhesive to replace the Barrier Layer

15u PA – polyamide Weight Yield Cost OTR 0%RH OTR 85% RH WVTRSunBar Barrier coating 0.30 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/dayLamination Adhesive 3.50 gsm 68.1 14.68 0.17 0.98 No data 3.6550u PE – polyethylene 38% -29%

Yield improved by 37.7% producing 4017 additional m2 per Tonne, Laminate Cost reduced by 0.07 Eur/m2

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Example 2 – PVdC Film replacement

Depending on the end use application, both SunBar and Paslim offer cost effective alternatives. The choice will be based on other factors eg printing and lamination capability.

Original Structure

TRIPLEX LAMINATE REPLACEMENT

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRLamination Adhesive 3.50 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day cm3/m2/day12u PVdC coated PET 87.98 11.37 0.20 1.97 No data 1.88Lamination Adhesive 3.50 gsm50u PE – polyethylene

Alternative Structure 1 - Using Barrier adhesive to replace the Barrier Layer

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRBarrier Adhesive 5.00 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/day50u PE – polyethylene 69.3 14.43 0.18 13.36 No data 2.87

27% -8%Yield improved by 27% producing 3063 additional m2 per Tonne, Laminate Cost reduced by 0.01 Eur/m2

Alternative Structure 2 - Using Barrier Coating and conventional adhesive to replace the Barrier Layer

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRSunBar Barrier coating 0.30 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/dayLamination Adhesive 3.50 gsm 68.1 14.68 0.14 0.99 No data 3.5550u PE – polyethylene 29% -28%

Yield improved by 29.2% producing 3318 additional m2 per Tonne, Laminate Cost reduced by 0.06 Eur/m2OTR improved

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Example 3 – VMPET replacement

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRLamination Adhesive 3.50 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day cm3/m2/day12u Met PET 87.98 11.37 0.19 0.99 No data 0.78Lamination Adhesive 3.50 gsm50u PE – polyethylene

Alternative Structure 1 - Using Barrier adhesive to replace the Barrier Layer

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRBarrier Adhesive 5.00 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/day50u PE – polyethylene 69.3 14.43 0.18 13.36 No data 2.87

27% -3%Yield improved by 27% producing 3063 additional m2 per Tonne, Laminate Cost reduced by 0.01 Eur/m2

Alternative Structure 2 - Using Barrier Coating and conventional adhesive to replace the Barrier Layer

12u PET – polyethylene terephthalate Weight Yield Cost OTR 0%RH OTR 85% RH WVTRSunBar Barrier coating 0.30 gsm gsm m2/kg Eur/m2 cc/m2/day cc/m2/day g/m2/dayLamination Adhesive 3.50 gsm 68.1 14.68 0.14 0.99 No data 3.5550u PE – polyethylene 29% -25%

Yield improved by 29.2% producing 3318 additional m2 per Tonne, Laminate Cost reduced by 0.05 Eur/m2

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Laser Marking

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1SunLase™ - Description of principle (1)

SunLase™ coating is used to print a white patch on a substrate

The graphics are created when a low power CO2 laser changes the colour of the patch to black where marked

Low powerCO2 laser

PRINTING

FORMING, FILLING

MARKING

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2SunLase™ - Description of principle (2)

Sun Chemical has developed the SunLase™ coatings which are sensitive to specific low energy lasers, allowing the marking of high definition variable data on various substrates.

SunLase™ coatings contain specific pigments, that change from white to black when hit by a low energy laser. There is no ablation.

SunLase™ range offers packers and end-users the platform to introduce greater efficiencies and productivity as well as higher quality on their identification marking applications

SunLase™ range covers most of printing and coating technologies: flexo, gravure, dry offset, water-based, solvent-based, oil-based, UV

Patch is printed with a SunLase™ coating

When the coating is marked with a laser – a high definition black graphic appears

Surface imaging Reverse imaging

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Option 2

Option 3

Option 13

Main substrate

Overprintlacquer

Lase

r

SunLase™ - Description of principle (3)

Printing options: surface, surface lacquered, or reverse

Main substrateLa

serImage SunLase™

coating

SU

RF

AC

EP

RIN

TIN

GR

EV

ER

SE

PR

INT

ING

SunLase™coating

Othersubstrate

Transparentsubstrate

(plastic film, glass…)La

ser

Adhesive

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1SunLase™ - Target markets and applications (1)

Markets: all packaging printers/converters or packing companies:– Corrugated containers– Flexible packaging– Folding carton– PE Films– Reverse-printed sleeves – Multiwall sack– Liquid carton packaging

Variable Data Applications:

– Need of sequential numbers per pack / batch…– Unique identifiers per pack, batch, consumer…– Personalisation – Network based coding– Primary coding on flexible packaging– Date / Price / Batch codes– Language / ingredients / GDA &

nutritional information

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2SunLase™ - Target markets and applications (2)

End-uses:

– High volume food producers with short shelf life products, for example: milk: sleeves and labels yogurts: PET/PP lids and labels beverage: beer bottle labels cereal primary packs

– Personal care labels and sleeves

– Pharmaceutical labels, foils, blisters

– Existing production over 5 million outer cartons per year

– Current users of Hi-Resolution ink jet –print and hand applied labels

– Businesses that suffer finesfor poor barcode quality

– etc

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Labelling

Ablation

SunLase™ - How it compares with labelling, inkjet, ablation

These comparisons are based on Sun Chemical’s internal rating, and would be slightly different case by case.

0

1

2

3

4

5Productivity

Downtime

Costof mark

Imagequality

Investment

Waste

Evolutionability

Qualitycontrol

0

1

2

3

4

5Productivity

Downtime

Costof mark

Imagequality

Investment

Waste

Evolutionability

Qualitycontrol

0

1

2

3

4

5Productivity

Downtime

Costof mark

Imagequality

Investment

Waste

Evolutionability

Qualitycontrol

5 is the best score

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Brand Protection

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For mid- to high-level, overt and covert security solutions

Taggant reader systemsHidden image technologyHologramsSpecialty inks and effects

Brand Protection Solutions

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Brand Protection & Anti Counterfeiting Portfolio

Green 1022-073

Overt Smart

Hologram®

Covert IR responsive Apollo Inks

Covert IR responsive Orion Inks

Covert UV fluorescing

inks

Covert Hidden Indicia®

Covert Verigard™ authentication –

yes/no

Overt SunShift™ colour shifting inks

Overt/Covert SunGram™

machine readable holograms/foils

Covert non line of site

authenticationForensic

authentication

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Thank You!

working for you.

Please visit us at www.SunChemical.com or for more information contact us at packaging@sunchemical.com