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Origins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

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Page 1: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Origins of the Theory of Superconductivity

Leon N Cooper

University of Illinois October 10, 2007

Page 2: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007
Page 3: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The Simple Facts of Superconductivity (as of 1955)

Page 4: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1911, Kammerling Onnes found that the resistance of a mercury sample disappeared suddenly below a critical temperature

Page 5: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1911, Kammerling Onnes found that the resistance of a mercury sample disappeared suddenly below a critical temperature

Page 6: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1911, Kammerling Onnes found that the resistance of a mercury sample disappeared suddenly below a critical temperature

T

RR

n

Tc

Page 7: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Soon afterwards, Onnes discovered that relatively small magnetic fields destroy superconductivity and that the critical magnetic field is a function of temperature.

Page 8: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Soon afterwards, Onnes discovered that relatively small magnetic fields destroy superconductivity and that the critical magnetic field is a function of temperature.

H

TcT

Hc

Page 9: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1933 Meissner and Ochsenfeld discovered what has come to be known as the Meissner effect: below the critical temperature, the magnetic field is expelled from the interior of the superconductor.

Page 10: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1933 Meissner and Ochsenfeld discovered what has come to be known as the Meissner effect: below the critical temperature, the magnetic field is expelled from the interior of the superconductor.

T > Tc

Page 11: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1933 Meissner and Ochsenfeld discovered what has come to be known as the Meissner effect: below the critical temperature, the magnetic field is expelled from the interior of the superconductor.

T > Tc T < T

c

Page 12: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Further, the electronic specific heat increases discontinuously at Tc and vanishes exponentially near T=0.

Page 13: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Further, the electronic specific heat increases discontinuously at Tc and vanishes exponentially near T=0.

TcT

Cv

Page 14: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Further, the electronic specific heat increases discontinuously at Tc and vanishes exponentially near T=0.

This and other evidence, indicates the existence of an energy gap in the single particle electronic energy spectrum.

TcT

Cv

Page 15: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

And it has been recently discovered that the transition temperature varies with the mass of the ionic lattice as

Page 16: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

And it has been recently discovered that the transition temperature varies with the mass of the ionic lattice as

constant M Tc=

Page 17: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

This is known as the isotope effect and indicates that the electron-phonon interaction is implicated in the transition into the superconducting state.

And it has been recently discovered that the transition temperature varies with the mass of the ionic lattice as

constant M Tc=

Page 18: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Discussing these same phenomena today we would be obligated to say that

Page 19: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Discussing these same phenomena today we would be obligated to say that

Superconductors show no d.c. resistance except in certain instances when they do.

Page 20: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Discussing these same phenomena today we would be obligated to say that

Superconductors show no d.c. resistance except in certain instances when they do.

Type I superconductors show a Meissner effect, while type II superconductors do not.

Page 21: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Discussing these same phenomena today we would be obligated to say that

Superconductors show no d.c. resistance except in certain instances when they do.

Type I superconductors show a Meissner effect, while type II superconductors do not.

Some superconductors show a specific heat curve such as the one above, while others do not.

Page 22: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Discussing these same phenomena today we would be obligated to say that

Superconductors show no d.c. resistance except in certain instances when they do.

Type I superconductors show a Meissner effect, while type II superconductors do not.

Some superconductors show a specific heat curve such as the one above, while others do not.

Some superconductors seem to have no energy gap and others show no isotope effect.

Page 23: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Yet the 1955 simple facts of superconductivity capture the great qualitative change that occurs in the transition to the superconducting state.

Page 24: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Yet the 1955 simple facts of superconductivity capture the great qualitative change that occurs in the transition to the superconducting state.

By focusing our attention on them we were able to construct a theory of superconductivity.

Page 25: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The Sommerfeld-Bloch individual particle model (refined as Landau’s Fermi liquid theory) gives a fairly good description of normal metals but no hint of superconductivity.

Page 26: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The Sommerfeld-Bloch individual particle model (refined as Landau’s Fermi liquid theory) gives a fairly good description of normal metals but no hint of superconductivity.

