Chemistry2APCourseSyllabusCurricularRequirements Page(s)CR1 Students and teachersusearecentlypublished (within the last10years) college-levelchemistry

textbook2

CR2 ThecourseisstructuredaroundtheenduringunderstandingswithinthebigideasasdescribedintheAPChemistryCurriculumFramework

1,2

CR3a ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea1:Structureofmatter.

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CR3b ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea2:Propertiesofmatter-characteristics,states,andforcesofattraction.

10

CR3c ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea3:Chemicalreactions.

7

CR3d ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea4:Ratesofchemicalreactions.

13

CR3e ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea5:Thermodynamics.

8

CR3f ThecourseprovidesstudentswithopportunitiesoutsidethelaboratoryenvironmenttomeetthelearningobjectiveswithinBigIdea6:Equilibrium.

14

CR4 Thecourseprovidesstudentswiththeopportunitytoconnecttheirknowledgeofchemistryandsciencetomajorsocietalortechnologicalcomponents(e.g.,concerns,technologicaladvances,innovations)tohelpthembecomescientificallyliteratecitizens.

15

CR5a Studentsareprovidedtheopportunitytoengageininvestigativelaboratoryworkintegratedthroughoutthecourseforaminimumof25percentofinstructional

1,2

CR5b Studentsareprovidedtheopportunitytoengageinaminimumof16hands-onlaboratoryexperimentsintegratedthroughoutthecoursewhileusingbasiclaboratoryequipmenttosupportthelearningobjectiveslistedwithintheAPChemistryCurriculumFramework.

4,6-17

CR6 ThelaboratoryinvestigationsusedthroughoutthecourseallowstudentstoapplythesevensciencepracticesdefinedintheAPChemistryCurriculumFramework.Atminimum,sixoftherequired16labsareconductedinaguided-inquiryformat.

4,6,7,8,10-15,17

CR7 Thecourseprovidesopportunitiesforstudentstodevelop,record,andmaintainevidenceoftheirverbal,written,andgraphiccommunicationskillsthroughlaboratoryreports,summariesofliteratureorscientificinvestigations,andoral,written,andgraphicpresentations.

3

CourseDescriptionChemistry2APisdesignedtobetheequivalentofthegeneralchemistrycoursetakenduringthefirstcollegeyear.[CR2]ThecourseisstructuredaroundthesixbigideasarticulatedintheAPChemistrycurriculumframeworkprovidedbytheCollegeBoard.Thesevensciencepracticeswillbeemphasizedthroughouttheunits,andthespecificlearningobjectivesandessentialknowledgestandardswillbecoveredaccordingotopic.StudentswhowishtoenrollinChemistry2APmusthavecompletedafirst-yearcourseinBiology1orBiology1HonorsandChemistry1orChemistry1Honors,withastrongperformanceinChemistry1orChemistry1Honors.Chemistry2APstudentsaregenerallyjuniors.AllofthestudentstaketheAPChemistryExamattheendoftheyear.Withablockschedule,theclassmeetsfivetimesduringatwoweekperiod.Theblockis113minutes.Theequivalentofoneblockperweekisspentinthelaboratory,withatleast25%oftotalinstructionaltimespentinhands-onlaboratoryexperiencesthroughoutthecourse[CR5a].Studentsareexpectedtodo1to1½hoursofhomeworkanight.BigIdea1:StructureofMatter(Ch.2,5,7,8,9,10)BigIdea2:Propertiesofmatter-characteristics,states,andforcesofattraction(Ch.2,5,7,8,9,10,11,19,20)BigIdea3:ChemicalReactions(Ch.3,4,17)BigIdea4:RatesofChemicalReactions(Ch.12)BigIdea5:Thermodynamics(Ch.6,16)BigIdea6:Equilibrium(Ch.13,14,15)

CourseOverviewTheoverviewisbasedona40-weekcoursedividedintofourquarters.ReadingandproblemsareassignedduringthesummeraswellasduringtheWinterandSpringbreaks.Thepaceandcontentofthecoursethroughouttheyearisverychallenging.Duringthefirsthalfoftheyear,classsessionsaredominatedbystudentquestionsandtimespentsolvingproblemsaswereviewandelaborateonmaterialcoveredduringthefirstyearchemistrycourse.Thesecondhalfoftheyearrequiresmoretimespentinlecturewithrelativelynewmaterialforthesecondyearchemistrystudent,applicationsofaqueousequilibrium,spontaneity,entropy,andfreeenergy,andelectrochemistry.CourseObjectivesStudentswill:1.Learntheinquiryprocessthroughnumerouslaboratoryinvestigations.2.GainanunderstandingofthesixbigideasasarticulatedintheAPChemistryCurriculumFramework.[CR2]3.Applymathematicalandscientificknowledgeandskillstosolvequantitative,qualitative,spatial,andanalyticproblems.4.Applybasicarithmetic,algebraic,andgeometricconcepts.5.Formulatestrategiesforthedevelopmentandtestingofhypotheses.6.Usebasicstatisticalconceptstodrawbothinferencesandconclusionsfromdata.7.Identifyimplicationsandconsequencesofdrawnconclusions.8.UsemanipulativeandtechnologicaltoolsincludingtheTexasInstrumentsNspireCASCXHandhelds,VernierLabQuests,VernierProbes,andVernier’sLoggerProsoftware.9.Measure,compare,order,scale,locate,andcodeaccurately.10.Doscientificresearchandreportanddisplaytheresultsofthisresearch.11.Learntothinkcriticallyinordertosolveproblems.TextbooksandLabBooks[CR1]ChemistrybyZumdahlandZumdahl,9thed.,CengageLearning,2013ISBN13: 978-1133611097TeacherReferenceTexts(includesbutnotlimitedto…)ChemistrybyZumdahlandZumdahl,7thed.,HoughtonMifflinCompany,2007ISBN13:978-0-618-52844-8ChemistryTheCentralSciencebyBrown,LeMay,andBursten,10thed.,PearsonEducation,Inc.,2006ISBN0-13-193719-7Chemistry&ChemicalReactivitybyKotz,Treichel,andWeaver,6thed.,ThomsonLearning,Inc.,2006ISBN0-534-99766-XExperimentalChemistrybyJamesF.Hall,7thed.,HoughtonMifflinCompany,2007ISBN:0-618-52848-2LaboratoryExperimentsforAdvancedPlacementChemistrybySallyAnnVonderbrink,Ph.D.,2nded.,FlinnScientific,Inc.,2006ISBN978-1-933709-03-1ChemicalDemonstrations:ASourcebookforTeachersbyLeeSummerlinandJamesL.Ealy,Jr,2ndEd,AmericanChemicalSociety,1985ISBN0841209235

