your partner in coatings, science & technology partner in coatings, science & technology ......
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Your Partner in Coatings, Science & Technology
Evaluation of bio-based products in architectural paints
M.Wenkin, C.de Lame, M.H.Delvaux, A.Lourtie, A.Pirmez, A.Richel, G.Olive
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205/05/2015
Close collaboration with IVP (the professional federation of industries active in varnishes, paints, sealants, printing inks and artists' colors). IVP represents around 70 companies in these sectors, approximately 3,500 employees
CoRI is a Belgian non-profit organization funded in 1957 in order to stimulate innovation and research in the paint, varnish and coatings industry by scientific
and technological developments.
Created by the Industry
For the Industry
Coatings Research Institute
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305/05/2015
to provide assistance, support and services by offering
Our mission
ad hoc analysis
problem-solving
contract research
technical assistance training
to paint manufacturers, raw materials suppliers, professional applicators and
industrial users
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405/05/2015
■ Research Collective research Contractual research Pre-normative
■ Testing and Analysis
■ Technical assistance and Expertise
■ Training - Congress
ACTIVITIES
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505/05/2015
Research area
Improving ecological footprint
Biomaterials, VOC, LCA, …
MultiFunctionalization
Reduction of building energy consumption,
anti corrosion, anti icing, color effects,
protection, conductivity, odors/VOC reduction Regulation
Market
Durability, resistance, substrates
(wood – Eco buildings)
29 collective research programs
between 2007 & 2015
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605/05/2015
Evaluation of bio-based products in architectural paint formulations
Bio-based products:
• Products wholly or partly derived from biomass, such as plants, trees or animals (the biomass can have undergone physical, chemical or biological treatment) (CEN 16575)
Objectives
http://www.codeve.fr/peinture-batiment/232-peinture-mur-interieur.html
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705/05/2015
Considered bio-based products (I)
• The first part focuses on the use of sugar esters, of commercial alkyl-polyglucosides and alkyl-polypentosides and of a commercial sugar base polymer as dispersing agents.
• APG (alkyl polyglucosides), APP (alkyl polypentosides) and sugar esters
- a class of non-ionic surfactants.- synthesized from renewable materials.- non-toxic, biodegradable, odourless and non-irritating.- APG and APP are widely used in a variety of household and industrial applications
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805/05/2015
Considered bio-based products (II):
• The second part is dedicated to the use of wheat gluten as binder or co-binder in architectural paints.
• Wheat gluten is a by-products of the wheat starch industry. It’s widely available and at low price.
• It can be distinguished from other industrial proteins by some of its particular properties like:
• its insolubility in water, • its viscoelastic behaviour, • its potential film-forming ability, • its RH-dependent gas barrier properties and its rather high
water vapour permeability.
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905/05/2015
Bio-based additives
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1005/05/2015
Selected commercial biobased additives
Selected bio-based additives
Name Chemical nature Active matter (%) Dry matter (%)Disp 1 non-ionic, modified fatty acid derivative 100Disp 2 polymer 32
Sugar based Chain-lenght Active matter (%) Dry matter (%)Disp 3 APG* C4 49-51Disp 11 APG* C8 65-70Disp 4 APG* C8 68-72Disp 5 APG* C8-C10 60Disp 6 APG* C8-C10 60Disp 7 APG* C10 50Disp 8 APP** C5 60Disp 9 APP** C5 and C10-C12 60Disp 10 Sugar-based polymer 51
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1105/05/2015
Synthesized sugar esters
Disp 12: Fructose palmitate ( (C10), Disp 13: Fructose laurate (C12)Disp 14: Fructose caprate (C16)
synthesised by the University of Liège according to an enzymatic process (Olive, G.; Pompeu Torezan, G.A.; Blecker, C.; C. R. Chimie 15 (2012) 1037)
Selected commercial petrochemical additive
Polyacrylic ammonium salt
Selected bio-based additives
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1205/05/2015
Dispersant demand curves measurements to determine the amount of additives required to fully wet and disperse the pigments and fillers.
Paints preparation
0
0,005
0,01
0,015
0,02
0,025
0,03
0 5 10 15 20 25
Visc
osity
(Pa.
s)
Conc. additive/pigments and fillers (%)
50%wt pigments and fillers
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1305/05/2015
Replacement of the petrochemical dispersing and wetting agent of a reference architectural paint by the bio-based additives with the optimized concentration.
The sugar ester were added with a fixed amount of 3.8% (ratio dry sugar ester/pigments and fillers).
Architectural paint:• The binder : anionic aqueous dispersion of acrylic ester and styrene
copolymer (Axilat UG DS2800 from Momentive). • Pigment volume concentration 38.5%• Dry matter 64.3%.
Paints preparation
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1405/05/2015
Storage stability
Viscosity measurements
• at the initial stage, • after a storage of 1 month at room temperature and at 50°C.
The results show a strong increase of the viscosity after 1 month storage at 50°C for paints prepared with
Disp 7 (APG C10) at the highest concentration,Disp 5 (APG C8-10), Disp 6 (APG C8-C10), Disp 13 (fructose ester C12) and Disp 14 (fructose ester C10)
meaning that these paints have a limited storage stability.