EF 5eV

kF108 cm−1

Page 27: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The Sommerfeld-Bloch individual particle model (refined as Landau’s Fermi liquid theory) gives a fairly good description of normal metals but no hint of superconductivity.

The normal ground state wavefunction is a filled Fermi sphere for both spin directions.

EF 5eV

kF108 cm−1

Page 28: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Superconductivity was thought to occur due to an interaction between electrons.

Page 29: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Electrons interact with each other due to the Coulomb force; this contributes an average energy of 1eV/atom.

Superconductivity was thought to occur due to an interaction between electrons.

Page 30: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Electrons interact with each other due to the Coulomb force; this contributes an average energy of 1eV/atom.

The average energy in the superconducting transition may be estimated from Tc as 10-8 eV/atom.

Superconductivity was thought to occur due to an interaction between electrons.

Page 31: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Electrons interact with each other due to the Coulomb force; this contributes an average energy of 1eV/atom.

The average energy in the superconducting transition may be estimated from Tc as 10-8 eV/atom.

Thus, the qualitative changes that occur at the transition temperature involve an energy change orders of magnitude smaller than the Coulomb energy.

Superconductivity was thought to occur due to an interaction between electrons.

Page 32: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Electrons interact with each other due to the Coulomb force; this contributes an average energy of 1eV/atom.

The average energy in the superconducting transition may be estimated from Tc as 10-8 eV/atom.

Thus, the qualitative changes that occur at the transition temperature involve an energy change orders of magnitude smaller than the Coulomb energy.

This huge energy difference contributed to the great difficulty of the problem.

Superconductivity was thought to occur due to an interaction between electrons.

Page 33: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But the Coulomb interaction is present in every metal; some of them are superconductors, and some are not, so one is led to guess that this interaction,even with its large energy, is somehow irrelevant.

Page 34: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But the Coulomb interaction is present in every metal; some of them are superconductors, and some are not, so one is led to guess that this interaction,even with its large energy, is somehow irrelevant.

After the work of Fröhlich, Bardeen and Pines the interaction that produces superconductivity was believed to arise due to phonon exchange which, under some conditions, would be an attractive interaction between electrons near the Fermi surface.

Page 35: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Normally phonons produce resistance

Page 36: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Normally phonons produce resistance

Page 37: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But the exchange of phonons can produce an interaction between electrons:

Page 38: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But the exchange of phonons can produce an interaction between electrons:

Page 39: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

This interaction is attractive in a small region near the Fermi surface and may in some cases dominate the repulsive Coulomb interaction.

Page 40: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

This interaction is attractive in a small region near the Fermi surface and may in some cases dominate the repulsive Coulomb interaction.

attractiveinteraction

region

kF

Page 41: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The density of states of one spin at the Fermi

surface, N(0)

1022 levels

eV cm3

Page 42: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

If there is an attractive interaction between electrons a very large number of these states interact with each other.

The density of states of one spin at the Fermi

surface, N(0)

1022 levels

eV cm3

Page 43: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

If there is an attractive interaction between electrons a very large number of these states interact with each other.

The system is very degenerate.

The density of states of one spin at the Fermi

surface, N(0)

1022 levels

eV cm3

Page 44: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The problem becomes how to diagonalize such a highly degenerate matrix.

Page 45: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The problem becomes how to diagonalize such a highly degenerate matrix.

Degenerate matrices have some very surprising properties.

Page 46: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The problem becomes how to diagonalize such a highly degenerate matrix.

Degenerate matrices have some very surprising properties.

Coherent superpositions of the original states, that are separated from them by a volume independent energy gap, can appear.

Page 47: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In the many electron system one can pick out highly degenerate submatrices in which a pair of electrons scatter near the Fermi surface.

Page 48: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In the many electron system one can pick out highly degenerate submatrices in which a pair of electrons scatter near the Fermi surface.

Page 49: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In the many electron system one can pick out highly degenerate submatrices in which a pair of electrons scatter near the Fermi surface.

Every such singlet spin zero-momentum pair state can scatter to every other.