RequiredMaterialsStudentswillberequiredtouseagraphingcalculator,splashproofgoggles,writingutensils,andacarboncapablelaboratorynotebook.LabsAtleast25%oftotalinstructionaltimewillbespentinhands-onlaboratoryexperiencesthroughoutthecourse[CR5a].Studentsworkinlabgroupsoftwo.Studentsarerequiredtokeepalabnotebookofalltheworktheyhavedoneinthelab.Formallabreportsarerequiredforeachlab,andwillrequirestudentstorecordthepurpose,procedure,data,dataanalysis,erroranalysis,results,andconclusionsinalabreportthatissubmittedforgrading[CR7].Labworkisdesignedtosupplementthematerialcurrentlybeingcoveredintheclass,andallworkiscompletedinaseparatelabnotebook.Studentswillphysicallymanipulateequipmentandmaterialsinordertomakerelevantobservationsandcollectdata;usethecollecteddatatoformconclusionsandverifyhypotheses;andcommunicateandcompareresultsandprocedures.The10PartsofaLaboratoryReport[CR7]:Studentswillberequiredtofollowaspecifiedlabreportformatforeachlaboratoryassignment.APChemistrylabreportsaremuchlongerandmoreindepththantheonescompletedinthefirstyearchemistrycourse.Therefore,itisimportantthatstudentsdon’tprocrastinatewhendoingpre-labandpost-labwork.Beforetheexperiment:

1. Pre-Lab.Thesearequestions/procedurestobecompletedbeforetheexperiment.2. Title.Thetitleshouldbedescriptiveandspecific.3. Date.Thisisthedatethestudentperformedtheexperiment.4. Purpose.Thepurposemustsummarizethemainobjectiveofthelabactivity.5. ProcedureOutline.Studentswillberequiredtowriteanoutlineoftheprocedure.Forinquiry

labs,studentsmustwriteoutacomplete,step-by-stepprocedurewithallmaterials.Conceptmapsmaybeusedtosupplementprocedures.

6. DataTables.Studentswillneedtodevelopdatatableswithspecificlabelsandunits.Duringtheexperiment:

7. Data.Datamustberecordedinlabnotebooksandbelabeledwithappropriateunits.Post-experiment:

8. CalculationsandGraphs.Studentsshouldshowallwork,fullylabelgraphs(includingtitles,axes,andscales).

9. Conclusions.Studentsmustanalyzetheirdataandcometoaconclusionregardingthepurpose.10. ErrorAnalysis.Studentsshouldanalyzeallpossiblesourcesoferrorandhowtheymayhave

affectedresults.SciencePractices(SP)

1. Thestudentcanuserepresentationsandmodelstocommunicatescientificphenomenaandsolvescientificproblems.

2. Thestudentcanusemathematicsappropriately.3. Thestudentcanengageinscientificquestioningtoextendthinkingortoguideinvestigations

withinthecontextoftheAPcourse.4. Thestudentcanplanandimplementdatacollectionstrategiesappropriatetoaparticular

scientificquestion.5. Thestudentcanperformdataanalysisandevaluationofevidence.6. Thestudentcanworkwithscientificexplanationsandtheories.7. Thestudentisabletoconnectandrelateknowledgeacrossvariousscales,conceptsand

representationsinandacrossdomains.

Inquiry-BasedLabActivities[CR5B][CR6]Foreachunit,multipleactivitiesandlabswillbecompleted,withmostlabs/activitiesestimatedtotakeoneblockperiod.Manyofthelabswillbeinquiry-driven,requiringdoublelabperiods,including(butnotlimitedto)thefollowinglabactivities:• DeterminingtheEmpiricalFormula:Thequantitativestoichiometricrelationshipsgoverningmass

andamountwillbestudiedusingthecombustionreactionofmagnesiummetal(Sciencepractices2,3,4,5,6)

• Spectrumandspectroscopylab:Studentslookataseriesofemissionspectraanddeterminetheidentityofanunknown.TheywillalsoreceiveandanalyzeIRandmassspectroscopydata.(Sciencepractices1,3,4,5,6)

• Acid-BaseTitration:StudentsperformatitrationandthendeterminetheconcentrationofanHClsolutionbyusingapotentiometrictitrationcurveandfindingtheequivalencepoint.Dataisgraphedinagraphingprogram.(Sciencepractices1,2,3,4,5,6)

