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    GREEN-MAC-LCCPA Tool for Assessing the Life Cycle Energy &

    Greenhouse Gas Emissions of Alternative Refrigerants

    Stella Papasavva, William R. HillGeneral Motors, R&D Center & HVAC Product Development

    For Presentation at the

    USEPA Mobile Air Conditioning Climate Protection Partnership

    December 9, 2008

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    OUTLINE Background

    GREEN-MAC-LCCP ModelRefrigerant System Assumptions

    Vehicle Assumptions

    Climate-Drive Assumptions

    Environmental Assumptions

    Globally Weighted LCCP Calculations

    Alternative Refrigerant s Global Fleet Results

    Conclusions

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    The European Union (EU) Directive 2006/40/EC (1) prohibitsrefrigerants with Global Warming Potentials (GWP) greater than150, starting from 2011

    Current automotive refrigerant HFC-134a (GWP = 1,430) will bebanned

    in all new type vehicle models sold in the EU starting January 1st,2011 in all new vehicles sold in the EU after January 1st, 2017

    The EU Directive is focused only on the Direct Climate Impact ofrefrigerant emissions

    The more significant Indirect Climate Impactof fuel use forvehicle air conditioning needs to be accounted for as well

    The greatest environmental benefit can be realized when asystems Life Cycle Analysis (LCA) approach guides voluntary

    and regulatory action

    BACKGROUND

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    Common Alternative Refrigerants

    Refrigerant 1234yfGWP=4

    CC

    C

    CO O

    R-744GWP=1

    F

    F

    F

    F

    H

    HC C

    R-134aGWP=1,430

    H

    F

    F

    H

    H

    H

    C C

    Leakage

    Rates

    Efficiency

    [COP]

    Capacity

    Energy toManufacture

    R-152aGWP=122

    Baseline

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    CO 2 CO 2CO 2

    TransportationMine

    Life Cycle Climate Performance (LCCP) of Refrigerants

    CO 2

    CO 2

    Refrigerant

    MANUFACTURING

    Transportation

    Indirect Emissions

    End-use of chemicals

    Direct Emissions

    CO2

    Recycling

    CO2

    Breakdown

    CO2

    HFC

    Atmospheric degradation products

    +

    HCOFCOF

    2

    HFTFA

    Alt. Refrigs

    Refrigerant

    USE

    RefrigerantEnd-of-Life

    Raw Materials

    Alt. Refrigs

    Alt. Refrigs

    Non-HFC

    or

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    50 world experts have agreed an LCCP Model:Experts from Industry, Governmental and Non-GovernmentalOrganizations, National Laboratories, and Academia

    Transparent assumptions, calculations, and results

    Globally peer reviewed and accepted worldwide as themost credible method of comparing the Life Cycle GHGemissions of alternative refrigerants

    Hosted on the US EPAs website:http://www.epa.gov/cppd/mac/

    An SAE standard, SAE J2766 has been balloted andapproved

    GREEN-MAC-LCCPPath-braking Work

    http://www.epa.gov/cppd/mac/http://www.epa.gov/cppd/mac/
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    Vancouver 33%Toronto 33%Montreal 33%

    New Delhi 33%Bombay 33%Bangalore 33%

    Beijing 50%Shanghai 50%

    101419

    15

    27

    17

    25

    18

    3126

    49

    40

    23

    50

    1726

    42

    40

    25

    21

    41

    32

    23

    19

    26

    19

    38

    18

    52

    33

    2024

    37

    28

    50

    30DC3225

    23

    26

    6941

    57

    2129

    58 43

    43

    6

    F

    DC

    Code for A/C& Dehumidification

    Fargo, NDChicago, IlBoston, MAWashington DC

    Houston, TXMiami, FL

    Assigned Climate

    Los Angeles

    Phoenix, AZ

    GREEN-MAC-LCCP -V361-City World Model ONE CAR & VEHICLE FLEETS

    http://images.google.com/imgres?imgurl=http://euobserver.com/onm/media/file3/56gJcr.png&imgrefurl=http://euobserver.com/9/26841&h=307&w=230&sz=129&hl=en&start=321&um=1&usg=__nQonYxqS7gXo9LkxoZCubaw8NSk=&tbnid=I06o4O1ak6n0XM:&tbnh=117&tbnw=88&prev=/images?q=images+car+fleets&start=320&ndsp=20&um=1&hl=en&sa=N
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    GREEN-MAC-LCCPVehicle Registrations

    The Vehicle Registrations presented here do not include SUVs & Trucks

    Total Midsize Vehicle Registrations in World Regions for 2008 & 2017

    0

    50

    100

    150

    200

    250

    300

    350

    North

    America

    South &

    Central

    America

    Europe Japan India China Other

    World

    Veh

    icleReg

    istatio

    n(millions

    )

    2008

    2017

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    Direct Emissions Indirect Emissions

    Regular Emissions Energy Consumption of ACSystem and Engine Cooling Fan

    Irregular Emissions Energy Consumption to MakeComponents

    Service Emissions Energy Consumption to MakeRefrigerant

    End-of-Life Emissions Energy to Transport EachComponent

    Leakage from Refrigerant Productionand Transportation

    Energy for the End-of-LifeRecycling and Recovery

    GREEN-MAC-LCCPModel Framework

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    Vehicle Assumptions Car Size