Page 50: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Diagonalizing one such pair submatrix gives the surprising result

Page 51: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Diagonalizing one such pair submatrix gives the surprising result

E

2EF 2(E

F+ ω )

Page 52: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Diagonalizing one such pair submatrix gives the surprising result

A single state, which is a coherent superposition of the original states, is separated from the rest by a volume independent energy gap.

E

2EF 2(E

F+ ω )

Page 53: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Diagonalizing one such pair submatrix gives the surprising result

A single state, which is a coherent superposition of the original states, is separated from the rest by a volume independent energy gap.

E

2EF 2(E

F+ ω )

Page 54: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Allow me to show you a page from my notes of that period with the pair solutions as they first appeared to me.

Page 55: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Allow me to show you a page from my notes of that period with the pair solutions as they first appeared to me.

Page 56: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Allow me to show you a page from my notes of that period with the pair solutions as they first appeared to me.

The last crossing on the left is the coherent state.

Page 57: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Allow me to show you a page from my notes of that period with the pair solutions as they first appeared to me.

The last crossing on the left is the coherent state.

Page 58: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It is split from the continuum by a volume independent energy gap, displaying, the now well-known, essential singularity in the coupling constant.

Allow me to show you a page from my notes of that period with the pair solutions as they first appeared to me.

The last crossing on the left is the coherent state.

Page 59: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

E − 2EF= −2ω

e2

N(0)V −1

Page 60: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In the weak coupling limitthis becomes

N(0)V <<1

E − 2EF= −2ω

e2

N(0)V −1

Page 61: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In the weak coupling limitthis becomes

N(0)V <<1

E − 2EF= −2ω

e2

N(0)V −1

E − 2EF −2(ω )e

− 2N(0)V

Page 62: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The energy of a ground state composed of such “bound” pair states would be proportional to and therefore inversely proportional to the isotopic mass as expected.

(ω )2

Page 63: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In addition, the exponential factor seemed to give a natural explanation of why the transition energy into the superconducting state is so small.

The energy of a ground state composed of such “bound” pair states would be proportional to and therefore inversely proportional to the isotopic mass as expected.

(ω )2

Page 64: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

However in the actual situation the pairs overlap.

Page 65: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

However in the actual situation the pairs overlap.

One can estimate that to pairs occupy the same volume.

106 107

Page 66: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

However in the actual situation the pairs overlap.

BCS solves this problem by introducing a wave function that satisfies the Pauli exclusion principle and that contains the many overlapping non-interacting pairs.

One can estimate that to pairs occupy the same volume.

106 107

Page 67: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The ground state wave function of the BCS superconductor is a linear superposition of states in which pairs are occupied or unoccupied. (k ↑ −k ↓)

Page 68: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The ground state wave function of the BCS superconductor is a linear superposition of states in which pairs are occupied or unoccupied. (k ↑ −k ↓)

k ↑

−k ↓

Page 69: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS ground state wave function can also be regarded as the anti-symmetrized product of single pair wave functions of the form χ↑↓(r

1− r

2)

Page 70: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS ground state wave function can also be regarded as the anti-symmetrized product of single pair wave functions of the form χ↑↓(r

1− r

2)

ψ 0= A[χ↑↓(r

1− r

2)χ↑↓(r

3− r

4)...χ↑↓(r

N−1 − rN

)]

Page 71: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS ground state wave function can also be regarded as the anti-symmetrized product of single pair wave functions of the form χ↑↓(r

1− r

2)

ψ 0= A[χ↑↓(r

1− r

2)χ↑↓(r

3− r

4)...χ↑↓(r

N−1 − rN

)]

Typically the pair function, , extends cm; this has come to be called off- diagonal long range order.

χ↑↓(r )

10−4

Page 72: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS pairing Hamiltonian is composed of a kinetic energy term and an interaction term in which any occupied pair can scatter into any available pair state.

Page 73: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS pairing Hamiltonian is composed of a kinetic energy term and an interaction term in which any occupied pair can scatter into any available pair state.

The ground state is obtained by finding the pair function that minimizes the energy of the pairing Hamiltonian.