• TypesofReactions:Inthislaboratoryexperiment,studentswillperformaseriesofreactionsknownasthecoppercycleandidentifythedifferentreactiontypesbasedonobservations.Studentswillextendtheirinvestigationbydevelopingreactionsbasedonavailablereactants.(Sciencepractices3,4,5,6)

• Calorimetry:Studentswilldesignanexperimentthatwilldemonstratethemeasurementofheattransferfromonesubstancetoanother.(Sciencepractices2,3,4,5,6,7)

• BondingInquiry:Studentswillexperimentallyinvestigateionicandmolecularsubstancesdeducingpropertiesoftheirbondsintheprocess.(Sciencepractices3,4,5,6,7)

• PenniesintoGold:Studentswillutilizetheirunderstandingofoxidation-reductionreactionsandallowstotransformthebrassalloycoatingonpennies.(Sciencepractices2,3,4,5,6)

• Beer’sLaw:Studentswillstudythelightabsorptionofaqueouscopper(II)ionsandinvestigatehowtocalculatethemolarityofasolutiongivenanothersolutionofknownconcentration.(Sciencepractices1,2,3,4,5,6,7)

• ChemicalKinetics:EffectsofConcentrationandTemperature.Studentswilldeterminetheratelawofachemicalreactionaswellastheactivationenergyofachemicalreactionbyutilizingtheirknowledgeofkinetics.(Sciencepractices2,3,4,5,6)

• EquilibriumandLeChatelier’sPrinciple.StudentswillpredictandanalyzetheeffectsofseveralstressestodourdifferentchemicalsystemstodemonstrateLeChatelier’sPrinciple.Studentswillthenapplytheirknowledgetodevelopaninquiry-basedinvestigationonadifferentsystem.(Sciencepractices3,4,5,6)

• Solubility-ProductConstant:Studentswillinvestigateequilibriabydeterminingthevalueofthesolubility-productconstantforasparinglysolublesalt.(Sciencepractices2,3,4,5,6)

APExamReview:ThefinaltenfullclassdaysbeforetheAPChemistryExamareusedforexamreviewandpracticetestsusingoldAPChemistryexammaterials.Studentsworkincooperativegroupstosolveapacketoffreeresponseproblemsfrompreviousexams.Studentspracticenetionicequationsandarequizzedontheirprogress.SeveralpracticeAPExamsareadministeredaspartofthetwo-weekreviewpriortotheAPChemistryExam.

APChemistryUnitOverviewUnit1:IntroductoryandReviewConcepts TestsAssigned:1Chapters:1,2,3,5TimeRequirement:2½-3½Weeks(primarilycompletedduringthesummer)TopicsCovered: CurriculumFrameworkArticulation:LabSafety/Equipment Measurement/Precision/Accuracy/SignificantFigures/DimensionalAnalysis/Temperature/Density

(BI.1.D.1.a,LO1.3,SP2,5)

AtomicTheory/Thomson’sexperiment/Rutherford’sexperiment/Milliken’sexperiment

(1.A.1.b)

Symbolsandformulas/Atoms,moleculesandions (1.E.1.a,1.E.1.c,1.E.2.b)PeriodicTable (1.B.1.a,1.B.1.c,1.B.2.b,1.B.2.d,1.C.1.b,1.C.1.c,

1.C.1.d,1.D.1.b,2.C.1.a,2.C.1.d)CovalentandIonicBonds (2.A.1.a,2.A.1.d,2.C.3,2.C.1.c,2.C.1.e,2.C.1.f)Nomenclature (1.E.2.b)Averageatomicmass/Themole (1.A.3.b,1.A.3.c,1.A.3.d,1.E.2.b)Stoichiometry/Balancingequations/%fromformula/Empiricalandmolecularformulas/Limitingreactant

(1.A.3.a,1.E.1.b,3.A.2.a)

Pressure (2.A.2.a)GasLaws/IdealGases/Boyle’sLaw/Charles’Law/Gay-Lussac’sLaw/Avogardro’sLaw/Dalton’sLawofPartialPressures/Graham’sLaw/IdealGasLaw

(2.A.2.a,2.A.2.b,2.A.2.c)

GasesandStoichiometry (3.A.2.b)KineticMolecularTheory (2.A.2.d,5.A.1)RealGases (2.A.2.e,2.A.2.f,2.A.2.g,2.B.2.c,2.B.2.d)Thestudentwill:1.Useanddefinetermssuchasaccuracy,precision,matter,element,compound,mixture,solution,pressure,standardpressure,STP,molarvolume,partialpressure,diffusion,effusion,realgas.2.Solveproblemsusingthemetricsystemanddimensionalanalysis.3.Understandandworkwiththepropernumberofsignificantfigures.4.Applyknowledgeofsignificantfigures,accuracy,andprecisiontolaboratorywork.5.Correctlyuseananalyticalbalance.6.Knowthenameandhowtousethecommonlaboratoryequipmentusedinthiscourse.7.Namethepolyatomicions,giventheformulaandviceversa.8.Nameinorganiccompounds,includingacids,usingtheStocksystem.9.Writeformulasgiventhenamesofinorganiccompounds.

10.Solveproblemsinvolvingthemole,molecularmass,percentcomposition,empiricalformulas,andmolecularformulas.

11.Balancechemicalequations.12.Solvestoichiometryproblems,determinethepercentyieldandthelimitingreactant.13.Stateanddiscussthepostulatesofthekineticmoleculartheoryastheyrelatetotheparticlesofanidealgas.14.Convertbetweenunitsofpressure.15.WorkproblemsusingBoyle’sLaw,Charles’Law,Gay-Lussac’sLaw,Avogadro’sLaw,Dalton’slaw,theIdealGasLaw,andthevanderWaalsequation.