Liquid paints characterization
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1505/05/2015
Drying time ASTM D5895 -“Standard test methods for evaluating drying and curing during film formation of organic coatings using mechanical recorders”.
Liquid paints characterization
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1605/05/2015
Open time ASTM D7488 - "Test method for open time of latex"
Liquid paints characterization
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1705/05/2015
Open time
Liquid paints characterization
ASTM D5895
0 1 2 3 4 5 6 7
Disp 14 - Caprate 3,8%Disp 13 - Laurate 3,8%
Disp 12 -Palmitate 3,8%Disp 10 - 3%
Disp 9 (APP C5 et C10-12) - 7,5%Disp 8 (APP C5) - 3%
Disp 7 (APG C10) - 11%Disp 7 (APG C10) - 7,5%
Disp 6 (APG C8-C10) - 6%Disp 5 (APG C8-C10) - 7,5%
Disp 11 (APG C8) - 1,5%Disp 3 (APG C4) - 7,5%
Disp 2 - 10%Disp 2 - 8%Disp 1 - 4%
Ref 7,4%
Time (min.)
Open time (22°C/50%HR)
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1805/05/2015
Dynamic surface tension
Liquid paints characterization
Krüss tensiometer at room temperature (platinum ring – vessel diameter: 44.5 mm - paint volume 20ml – immersion depth: 3 mm - rate :3 mm/min – Harkins Jordan method).
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1905/05/2015
Spreading rate at a hiding power of 98 % ASTM D2805-11 –“Standard Test Method for Hiding Power of Paints by Reflectometry”.
Dry paints characterization
0
2
4
6
8
10
Spreading rate (m²/l)
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2005/05/2015
Wet scub resistance ISO 11998 – « Paints and varnishes --Determination of wet-scrub resistance and cleanability of coatings».
Dry paints characterization
0
2
4
6
8
10
µm
Thickness loss after 200 cycles
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2105/05/2015
Biobased additives : conclusions
Name Chemical natureAdditive/fillers and pigments
(%)Storage stability
Open time
Spreading rate
Wet srub resistance
Disp 1 4
Disp 28
Disp 210
Sugar based Chain-lenghtDisp 3 APG* C4 7,5
Disp 11 APG* C8 1,5Disp 4 APG* C8 7,5 n.a.Disp 5 APG* C8-C10 7,5Disp 6 APG* C8-C10 6Disp 7 APG* C10 7,5Disp 7 APG* C10 11 ++Disp 8 APP** C5 3Disp 9 APP** C5 and C10-C12 7,5
Disp 10 3Disp 12 Fructose C16 3,8Disp 13 Fructose C12 3,8Disp 14 Fructose C10 3,8
non-ionic, modified fatty acid derivative
aq. sol. of a polymer based on a renewable resource
aq. sol. of a polymer based on a renewable resource
Sugar based bio polymer
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2205/05/2015
Gluten
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2305/05/2015
Dispersion of wheat gluten (from Aldrich) in an aqueous solution
Adjustment of the pH of the gluten dispersion to 8
Mixing of the gluten dispersion with a styrene-acrylic dispersion (Axilat DS2100 or Axilat DS2800 from Momentive)
Paints preparation
Paint Binder Dry ratio Gluten/Axilat
Dry content PVC
A Gluten/Axilat DS2100 1/6 33,8 41B Gluten/Axilat DS2800 1/6 33,8 41C Gluten/Axilat DS2100 1/1 36 12D Gluten/Axilat DS2800 1/1 36 12
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2405/05/2015
Paints characterization
Storage stability
• Measurement of the viscosity at the initial stage, after a storage of one month at RT and at 50°C
• Paint B (Gluten/Axilat DS2800 1/6) is stable
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2505/05/2015
Paints characterization
Dry paints characterization
(1)Application on tinned iron panels (200 µm wet (2)Application on porous substrate (two layers)(3)Free films composed of two layers (4)Free films composed of two layers
Persoz(s)(1)
ISO1522
Liquid water permeability
(ml)(2)
after 24H
Vapour water transmission
coefficient (g/m2/24h) (dry thickness) (3)
ASTM D1653
Wet scrub resistance –
thickness loss after 200 cycles
(µm)(4)
ISO11998
A :Glut 2100 1/6 90 5 406 + 29 (88 + 8 µm) 12,9
B : Glut 2800 1/6 28 1 165 + 11 (75 + 3 µm) 4,7
C : Glut 2100 1/1 85 6,5 545 + 17 (60 + 2 µm) 26,2
D : Glut 2800 1/1 64 7 542 + 17 (67 + 2 µm) 24,6
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2605/05/2015
In the tested architectural paint, some sugar-based additives gave results at least similar to the petrochemical one.
The most promising ones are APG-C8 and APP-C5. Only small amount of dispersant is required
Paints were successfully prepared from gluten and styrene-acrylic dispersion. One of them has good storage stability, high wet scrub resistance, high water vapour permeability and low liquid water permeability.
Conclusion
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05/05/2015
27
…thank you for your attention