    Compact [current] Midsize [current] SUV [current]

    Engine type L4 [current] V6 [current] V8 [current]

    Refrigerant System Assumptions: Leakages System Mass Temperature at Evaporator Outlet COP, Qe (from Bench or Vehicle tests) Condenser/Gas Cooler Air Inlet air at idle

    conditions

    Front End Air Flow Engine Cooling Fan

    Vehicle Usage & Climate Assumptions: Distance based on region % Drive Time in Ambient during 6AM - 24PM

    Different for Each City

    Cabin Comfort -% Time with A/C ON Driving cycle based on region

    Environmental Assumptions: CO2-eq from refrigerant production Transportation, End-of-Life and By-

    Product Emissions

    Ambient Temperature Operation Humidity effects

    Model

    GREEN-MAC-LCCPModel Input Assumptions

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    GREEN-MAC-LCCP -V3MAC Material Input - Example

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    GREEN-MAC-LCCP - V3Data Input Examples Climate & Driving

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    Temperature Variation per World Region

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    U.SAvg

    .

    Cana

    da

    S.Amer

    ica

    EUAvg

    .

    JapanA

    vg.

    IndiaA

    vg.

    ChinaA

    vg.

    Othe

    rWorld

    %T

    ime

    Spen

    tinTempera

    ture

    Ranges

    =38

    GREEN-MAC-LCCPClimate Conditions

    Relative Humidity for Various Temperature Bins in Each World Region

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    U.S Avg. Canada South

    America

    EU Avg. Japan

    Avg.

    India Avg. China

    Avg.

    Other

    World

    %

    RelativeHumidityperTem

    peratureBin

    3-1112-20

    21-29

    30-37

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    GREEN-MAC-LCCPComparison of Drive Cycles

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    US-

    BigCity

    US Avg. Japan EU &

    China

    India%T

    imeofAverageS

    peed

    10

    25

    65

    80

    >80

    Cabin Confort in Terms of % A/C ON Time

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    100%

    U.S Canada SouthAmerica

    EU Japan India China OtherWorld

    %A

    /CONTimeduringAnnualDriving

    =38

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    GREEN-MAC-LCCPData Input Examples

    Leakage Rates N. America Canada S. America

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    GREEN-MAC-LCCPLeak Rate Temp. dependence

    Ref: Denis Clodic, Mines ParisTech - ARMINES

    Dependence of Average Annual Temperature to Refrigerant Leaks

    0

    2

    4

    6

    8

    10

    12

    14

    16

    U.S Canada SouthAmerica

    EU Japan India China OtherWorld

    RefrigerantRegula

    rLeakage[g/y]

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    GREEN-MAC-LCCPData Plot for Small Car Fleet

    The results assume the use R134a for Vehicles in the Fleet prior to 2011 and

    All New Vehicles Produced after 2011 have the New Refrigerant

    2017 Global CO2-Eq by Region - Car Fleets

    0

    50

    100

    150

    200

    250

    300

    350

    Africa &

    M.East

    Asia E.Europe N. America S. & C.

    America

    W.Europe World

    CO

    2-Eq

    (MM

    T)

    Baseline R-134a HFC-1234yf R-744

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    GREEN-MAC-LCCP"Plot of data assuming entire fleet of vehicles has specified refrigerant in 2017"

    2017 Global CO2-Eq by Region - Car Fleets

    0

    50

    100

    150

    200

    250

    300

    350

    Africa &

    M.East

    Asia E.Europe N. America S. & C.

    America

    W.Europe World

    CO

    2-Eq

    (MMT

    )

    Baseline R-134a HFC-1234yf R-744

    AssumingAllVehicles Registered in 2017 have the New Refrigerant

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    GREEN-MAC-LCCPData Plot for Midsize Car Fleet

    The results assume the use R134a for Vehicles in the Fleet prior to 2011 and

    All New Vehicles Produced after 2011 have the New Refrigerant

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    CO2-eq Emissions for Global Fleets using R-134a in YEAR 2017

    0

    50

    100

    150

    200

    250

    300

    Africa &

    Middle East

    Asia EU North

    America

    S. & Central

    America

    Other World World

    LC

    CPCO2-Eq.Emissions(MMT

    )% Contribution of Regional CO2-eq.