Labs&Activities LearningObjectivesandSciencePractices

Studentsuseamassspectrometerprintoutoftherelativemassesofisotopesofanelementtodetermine(a)thepercentagesoftheisotopesand(b)theaverageatomicmassoftheelement[CR3a]

LO1.14SP1.5,5.1,5.3,6.1

FindingtheRatioofMolesofReactantsinaChemicalReaction:Studentsdeterminethecorrectmoleratioofreactantsinanexothermicreactionbymixingdifferentamountsofreactantsandgraphingtemperaturechanges.[CR5B]

LO1.4SP1.1,2.2,4.3,5.1

DeterminingtheEmpiricalFormula:Thequantitativestoichiometricrelationshipsgoverningmassandamountwillbestudiedusingthecombustionreactionofmagnesiummetal[CR5B][CR6]

LO1.2SP2.2,3.1,4.2,4.3,4.4,5.1,5.3,6.1

MolarVolumeofaGas(Dalton’sLawofPartialPressures/CollectingaGasoverwater)[CR5B]

LO1.1,3.3SP2.2,4.3,5.1

MolecularMassofaVolatileLiquid:StudentsusetheDumasmethodfordeterminationofthemolarmass/molecularmassofanunknownvolatileliquid.[CR5B]

LO2.4,2.5,5.2SP2.2,5.1

Spectrumandspectroscopylab:Studentslookataseriesofemissionspectraanddeterminetheidentityofanunknown.TheywillalsoreceiveandanalyzeIRandmassspectroscopydata.[CR5B][CR6]

LO1.5,1.6,1.7,1.8,1.14,1.15SP1,3.1,4.2,4.3,4.4,5.1,5.2,6.1,6.2

Unit2:TypesofChemicalReactionsandSolutionStoichiometry TestsAssigned:1Chapters:4TimeRequirement:2WeeksTopicsCovered: CurriculumFrameworkArticulation:Oxidationnumbers/RedoxReactions/BalancingRedoxReactions/Redoxtitrations

(3.B.3.a,3.B.3.b,3.B.3.c,3.B.3.d)

Water/Solutions/Electrolytes/Molarity/Dilution (2.A.3.h,1.D.3.c,2.A.3.i,2.A.3.j)Synthesis/Decomposition/SingleReplacement/DoubleReplacement/Combustion

(3.A.1,3.B.1.a,3.B.3.e,3.C.1.d)

Molecular,Ionic,andNetIonicEquations (3.A.1)Acid-BaseReactions/Titrations (1.E.2.f,3.A.2.c)Thestudentwill:1.Determinetheoxidationnumbersforelementsinthefreestate,inanion,orinacompound.2.Balanceredoxreactionsusingthehalf-reactionmethod.3.Usetheactivityseriesofelementstodeterminetheproductsofsinglereplacementreactions.4.Classifycompoundsasacids,bases,salts,andcovalentcompounds.4.Usethepropertiesofmetalsandnonmetalstopredictreactionproducts.5.Classifyandwritechemicalequationsforsynthesis,decomposition,singlereplacement,doublereplacement,redox,combustion,andacid-basereactions.6.Writebalancedmolecular,ionic,andnetionicequations.7.Solveproblemsinvolvingsolutionconcentrationsanddilution.Labs&Activities LearningObjectivesand

SciencePracticesStudentswillobserveaseriesofchemicalreactionsusingdifferentmedia(ex/video),andforeachtheywillclassifythereactiontype,writeabalancednetionicequation,andwriteadescriptionforeachreaction.[CR3c]

LO3.8SP5.1,5.2,5.3,6.1,6.2

Acid-BaseTitration:NeutralizationofaWeakAcidwithaStrongBase[CR5B]

LO1.2,3.9SP2.2,2.3,4.3,5.1

Acid-BaseTitration.StudentsperformatitrationandthendeterminetheconcentrationofanHClsolutionbyusingapotentiometrictitrationcurveandfindingtheequivalencepoint.Dataisgraphedinagraphingprogram.[CR5B][CR6]

LO1.2,3.9SP1.4,2.2,2.3,3.3,4.1,4.2,4.3,5.1,5.3,6.2

TypesofReactions:Inthislaboratoryexperiment,studentswillperformaseriesofreactionsknownasthecoppercycle.[CR5B][CR6]

LO1.4,3.1,3.2,3.5,3.63.10SP3.1,3.2,3.3,4.1,4.2,4.3,5.1,5.2,5.3,6.1,6.2

Unit3:ThermochemistryandNuclearChemistryTestsAssigned:1Chapters:6and18TimeRequirement:1½WeeksTopicsCovered: CurriculumFrameworkArticulation:Energy/Pressure-Volumework (5.B.1,5.E.2.a)Changeinenthalpy/Calorimetry (5.A.2,5.B.2,5.B.3.a,5.B.3.b,5.B.4)Hess’Law (5.B.3.a)EnthalpiesfromStandardEnthalpiesofFormation (5.C.2.g)NuclearStabilityandRadioactiveDecay (4.A.3.e)KineticsofRadioactiveDecay/Half-life (4.A.3)NuclearTransformations ThermodynamicStabilityoftheNucleus NuclearFission/NuclearFusion/NuclearReactors EffectsofRadiation Thestudentwill1.Useanddefinetermssuchasenthalpy,ΔH,exothermic,endothermic,system,surroundings,universe,heatofformation,calorimetry,heat,calorie,joule,standardmolarenthalpyofformation,molarheatofcombustion,nucleon,radioactivedecay,fission,fusion,decayseries,massdefect,bindingenergy,chainreaction,subcriticalreaction,criticalreaction,criticalmass,reactorcore,moderator,controlrods.2.Solvecalorimetryproblemsusingq=CmΔT3.UseHess’sLawtosolvefortheheatofreaction.4.Usestandardenthalpiesofformationtosolveforheatofreaction.5.Usestoichiometrytosolvethermochemistryproblems.6.Knowthetypesofradioactivedecay.7.Writebalancednuclearequationsshowingradioactivedecay,nuclearfission,andnuclearfusion.8.UseE=mc2todeterminethebindingenergyofanucleus.9.Willsolveproblemsinvolvingthekineticsofradioactivedecay.