Page 74: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The BCS pairing Hamiltonian is composed of a kinetic energy term and an interaction term in which any occupied pair can scatter into any available pair state.

The ground state is obtained by finding the pair function that minimizes the energy of the pairing Hamiltonian.

ψ 0H

pairingψ

0

Page 75: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The energy difference between the the superconducting and the normal state is

Wn−W

s= 2N(0)(ω )2

e2

N(0)V −1

Page 76: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The energy difference between the the superconducting and the normal state is

Wn−W

s= 2N(0)(ω )2

e2

N(0)V −1

In the weak coupling limit, this becomes

Wn−W

s= 2N(0)(ω )2e

−2N(0)V

Page 77: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The energy difference between the the superconducting and the normal state is

Wn−W

s= 2N(0)(ω )2

e2

N(0)V −1

In the weak coupling limit, this becomes

Wn−W

s= 2N(0)(ω )2e

−2N(0)V

The energy gap is

Δ = 2(ω )e− 1

N(0)V

Page 78: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Page 79: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Zero resistivity

Page 80: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Meissner effect

Zero resistivity

Page 81: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Meissner effect

Specific heat

Zero resistivity

Page 82: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Meissner effect

Specific heat

Isotope effect

Zero resistivity

Page 83: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

The idealized BCS theory reproduces the “simple” facts of superconductivity:

Meissner effect

Specific heat

Isotope effect

The energy gap

Zero resistivity

Page 84: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But, in addition, there are new, subtle and surprising effects.

Page 85: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

But, in addition, there are new, subtle and surprising effects.

In calculating matrix elements of interactions that involve operators such as

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But, in addition, there are new, subtle and surprising effects.

In calculating matrix elements of interactions that involve operators such as

B = B

k ′kk ′k∑ (c ′k ↑

* ck↑ ± c− ′k ↑

* c−k↑ )

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But, in addition, there are new, subtle and surprising effects.

In calculating matrix elements of interactions that involve operators such as

the initial and final states are connected in a new and unexpected way:

B = B

k ′kk ′k∑ (c ′k ↑

* ck↑ ± c− ′k ↑

* c−k↑ )

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The initial and final states are connected by .

c ′k ↑* c

k↑

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The initial and final states are connected by .

c ′k ↑* c

k↑

initial state

final state

c ′k ↑* c

k↑

k

′k

k

′k

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The initial and final states are connected by .

c ′k ↑* c

k↑

initial state

final state

c ′k ↑* c

k↑

k

′k

k

′k

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They are also connected by . c− ′k ↓

* c−k↓

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They are also connected by . c− ′k ↓

* c−k↓

initial state

final state k

′k

k

′k

c− ′k ↓

* c−k↓

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They are also connected by . c− ′k ↓

* c−k↓

initial state

final state k

′k

k

′k

c− ′k ↓

* c−k↓

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These occur in calculations of the interaction of superconductors with the electromagnetic field or with phonons:

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These occur in calculations of the interaction of superconductors with the electromagnetic field or with phonons:

Meissner effect

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These occur in calculations of the interaction of superconductors with the electromagnetic field or with phonons:

Meissner effect

Ultrasonic attenuation

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These occur in calculations of the interaction of superconductors with the electromagnetic field or with phonons:

Meissner effect

Ultrasonic attenuation

Nuclear spin relaxation

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Some of the calculations can become very complex.

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Some of the calculations can become very complex.

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The superposition of these two amplitudes results in strikingly different behavior for interactions depending on how they transform under time reversal.

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In time reversal the coordinates transform as

x → x

y → y

z → z

t → −t

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In time reversal the coordinates transform as

x → x

y → y

z → z

t → −t

while various operators transform as

j(r, t)→ − j(r,−t)

ρ(r, t)→ +ρ(r,−t)

σz(t)→ −σ

z(−t)

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Ultrasonic attenuation involves ρ

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Ultrasonic attenuation involves ρ

Nuclear spin relaxation involves σ

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Ultrasonic attenuation, as a function of temperature, falls off very rapidly across the superconducting transition.

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Ultrasonic attenuation, as a function of temperature, falls off very rapidly across the superconducting transition.