    Emissions during A/C Operation

    17%

    1%

    7%

    10%

    10%

    19%

    11%

    23%

    U.S

    Canada

    SouthAmericaEU

    Japan

    India

    China

    OtherWorld

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    R-134a Components of Lifetime CO2 Emissions

    0

    2,000

    4,000

    6,000

    8,000

    10,000

    12,000

    14,000

    16,000

    18,000

    Pho

    enix

    Hou

    ston

    Bos

    ton

    Chi

    cago

    Farg

    o

    WD

    C

    LosA

    ngel

    es

    Mia

    mi

    Mon

    treal

    Toro

    nto

    Van

    couv

    er

    Mexic

    oC

    ity

    Bue

    nosA

    ires

    Rio

    deJa

    neiro

    C.Am

    eric

    a

    C.A

    M.O

    ther

    S.A

    M.O

    ther

    Car

    acas

    Hel

    sinki

    Mos

    cow

    Sto

    ckho

    lmO

    slo

    Cop

    enha

    gen

    Pra

    gue

    War

    saw

    Lju

    blja

    na

    E.E

    U.O

    ther

    Dublin

    Am

    sterda

    m

    Vie

    nna

    Fran

    kfurt

    Bru

    ssel

    s

    Ank

    ara

    Lond

    on

    Deb

    rece

    n

    Gen

    eva

    Bra

    tisla

    va

    Bucha

    rest

    Paris

    Por

    to

    Mad

    rid

    Rom

    e

    Ath

    ens

    Jeru

    sale

    m

    M.E

    .Oth

    er

    Toky

    o

    Kag

    oshi

    ma

    Sap

    poro

    Ban

    galo

    re

    Bom

    bay

    New

    Delhi

    Syd

    ney

    Beijin

    g

    Sha

    ngha

    i

    Kw

    angj

    u

    Tehr

    an

    Taip

    ei

    Kuala

    Lum

    pur

    Ban

    gkok

    Asi

    aO

    ther

    Joha

    nnesbu

    rg

    LCCPLifetimeCO

    2-eq.emissions(kg

    )

    Indirect Emissions due to A/C

    Vehicle OperationRefrigerant Emissions Due to

    LeakageA/C Mass Transportation

    Recover/Recycle/Recharge

    RefrigerantTotal EOL

    Component Mfg

    Atmospheric Degradation

    0

    500

    1,000

    1,500

    2,000

    2,500

    3,000

    3,500

    4,000

    4,500

    WDC Phoenix

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    Refrigerant R-1234yf Components of Lifetime CO2 Emissions

    0

    2,000

    4,000

    6,000

    8,000

    10,000

    12,000

    14,000

    16,000

    18,000

    20,000

    Pho

    enix

    Hou

    ston

    Bos

    ton

    Chi

    cago

    Far

    go

    WD

    C

    LosA

    ngel

    es

    Mia

    mi

    Mon

    treal

    Tor

    onto

    Van

    couv

    er

    Mexic

    oC

    ity

    Bue

    nosAire

    s

    Rio

    deJa

    neiro

    C.Am

    eric

    a

    C.A

    M.O

    ther

    S.A

    M.O

    ther

    Car

    acas

    Hel

    sinki

    Mos

    cow

    Sto

    ckho

    lmO

    slo

    Cop

    enha

    gen

    Pra

    gue

    War

    saw

    Lju

    blja

    na

    E.E

    U.O

    ther

    Dublin

    Am

    ster

    dam

    Vie

    nna

    Fra

    nkfu

    rt

    Bru

    ssel

    s

    Ank

    ara

    Lond

    on

    Deb

    rece

    n

    Gen

    eva

    Bratis

    lava

    Bucha

    rest

    Paris

    Porto

    Mad

    rid

    Rom

    e

    Ath

    ens

    Jeru

    sale

    m

    M.E

    .Oth

    er

    Tok

    yo

    Kag

    oshi

    ma

    Sap

    poro

    Ban

    galo

    re

    Bom

    bay

    New

    Delhi

    Syd

    ney

    Beijin

    g

    Sha

    ngha

    i

    Kw

    angj

    u

    Teh

    ran

    Tai

    pei

    Kuala

    Lum

    pur

    Ban

    gkok

    Asi

    aO

    ther

    Joha

    nnesbu

    rg

    LCCPLife

    time

    CO

    2-eq.

    em

    iss

    ions

    (kg

    )

    Indirect Emissions due to A/C Vehicle

    OperationRefrigerant Emissions Due to Leakage

    A/C Mass Transportation

    Recover/Recycle/Recharge Refrigerant

    Total EOL

    Component Mfg

    Atmospheric Degradation

    0

    500

    1,000

    1,500

    2,000

    2,500

    3,000

    3,500

    4,000

    WDC Phoenix

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    GREEN-MAC-LCCPModel has been peer reviewed andaccepted as a global standard by more than 50 expertsrepresented by 25 companies & other organizations

    GREEN-MAC-LCCPModel will continue to be the

    trusted method to guide refrigerant choice worldwide andto reward systems and companies achieving the highestenvironmental performance

    Model accurately compares refrigerants under the same

    boundary conditions

    No other model has been offered freely

    CONCLUSIONS

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    The new Alternative Refrigerant HFO-1234yf has lower LCCP in all world

    regions.

    Results for both Small and Midsize Car provide same conclusions

    HFO-1234yf reduces LCCP GHG emissions in both type of vehicles

    R-744 with TXV shows equal performance to baseline HFC-134a for smallcars and slight increase in GHG emissions for Midsize cars, equippedwith OTB

    R-744 performs better than R-134a in cooler/mild climates. Large cars inmild climates can use R-744 where cost is no object

    CONCLUSIONS