10.Researchandwritea3–5pageessayonatopicofhisorherchoiceinvolvingnuclearchemistrythatrequiresgoingbeyondthetextbookintermsofinformationpresented.Labs&Activities LearningObjectivesand

SciencePracticesCalorimetry:HeatCapacityofaSolid[CR5B]

LO5.6SP2.2,4.3

Calorimetry:HeatofReaction.Toconductaclass-designedexperimentthatwilldemonstratethemeasurementofheattransferfromonesubstancetoanother.[CR5B][CR6]

LO5.7SP2.2,3.1,4.2,4.3,5.1,5.2,5.3,6.1,6.2,7.2

Utilizingsimulateddata,studentsanalyzedataandgraphthetemperatureofanunknownasitcools,givingthemtheabilitytocalculatetheenergyreleased.[CR3e]

LO5.7SP1.1,1.4,2.2

Unit4:AtomicStructure TestsAssigned:1Chapters:7TimeRequirement:1½WeeksTopicsCovered: CurriculumFrameworkArticulation:Evidencefortheatomictheory SP6.1,6.2,6.3,6.5ElectromagneticRadiation/DualNatureofLight (1.C.2.e,1.D.3.a,5.E.4.b)BohrModeloftheHydrogenAtom/AtomicSpectra (1.B.1.d,1.B.1.e,1.D.3.b)QuantumMechanics/Quantumnumbers (1.C.2.b,1.C.2.c,1.C.2.d)Electronconfigurations (1.B.2.a,1.B.2.c)PeriodicTable/PeriodicTrends (1.B.1.b,1.B.1.c,1.B.2.b,1.B.2.d,1.C.1.c,1.D.1.b,

2.C.1.a,2.C.1.b)Thestudentwill:1.DiscusstheBohrmodeloftheatomandcompareittothequantummechanicalmodeloftheatom.2.Calculatetheenergyinvolvedinelectrontransitions.3.Writethecompletesetofquantumnumbersfortheelectronsinanatom.4.Defineandapplythefollowingtermsorconcepts:Heisenberguncertaintyprinciple,Pauliexclusionprinciple,wave-particledualityofmatter,orbitals,aufbauprinciple,andHund’srule.5.Drawandnamethes,p,anddorbitals.6.Makepredictionsbasedontheperiodiclawwithrespecttoatomicradius,ionizationenery,electronaffinity,andelectronegativity.7.Accountforthetrendsintheperiodicproperties.Labs&Activities LearningObjectivesand

SciencePracticesEnergyLevelsintheHydrogenAtom/HydrogenEmissionSpectrum

LO1.15SP5.1,6.1,6.3,6.5

ElectronArrangements:Studentswillmodelelectronconfigurations,orbitaldiagrams,andelectron-dotdiagrams.

LO1.10SP5.1,6.2

PeriodicityandthePredictionofProperties.Studentswillstudysolubilityandoxidizingstrengthtoevaluateperiodicproperties.[CR5B]

LO1.10SP3.2,3.3,5.1,5.3,6.1,6.2,6.4

Unit5:BondingandMolecularStructure TestsAssigned:1Chapters:8and9TimeRequirement:3½WeeksTopicsCovered: CurriculumFrameworkArticulation:CovalentBonds/IonicBonds (2.C.1,2.C.2)Electronegativity/BondPolarity (2.C.1.e)LatticeEnergy (1.B.1.a,1.C.2.a,2.C.1.d,2.C.2.a,2.C.2.b,2.D.1.b)BondEnergy (2.C.1)LewisStructures/VSEPR/MolecularGeometry/Polarityofmolecules/ResonanceStructures/FormalCharge

(2.C.4.g,2.C.4.h,2.C.4.i)

ValenceBondTheory/hybridizationoforbitals/sigmabonds/pibonds

(2.C.4.g)

MolecularOrbitalTheory/bondingandantibondingmolecularorbitals/bondorder

(2.C.4.i)

Thestudentwill:1.Calculatethelatticeenergyforanioniccompound.2.Calculatethestandardenthalpyofformationofanioniccompoundusingthelatticeenergy.3.Useperiodictrendsofelectronegativitytopredictbondtype.4.DrawLewisstructuresforcommonatoms,ions,andmolecules.5.UseLewisstructuresandVSEPRtopredictthegeometry,bondangles,polarity,hybridization,andthenumberofsigmaandpibondsforcommonmoleculesandions.6.Drawresonancestructuresandassignformalcharges.7.Drawmolecularorbitalenergyleveldiagramsforanyfirstperiodhomonuclearorheteronucleardiatomicmolecules.Usethemolecularorbitalenergydiagramstopredictstability,bondorder,bondlength,andmagneticproperties.Labs&Activities LearningObjectivesand

SciencePracticesStudentswillmakedrawingsandmodelsofaseriesofmolecules,andfromthosedrawingspredictgeometry,hybridization,andpolarity[CR3b]

