msds k-othrine 20 ew

7/21/2019 MSDS K-othrine 20 EW

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Bayer CropScienceMATERIAL SAFETY DATA SHEET

K-OTHRINE EW20 12X1L BOT IDVersion 3/ EU Revision Date: 06.01.2011102000011794 Print Date: 15.01.2011

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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING

Product informationTrade name : AQUA K-OTHRINE EW20 12X1L BOT IDProduct code : (UVP) 06477399Usage : InsecticideCompany : Bayer CropScience AG

Alfred-Nobel-Strae 5040789 Monheim am RheinGermany

Telephone : +49(0)2173-38-3373Telefax : +49(0)2173-38-7394

Responsible Department : Material and Transport Safety Management+49(0)2173-38-3409/4566

Email : [email protected] telephone number : +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)

2. HAZARDS IDENTIFICATIONRisk advice to man and the environmentHarmful if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Harmful: may cause lung damage if swallowed.Repeated exposure may cause skin dryness or cracking.

3. COMPOSITION/INFORMATION ON INGREDIENTSChemical natureEmulsion, oil in water (EW) : Deltamethrin 20 g/l

Hazardous components

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURESGeneral adviceRemove contaminated clothing immediately and dispose of safely.

InhalationMove to fresh air. Keep patient warm and at rest. If symptoms persist, call a physician.


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Skin contactIn case of skin contact, immediately wash with plenty of water and soap for at least 15 minutes. After skincontact: Apply Vitamin E cream or a simple body milk. If symptoms persist, call a physician.

Eye contactRinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contactlenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritationdevelops and persists.

IngestionRinse out mouth and give water in small sips to drink. Do NOT induce vomiting. Risk of product enteringthe lungs on vomiting after ingestion. If swallowed, seek medical advice immediately and show thiscontainer or label.

Notes to PhysicianSymptomsLocal:, skin and eye paraesthesia which may be severe, Usually transient with resolution within 24 hours.,eye and mucous membrane irritation, cough

SymptomsSystemic:, discomfort in the chest, tachycardia, hypotension, nausea, Abdominal pain, Diarrhoea,Vomiting, dizziness, blurred vision, headache, anorexia, somnolence, Coma, Convulsions, Tremors,prostration

RisksThis product contains a pyrethroid. Must NOT be confused with organophosphorus compounds!

TreatmentLocal treatment:Initial treatment: symptomatic.

TreatmentSystemic treatment:Endotracheal intubation and gastric lavage, followed by administration of charcoal.Monitoring of respiratory and cardiac functions.ECG - monitoring (Electrocardiogram).Check for pulmonary oedema in event of inhalation.Keep airway clear, administer artificial respiration if necessary.Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully sedated;for children 2.5 mg i.v.

There is no specific antidote.Contraindication: atropine.Contraindication: derivatives of adrenaline.Spontaneous recovery.

5. FIRE-FIGHTING MEASURESSuitable Extinguishing MediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.


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Extinguishing media which should not be used for safety reasonsHigh volume water jet

Specific hazards during fire fightingDangerous gases are evolved in the event of a fire.

Special protective equipment for fire-fightersIn the event of fire and/or explosion do not breathe fumes.In the event of fire, wear self-contained breathing apparatus.

Further informationRemove product from areas of fire, or otherwise cool containers with water in order to avoid pressure

being built up due to heat.Whenever possible, contain fire-fighting water by diking area with sand or earth.

6. ACCIDENTAL RELEASE MEASURESPersonal PrecautionsKeep people away from and upwind of spill/leak.Avoid contact with spilled product or contaminated surfaces.When dealing with a spillage do not eat, drink or smoke.

Environmental PrecautionsDo not allow to get into surface water, drains and ground water.Methods for Cleaning Up

Keep in suitable, closed containers for disposal.Clean floors and contaminated objects with plenty of water.Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).

Additional AdviceInformation regarding safe handling, see section 7.Information regarding personal protective equipment, see section 8.Information regarding waste disposal, see section 13.Check also for any local site procedures.

7. HANDLING AND STORAGE

HandlingAdvice on safe handlingNo specific precautions required when handling unopened packs/containers; follow relevant manualhandling advice.Use only in area provided with appropriate exhaust ventilation.Advice on protection against fire and explosionKeep away from heat and sources of ignition.Vapours may form explosive mixture with air.


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StorageRequirements for storage areas and containersStore in a place accessible by authorized persons only.Keep away from direct sunlight.Keep containers tightly closed in a dry, cool and well-ventilated place.Protect from freezing.Advice on common storageKeep away from food, drink and animal feedingstuffs.Suitable materialsCoextruded containers with an internal barrier layer made of ethylene vinyl alcohol copolymer (EVOH)Coextruded containers with an internal barrier layer made of polyamide (PA)Fluorinated HDPE (high density polyethylene) container

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONComponents with workplace control parameters

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"Additional Advice

Observe: Exposure Limits In Air, Group 3: 100 mg/m/ 20 ppm. (aromatic-rich hydrocarbonmixes with > 25% aromatics TRGS 901, No. 72).

Personal protective equipment

In normal use and handling conditions please refer to the label and/or leaflet. In all other cases thefollowing recommendations would apply.

Respiratory Protection No personal respiratory protective equipment normally required.Respiratory protection should only be used to control residual risk ofshort duration activities, when all reasonably practicable steps have beentaken to reduce exposure at source e.g. containment and/or local extractventilation. Always follow respirator manufacturer's instructions regardingwearing and maintenance.

Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimumthickness 0,40 mm). Wash when contaminated. Dispose of whencontaminated inside, when perforated or when contamination

outside cannot be removed. Wash hands always before eating, drinking,smoking or using the toilet.

Eye Protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

Skin and body protection Wear standard coverall and type 6 suit.Wear two layers of clothing wherever possible. Polyester/cotton or cottonoveralls should be worn under chemical protection suit and should beprofessionally laundered frequently.


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Hygiene measuresWhen using, do not eat, drink or smoke.Remove soiled clothing immediately and clean thoroughly before using again.Wash hands immediately after work, if necessary take a shower.

9. PHYSICAL AND CHEMICAL PROPERTIES

AppearanceForm suspension, opaqueColour whiteOdour strong, characteristic

Safety datapH 3,5 - 5,0 at 100 % (20 C)pH 4,5 - 7,0 at 1 % (20 C)Ignition temperature > 450 C

The data refer to solvent naphtha petroleum.Upper explosion limit 7,00 %(V)

The data refer to solvent naphtha petroleum.Lower explosion limit 0,8 %(V)

The data refer to solvent naphtha petroleum.Relative vapour density 1,00

The data refer to solvent naphtha petroleum.Density approx. 1,00 g/cm at 20 CWater solubility miscible

Viscosity, dynamic 5,80 mg/lExposure time: 4 hHighest attainable concentration.When inhaled in high concentration, the solvent vapours cause anarcotic effect.


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Acute Dermal Toxicity LD50 (rat) > 5.000 mg/kg

Skin Irritation Slight irritant effect - does not require labelling. (rabbit)

Eye Irritation Slight irritant effect - does not require labelling. (rabbit)

Sensitization Non-sensitizing. (guinea pig)OECD Test Guideline 406, Buehler test

Further informationCutaneous sensations may occur, such as burning or stinging on the face and mucosae.However, these sensations cause no lesions and are of a transitory nature (max. 24 hours).

12. ECOLOGICAL INFORMATIONElimination information (persistence and degradability)Bioaccumulation Bluegill sunfish

Bioconcentration factor (BCF): 1.400The value mentioned relates to the active ingredient deltamethrin.

Ecotoxicity effectsToxicity to Fish LC50 (Cyprinus carpio (Carp)) 0,0539 mg/l

Exposure time: 96 h

Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0,00056 mg/lExposure time: 48 h

The value mentioned relates to the active ingredient deltamethrin.

Toxicity to algae EC50 (Algae) > 9,1 mg/lExposure time: 72 hThe value mentioned relates to the active ingredient deltamethrin.

Bird toxicity LD50: > 5,000 mg/kg duckLD50: > 10,000 mg/kg quail

Bee toxicity Deltamethrin found to be highly toxic in lab studies but considered lesstoxic under natural conditions

Environmental fate, Deltamethrin is not persistent in the environment. It is destroyed by soil

persistence and degradation micro-organisms and does not leave residues in the environment or buildup in the food chain..

13. DISPOSAL CONSIDERATIONSProduct

In accordance with current regulations and, if necessary, after consultation with the siteoperator and/or with the responsible authority, the product may be taken to a waste disposalsite or incineration plant.


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Contaminated packagingTriple rinse containers.Do not re-use empty containers.Not completely emptied packagings should be disposed of as hazardous waste.

Waste key for the unused product020108 agrochemical waste containing dangerous substances

14. TRANSPORT INFORMATIONADR/RID/ADNR

UN-Number 3082Labels 9

Packaging group IIIHazard no. 90Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (DELTAMETHRIN SOLUTION)IMDG

UN-Number 3082Labels 9Packaging group IIIEmS F-A , S-FMarine pollutant Marine pollutantDescription of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (DELTAMETHRIN SOLUTION)

IATAUN-Number 3082Labels 9Packaging group IIIDescription of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (DELTAMETHRIN SOLUTION )

15. REGULATORY INFORMATIONClassification and labelling in accordance with the EC Directive on dangerouspreparations 1999/45/EC as amended.

Classification:Hazard warning labelling compulsory

Hazardous components which must be listed on the label:

Deltamethrin

Solvent Naphtha (petroleum), heavy aromatic

Symbol(s)Xn HarmfulN Dangerous for the environment


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R-phrase(s)R22 Harmful if swallowed.R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R65 Harmful: may cause lung damage if swallowed.R66 Repeated exposure may cause skin dryness or cracking.

S-phrase(s)S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.S62 If swallowed, do not induce vomiting: seek medical advice immediately andshow this container or label.

Exceptional labellingTo avoid risks to man and the environment, comply with the instructions for use.

Further informationWHO-classification: III (Slightly hazardous)

16. OTHER INFORMATIONFurther information

Text of R-phrases mentioned in Section 3R23/25 Toxic by inhalation and if swallowed.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

R65 Harmful: may cause lung damage if swallowed.R66 Repeated exposure may cause skin dryness or cracking.

The information given in this Data Sheet has been included in accordance with the guidelines establishedby Regulation (EC) 1907/2006. This data sheet complements the user's instructions, but does not replacethem. The information it contains is based on the knowledge available about the product concerned at thetime it was compiled. Users are further reminded of the possible risks of using a product for purposesother than those for which it was intended. The required information complies with current EEC legislation.Addressees are requested to observe any additional national requirements.

Changes since the last version are highlighted in the margin. This version replaces all previousversions.

msds k-othrine 20 ew

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