PROCEEDII\GS OF THE l0th INTERI{ATIOI\ALCONGRESS ON CATALYSIS. PART A

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EDITED bv L. GtjC ZI , F. SOLYMOSI, P. rÉrÉruvt

NEW FRONTI ERSIN CATALYSISProceedings of the 1Oth lnternat ional Congress

' on Catalys is ,Budapest, 19-24 July, 1992

. PART A

, Éditors

L . GUCZIlnstitute of lsotopes of the Hungarian Academy of SciencesP. O. Box 77, H-l525 Budapest, Hungary

F . SOLYMOSIlnstitute of Solid State and Radiochemistry, József Attila UniversityP. O. Box 168, H-6701 Szeged, Hungary

P. TÉTÉNYIlnstitute of lsotopes of the Hungarian Academy of SciencesP. O. Box 77, H-1525 Budapest. Hungary

AKADÉnnlnt KIADT, BUDAPEST 1993

.:i::::.:i

This book ís publ ished as Vo|ume 75 in the Elsevier ser iesStudies in Surface Science and Catalysis

Jo in t ed i t ion by

Elsevier Science Publ ishers, Amsterdam, The Nether landsand

Akadémiai Kiadó, Budapest, Hungary

ISBN 963 05 6489 0 (Series)ISBN 963 05 6490 4 (Part A)

O 1993 Elsevier Science Publishers B. V.

Al l r ights reserved.

Printed in Hungary

PREFACE

The Tenth International Congress on Catalysis was held in Hungary, Budapest,

July 19-24, 1992 under the auspices of the Council of the Congress on Catalysis, theHungarian Academy of Sciences, the Chemical Society of Hungary and theInternational Union of Pure and Applied Chemistry. Z. G. Szabó was the HonoraryChairman and P. Tétényi and F. Nagy served as the Chairman and Co-Chairman,respectively. The organizing Committee included L. Guczi (Chair)' A. Sárlc{ny(Secretary) M. Bartók, P. Fejes, Gy. Gáti' D. Kalló' J. Margitfalvi, L. Markó, Z.Paá|, J.Petró and F. Solymosi.

More than 1000 delegates (including local organizers) attended the Congress whichwas headquartered in the Budapest Convention Centre located in the pleasant hills ofthe Buda part of the Hungarian capital. As has been the tradition in previousCongresses, this Congress \üas divided into two parallel sessions with 105 oralpresentations and two further sessions in which 360 posters were displayed. All thesepresentations and posters were chosen by the Paper Selection Committee from theapproximately 800 abstracts that were submitted. The theme of the Congress was "NewFrontiers in Catalysis". Judging from the lively discussions (on the average 9 per oralpresentation) this theme was of considerable interest to the participants. Both thepapers selected for oral presentation (together with discussions) and those in the postersessions are contained in these Proceedings.

We are grateful to the outstanding scientists who accepted our invitation to presentthe 6 plenary lectures that introduced the various topics covered in the Congress.

Generous financial contributions from the Council of the European Communitiesand many institutions and corporations made it possible for about 80 scientists fromCentral and Eastern Europe, the EC countries, China, USA and India to participate inthe Congress. Several students were also able to attend because they were allowed topay a reduced registration fee.

Social events including receptions, a Congress banquet, a concert, sightseeing toursand excursions were organized to make the stay of our foreign guests more enjoyable.

The organizers are deeply indebted to the scíentists from 42 countries whoaccepted our invitation to come to Hungary and make the Congress yet anotheroutstanding success in the 40 year tradition of such events. We hope you enjoyed themeeting and will find these Proceedings a valuable addition to your catalysis library.Our best wishes go to the Organizers of the Eleventh International Congress onCatalysis which will be held during July 1996 in Baltimore, Maryland in the UnitedStates.

Budapest, December 1992The Editors

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CONTENTS

PART APrefaceCatatys i i : 'pait , pr lseni and but" i" ' 'J. A. RaboInterfacial C-oordination Chemistry: Concepts and Relevance to

ICatalysis

PhenomenaM. Che 3lN.* Catatyiic A'p".i'. ;f H;";óolyácids uno n"tut"á co'pouna. - To theMolecular Design of Practical CatalystsM. Misono 09The Catalytic Conversion of Mcthanc to Oxygenates and Higher HydrocarbonsJ .H . Luns f o rd . . 103New Reactions in Various Fields and Production of Specialty ChemicalsW.F. Hölderich . 127