LO2.21SP1.1

MolecularBondingandStructureofCovalentCompounds(Molecularmodels)[CR5B]

LO2.29,LO2.30,LO2.31SP1.1,6.4

InterhalogenSpecies(MolecularModels) LO2.29,LO2.30,LO2.31SP1.1,6.4

BondingInquiry:Studentsexperimentallyinvestigateionicandmolecularsubstancesdeducingpropertiesoftheirbondsintheprocess.[CR5B][CR6]

LO2.1,2.17,2.19,2.20,5.1,5.10SP3.1,3.2,4.1,4.2,4.3,5,6.1,6.2,7.2

Unit6:LiquidsandSolids TestsAssigned:1Chapters:10TimeRequirement:2WeeksTopicsCovered: CurriculumFrameworkArticulation:BondingReviewandIntermolecularForces (2.A.1.a,2.A.1.b,2.A.1.d,2.B.1.a,2.B.1.b,2.B.1.c,

2.B.2.a,2.B.2.b,2.B.2.c,2.B.2.d,2.B.3.a,5.D.1)PropertiesofLiquids (2.A.1)TypesofSolids/PropertiesofSolids (2.A.1)Semiconductors (2.D.3)VaporPressure (2.A.3)ChangesofState (2.D.4)PhaseDiagrams HeatingandCoolingCurves (2.A.1.e,5.B.3.c,5.B.3.d)Thestudentwill:1.Applythekineticmoleculartheorytoliquidsandsolids.2.Discusstheintermolecularforcesandrelatethemtophysicalpropertiesofliquidsandsolids.3.Drawandlabelheatingandcoolingcurves.4.Calculatetheenergyinvolvedduringchangesofstate.5.Interpretphasediagramsandcorrectlydefinetermssuchastriplepoint,criticaltemperature,criticalpressure,normalboilingpointandnormalmeltingpoint.6.UseX-raydiffractiondatatocalculateunitcells.7.UsetheClausius-Clapyronequationtocalculatethemolarenthalpyofvaporizationorboilingpointofaliquid.Labs&Activities LearningObjectivesand

SciencePracticesVaporPressureandEnthalpyofVaporizationofWater[CR5B] LO2.3,2.12,2.13,2.16

SP2.2,2.3,4.3,5.1PenniesintoGold:Studentswillutilizetheirunderstandingofoxidation-reductionreactionsandallowstotransformthebrassalloycoatingonpennies.[CR5B][CR6]

LO3.8,2.25SP2.2,3.1,4.1,4.2,4.3,5.1,5.2,6.1,6.2

ANon-NewtonianFluid:Studentswillinvestigatethepropertiesofanon-Newtonianfluidthroughthecreationandtestingofslime.[CR5B]

LO2.16,2.19SP3.1,3.2,4.1,4.2,4.3,6.2

Unit7:Solutions TestsAssigned:1Chapters:11TimeRequirement:1½WeeksTopicsCovered: CurriculumFrameworkArticulation:Molarity/Molality/MassPercent/MoleFraction (2.A.3)Solubility/EnergiesofSolutionFormation (2.A.1.c,2.A.3.b,2.A.3.c,2.B.3.b)Raoult’sLaw (2.B.3)FreezingPointDepression/BoilingPointElevation/OsmoticPressure

Colloids (2.A.3.a,2.A.3.b,2.A.3.g)Thestudentwill:1.Definesolutionvocabulary:solute,solvent,solution,salvation,hydration,saturated,supersaturated,unsaturated,idealsolutions,nonidealsolutions,colloid,Tyndalleffect.2.Explaintheprocessofdissolving.Incorporatethepropertiesofthesoluteandsolvent,intermolecularforces,andpolarityofthesoluteandsolventintheexplanation.3.Solveproblemsinvolvingmolarity,molality,masspercent,andmolefraction.4.Usedensityincalculationstoconvertbetweenunitsofconcentration.5.Listthecolligativepropertiesandexplaintheeffectofaddingmoresoluteontheseproperties.6.DocalculationsinvolvingRaoult’slawtofindthevaporpressureandcompositionofasolutionandthevapor.7.Docalculationinvolvingfreezingpointdepression,boilingpointelevation,andosmoticpressure.Labs&Activities LearningObjectivesand

SciencePracticesBeer’sLaw.Studentswillstudythelightabsorptionofaqueouscopper(II)ionsandinvestigatehowtocalculatethemolarityofasolutiongivenanothersolutionofknownconcentration.[CR5B][CR6]

LO2.9SP1.2,1.4,2.1,2.2,3.1,3.2,4.1,4.2,4.3,5.1,5.2,6.1,6.2,7.2

PeanutBrittle[CR5B] LO3.3SP4.3,5.1,6.1

IceCream[CR5B] LO3.3SP4.3,5.1,6.1

MolecularMassbyFreezingPointDepression.Studentswillcreateaseriesofsolutionstodeterminethefreezingpointdepressionconstant,andthenusetheirresultstoinvestigatehowtocalculatethemolarmassofanunknownsolid[CR5B]

LO1.4SP2.2,3.3,4.3,5.1

Unit8:ChemicalKinetics TestsAssigned:1Chapters:12TimeRequirement:1½WeeksTopicsCovered: CurriculumFrameworkArticulation:Rateofreaction (4.A.1.a)Orderofthereaction/DifferentialRateLaw/IntegratedRateLaw

(4.A.2.a,4.A.2.b,4.A.2.c)