Morse and Bohm (1957)

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In contrast, the nuclear spin relaxation rate increases across the transition temperature.

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In contrast, the nuclear spin relaxation rate increases across the transition temperature.

The circles are the experimental data of Hebel and Slichter (1959), the crosses data of Redfield and Anderson (1959).

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Comparison with the BCS theory

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Comparison with the BCS theory

Data from Morse and Bohm (1957)

Ultrasonic Attenuation

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Comparison with the BCS theory

The circles are the experimental data of Hebel and Slichter (1959), the crosses data of Redfield and Anderson (1959).

Nuclear Spin Relaxation

Data from Morse and Bohm (1957)

Ultrasonic Attenuation

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“...such a striking phenomenon as superconductivity [was] ... nothing more exciting than a footling small interaction between atoms and lattice vibrations.”

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Since 1957 the situation has become richer and much more complex.

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Since 1957 the situation has become richer and much more complex.

There have been many new discoveries as well as a myriad of practical applications.

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Since 1957 the situation has become richer and much more complex.

There have been many new discoveries as well as a myriad of practical applications.

I can mention just a few:

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The BCS theory has had a profound effect on other areas of physics.

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The BCS theory has had a profound effect on other areas of physics.

Pairing in:

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The BCS theory has had a profound effect on other areas of physics.

Pairing in:

Nucleii

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The BCS theory has had a profound effect on other areas of physics.

Pairing in:

Nucleii

Neutron stars

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The BCS theory has had a profound effect on other areas of physics.

Pairing in:

Nucleii

Neutron stars

Helium 3

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The BCS theory has had a profound effect on other areas of physics.

Pairing in:

Nucleii

Neutron stars

Helium 3

Color superconductivity in dense quark matter

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Transition Between Bose Einstein and BCS Condensation

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The interaction between Fermions in Bose-Einstein condensates can be varied, using the Feshbach resonance, changing the range of the pair wave function

Transition Between Bose Einstein and BCS Condensation

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The interaction between Fermions in Bose-Einstein condensates can be varied, using the Feshbach resonance, changing the range of the pair wave function

Transition Between Bose Einstein and BCS Condensation

χ↑↓(r1− r

2)

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The interaction between Fermions in Bose-Einstein condensates can be varied, using the Feshbach resonance, changing the range of the pair wave function

so that a transition between a Bose Einstein and a BCS condensation can be seen.

Transition Between Bose Einstein and BCS Condensation

χ↑↓(r1− r

2)

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The broken symmetry displayed by the BCS pair function (the order parameter of the Ginsburg- Landau theory)

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The broken symmetry displayed by the BCS pair function (the order parameter of the Ginsburg- Landau theory)

0 ψ↓(r )ψ↑(r ) 0 ≠ 0

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The broken symmetry displayed by the BCS pair function (the order parameter of the Ginsburg- Landau theory)

is the model for the Higgs field broken symmetry of the standard model of elementary particles and fields

0 ψ↓(r )ψ↑(r ) 0 ≠ 0

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The broken symmetry displayed by the BCS pair function (the order parameter of the Ginsburg- Landau theory)

is the model for the Higgs field broken symmetry of the standard model of elementary particles and fields

0 ψ↓(r )ψ↑(r ) 0 ≠ 0

0 φ(x ) 0 ≠ 0

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Type ll Superconductors

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Type ll Superconductors

In some situations, it is energetically favorable for a magnetic field to partially penetrate a superconductor breaking it up into many superconducting and normal regions.

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Type ll Superconductors

In some situations, it is energetically favorable for a magnetic field to partially penetrate a superconductor breaking it up into many superconducting and normal regions.

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Type ll superconductors have been developed that can carry high currents as well as sustain very large magnetic fields.

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Type ll superconductors have been developed that can carry high currents as well as sustain very large magnetic fields.

J

H

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Type ll superconductors have been developed that can carry high currents as well as sustain very large magnetic fields.

J

H

Some commonly used materials for both civilian and military applications are niobium-tin and niobium-titanium. Niobium-titanium is often chosen because of its superior mechanical properties. It has a critical magnetic field of 15 Tesla and a critical temperature of 10 K.