Structure-Function Rclationships in Heterogeneous Catalysis: The EmbcddedSurface Molccule Approach and its ApplicationsP. Johnston and R. W. Joyner 165Isotopic Tracer Studies of Chain Propagation and Termination during Fischer-Tropsch Synthcsis over Ru/TiO2K. R. Krishna and A. T. Bell t 8'tLiquid Phase Oxidation of Glyoxal to Glyoxylic Acid by Air on Platinum CatalystsP. Gallezot, F. Fache, R. de Mesanstourne, Y. Christidis, G. Mattioda andA. Schouteeten 195Thc Effect of Oxygen Binding Energy on the Se lective Oxidation of Butane overV/y-AlzOtP. J. Andersen and H. H. Kung 205Secondary Oxygen Exchange Reactions during the Partial Oxidation of MethaneM. M. Kctrannc, J. G. Goodwin, Jr. and G. Marcelin . . . z1gRole of Frce Radicals in Heterogencous Complete Oxidation of Organic Compoundsover IV Period Transition Metal OxidesZ. R. Ismagilov, S. l,{. Pab L. G. Krishtopa and V. K Yermolaev . . 231iH Broad-Line NMR at 4 K for Studying the Acidity of Solids: Application toZeolitesP. Batanruck C. Dorcmieux-Morin andJ. Fraissard 243Preparation of Bifunctional Catalysts by Solid-State Ion Exchange in Zeolites andCatalytic TestsH. G. Karge, Y. Zhang and H.K. Beyer ZS7Transition MetallZeolite Catalysts by Design: Nucleation and Growth of Mono- andBimetall ic Particles in Zeolite YW. M. H. Sachtler, Z. Zhang, A. Yu. Stakheev andJ. S. FeeleyPromotion of H-ZSM-5 bv AluminaJ. VöIter, H. D. Lanh, B. Parlitz, E. Schreier and K Ulbricht , . .The Effect of Preparation Method on Metal-Support lnteraction in PdlL-ZeoliteCatalystsG. Larsen and G. L. HallerOn the Nature of Superactive Centers in H-FeZSM-5 Trnlites. Quantum-ChemicalCalculationsM. J. Filatov, A. G. Pelntenschikov and G. M. Zhidomirov . .

271

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XXIX

CO2 Hydrogenation over Platinum Group Metals Supported on CeO2: Evidence for aTransient Metal-Support InteractionA. Trovarelli, G. Dolcetti, C. de Leitenburg andJ. Kaspar 2781Potassium Promotion of Cu-ZnO-Al2O3 Catalysts for Higher Alcohol SynthesisI. Boz, D. ChadwicN I. S. Metcalfe and K. Zheng 27BsConversion of Syngas to Aromatic Hydrocarbons on Cobalt-Manganese-Zr,oliteCatalvstsG. Báurle, K. Guse, M. Lohrengel and H. Papp 2789Light Olefins Formation from Syngas over ZrO2-ZnO CatalystsW. Zhang, R. Gao, G. Sn andY.Yin . . z7g3High Selectivity of Diesel Fraction in Fischer-Tropsch Synthesis with CoA.{bzOsA. Fryúnan, R. R. Soares and M. Schmal 2797The Catalytic Behavior of Some Zr-Ni-Co-Cu-Ru Intermetallic C-ompounds inFischer Tropsch ReactionsI. R. Harris, I. T. Caga, A. Y. Tata andJ. M. Winterbottom 2BO jX-Ray Powder Diffraction In Situ Characterisation of the (Cu, Zn, Al)-HydrotalcitePhase in Cu-ZnO-Al2O1-Catalysts Highly Active in Methanol SynthesisK. Richter, W. Kraus., d. Notző and B|Péptinski . 2805Catalyst Component Interactions in Ag-CufZnOlAlzO3 Catalyst for CarbonOxygenate SynthesisE. Kls,' G. Lomic, G. Boskovic, R. Neducin and P. PuÍanov . . 2809Cobalt Reducibility and Magnesium Promotion in Silica-Supported Fischer-TropschCatalystsI. Puskás, T. H. Fleisch, J. B. HaI| B. L. Meyers and R. T. Roginski . 28.l3Transient Response Study of the Oxidation and Hydrogenation of Carbon MonoxideAdsorbed on Pd/AlrOrG. Kadinov, S. Todörőva and A. Palazov 2817Higher Alcohol Synthesis over Functionalized Solid-Base Catalysts from Methanolas a Building BlockW. Ueda T. Ohshida, T. Kuwabara andY. Morikawa . . zBzIIn Situ lH MvtR Study of the Adsorption of Hydrogen and Formic Acid on CopperBased Methanol Synthesis CatalystsA. Bendad4 J. B. C. Cobb, B. T. Heaton andJ. A. Iggo z1zshomerisation of l-ong-Chain n-Alkanes on PtlH-7SM-22 and Pt/g-y T,eoliteCatalysts and on their Intimate MixturesJ. A. Martens, L. Uytterhoeven, P. A. Jacobs and G. F. Froment . . . ZBzgKinetics of Bimodal Grain Size Distribution of a Ni Catalyst During Hydrogenationof COM. KoIb, M. Agnelli and C. Mirodatos . . 2833Critical Point Properties of the Surface Structure During CO OxidationM. Kolb 2837Selectivitv Effects Related with Reaction Mechanism and Diffusion Limitations overDeactivati ng CatalystsK lfumbilievq S. L. Kiperman andL. Petrov 2B4l

Author index 2845