Factorsthataffecttherateofreaction (4.A.1.b,4.A.1.c,4.D.1,4.D.2)CollisionTheory (4.A.1.b,4.A.1.c,4.D.1,4.D.2)ActivationEnergy/ArrheniusEquation (4.B.2.,4.B.3.c)Catalysts/Inhibitors (4.D.1,4.D.2)ReactionMechanism/RateDeterminingStep (4.A.2.a,4.A.3,4.B.1,4.C.1,4.C.2,4.C.3)Thestudentwill:1.Listthefactorsthatinfluencereactionrate.2.Useexperimentaldatatodeterminetheorderwithrespecttoeachreactanttodeterminetheratelaw,andcalculatetherateconstantandtheunitsfortherateconstant.3.Graphdatatodeterminetheintegratedratelawforareaction.4.Discusshowchangingtheconditionsofareactionaffectstherateandtherateconstantofareaction.5.Calculatethehalf-lifeofareaction.6.SolveproblemsusingtheArrheniusequationtocalculatetheactivationenergy.Labs&Activities LearningObjectivesand

SciencePracticesStudentsorallypresentthesolutiontoaproblemgivenasetofdataofthechangeofconcentrationversustimetotheclass,indicatingtheorderofthereactionandtherateconstantwithappropriateunits[CR3d]

LO1.16,4.2,4.3,4.4SP2.1,2.2,3.1,3.3,5.1,6.2,6.4,6.5

ChemicalKinetics:EffectsofConcentrationandTemperature.Studentswilldeterminetheratelawofachemicalreactionaswellastheactivationenergyofachemicalreactionbyutilizingtheirknowledgeofkinetics.[CR5B][CR6]

LO4.5,4.6SP2.2,2.3,3.3,4.2,4.3,5.1,5.3,6.1,6.2

Unit9:Equilibrium TestsAssigned:1Chapters:13TimeRequirement:1WeekTopicsCovered: CurriculumFrameworkArticulation:Equilibrium (6.A.1,6.A.3.a,6.A.3.b,6.A.3.c,6.A.3.f)Equilibriumconstants/Kp/Kc/Q/LawofMassAction (6.A.3.d,6.A.3.e,6.A.4)LeChatelier’sPrinciple (6.A.3.b,6.B.1,6.B.2,6.C.3.e,6.C.3.f)Thestudentwill:1.Describethemeaningofphysicalandchemicalequilibrium.2.Writethelawofmassactionforanysystematequilibrium.3.Interpretthepositionofequilibriumfromthesizeoftheequilibriumconstant.4.UseQtodeterminethedirectionasystemwillshifttoreachequilibrium.5.Solveproblemstocalculatetheequilibriumconstantortodetermineequilibriumorstartingconcentrations.6.UseLeChatelier’sprincipletopredictthedirectionasystematequilibriumwillshifttoregainequilibrium.7.Knowthatchangingtemperature,pressure,andconcentrationofreactantsandproductswillshiftthepositionofequilibrium.8.Understandthatacatalystwillnothaveaneffectontheequilibriumortheequilibriumconstant.Labs&Activities LearningObjectivesand

SciencePracticesInanonlineinquiryactivity,studentsareabletomanipulatetheenvironmentandproducestressesthatverifythetendencyofLeChatelier’sprinciple[CR3f]

LO5.16SP1.2,1.3,1.4,3.1,3.2,6.2

EquilibriumandLeChatelier’sPrinciple.StudentswillpredictandanalyzetheeffectsofseveralstressestodourdifferentchemicalsystemstodemonstrateLeChatelier’sPrinciple.Studentswillthenapplytheirknowledgetodevelopaninquiry-basedinvestigationonadifferentsystem.[CR5B][CR6]

LO5.16,LO6.3SP3.1,3.2,4.2,4.3,5.1,5.3,6.1,6.2

Unit10:Acids,Bases,andApplicationsofAqueousEquilibria TestsAssigned:2Chapters:14and15TimeRequirement:3WeeksTopicsCovered: CurriculumFrameworkArticulation:Acid-BaseDefinitions/Arrhenius/Bronsted-Lowry/Lewis

(3.B.2,6.C.1.c,6.C.1.d,6.C.1.e)

IonizationofAcids/Ka/Relativestrengthofacids (6.C.1.h)Acid-BaseNeutralization (3.B.2)Polyproticacids (6.C.1.h)Salts/Effectsofstructureonacidstrength/acidanhydrides/LewisAcids

CommonIoneffect Buffersystems (6.C.2)Titrations (6.C.1.i,6.C.1.j,6.C.1.k,6.C.1.l,6.C.1.m)Indicators SolubilityEquilibria/Ksp (6.C.3.a,6.C.3.b)ComplexIons Thestudentwill:1.Distinguishbetweenthevarioustheoriesofacidsandbases.2.Nameandwriteformulasforacids,bases,andsalts.3.Writebalancedequationsinvolvingacids,bases,andsalts.4.Listthesixstrongacids.5.Labeltheconjugateacid-basepairsinareaction.6.Arrangeacidsandbasesinorderofincreasingacid-basestrength.7.DocalculationsinvolvingpH,pOH,Ka,Kb,Kw.8.Identifybuffersystems.9.Writeequationsforthereactionsthatoccurinbuffersystems.10.CalculatethechangesinpHwhenacidorbaseisaddedtoabuffersystem.11.CalculatethepHatvariouspointsinatitration.12.UseapHcurvetocalculatetheKa.13.UseapHmetertodetermineatitrationcurveandtheKa.14.Pickasuitableindicatorforatitration.15.Writesolubilityproductexpressionsforslightlysolubleioniccompounds.16.Solveproblemsusingorfindingthesolubilityproductconstant.Labs&Activities LearningObjectivesand