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Among the many applications:

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Magnetic Resonance Imaging

Among the many applications:

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Japanese superconducting magnetically levitated train

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Superconducting magnet used to detonate mines

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Many other military and civilian applications are either contemplated or in use:

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Many other military and civilian applications are either contemplated or in use:

High energy accelerators and detectors

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Many other military and civilian applications are either contemplated or in use:

High energy accelerators and detectors

Magnetic energy power storage

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Many other military and civilian applications are either contemplated or in use:

High energy accelerators and detectors

Magnetic energy power storage

Toroidal fusion reactors

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Many other military and civilian applications are either contemplated or in use:

High energy accelerators and detectors

Magnetic energy power storage

Toroidal fusion reactors

.

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Many other military and civilian applications are either contemplated or in use:

High energy accelerators and detectors

Magnetic energy power storage

Toroidal fusion reactors

.

.

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Superconductor Electronics

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Josephson Junctions

Superconductor Electronics

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Josephson Junctions

Superconductor Electronics

1 2

superconductors

barrier

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Superconducting Quantum Interference Devices (SQUIDS)

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Superconducting Quantum Interference Devices (SQUIDS)

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Superconducting Quantum Interference Devices (SQUIDS)

Very sensitive measurement of magnetic fields

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Numerous civilian and military applications

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Numerous civilian and military applications

Submarine detection

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Numerous civilian and military applications

Submarine detection

Oil prospecting

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Numerous civilian and military applications

Submarine detection

Oil prospecting

Precision sensors in scientific experiments

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Numerous civilian and military applications

Submarine detection

Oil prospecting

Precision sensors in scientific experiments

Gravity waves

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Numerous civilian and military applications

Submarine detection

Oil prospecting

Precision sensors in scientific experiments

Gravity waves

Tests of General Relatvity

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Numerous civilian and military applications

Submarine detection

Oil prospecting

Precision sensors in scientific experiments

Gravity waves

Tests of General Relatvity

Medical diagnostics

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SQUID Superconducting Quantum Interference Device in a medical application

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SQUID Superconducting Quantum Interference Device in a medical application

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Quantum Computing

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Quantum Computing

Single pair box

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Quantum Computing

Single pair box

barrier

superconductingelectrodes

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Quantum Computing

Single pair box

The single pair box utilizes a Josephson junction between two superconducting electrodes. Pairs can tunnel coherently through such junctions. This may serve as a qubit.

barrier

superconductingelectrodes

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High Tc Superconductors

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High Tc Superconductors

These materials can be superconducting at liquid nitrogen temperatures making possible long distance transmission of electric power as well as all of the other applications we have discussed but at higher temperatures.

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High Tc Superconductors

These materials can be superconducting at liquid nitrogen temperatures making possible long distance transmission of electric power as well as all of the other applications we have discussed but at higher temperatures.

Nuclear electric power plants in remote areas.

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High Tc Superconductors

These materials can be superconducting at liquid nitrogen temperatures making possible long distance transmission of electric power as well as all of the other applications we have discussed but at higher temperatures.

Nuclear electric power plants in remote areas.

Hydrogen economy.

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Some of these applications we could foresee but most we could not.

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In doing fundamental science, perhaps, most important is what we cannot foresee.

Some of these applications we could foresee but most we could not.

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Almost all of the technology we rely on for civilian and military use:

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Communications

Almost all of the technology we rely on for civilian and military use:

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Communications

Computers

Almost all of the technology we rely on for civilian and military use:

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Communications

Computers

Electronics

Almost all of the technology we rely on for civilian and military use:

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Communications

Computers

Electronics

Medical imaging

Almost all of the technology we rely on for civilian and military use:

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Communications

Computers

Electronics

Medical imaging

Laser surgery . . .