SciencePracticesStudentsconductaninvestigationintothemajorcomponentsofacidrainandwritethereactionsthatoccurbetweenthepollutantandthecompoundsnaturallypresent(i.e.water,oxygen,carbondioxide)[CR4]

LO6.15,LO6.17SP1.3,1.4,7.1,7.2

StudentswillcompleteseveraltitrationsmonitoredwithapHmeter:titrationofastrongacidwithastrongbase,titrationofaweakacidwithastrongbase,andtitrationofaweakbasewithastrongacid.[CR5B]

LO6.11,6.12,6.13,6.14,6.15,6.16,6.17SP2.2,2.3,4.3,5.1

Solubility-ProductConstant:Studentswillinvestigateequilibriabydeterminingthevalueofthesolubility-productconstantforasparinglysolublesalt.[CR5B][CR6]

LO2.2,3.7SP2.1,2.2,3,4.2,4.3,4.4,5.1,5.3,6.1,6.2

Unit11:ChemicalThermodynamics&Electrochemistry TestsAssigned:2Chapters:16and17TimeRequirement:2½WeeksTopicsCovered: CurriculumFrameworkArticulation:StateFunctions (5.C.2)LawofThermodynamics (5.A.1,5.A.2)FreeEnergy/Spontaneity/EquilibriumConstants (5.E.2.d,5.E.2.e,5.E.2.f,6.C.3.c,6.D.1.a,6.D.1.d,5.E.2.e,

5.E.5)GalvanicCells/CellPotentials (3.B.3.a,3.B.3.b,3.B.3.c,3.B.3.d,3.C.3.a,3.C.3.b,

3.C.3.c,5.E.4.a)NernstEquations,Batteries (3.C.3.d)ElectrolyticCells (3.C.3.f)Thestudentwill:1.Defineandgivetheunitsforentropy,enthalpy,andfreeenergy.2.Distinguishbetweenastatefunctionandapathfunction.3.UseHess’Lawtocalculatethechangeinenthalpyofareaction,thechangeinentropyofareaction,andthechangeinfreeenergyofareaction.4.Determinethespontaneityofareaction.5.Calculatetheequilibriumconstantfromthechangeinfreeenergy.6.Defineelectrochemicaltermssuchasredox,anode,anion,cathode,cation,oxidizingagent,reducingagent,emf,electrode,etc.7.Distinguishbetweenanelectrolyticandavoltaiccellintermsoffunction,Eo,andspontaneity.8.Labeltheanode,cathode,half-reactionsoccurringateachelectrode,directionofelectronflowanddirectionofionflowinavoltaiccell9.Calculatethevoltageforavoltaiccell.10.Predictreactionproductsforavoltaiccell.11.SolveproblemsusingtheNernst’sequation.12.Solveproblemsinvolvethecellvoltage,freeenergy,andtheequilibriumconstant.13.Usestoichiometryforcalculationsinvolvingelectrolyticcellstofindthecurrent,timeneededforareaction,andthemassormolesofproductformed.Labs&Activities LearningObjectivesand

SciencePracticesVoltaiccells:Studentsfindthereductionpotentialsofaseriesofreactionsusingmulti-metersandbuildtheirownreductionpotentialtable.DilutionswillbemadeandtheNernstequationwillalsobetested.[CR5B]

LO3.12,3.13,5.16SP1.4,2.1,2.2,4.3,5.1

Unit12:RepresentativeElements,TransitionMetals,andOrganicChemistryTestsAssigned:2Chapters:19,20,21,22TimeRequirement:2Weeks+SpringBreakTopicsCovered: CurriculumFrameworkArticulation:SurveyoftheRepresentativeElements (2.C.1)ReactionsoftheRepresentativeElements SurveyoftheTransitionMetals Propertiesofthetransitionmetals Reactionsofthetransitionmetals CoordinationCompounds/Nomenclature Alkanes/Alkenes/Alkynes/CyclicHydrocarbons/AromaticHydrocarbons

Condensed/Structuralformulasofhydrocarbons. Nomenclature. Functionalgroups. (6.C.2)Addition/Substitution/Oxidationreactionsinvolvingorganiccompounds.

Structuralisomers/Geometricisomers/Opticalisomers

(2.C.4)

Thestudentwill:1.Reviewnamingandwritingformulasforcompoundsinvolvingtherepresentativeelementsandtransitionmetals.2.Predicttheproductsofreactionsinvolvingtherepresentativeelementsandtransitionmetals.3.ReviewLewisStructuresandperiodicpropertieswithrespecttotherepresentativeelements.4.Learnthechemicalpropertiesoftherepresentativeelementsandthetransitionmetals.5.Namecoordinationcomplexes.6.Drawstructuralformulasfororganiccompounds.7.NameorganiccompoundsusingtheIUPACsystem.8.Drawandnameisomersfororganiccompounds.9.Classify,drawandnameorganiccompoundscontainingfunctionalgroups.10.Writeaddition,substitution,andoxidationreactionsinvolvingorganiccompounds.Labs&Activities LearningObjectivesand

SciencePracticesPreparationofEsters LO3.5,LO3.6

SP3.3,4.3,6.1PreparationofaPolymer LO3.5,LO3.6

SP3.3,4.3,6.1NylonRope.Studentswillusetheirunderstandingofthepreparationofpolymerstocreatea‘nylonrope’andinvestigateitsproperties.[CR5B][CR6]

LO1.1SP3.3,4.2,4.3,6.1