Almost all of the technology we rely on for civilian and military use:

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Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Almost all of the technology we rely on for civilian and military use:

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Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Maxwell,

Almost all of the technology we rely on for civilian and military use:

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Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Maxwell,

Almost all of the technology we rely on for civilian and military use:

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Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Einstein,Maxwell,

Almost all of the technology we rely on for civilian and military use:

Page 181: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Einstein, Kammerling OnnesMaxwell,

Almost all of the technology we rely on for civilian and military use:

Page 182: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Einstein,Schrödinger,

Kammerling OnnesMaxwell,

Almost all of the technology we rely on for civilian and military use:

Page 183: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Einstein,Schrödinger, Heisenberg,

Kammerling OnnesMaxwell,

Almost all of the technology we rely on for civilian and military use:

Page 184: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Communications

would be in a most primitive state, or non-existent, without the fundamental science of

Computers

Electronics

Medical imaging

Laser surgery . . .

Lorentz, Einstein,Schrödinger, Heisenberg, Dirac and many others.

Kammerling OnnesMaxwell,

Almost all of the technology we rely on for civilian and military use:

Page 185: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It is widely appreciated that these technologies have enormous economic and social impact.

Page 186: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It is widely appreciated that these technologies have enormous economic and social impact.

But their link to fundamental science is less well understood.

Page 187: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It sometimes takes a long time to go from fundamental science to the technology it makes possible.

It is widely appreciated that these technologies have enormous economic and social impact.

But their link to fundamental science is less well understood.

Page 188: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It sometimes takes a long time to go from fundamental science to the technology it makes possible.

It is widely appreciated that these technologies have enormous economic and social impact.

In addition....

But their link to fundamental science is less well understood.

Page 189: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

It is almost impossible to predict what technologies will flow from fundamental science.

Page 190: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Maxwell, Lorentz, Einstein(Electromagnetic Theory)

It is almost impossible to predict what technologies will flow from fundamental science.

Page 191: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Maxwell, Lorentz, Einstein(Electromagnetic Theory)

Communications

It is almost impossible to predict what technologies will flow from fundamental science.

Page 192: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Kammerling Onnes(Superconductivity)

It is almost impossible to predict what technologies will flow from fundamental science.

Page 193: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Kammerling Onnes(Superconductivity)

Mine detonator

It is almost impossible to predict what technologies will flow from fundamental science.

Page 194: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Schrödinger, Heisenberg(Quantum Mechanics)

It is almost impossible to predict what technologies will flow from fundamental science.

Page 195: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Schrödinger, Heisenberg(Quantum Mechanics)

Transistors,Computers

It is almost impossible to predict what technologies will flow from fundamental science.

Page 196: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Townes(Millimeter Radiation)

It is almost impossible to predict what technologies will flow from fundamental science.

Page 197: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Townes(Millimeter Radiation)

Laser Surgery

It is almost impossible to predict what technologies will flow from fundamental science.

Page 198: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Bloch, Purcell(Solid-State Research)

It is almost impossible to predict what technologies will flow from fundamental science.

Page 199: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Bloch, Purcell(Solid-State Research)

MRI

It is almost impossible to predict what technologies will flow from fundamental science.

Page 200: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Premature targeted programs to obtain these technologies would have failed. Worse, resources would have been taken away from the scientists who in fact made them possible.

Page 201: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

Premature targeted programs to obtain these technologies would have failed. Worse, resources would have been taken away from the scientists who in fact made them possible.

Page 202: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1887 Edward Bellamy wrote, with a certain optimism:

Page 203: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1887 Edward Bellamy wrote, with a certain optimism:

If we could have devised an arrangement for providing everybody with music in their homes, perfect in quality, unlimited in quantity, suited to every mood, and beginning and ceasing at will,

Page 204: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007

In 1887 Edward Bellamy wrote, with a certain optimism:

If we could have devised an arrangement for providing everybody with music in their homes, perfect in quality, unlimited in quantity, suited to every mood, and beginning and ceasing at will,

we should have considered the limit of human felicity already attained, and ceased to strive for further improvements.

Page 205: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007
Page 206: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007
Page 207: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007
Page 208: Origins of the Theory of Superconductivityconferences.illinois.edu/bcs50/PDF/cooper.pdfOrigins of the Theory of Superconductivity Leon N Cooper University of Illinois October 10, 2007